CN106854364A - A kind of anti-static silicon rubber sleeve and preparation method thereof - Google Patents
A kind of anti-static silicon rubber sleeve and preparation method thereof Download PDFInfo
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- CN106854364A CN106854364A CN201611100961.5A CN201611100961A CN106854364A CN 106854364 A CN106854364 A CN 106854364A CN 201611100961 A CN201611100961 A CN 201611100961A CN 106854364 A CN106854364 A CN 106854364A
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- silicon rubber
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- rubber sleeve
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
- C08L83/04—Polysiloxanes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
- H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
- H01B3/28—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances natural or synthetic rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/04—Antistatic
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/20—Applications use in electrical or conductive gadgets
- C08L2203/202—Applications use in electrical or conductive gadgets use in electrical wires or wirecoating
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Spectroscopy & Molecular Physics (AREA)
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Abstract
The invention discloses a kind of anti-static silicon rubber sleeve and preparation method thereof, it is made up of following mass fraction formula components：30 60 parts of silicon rubber, 24 parts of zinc stearate, 13 parts of fire retardant, 14 16 parts of white carbon, 57 parts of silane coupler, 35 parts of activator, 13 15 parts of conductive filler, 24 parts of resin, 12 parts of stabilizer, 10 12 parts of hydroxy silicon oil, 24 parts of zinc oxide, 10 20 parts of calcinated argil, 57 parts of containing hydrogen silicone oil, 12 parts of vulcanizing agent, the present invention has good stability and high-temperature resistant, oil resistant high, solvent resistance, and, with good antistatic behaviour.
Description
Technical field
The present invention relates to cable material field, in particular to a kind of anti-static silicon rubber sleeve and preparation method thereof.
Background technology
At present, macromolecular material has been widely used in daily life and has prepared each field, and it has light weight, corrosion-resistant
And insulaion resistance it is high the advantages of, its sheet resistance generally up to 1014 to 1017 Ω, but just because of with good insulation
Can often there is an electrostatic hazard when in use in performance, macromolecular material, in routine use, due to rubbing,
Easily accumulated on the product that macromolecular material is made and take poly- electrostatic, frequent surface meeting dust suction, influence clean aesthetic, and also it is eventually possible
Cause to produce spark or equipment short circuit because of electric discharge, therefore, antistatic is an important problem.
At present, generally using the addition of antistatic additive, carbon black or metal dust in macromolecular material, have high molecular products
Have certain electric conductivity namely with antistatic property, in number please disclose " anti-quiet for an open file of 200710011766.X
The goddess of lightning expect and high-strength polyvinyl chloride pipe for coal mine preparation method, because polychloroethylene pipes are in heatproof, oil resistant and resistance to
Solvent aspect Performance comparision is poor, it is impossible to meet high-temperature resistant, oil resistant high, solvent-proof needs, therefore, in society now, do not have also
The need for having a kind of high-temperature resistant, solvent-proof antistatic products to adapt to people's preparation and life.
The content of the invention
The invention provides a kind of anti-static silicon rubber sleeve and preparation method thereof, the present invention has good stability and Gao Nai
Oil resistant warm, high, solvent resistance, and, with good antistatic behaviour.
To achieve the above object, the present invention provides following technical scheme：
A kind of anti-static silicon rubber sleeve and preparation method thereof, is made up of following mass fraction formula components：Silicon rubber 30-60
Part, zinc stearate 2-4 parts, fire retardant 1-3 parts, white carbon 14-16 parts, silane coupler 5-7 parts, activator 3-5 parts, conduction fills out
Material 13-15 parts, resin 2-4 parts, stabilizer 1-2 parts, hydroxy silicon oil 10-12 parts, zinc oxide 2-4 parts, calcinated argil 10-20 parts,
Containing hydrogen silicone oil 5-7 parts, vulcanizing agent 1-2 parts.
Further：It is made up of following mass fraction formula components：It is 30 parts of silicon rubber, 2 parts of zinc stearate, 1 part of fire retardant, white
14 parts of carbon black, 5 parts of silane coupler, 3 parts of activator, 13 parts of conductive filler, 2 parts of resin, 1 part of stabilizer, 10 parts of hydroxy silicon oil,
2 parts of zinc oxide, 10 parts of calcinated argil, 5 parts of containing hydrogen silicone oil, 1 part of vulcanizing agent.
