CN106849607B - Low-temperature waste heat power generation system based on the high magnetic conduction fluid of carbon dioxide-base nanometer mixed phase - Google Patents

Low-temperature waste heat power generation system based on the high magnetic conduction fluid of carbon dioxide-base nanometer mixed phase Download PDF

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CN106849607B
CN106849607B CN201710007019.2A CN201710007019A CN106849607B CN 106849607 B CN106849607 B CN 106849607B CN 201710007019 A CN201710007019 A CN 201710007019A CN 106849607 B CN106849607 B CN 106849607B
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carbon dioxide
heat
fluid
mixed phase
magnetic conduction
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CN106849607A (en
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胡少斌
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Jiangsu Zhong Kong Energy Technology Co Ltd
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    • HELECTRICITY
    • H02GENERATION; CONVERSION OR DISTRIBUTION OF ELECTRIC POWER
    • H02KDYNAMO-ELECTRIC MACHINES
    • H02K44/00Machines in which the dynamo-electric interaction between a plasma or flow of conductive liquid or of fluid-borne conductive or magnetic particles and a coil system or magnetic field converts energy of mass flow into electrical energy or vice versa
    • H02K44/08Magnetohydrodynamic [MHD] generators
    • H02K44/085Magnetohydrodynamic [MHD] generators with conducting liquids
    • HELECTRICITY
    • H02GENERATION; CONVERSION OR DISTRIBUTION OF ELECTRIC POWER
    • H02NELECTRIC MACHINES NOT OTHERWISE PROVIDED FOR
    • H02N11/00Generators or motors not provided for elsewhere; Alleged perpetua mobilia obtained by electric or magnetic means
    • H02N11/002Generators

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  • Physics & Mathematics (AREA)
  • Fluid Mechanics (AREA)
  • Engineering & Computer Science (AREA)
  • Power Engineering (AREA)
  • Processing Of Solid Wastes (AREA)
  • Engine Equipment That Uses Special Cycles (AREA)

Abstract

The invention discloses a kind of low-temperature waste heat power generation systems based on the high magnetic conduction fluid of carbon dioxide-base nanometer mixed phase, are related to low-temperature cogeneration field.This system is: low temperature exhaust heat heat dump, stream of supercritical carbon dioxide move guide rail, hydromagnetic generating device, radiator and solar energy heat absorbing device and are in turn connected to form closure entirety;Tank body moves guide rail with stream of supercritical carbon dioxide by valve and is connected;The high magnetic conduction fluid of carbon dioxide-base nanometer mixed phase is packaged in tank body;Solar energy heat absorbing device absorbs solar energy.The present invention is situated between using postcritical carbon dioxide as circulation industrial, and excellent physical characteristic makes the low temperature exhaust heat temperature range of the system recoverable lower, and generating efficiency is higher;Using the generation mode of carbon dioxide-base nanometer mixed phase magnetic fluid, electric energy is directly converted heat into, it is more directly and efficient with previous thermal energy-mechanical energy-electric energy transform mode;In the way of magnetohydrodynamic generator, structure is simple, and machining, sealing etc. are easy to connect.

