CN102977754A - Polyurethane crackle paint for glass coating, and preparation method and applying method thereof - Google Patents

Polyurethane crackle paint for glass coating, and preparation method and applying method thereof Download PDF

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Publication number
CN102977754A
CN102977754A CN2011102629156A CN201110262915A CN102977754A CN 102977754 A CN102977754 A CN 102977754A CN 2011102629156 A CN2011102629156 A CN 2011102629156A CN 201110262915 A CN201110262915 A CN 201110262915A CN 102977754 A CN102977754 A CN 102977754A
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component
urethane
glass
strain indicating
indicating lacquer
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CN102977754B (en
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周琼辉
刘志刚
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Beijing Zhanchen Intelligent Property Management Co ltd
China Zhanchen New Materials Group Co.,Ltd.
Shanghai Zhanchen Paint Co ltd
Zhuhai Zhanchen New Material Co ltd
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Shanghai Fuchen Chemical Co Ltd
Beijing Zhanchen Chemical Co Ltd
Zhanchen Paint Group Co Ltd
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Abstract

The present invention discloses a polyurethane crackle paint for glass coating. The polyurethane crackle paint includes two components, wherein, on a weight basis, hydroxyl group-containing component A comprises: 32%-50% of hydroxy acrylic resin, 28% -38% of a solvent, 4%-5% of cellulose acetate butyrate, 15%-20% of fumed silica, 2%-3% of an adhesion-promoting agent, and 1%-2% of an additive; and a curing agent component B comprises: 40%-45% of hexamethylene diisocyanate biuret, and 55%-60% of a solvent. The present invention also discloses a preparation method and an applying method for the polyurethane crackle paint for glass coating. The present invention is a polyurethane crackle paint which can be dried at room temperature, and is applied on the glass surface with the supporting use of the curing agent; the product obtained after the applying has a fast drying speed at room temperature, high gloss, completely transparent crackle paint without affecting the decorative effect for the glass, and very good adhesion strength and hardness on the glass, thereby achieving purposes of excellent decoration and protection.