Further：It is made up of following mass fraction formula components：It is 45 parts of silicon rubber, 3 parts of zinc stearate, 2 parts of fire retardant, white
15 parts of carbon black, 6 parts of silane coupler, 4 parts of activator, 14 parts of conductive filler, 3 parts of resin, 1.5 parts of stabilizer, hydroxy silicon oil 11
Part, 3 parts of zinc oxide, 15 parts of calcinated argil, 6 parts of containing hydrogen silicone oil, 1.5 parts of vulcanizing agent.
Further：It is made up of following mass fraction formula components：It is 60 parts of silicon rubber, 4 parts of zinc stearate, 3 parts of fire retardant, white
16 parts of carbon black, 7 parts of silane coupler, 5 parts of activator, 15 parts of conductive filler, 4 parts of resin, 2 parts of stabilizer, 12 parts of hydroxy silicon oil,
4 parts of zinc oxide, 20 parts of calcinated argil, 7 parts of containing hydrogen silicone oil, 2 parts of vulcanizing agent.
Further：Preparation method of the present invention has following steps：
Step one, by the silicon rubber of above-mentioned formula, zinc stearate, white carbon, resin, hydroxy silicon oil, zinc oxide, calcining pottery
Soil and containing hydrogen silicone oil are added in vacuum kneader, uniform in normal temperature mixing, are then vacuumized 1-4 hours at 140 DEG C and are made silicon rubber
Glue elastomeric compound；
Conductive filler, activator, fire retardant, silane coupled is added in step 2, the elastomeric compound A being made in the first step
Agent, stabilizer, then knead uniform in vacuum kneader；
Step 3, the conducting resinl being made in the second step add vulcanizing agent, then knead on a mill uniform；
Step 4, the sheet elastomeric compound that will be made in third step are extruded after being cut into small bar on extruder, then through hot empty
Vulcanize sizing in gas drying tunnel or vulcanize sizing in molding apparatus, be thus made antistatic silicone rubber sleeve pipe.
The beneficial effects of the invention are as follows：
1st, the present invention has good stability and high-temperature resistant, oil resistant high, solvent resistance；
2nd, with good antistatic behaviour.
Specific embodiment
Below in conjunction with the embodiment of the present invention, the technical scheme in the embodiment of the present invention is clearly and completely described,
Obviously, described embodiment is only a part of embodiment of the invention, rather than whole embodiments.Based in the present invention
Embodiment, the every other embodiment that those of ordinary skill in the art are obtained under the premise of creative work is not made, all
Belong to the scope of protection of the invention.
Embodiment one：
A kind of anti-static silicon rubber sleeve is made up of following mass fraction formula components：Silicon rubber 30-60 parts, zinc stearate 2-
4 parts, fire retardant 1-3 parts, white carbon 14-16 parts, silane coupler 5-7 parts, activator 3-5 parts, conductive filler 13-15 parts, tree
Fat 2-4 parts, stabilizer 1-2 parts, hydroxy silicon oil 10-12 parts, zinc oxide 2-4 parts, calcinated argil 10-20 parts, containing hydrogen silicone oil 5-7
Part, vulcanizing agent 1-2 parts.
Embodiment two：
A kind of anti-static silicon rubber sleeve is made up of following mass fraction formula components：30 parts of silicon rubber, 2 parts of zinc stearate,
1 part of fire retardant, 14 parts of white carbon, 5 parts of silane coupler, 3 parts of activator, 13 parts of conductive filler, 2 parts of resin, 1 part of stabilizer,
10 parts of hydroxy silicon oil, 2 parts of zinc oxide, 10 parts of calcinated argil, 5 parts of containing hydrogen silicone oil, 1 part of vulcanizing agent.
Embodiment three：
A kind of anti-static silicon rubber sleeve is made up of following mass fraction formula components：45 parts of silicon rubber, 3 parts of zinc stearate,
2 parts of fire retardant, 15 parts of white carbon, 6 parts of silane coupler, 4 parts of activator, 14 parts of conductive filler, 3 parts of resin, stabilizer 1.5
Part, 11 parts of hydroxy silicon oil, 3 parts of zinc oxide, 15 parts of calcinated argil, 6 parts of containing hydrogen silicone oil, 1.5 parts of vulcanizing agent.