Description

Low-temperature waste heat power generation system based on the high magnetic conduction fluid of carbon dioxide-base nanometer mixed phase
Technical field
The present invention relates to low-temperature cogeneration fields, more particularly to one kind to be based on the high magnetic conduction stream of carbon dioxide-base nanometer mixed phase The low-temperature waste heat power generation system of body;Big industry such as cement, steel, thermoelectricity, ceramics and coloured are discharged more particularly to industrial waste heat The low taste heat resource power generation in the fields such as metal, also including the use of generations of electricity by new energy such as solar energy, geothermal energy and sea water heat energies.
Background technique
Currently, the generation mode of mainstream is the thermoelectricity based on the fossil fuels such as coal and natural gas, but fossil fuel conduct A kind of non-regeneration energy has one day exhausted eventually.Currently, a kind of very promising scheme is sent out using low-grade heat source Electricity.Industrial waste heat discharges big industry such as cement, steel, thermoelectricity, ceramics and non-ferrous metal etc., these industries not still waste heat Rich and influential family is discharged, and is also the main industries of room temperature air discharge.
The basic reason of China's Energy situation sternness at present is that energy consumption efficiency is low.The output of China's standard coal per ton is imitated Rate just corresponds to the 28.6% of the 10.3% of the Japan, U.S..Nearly 60~65% energy conversion is waste heat money in China's energy consumption of industry Source.The most country of UTILIZATION OF VESIDUAL HEAT IN is the U.S. at present, and for its utilization rate up to 60%, European utilization rate is 50%, we are national only Have 30%.With regard to waste heat (waste heat) using status from the point of view of, China utilizes space there are also very big.350 DEG C of domestic industry enterprise at present Low temperature exhaust heat below accounts for 60% or more of waste heat total amount, because its utility value is lower, recovery technology relatively fall behind, the rate of recovery and Recovery value is low, and invests retirement period long (6~7 years) and abandoned by most enterprises.
The highly energy-consumings industry development such as cement, steel and the ceramics in China is rapid, has driven the quick of high, middle temperature cogeneration Development, has formd more complete industry, but low-temperature cogeneration has then just started.As the worldwide energy is tight It lacks, various countries are committed to energy conservation and emission reduction, strive sustainably developing.Such a fact based on energy shortages, more than low temperature The problem of heat utilization, each state was all in the investment and research for reinforcing this respect at more and more important energy striving direction, it is desirable to Obtain bigger and more incomes.
Currently, low-temperature cogeneration technology mainly includes following several:
1, organic working medium cycle power generation system
Organic working medium cycle power generation system is to be different from traditional electricity generation system with water (steam) for cycle fluid, is used Power generation of the organic working medium (such as R123, R245fa, R152a, chloroethanes, propane, normal butane and iso-butane) as cycle fluid System generates higher pressure since organic working medium can gasify at a lower temperature, pushes turbine (turbine) acting, Therefore organic working medium cycle power generation system can be at 200 DEG C of flue-gas temperature or so, water temperature has utility value in 80 DEG C or so realizations Power generation.This technology is exactly more advanced application technology in developed country, and the enterprise that China has in recent years is absorbed by introducing, Also this technology has been grasped, has also had more outstanding product at home and abroad to apply.
2, Stirling thermomotor cycle generating system
Stirling thermomotor cycle generating system is the waste heat recovery plant using low-temperature cogeneration, can be recycled 100 DEG C To 300 DEG C of waste heat, 20% generating efficiency can be reached.From the point of view of data, generating efficiency is better than the Low Temperature Steam of existing market The generating efficiency of cycle generating system and organic working medium electricity generation system, system generating efficiency under the conditions of 100 DEG C of waste heat reach 7.3%, generating efficiency is up to generating efficiency under conditions of 13.7%, 200 DEG C up under conditions of 18.4%, 250 DEG C under conditions of 150 DEG C Generating efficiency is up to generating efficiency under conditions of 22.1%, 300 DEG C up to 25.0%.It can reach in this way under the conditions of such temperature of waste heat Generating efficiency be at present it can be seen that best level, reached the advanced technology water that electric energy is converted into from low temperature heat energy It is flat.In low temperature to moderate temperature (100~300 DEG C) range, Stirling engine be by the development of evil in febrile disease of low level thermal energy at mechanical or The optimal selection of electric power.
3, supercritical carbon dioxide cycle generating system
Supercritical carbon dioxide electricity generation system is the working medium that supercritical carbon dioxide liquid is rankine cycle system, with dioxy Change the newest cogeneration technology that carbon turbine specific turbine is core technology.This electricity generation system has wider in terms of cogeneration General application advantage, all technical be better than water vapour wave agree the circulatory system and current state-of-the-art organic wave is agreed The circulatory system especially has apparent advantage in terms of generating efficiency and equipment volume.Supercritical carbon dioxide heat engine is one Kind platform technology, efficiency is up to 30%.Application range include gas turbine, fixed dynamic power unit, industrial waste heat recycling, The recycling heat energy of solar heat, underground heat and mixing internal combustion engine etc..Currently, it is limited due to being machined with the technology of sealing etc. System, China is in terms of supercritical carbon dioxide turbine circulating generation also in test development phase.