Description

The urethane strain indicating lacquer and preparation method thereof and the constructional method that are used for the glass application
Technical field
The present invention relates to industry and architectural decoration coating material, specifically, is urethane strain indicating lacquer and preparation method thereof and the constructional method for the glass application.
Background technology
Strain indicating lacquer has the covering with paint that decorative effect preferably is widely used in family, hotel and various materials because of it.
At present, the strain indicating lacquer that is widely known by the people is single-component, be generally nitro class or single-component acrylic type, its crackle principle is by powders such as nitro-cotton in the nitro crack lacquer and more sedimentation type silicon-dioxide or talcum powder, and rapid drying is shunk and the irregular crackle effect that forms after construction.
Although the one-pack type strain indicating lacquer has the comparative maturity of good application property and development, the single-component strain indicating lacquer is owing to contain more powder, its transparency poor and on glass, metal and other various material sticking power bad, intensity is relatively poor, has affected its application.
Summary of the invention
The object of the invention is to, be provided for urethane strain indicating lacquer and preparation method thereof and the constructional method of glass application, to overcome the existing above-mentioned shortcoming and defect of prior art.
The technical problem that will solve required for the present invention can be achieved through the following technical solutions:
As a first aspect of the present invention, be used for the urethane strain indicating lacquer of glass application, it is characterized in that, comprise the component of following weight percent:
The first component comprises the component of following weight percent:
Hydroxylated acrylic resin 32%~50%,
Solvent 28%~38%,
Cellaburate 4%~5%,
Aerosil 15~20%,
Adhesion promoter 2%~3%,
Auxiliary agent 1%~2%,
The per-cent sum of said components is 100%;
Component B comprises the component of following weight percent:
Hexamethylene diisocyanate biuret 40%~45%,
Solvent 55%~60%,
The per-cent sum of said components is 100%.
Described Hydroxylated acrylic resin is solution state, and outward appearance is the water-white transparent liquid, and technical requirements is: solid content 50~52%, hydroxy radical content 1.0 ± 0.1% can adopt the A450 of Bayer A.G.
Wherein, the solvent in the first component refers to the solvent of ammonia ester level, can adopt the N-BUTYL ACETATE of Taixing Jin Jiang.
Described cellaburate refers to cellulose acetate butyrate, and technical requirements is viscosity 0.2 second, and butyryl radicals content is 53%, can adopt the CAB551-0.2 of U.S. Yi Si Man.
Described aerosil can adopt the A380 type aerosil of German EVONIK company, and technical requirements: specific surface area is 380 ± 20m 2/ g.
Described adhesion promoter is amino silicane coupling agent, technical requirements: molecular weight 222.4, can adopt the KBM-603 of Japan XINYUE.
Described auxiliary agent is defoamer, selects polysiloxane-polyether copolymer, can adopt the BYK066 of German BYK company.
The technical requirements of the hexamethylene diisocyanate biuret in the described component B is: solid content 75 ± 2%, NCO content 16.5 ± 1% can adopt the N75 of Bayer A.G.
Wherein, the solvent in the component B refers to the solvent of ammonia ester level, can adopt the N-BUTYL ACETATE of Taixing Jin Jiang.
As a second aspect of the present invention, be used for the preparation method of the urethane strain indicating lacquer of glass application, comprise the steps:
The first component:
(1) at first N-BUTYL ACETATE is added in the cylinder, then under agitation add cellulose acetate butyrate, dissolve complete;
(2) then add Hydroxylated acrylic resin, defoamer and adhesion promoter;
(3) at last aerosil is added, with rotating speed 2500 speed of walking around, high speed dispersion 15 minutes, at last product is crossed three rollers to fineness less than 10 microns;
Component B:
The hexamethylene diisocyanate biuret is even with stirring solvent.
Wherein, the solvent in first component, the component B is the N-BUTYL ACETATE of ammonia ester level.
As a third aspect of the present invention, be used for the constructional method of the urethane strain indicating lacquer of glass application, comprise the steps:
(1) base material treatment: with solvent glass surface is cleaned up first wipe oil and impurity;
Described base material is commercially available simple glass;
(2) sprayed glass urethane white paint, with N-BUTYL ACETATE the urethane white paint being adjusted viscosity is 15 to 20 seconds, evenly sprays 4 rifles, 0.5 to 1 hour time of drying;
(3) spraying polyurethane strain indicating lacquer: first component and component B weight ratio is even by allotment in 5: 1, with N-BUTYL ACETATE viscosity is adjusted to 11 to 12 seconds again, evenly spray 2 rifles, be 8 hours time of drying, can pack.
Above viscosity is rock field-2# cup viscosity.
Beneficial effect of the present invention:
But the present invention is the urethane strain indicating lacquer of Air drying; construct behind the complete curing agent in glass surface; the decorative effect that its product has that Air drying speed is fast, high gloss, clear strain indicating lacquer are fully transparent, do not affect glass; and has fabulous adhesion strength and hardness on glass, to reach excellent decoration and the purpose of protection.
Embodiment
Below in conjunction with specific embodiment, the invention will be further described.Should be understood that following examples are only for explanation the present invention but not for limiting scope of the present invention.
The experimental technique of unreceipted actual conditions in the following example, usually according to normal condition, or the condition that manufacturer provides is carried out.
Embodiment 1
Prescription 1
The first component prescription of hydroxyl: (weight)
Hydroxylated acrylic resin 45%,
Solvent 30%,
Cellaburate 4%,
Aerosil 18%,
Adhesion promoter 2%,
Auxiliary agent (defoamer) 1%,
Solidifying agent component B prescription: (weight)
Hexamethylene diisocyanate biuret 40%,
Solvent 60%.
All the other, prescription sees table 1 for details.
Each prescription of table 1 the present invention Kg
Figure BDA0000089338600000041
Hydroxylated acrylic resin in the first component can be used the A450 of Beyer Co., Ltd.
Solvent can adopt the N-BUTYL ACETATE of gold river, Taixing ammonia ester level.
Cellaburate refers to cellulose acetate butyrate, and technical requirements is viscosity 0.2 second, can adopt the CAB551-0.2 of U.S. Yi Si Man.
Aerosil can adopt the A380 type aerosil of German EVONIK company, and technical requirements: specific surface area is 380 ± 20m 2/ g.
Adhesion promoter is amino silicane coupling agent, technical requirements: molecular weight 222.4, can adopt the KBM-603 of Japan XINYUE.
Auxiliary agent is defoamer, selects polysiloxane-polyether copolymer, can adopt the BYK066 of German BYK company.
Hexamethylene diisocyanate biuret in the component B can adopt the N75 of Bayer A.G.
Solvent in the component B can adopt the N-BUTYL ACETATE of the ammonia ester level of Taixing Jin Jiang.
The preparation method:
The first component:
(1) at first N-BUTYL ACETATE is added in the cylinder, then under agitation add cellulose acetate butyrate, dissolve complete.
(2) then add Hydroxylated acrylic resin, defoamer and adhesion promoter.
(3) at last aerosil is added, with rotating speed 2500 speed of walking around, high speed dispersion 15 minutes, at last product is crossed three rollers to fineness less than 10 microns.
Component B:
The hexamethylene diisocyanate biuret is even with stirring solvent.
Constructional method:
(1) base material treatment: with solvent glass surface is cleaned up first wipe oil and impurity;
Described base material is commercially available simple glass;
(2) sprayed glass urethane white paint, with N-BUTYL ACETATE the urethane white paint being adjusted viscosity is 15 to 20 seconds, evenly sprays 4 rifles, 0.5 to 1 hour time of drying;
(3) spraying polyurethane strain indicating lacquer: first component and component B weight ratio is even by allotment in 5: 1, with N-BUTYL ACETATE viscosity is adjusted to 11 to 12 seconds again, evenly spray 2 rifles, be 8 hours time of drying, can pack.
Above viscosity is rock field-2# cup viscosity.
Detected result is as follows:
Sticking power: 1 grade of GB 4893.4-1985
Hardness: pencil hardness 1H GB/T 6739-2006
The transparency: excellent range estimation
Gloss: 50 degree BYK-GARDNER, 60 degree angular measurement examinations.
But the present invention is the urethane strain indicating lacquer of Air drying, construct behind the complete curing agent in glass surface, its product has that Air drying speed is fast, rate of drying is fast behind the high gloss, application, can form larger and regular crackle, be easy to form the crackle effect with ornamental value, test at the crack initiation place and other places after 24 hours, sticking power is 1 grade, pencil hardness 1H, the cracking place transparency is excellent, and clear strain indicating lacquer is fully transparent, range estimation does not affect printing opacity.Do not affect the decorative effect of glass, and have fabulous adhesion strength and hardness on glass, to reach excellent decoration and the purpose of protection.
More than show and described ultimate principle of the present invention, principal character and advantage of the present invention.The technician of the industry should understand; the present invention is not restricted to the described embodiments; that describes in above-described embodiment and the specification sheets just illustrates principle of the present invention; the present invention also has various changes and modifications without departing from the spirit and scope of the present invention, and these changes and improvements all fall in the claimed scope of the invention.The claimed scope of the present invention is defined by appending claims and equivalent thereof.

