CN102250426A - Cable sheath rubber - Google Patents
Cable sheath rubber Download PDFInfo
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- CN102250426A CN102250426A CN 201110151384 CN201110151384A CN102250426A CN 102250426 A CN102250426 A CN 102250426A CN 201110151384 CN201110151384 CN 201110151384 CN 201110151384 A CN201110151384 A CN 201110151384A CN 102250426 A CN102250426 A CN 102250426A
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Abstract
The invention provides cable sheath rubber, which is characterized in that the raw material comprises 100 weight parts of chlorinated polyethylene, 2 to 6 weight parts of organic peroxide vulcanizing agent, 3 to 6 weight parts of sulfurization assisting agent, 0.5 to 1.5 weight parts of antiaging agent, 10 to 30 weight parts of fire retardant and 20 to 40 weight parts of reinforcing agent. The product has high fuel oil resistance, high mineral oil resistance, high resistance to low temperature after aging; the cable sheath rubber can be filled with more filler and has high compression deformation performance and toughness; and the smooth appearance of the rubber has high processing technical performance and high flame retarding performance.
Description
Technical field
The present invention relates to a kind of cable sheath rubber, belong to the rubber technology field.
Background technology
Chlorinatedpolyethylene (CM/CP) main application abroad is to make cable.CM has the performance close with chlorosulfonated polyethylene with neoprene, but CM is difficult for incipient scorch, and processing characteristics is good, no roll banding phenomenon.CM has stability preferably to chromic acid, clorox and strong oxidizing property pharmaceutical chemicals, and anti-mineral oil is functional.Normally used CM cl content has the characteristic of rubber like between 30%～40%, along with the raising of cl content, the extrusion performance of CM and oil resistant, wear-resisting, flame retardant properties obtain corresponding improvement, and elasticity and winter hardiness descend.
Summary of the invention
The purpose of this invention is to provide a kind of cable sheath rubber of fuel oil resistance, anti-mineral oiliness, lower temperature resistance and resistance to heat aging preferably that has simultaneously.
In order to achieve the above object, the invention provides a kind of cable sheath rubber, it is characterized in that its raw material comprises:
Chlorinatedpolyethylene 100 weight parts;
Organic peroxide sulfuration agent 2～6 weight parts;
Help sulphur agent 3～6 weight parts;
Anti-aging agent 0.5～1.5 weight part;
Fire retardant 10～30 weight parts;
Strengthening agent 20～40 weight parts.
Preferably, described chlorinatedpolyethylene is an EXT1000(Dow Chemical).
Preferably, described organic peroxide sulfuration agent is dicumyl peroxide (DCP).Vulcanizing agent dicumyl peroxide and cooperation can improve degree of crosslinking after helping the sulphur agent, can give the good heat-proof aging of cross-linked rubber, oil-proofness.
It is preferably, described that to help the sulphur agent be iso-cyanuric acid triallyl ester (TAIC).Iso-cyanuric acid triallyl ester can be accelerated vulcanization rate, improves cross-linked speed, shortens curing time.
Preferably, described anti-aging agent is 2,2,4-trimethylammonium-1,2-dihyaroquinoline polymkeric substance (RD).RD is a kind of ketoamine class anti-aging agent, protection to thermo-oxidative ageing is very effective, and toxicity is little, can suppress the catalyzed oxidation of the harmful metal ions such as copper of harshness, be suitable as elastomeric oxidation inhibitor, also aging, the thermal ageing of climate protection and the be full of cracks that circumnutates effectively.
Preferably, described fire retardant is decabromodiphynly oxide and antimonous oxide.Decabromodiphynly oxide, mainly as additive flame retardant, brominated amount is big, Heat stability is good, flame-retarded efficiency height, it has higher bromine content and good thermostability, is a kind of nontoxic, free of contamination efficient flame-retarding agent.Then there are good synergistic antimonous oxide and halogen thing and time spent, and flame retardant effect obviously improves.
Preferably, described strengthening agent is carbon black N550.Carbon black N550 is the furnace black with medium strengthening action, and particle surface is smooth, can give sizing material with higher very property, extruder rate is fast, the extrudate smooth surface, its other soft carbon of reinforcement energy force rate is all high, can give cross-linked rubber good temperature resistance, wear resistance and thermal conductivity.
Preferably, described cable sheath rubber raw materials also comprises:
Nanometer potter's clay 40～80 weight parts;
Extra light calcined magnesia 10～20 weight parts;
Chlorinated paraffinic oil 10～20 weight parts;
Dioctyl sebacate 10～20 weight parts;
Microcrystalline Wax 5～10 weight parts;
Lead stearate 3～7 weight parts;
Silane coupling A-172 0.5～1.5 weight part.