Summary of the invention
The object of the invention is that overcoming shortcoming and defect of the existing technology, provide a kind of based on carbon dioxide-base The low-temperature waste heat power generation system of the nanometer high magnetic conduction fluid of mixed phase;The system can improve low temperature heat efficiency, recycle more Industrial waste heat in temperature range, and electric energy is directly converted heat into, removal " thermal energy-mechanical energy-electric energy " energy conversion The intermediate of mode converts link;The system has a more efficient energy transformation ratio, lower low temperature heat range, more simply Compact structure design, the low taste heat resource power generation in addition to the fields such as cement, steel, thermoelectricity, ceramics and non-ferrous metal can be utilized, Also the generations of electricity by new energy such as solar energy, geothermal energy and sea water heat energy can be utilized.
The object of the present invention is achieved like this:
The present invention is significantly different with previous low-temperature cogeneration, is both different from carbon dioxide turbine cycle generating system, Different from general hydromagnetic generating device.Present invention incorporates nanotechnology, carbon dioxide to utilize technology and magnetic fluid technique, at Function develops the high magnetic conduction fluid of carbon dioxide-base nanometer, the mass-and heat-transfer object that on the one hand supercritical carbon dioxide can be utilized excellent Characteristic is managed, the work for providing excellent thermal cycle for low-temperature cogeneration device is situated between;On the other hand, nanoscale magnetic fluid with it is postcritical Carbon dioxide forms the high magnetic conduction fluid of mixed phase, and nanometer magnetofluid circulation, benefit are pushed in supercritical carbon dioxide Thermal Cycling With magnetic fluid flow process cutting magnetic induction coil to generate induced electromotive force.The device successfully avoided to machining and it is close The turbo-expander that envelope requires height to rely on, on the one hand, directly convert heat into electric energy, lacked required for carbon dioxide turbine This process of thermal energy-mechanical energy-electric energy of experience, so as to greatly improve thermo-electrically transformation efficiency;On the other hand, it is not required to Complicated turbo-expander manufacturing process is wanted, and magnetohydrodynamic generator is quiet, efficient, structure is simple, so as to greatly mention High environmental suitability and economy.
Specifically:
One, the low-temperature waste heat power generation system (abbreviation system) based on the high magnetic conduction fluid of carbon dioxide-base nanometer mixed phase
This system include valve, low temperature exhaust heat heat dump, stream of supercritical carbon dioxide move guide rail, hydromagnetic generating device, The high magnetic conduction fluid of radiator, solar energy heat absorbing device, tank body, carbon dioxide-base nanometer mixed phase and solar energy;
Its position and connection relationship are:
Low temperature exhaust heat heat dump, stream of supercritical carbon dioxide are moved guide rail, hydromagnetic generating device, radiator and solar energy and are inhaled It is whole that thermal is in turn connected to form closure;Tank body moves guide rail with stream of supercritical carbon dioxide by valve and is connected;
The high magnetic conduction fluid of carbon dioxide-base nanometer mixed phase is packaged in tank body
Solar energy heat absorbing device absorbs solar energy.
Two, high magnetic conduction fluid of carbon dioxide-base nanometer mixed phase and preparation method thereof
1, the high magnetic conduction fluid of carbon dioxide-base nanometer mixed phase
The component of the high magnetic conduction fluid of carbon dioxide-base nanometer mixed phase says by mass percentage, supercritical carbon dioxide: nanometer Grade metal MHD: carbon dioxide thickener: dispersing agent: stabilizer: oil-base fluid 40%:30%:5%:3%:2%:20%;
It is 5-8MPa that initial pressure, which is arranged, in supercritical carbon dioxide;
2, preparation method:
1. material mixes
Nano level metal magnetic fluid, carbon dioxide thickener, dispersing agent, stabilizer and oil-base fluid are mixed according to predetermined ratio It closes uniformly, and is stored in tank body 7;
2. injecting postcritical carbon dioxide
Postcritical carbon dioxide is injected to predetermined pressure;
3. fluid-mixing
It is to be mixed uniformly rear up to the high magnetic conduction fluid of carbon dioxide-base nanometer mixed phase.
The present invention has following advantages and good effect:
1. being situated between using postcritical carbon dioxide as circulation industrial, excellent physical characteristic makes the recyclable benefit of the system Low temperature exhaust heat temperature range is lower, and generating efficiency is higher;
2. utilizing the generation mode of carbon dioxide-base nanometer mixed phase magnetic fluid, electric energy is directly converted heat into, with previous Thermal energy-mechanical energy-electric energy transform mode is more directly and efficient;
3. structure is simple in the way of magnetohydrodynamic generator, machining, sealing etc. are easy to connect;
4. equipment operation is quiet, steady, it is suitable for controlling environmental noise in stringent region.
Detailed description of the invention
Fig. 1 is the structural schematic diagram of this system;
In figure:
1-valve;
2-low temperature exhaust heat heat dumps;
3-stream of supercritical carbon dioxide move guide rail;
4-hydromagnetic generating devices,
4-1-the pole kicker magnet S, 4-2-pole kicker magnet N, the 1st electrode of 4-3-, the 2nd electrode of 4-4-,
4-5-rail joint, 4-6-magnetic induction coil;
5-radiators;
6-solar energy heat absorbing devices;
7-tank bodies;
The high magnetic conduction fluid of A-carbon dioxide-base nanometer mixed phase;
B-solar energy.
Specific embodiment