Example IV：
A kind of anti-static silicon rubber sleeve is made up of following mass fraction formula components：60 parts of silicon rubber, 4 parts of zinc stearate,
3 parts of fire retardant, 16 parts of white carbon, 7 parts of silane coupler, 5 parts of activator, 15 parts of conductive filler, 4 parts of resin, 2 parts of stabilizer,
12 parts of hydroxy silicon oil, 4 parts of zinc oxide, 20 parts of calcinated argil, 7 parts of containing hydrogen silicone oil, 2 parts of vulcanizing agent.
Embodiment five：
A kind of preparation method preparation method of anti-static silicon rubber sleeve comprises the following steps：
Step one, by the silicon rubber of above-mentioned formula, zinc stearate, white carbon, resin, hydroxy silicon oil, zinc oxide, calcining pottery
Soil and containing hydrogen silicone oil are added in vacuum kneader, uniform in normal temperature mixing, are then vacuumized 1-4 hours at 140 DEG C and are made silicon rubber
Glue elastomeric compound；
Conductive filler, activator, fire retardant, silane coupled is added in step 2, the elastomeric compound A being made in the first step
Agent, stabilizer, then knead uniform in vacuum kneader；
Step 3, the conducting resinl being made in the second step add vulcanizing agent, then knead on a mill uniform；
Step 4, the sheet elastomeric compound that will be made in third step are extruded after being cut into small bar on extruder, then through hot empty
Vulcanize sizing in gas drying tunnel or vulcanize sizing in molding apparatus, be thus made antistatic silicone rubber sleeve pipe.
Moreover, it will be appreciated that although the present specification is described in terms of embodiments, not each implementation method is only wrapped
Containing an independent technical scheme, this narrating mode of specification is only that for clarity, those skilled in the art should
Specification an as entirety, the technical scheme in each embodiment can also be formed into those skilled in the art through appropriately combined
May be appreciated other embodiment.
Claims (5)
1. a kind of anti-static silicon rubber sleeve, it is characterised in that：It is made up of following mass fraction formula components：
Silicon rubber 30-60 parts, zinc stearate 2-4 parts, fire retardant 1-3 parts, white carbon 14-16 parts, silane coupler 5-7 parts, work
Agent 3-5 parts, conductive filler 13-15 parts, resin 2-4 parts, stabilizer 1-2 parts, hydroxy silicon oil 10-12 parts, zinc oxide 2-4 parts,
Calcinated argil 10-20 parts, containing hydrogen silicone oil 5-7 parts, vulcanizing agent 1-2 parts.
2. a kind of anti-static silicon rubber sleeve according to claim 1, it is characterised in that：By following mass fraction formula components
Composition：
30 parts of silicon rubber, 2 parts of zinc stearate, 1 part of fire retardant, 14 parts of white carbon, 5 parts of silane coupler, 3 parts of activator, conduction
13 parts of filler, 2 parts of resin, 1 part of stabilizer, 10 parts of hydroxy silicon oil, 2 parts of zinc oxide, 10 parts of calcinated argil, 5 parts of containing hydrogen silicone oil, sulphur
1 part of agent.
3. a kind of anti-static silicon rubber sleeve according to claim 1, it is characterised in that：By following mass fraction formula components
Composition：
45 parts of silicon rubber, 3 parts of zinc stearate, 2 parts of fire retardant, 15 parts of white carbon, 6 parts of silane coupler, 4 parts of activator, conduction
14 parts of filler, 3 parts of resin, 1.5 parts of stabilizer, 11 parts of hydroxy silicon oil, 3 parts of zinc oxide, 15 parts of calcinated argil, 6 parts of containing hydrogen silicone oil,
1.5 parts of vulcanizing agent.
4. a kind of anti-static silicon rubber sleeve according to claim 1, it is characterised in that：By following mass fraction formula components
Composition：
60 parts of silicon rubber, 4 parts of zinc stearate, 3 parts of fire retardant, 16 parts of white carbon, 7 parts of silane coupler, 5 parts of activator, conduction
15 parts of filler, 4 parts of resin, 2 parts of stabilizer, 12 parts of hydroxy silicon oil, 4 parts of zinc oxide, 20 parts of calcinated argil, 7 parts of containing hydrogen silicone oil, sulphur
2 parts of agent.