Wherein, extra light calcined magnesia and lead stearate are promoting agents, are processing aid, and lead stearate also has the softening and effect on thermal of plasticising.Chlorinated paraffinic oil are chlorinated derivatives of paraffinic hydrocarbon, have low volatility, fire-retardant, electrical insulating property is good, advantage such as inexpensive, can be used as fire retardant.Dioctyl sebacate (DOS) is a kind of good cold resistant plasticizer, the plasticizing efficiency height, and volatility is low, has both had good winter hardiness, and better heat-resisting, photostabilization and electrical insulating property are arranged again.Vinyl three ('beta '-methoxy oxyethyl group) silane (claiming silane coupling A-172 again) uses as coupling agent.
The present invention makes rubber have good thermal ageing by add elasticity and the winter hardiness that a certain amount of auxiliary agent improves rubber unvulcanizate in mixing process simultaneously, has realized the balance of heat-resisting, low temperature resistant and oil resistance, the mechanical and physical performance excellence.
Advantage of the present invention is as follows:
1, You Yi fuel oil resistance, anti-mineral oil performance and the later low-temperature performance of heat-proof aging.
2, can fill more filler and have good compression deformation performance and toughness.
3, slick apparent characteristic has excellent process industrial art performance.
4, excellent flame-retardant.
Embodiment
Specify the present invention below in conjunction with embodiment.
Embodiment 1
A kind of cable sheath rubber, make by following raw material:
Chlorinatedpolyethylene EXT1000 100 weight parts;
Dicumyl peroxide 4 weight parts;
Iso-cyanuric acid triallyl ester 5 weight parts;
Anti-aging agent RD 1 weight part;
Decabromodiphynly oxide 15 weight parts;
Antimonous oxide 5 weight parts;
Carbon black N550 30 weight parts;
Nanometer potter's clay 70 weight parts;
Extra light calcined magnesia (reactivity coefficient is 15S) 15 weight parts;
Chlorinated paraffinic oil (52#) 15 weight parts;
Dioctyl sebacate 15 weight parts;
Microcrystalline Wax (60#) 8 weight parts;
Lead stearate 5 weight parts;
Silane coupling A-172 0.5 weight part.
Its preparation method is: various raw materials of weighing in proportion, earlier Banbury mixer is heated to 70 ℃, and add chlorinatedpolyethylene and plasticated 3 minutes, added other raw material more mixing 5 minutes, screw speed is 40 rev/mins.After the Banbury mixer blanking, mill thin-pass 5 times, last mill blanking finishes.
Embodiment 2
A kind of cable sheath rubber, make by following raw material:
Chlorinatedpolyethylene EXT1000 100 weight parts;
Dicumyl peroxide 6 weight parts;
Iso-cyanuric acid triallyl ester 6 weight parts;
Anti-aging agent RD 1.5 weight parts;
Decabromodiphynly oxide 20 weight parts;
Antimonous oxide 10 weight parts;
Carbon black N550 40 weight parts;
Its preparation method is: various raw materials of weighing in proportion, earlier Banbury mixer is heated to 70 ℃, and add chlorinatedpolyethylene and plasticated 3 minutes, added other raw material more mixing 5 minutes, screw speed is 40 rev/mins.After the Banbury mixer blanking, mill thin-pass 5 times, last mill blanking finishes.
Embodiment 3
A kind of cable sheath rubber, make by following raw material:
Chlorinatedpolyethylene EXT1000 100 weight parts;
Dicumyl peroxide 2 weight parts;
Iso-cyanuric acid triallyl ester 3 weight parts;
Anti-aging agent RD 0.5 weight part;
Decabromodiphynly oxide 5 weight parts;
Antimonous oxide 5 weight parts;
Carbon black N550 20 weight parts;
Nanometer potter's clay 40 weight parts;
Extra light calcined magnesia (reactivity coefficient is 15S) 10 weight parts;
Chlorinated paraffinic oil (52#) 10 weight parts;
Dioctyl sebacate 10 weight parts;
Microcrystalline Wax (60#) 5 weight parts;
Lead stearate 3 weight parts;
Silane coupling A-172 0.5 weight part.
Its preparation method is: various raw materials of weighing in proportion, earlier Banbury mixer is heated to 70 ℃, and add chlorinatedpolyethylene and plasticated 3 minutes, added other raw material more mixing 5 minutes, screw speed is 40 rev/mins.After the Banbury mixer blanking, mill thin-pass 5 times, last mill blanking finishes.