It is described in detail with reference to the accompanying drawings and examples:
One, system
1, overall
This system includes valve 1, low temperature exhaust heat heat dump 2, stream of supercritical carbon dioxide moves guide rail 3, magnetohydrodynamic generator fills Set 4, radiator 5, solar energy heat absorbing device 6, tank body 7, carbon dioxide-base nanometer mixed phase high magnetic conduction fluid A and solar energy B;
Its position and connection relationship are:
Low temperature exhaust heat heat dump 2, stream of supercritical carbon dioxide move guide rail 3, hydromagnetic generating device 4, radiator 5 and the sun It is whole that energy heat sink 6 is in turn connected to form closure;Tank body 7 moves guide rail 3 with stream of supercritical carbon dioxide by valve 1 and is connected It is logical;
The high magnetic conduction fluid A of carbon dioxide-base nanometer mixed phase is packaged in tank body 7
Solar energy heat absorbing device 6 absorbs solar energy B.
2, functional component
1) valve 1
Valve 1 is a kind of common high pressure valve;
Its function is the high magnetic conduction fluid tank body 7 of control carbon dioxide-base nanometer and the dynamic guide rail 3 of stream of supercritical carbon dioxide Connected state.
2) low temperature exhaust heat heat dump 2
Low temperature exhaust heat heat dump 2 is a kind of copper heat-transfer device, for absorbing the heat with conduction heat sources;
Its function is that extraneous low temperature exhaust heat is conducted to the high magnetic conduction fluid of inside supercritical carbon dioxide-base nanometer mixed phase.
3) stream of supercritical carbon dioxide moves guide rail 3
Supercritical carbon dioxide guide rail 3 is a kind of high pressure resistant pipe being made by stainless steel material or aluminum alloy material Road;
Its function is encapsulation and the high magnetic conduction fluid of water conservancy diversion High-pressure supercritical carbon dioxide mixed phase.
4) hydromagnetic generating device 4
Hydromagnetic generating device 4 includes kicker magnet S pole 4-1, kicker magnet N pole 4-2, the 1st electrode 4-3, the 2nd electrode 4-4, leads Rail connector 4-5 and magnetic induction coil 4-6;
Its position and connection relationship are:
Magnetic induction coil 4-6 is provided between kicker magnet S pole 4-1 and kicker magnet N pole 4-2 parallel to each other;
The 1st electrode 4-3 and the 2nd electrode 4-4 are connected separately at the both ends of magnetic induction coil 4-6;
Rail joint 4-5 is connected between supercritical carbon dioxide guide rail 3 and magnetic induction coil 4-6.
Its function is will to pass through cutting magnetic induction in the high magnetic conduction fluid of swiftly flowing supercritical carbon dioxide nanometer mixed phase It answers coil 4-6 and is converted into power output.
* the pole kicker magnet S 4-1, kicker magnet N pole 4-2
Kicker magnet S pole 4-1, kicker magnet N pole 4-2 are a kind of strong magnets, for generating high-intensity magnetic field;
* the 1 electrode 4-3, the 2nd electrode 4-4
1st electrode 4-3, the 2nd electrode 4-4 are made of copper sheet;
Its function is to collect induced electromotive force as electrode.
* rail joint 4-5
Rail joint 4-5 is a kind of connector;Its function is by hydromagnetic generating device 4 and supercritical carbon dioxide guide rail 3 connect.
* magnetic induction loop 4-6
The screw mechanism that magnetic induction loop 4-6 is made of thin copper wire;
Its function is cutting magnetic induction line, generates induced electromotive force.
5) radiator 5
Radiator 5 is a kind of copper heat-transfer device, is used to discharge heat to low temperature environment;
Its function is by the waste heat of swiftly flowing high-temperature supercritical carbon dioxide miscible fluids further to low Warm Environment release, to further reduce own temperature and pressure.
6) solar energy heat absorbing device 6
Solar energy absorption plant 6 is a kind of heat-absorbing material for absorbing solar energy;
Its function is to absorb solar energy, so that its temperature increases, and high temperature is conducted to supercritical carbon dioxide.
7) tank body 7
Tank body 7 is a kind of high pressure resistant stainless steel sealed shell of tank;
Its function is the encapsulation high magnetic conduction fluid A of carbon dioxide-base nanometer mixed phase.
Two, the application method of this system
1. the tank body 7 for encapsulating the high magnetic conduction fluid A of carbon dioxide-base nanometer mixed phase is passed through valve 1 and low temperature exhaust heat heat dump 2 are connected to supercritical carbon dioxide guide rail 3, open valve 1, inject the high magnetic conduction fluid of carbon dioxide-base nanometer mixed phase to tank body 7 A, until predetermined pressure, closes valve 1;
2. extraneous low temperature exhaust heat is connected with heat dump 2, or solar energy B is recycled through solar energy absorption plant 6;
3. by radiator 5 with extraneous low temperature environment connection, so that waste heat is passed through the outwardly heat release of radiator 5;
4. induced electromotive force is formed in hydromagnetic generating device 4, electric energy is directly utilized or is connected with energy storage, Store electric energy.
Three, the working principle of this system
The high magnetic conduction fluid A of carbon dioxide-base nanometer mixed phase well prepared in advance is injected into supercritical carbon dioxide guide rail 3, two The high magnetic conduction fluid A of carbon-based nano mixed phase is aoxidized after low temperature exhaust heat heat dump 2 or solar energy absorption plant 6, temperature increases, So that postcritical pressure carbon dioxide is sharply increased and is expanded, with the postcritical dioxy condensed by radiator 5 Change carbon and form pressure difference, postcritical carbon dioxide quickly flows through hydromagnetic generating device 4, the nanoscale in flow process High magnetic conduction fluid is reinforced converging and formed the magnetic line of force under the action of magnetic field outside, and acts in postcritical carbon dioxide motive force Lower cutting magnetic induction coil 4-6, to form induced electromotive force between electrode 4-3 and electrode 4-4.