5. a kind of a kind of preparation method of anti-static silicon rubber sleeve according to claim 1, it is characterised in that：Including as follows
Step：
Step one, by the silicon rubber of above-mentioned formula, zinc stearate, white carbon, resin, hydroxy silicon oil, zinc oxide, calcinated argil and
Containing hydrogen silicone oil is added in vacuum kneader, uniform in normal temperature mixing, then vacuumizes that to be made within 1-4 hour silicon rubber mixed at 140 DEG C
Refining glue；
In step 2, the elastomeric compound A being made in the first step add conductive filler, activator, fire retardant, silane coupler,
Stabilizer, then kneads uniform in vacuum kneader；
Step 3, the conducting resinl being made in the second step add vulcanizing agent, then knead on a mill uniform；
Step 4, the sheet elastomeric compound that will be made in third step are extruded after being cut into small bar on extruder, then are dried through hot-air
Vulcanize sizing in road or vulcanize sizing in molding apparatus, be thus made antistatic silicone rubber sleeve pipe.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611100961.5A CN106854364A (en) | 2016-12-05 | 2016-12-05 | A kind of anti-static silicon rubber sleeve and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611100961.5A CN106854364A (en) | 2016-12-05 | 2016-12-05 | A kind of anti-static silicon rubber sleeve and preparation method thereof |
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| CN106854364A true CN106854364A (en) | 2017-06-16 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201611100961.5A Pending CN106854364A (en) | 2016-12-05 | 2016-12-05 | A kind of anti-static silicon rubber sleeve and preparation method thereof |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107674430A (en) * | 2017-10-20 | 2018-02-09 | 东莞新东方科技有限公司 | Transparent antistatic silica gel and preparation method thereof |
| CN108892953A (en) * | 2018-08-10 | 2018-11-27 | 浙江久运汽车零部件有限公司 | One kind plus the hoop thermally conductive high pressure silicone tube of modified and preparation method thereof |
| CN111675906A (en) * | 2020-07-02 | 2020-09-18 | 宿州市信顺塑胶有限公司 | PVC-U light electrical casing and preparation process thereof |
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| CN102516675A (en) * | 2011-11-21 | 2012-06-27 | 安徽蓝德集团股份有限公司 | Mining cable rubber sheath glue |
| CN104710797A (en) * | 2015-03-17 | 2015-06-17 | 赵雪雅 | Silicone rubber compound and preparation method thereof |
| CN105218904A (en) * | 2014-06-04 | 2016-01-06 | 安徽弘博电缆集团有限公司 | A kind of preparation technology of high-performance mine cable chloroprene rubber sheath material |
-
2016
- 2016-12-05 CN CN201611100961.5A patent/CN106854364A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102243913A (en) * | 2010-05-12 | 2011-11-16 | 深圳市沃尔核材股份有限公司 | Anti-static silicon rubber sleeve and preparation method thereof |
| CN102516675A (en) * | 2011-11-21 | 2012-06-27 | 安徽蓝德集团股份有限公司 | Mining cable rubber sheath glue |
| CN105218904A (en) * | 2014-06-04 | 2016-01-06 | 安徽弘博电缆集团有限公司 | A kind of preparation technology of high-performance mine cable chloroprene rubber sheath material |
| CN104710797A (en) * | 2015-03-17 | 2015-06-17 | 赵雪雅 | Silicone rubber compound and preparation method thereof |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107674430A (en) * | 2017-10-20 | 2018-02-09 | 东莞新东方科技有限公司 | Transparent antistatic silica gel and preparation method thereof |
| CN108892953A (en) * | 2018-08-10 | 2018-11-27 | 浙江久运汽车零部件有限公司 | One kind plus the hoop thermally conductive high pressure silicone tube of modified and preparation method thereof |
| CN111675906A (en) * | 2020-07-02 | 2020-09-18 | 宿州市信顺塑胶有限公司 | PVC-U light electrical casing and preparation process thereof |
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