Claims (10)

1. be used for the urethane strain indicating lacquer of glass application, it is characterized in that, comprise the component of following weight percent:
The first component comprises the component of following weight percent:
Hydroxylated acrylic resin 32%~50%,
Solvent 28%~38%,
Cellaburate 4%~5%,
Aerosil 15~20%,
Adhesion promoter 2%~3%,
Auxiliary agent 1%~2%,
The per-cent sum of said components is 100%;
Component B comprises the component of following weight percent:
Hexamethylene diisocyanate biuret 40%~45%,
Solvent 55%~60%,
The per-cent sum of said components is 100%.
2. urethane strain indicating lacquer according to claim 1 is characterized in that, the solid content 50~52% of described Hydroxylated acrylic resin, hydroxy radical content 1.0 ± 0.1%.
3. urethane strain indicating lacquer according to claim 1 is characterized in that, the viscosity of described cellaburate 0.2 second, and butyryl radicals content is 53%.
4. urethane strain indicating lacquer according to claim 1 is characterized in that, the specific surface area 380m of described aerosil 2/ g.
5. urethane strain indicating lacquer according to claim 1 is characterized in that, described adhesion promoter is amino silicane coupling agent, molecular weight 222.4.
6. urethane strain indicating lacquer according to claim 1 is characterized in that, described froth breaking auxiliary agent is polysiloxane-polyether copolymer.
7. urethane strain indicating lacquer according to claim 1 is characterized in that, the solid content 75 ± 2% of the hexamethylene diisocyanate biuret of described component B, NCO content 16.5 ± 1%.
8. urethane strain indicating lacquer according to claim 1 is characterized in that, the solvent in first component, the component B is the N-BUTYL ACETATE of ammonia ester level.
9. the preparation method of each described urethane strain indicating lacquer for the glass application is characterized in that according to claim 1~8, comprises the steps:
The first component:
(1) at first N-BUTYL ACETATE is added in the cylinder, then under agitation add the cellulose acetate butyrate dissolve complete;
(2) then add Hydroxylated acrylic resin, defoamer and adhesion promoter;
(3) at last aerosil is added, with rotating speed 2500 speed of walking around, high speed dispersion 15 minutes, at last product is crossed three rollers to fineness less than 10 microns;
Component B:
The hexamethylene diisocyanate biuret is even with stirring solvent.
10. the constructional method of the urethane strain indicating lacquer for the glass application as claimed in claim 9 comprises the steps:
(1) base material treatment: with solvent glass surface is cleaned up first wipe oil and impurity;
Described base material is commercially available simple glass;
(2) sprayed glass urethane white paint, with N-BUTYL ACETATE the urethane white paint being adjusted viscosity is 15 to 20 seconds, evenly sprays 4 rifles, 0.5 to 1 hour time of drying;
(3) spraying polyurethane strain indicating lacquer: first component and component B is even by weight allotment in 5: 1, with N-BUTYL ACETATE viscosity is adjusted to 11 to 12 seconds again, evenly spray 2 rifles, be 8 hours time of drying, can pack.
CN201110262915.6A 2011-09-06 2011-09-06 For urethane strain indicating lacquer and preparation method thereof and the constructional method of glass application Active CN102977754B (en)