Embodiment 4
A kind of cable sheath rubber, make by following raw material:
Chlorinatedpolyethylene EXT1000 100 weight parts;
Dicumyl peroxide 6 weight parts;
Iso-cyanuric acid triallyl ester 6 weight parts;
Anti-aging agent RD 1.5 weight parts;
Decabromodiphynly oxide 20 weight parts;
Antimonous oxide 10 weight parts;
Carbon black N550 40 weight parts;
Nanometer potter's clay 80 weight parts;
Extra light calcined magnesia (reactivity coefficient is 15S) 20 weight parts;
Chlorinated paraffinic oil (52#) 20 weight parts;
Dioctyl sebacate 20 weight parts;
Microcrystalline Wax (60#) 10 weight parts;
Lead stearate 7 weight parts;
Silane coupling A-172 1.5 weight part.
Its preparation method is: various raw materials of weighing in proportion, earlier Banbury mixer is heated to 70 ℃, and add chlorinatedpolyethylene and plasticated 3 minutes, added other raw material more mixing 5 minutes, screw speed is 40 rev/mins.After the Banbury mixer blanking, mill thin-pass 5 times, last mill blanking finishes.
The specific performance test value such as the following table of embodiment 1-4 products obtained therefrom:
(touchstone: GB/T2591-2008, GB/T2406-2009)
Claims (7)
1. a cable sheath rubber is characterized in that, its raw material comprises:
Chlorinatedpolyethylene 100 weight parts;
Organic peroxide sulfuration agent 2～6 weight parts;
Help sulphur agent 3～6 weight parts;
Anti-aging agent 0.5～1.5 weight part;
Fire retardant 10～30 weight parts;
Strengthening agent 20～40 weight parts.
2. cable sheath rubber as claimed in claim 1 is characterized in that, described chlorinatedpolyethylene is EXT1000.
3. cable sheath rubber as claimed in claim 1 is characterized in that, described organic peroxide sulfuration agent is a dicumyl peroxide.
4. cable sheath rubber as claimed in claim 1 is characterized in that, described to help the sulphur agent be iso-cyanuric acid triallyl ester.
5. cable sheath rubber as claimed in claim 1 is characterized in that, described anti-aging agent is 2,2,4-trimethylammonium-1,2-dihyaroquinoline polymkeric substance.
6. cable sheath rubber as claimed in claim 1 is characterized in that, described strengthening agent is carbon black N550.
7. cable sheath rubber as claimed in claim 1 is characterized in that, its raw material also comprises:
Nanometer potter's clay 40～80 weight parts;
Extra light calcined magnesia 10～20 weight parts;
Chlorinated paraffinic oil 10～20 weight parts;
Dioctyl sebacate 10～20 weight parts;
Microcrystalline Wax 5～10 weight parts;
Lead stearate 3～7 weight parts;
Silane coupling A-172 0.5～1.5 weight part.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201110151384 CN102250426A (en) | 2011-06-08 | 2011-06-08 | Cable sheath rubber |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201110151384 CN102250426A (en) | 2011-06-08 | 2011-06-08 | Cable sheath rubber |
Publications (1)
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| CN102250426A true CN102250426A (en) | 2011-11-23 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 201110151384 Pending CN102250426A (en) | 2011-06-08 | 2011-06-08 | Cable sheath rubber |
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Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102399398A (en) * | 2011-11-25 | 2012-04-04 | 成都亨通光通信有限公司 | High-voltage shielding flexible cable |
| CN102424711A (en) * | 2011-11-25 | 2012-04-25 | 成都亨通光通信有限公司 | Manufacturing process of impact-resistant cable |
| CN102675759A (en) * | 2012-06-18 | 2012-09-19 | 天津市振海橡胶科技发展有限公司 | Flame retarding and sound insulating pad with high density and low smoke toxicity and preparation method thereof |
| CN103483710A (en) * | 2013-09-25 | 2014-01-01 | 镇江市华银仪表电器有限公司 | Oil-proof and water-proof insulating cable material and preparation method thereof |
| CN103509261A (en) * | 2013-08-30 | 2014-01-15 | 安徽天民电气科技有限公司 | Non-flame spread CPE rubber sheath material and preparation method thereof |
| CN103758925A (en) * | 2014-01-21 | 2014-04-30 | 宁波裕江特种胶带有限公司 | Chlorosulfonated polyethylene automobile synchronous belt and manufacturing method thereof |
| CN104795149A (en) * | 2014-05-28 | 2015-07-22 | 安徽天星光纤通信设备有限公司 | High-performance communication cable for coal mine wells |
| CN104877243A (en) * | 2015-05-25 | 2015-09-02 | 南洋电缆（天津）有限公司 | Low-toxicity, high-fire-retardant, and uvioresistant cable sheath and preparation method thereof |
| CN105860302A (en) * | 2016-05-18 | 2016-08-17 | 安徽华通电缆集团有限公司 | Formulation and preparation method of high flame-retardant cable jacket material |
| CN112133482A (en) * | 2020-08-31 | 2020-12-25 | 江苏亨通电力电缆有限公司 | Cold-resistant flexible cable and preparation process thereof |
| CN112724688A (en) * | 2020-12-28 | 2021-04-30 | 浙江万马专用线缆科技有限公司 | High-strength cable sheath material, preparation method thereof and cable sheath |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101597410A (en) * | 2009-07-02 | 2009-12-09 | 俞国麟 | Grease proofing, fire-retardant chlorinated polyethylene sheath material of good weatherability and preparation method thereof |
| CN101735522A (en) * | 2009-12-28 | 2010-06-16 | 佛山市顺德区凯华电器实业有限公司 | Rubber wire sheath material and manufacturing method thereof |
-
2011
- 2011-06-08 CN CN 201110151384 patent/CN102250426A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101597410A (en) * | 2009-07-02 | 2009-12-09 | 俞国麟 | Grease proofing, fire-retardant chlorinated polyethylene sheath material of good weatherability and preparation method thereof |
| CN101735522A (en) * | 2009-12-28 | 2010-06-16 | 佛山市顺德区凯华电器实业有限公司 | Rubber wire sheath material and manufacturing method thereof |
Cited By (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102424711A (en) * | 2011-11-25 | 2012-04-25 | 成都亨通光通信有限公司 | Manufacturing process of impact-resistant cable |
| CN102399398A (en) * | 2011-11-25 | 2012-04-04 | 成都亨通光通信有限公司 | High-voltage shielding flexible cable |
| CN102675759B (en) * | 2012-06-18 | 2015-01-07 | 天津市橡胶工业研究所有限公司 | Flame retarding and sound insulating pad with high density and low smoke toxicity and preparation method thereof |
| CN102675759A (en) * | 2012-06-18 | 2012-09-19 | 天津市振海橡胶科技发展有限公司 | Flame retarding and sound insulating pad with high density and low smoke toxicity and preparation method thereof |
| CN103509261A (en) * | 2013-08-30 | 2014-01-15 | 安徽天民电气科技有限公司 | Non-flame spread CPE rubber sheath material and preparation method thereof |
| CN103509261B (en) * | 2013-08-30 | 2016-04-13 | 安徽天民电气科技有限公司 | One does not prolong combustion CPE eraser sheath material and preparation method thereof |
| CN103483710A (en) * | 2013-09-25 | 2014-01-01 | 镇江市华银仪表电器有限公司 | Oil-proof and water-proof insulating cable material and preparation method thereof |
| CN103483710B (en) * | 2013-09-25 | 2016-02-10 | 镇江市华银仪表电器有限公司 | A kind of grease-proof and waterproof insulated cable material and preparation method thereof |
| CN103758925A (en) * | 2014-01-21 | 2014-04-30 | 宁波裕江特种胶带有限公司 | Chlorosulfonated polyethylene automobile synchronous belt and manufacturing method thereof |
| CN104795149A (en) * | 2014-05-28 | 2015-07-22 | 安徽天星光纤通信设备有限公司 | High-performance communication cable for coal mine wells |
| CN104877243A (en) * | 2015-05-25 | 2015-09-02 | 南洋电缆（天津）有限公司 | Low-toxicity, high-fire-retardant, and uvioresistant cable sheath and preparation method thereof |
| CN105860302A (en) * | 2016-05-18 | 2016-08-17 | 安徽华通电缆集团有限公司 | Formulation and preparation method of high flame-retardant cable jacket material |
| CN112133482A (en) * | 2020-08-31 | 2020-12-25 | 江苏亨通电力电缆有限公司 | Cold-resistant flexible cable and preparation process thereof |
| CN112724688A (en) * | 2020-12-28 | 2021-04-30 | 浙江万马专用线缆科技有限公司 | High-strength cable sheath material, preparation method thereof and cable sheath |
| CN112724688B (en) * | 2020-12-28 | 2022-08-05 | 浙江万马专用线缆科技有限公司 | High-strength cable sheath material, preparation method thereof and cable sheath |
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Application publication date: 20111123 |