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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104098957A (en) * 2013-04-02 2014-10-15 陈湛玲 Crackle paint for spray-coating glass and use thereof
CN105199511A (en) * 2015-09-24 2015-12-30 维新制漆(深圳)有限公司 Varnish for stainless steel substrate and preparation method and application of varnish
CN107163746A (en) * 2017-07-26 2017-09-15 太仓市科教新城琉璃艺术策划中心 A kind of coloured glaze protective paint
CN108137986A (en) * 2015-11-11 2018-06-08 关西涂料株式会社 Water-based paint compositions
CN112341880A (en) * 2020-11-03 2021-02-09 湖北双键精细化工有限公司 Water-based double-component single-coating crack paint
CN115107389A (en) * 2022-06-29 2022-09-27 河钢集团衡水板业有限公司 Method for producing explosive oil product by drying room and RTO

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CN101386771A (en) * 2008-10-24 2009-03-18 深圳市广田环保涂料有限公司 Elastic polyurethane silver paint and preparation method and use method thereof
CN101619194A (en) * 2008-07-02 2010-01-06 紫荆花制漆(上海)有限公司 Yellowing-resistant quick-drying polyurethane wood paint and using method thereof

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CN101619194A (en) * 2008-07-02 2010-01-06 紫荆花制漆(上海)有限公司 Yellowing-resistant quick-drying polyurethane wood paint and using method thereof
CN101386771A (en) * 2008-10-24 2009-03-18 深圳市广田环保涂料有限公司 Elastic polyurethane silver paint and preparation method and use method thereof

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Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104098957A (en) * 2013-04-02 2014-10-15 陈湛玲 Crackle paint for spray-coating glass and use thereof
CN105199511A (en) * 2015-09-24 2015-12-30 维新制漆(深圳)有限公司 Varnish for stainless steel substrate and preparation method and application of varnish
CN105199511B (en) * 2015-09-24 2017-12-29 维新制漆(深圳)有限公司 A kind of stainless steel ground varnish and its preparation method and application
CN108137986A (en) * 2015-11-11 2018-06-08 关西涂料株式会社 Water-based paint compositions
CN108137986B (en) * 2015-11-11 2020-10-23 关西涂料株式会社 Aqueous coating composition
CN107163746A (en) * 2017-07-26 2017-09-15 太仓市科教新城琉璃艺术策划中心 A kind of coloured glaze protective paint
CN112341880A (en) * 2020-11-03 2021-02-09 湖北双键精细化工有限公司 Water-based double-component single-coating crack paint
CN115107389A (en) * 2022-06-29 2022-09-27 河钢集团衡水板业有限公司 Method for producing explosive oil product by drying room and RTO
CN115107389B (en) * 2022-06-29 2023-08-22 河钢集团衡水板业有限公司 Method for producing explosive oil product by baking house and RTO

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