Claims (1)

1. a kind of low-temperature waste heat power generation system based on the high magnetic conduction fluid of carbon dioxide-base nanometer mixed phase,
Guide rail (3), hydromagnetic generating device are moved including valve (1), low temperature exhaust heat heat dump (2), stream of supercritical carbon dioxide (4), the high magnetic conduction fluid (A) of radiator (5), solar energy heat absorbing device (6), tank body (7), carbon dioxide-base nanometer mixed phase and the sun Energy (B);
Its position and connection relationship are:
Low temperature exhaust heat heat dump (2), stream of supercritical carbon dioxide move guide rail (3), hydromagnetic generating device (4), radiator (5) and It is whole that solar energy heat absorbing device (6) is in turn connected to form closure;Tank body (7) is dynamic by valve (1) and stream of supercritical carbon dioxide Guide rail (3) is connected;
The high magnetic conduction fluid (A) of carbon dioxide-base nanometer mixed phase is packaged in tank body (7);
Solar energy heat absorbing device (6) absorbs solar energy (B);
The hydromagnetic generating device (4) includes the pole kicker magnet S (4-1), the pole kicker magnet N (4-2), the 1st electrode (4-3), the 2nd Electrode (4-4), rail joint (4-5) and magnetic induction coil (4-6);
Its position and connection relationship are:
Magnetic induction coil (4-6) is provided between the pole kicker magnet S (4-1) and the pole kicker magnet N (4-2) parallel to each other;
The 1st electrode (4-3) and the 2nd electrode (4-4) are connected separately at the both ends of magnetic induction coil (4-6);
Rail joint (4-5) is connected to stream of supercritical carbon dioxide and moves between guide rail (3) and magnetic induction coil (4-6);
It is characterized by:
The high magnetic conduction fluid (A) of the carbon dioxide-base nanometer mixed phase is:
By mass percentage, supercritical carbon dioxide: nano level metal magnetic fluid: carbon dioxide thickener: dispersing agent: stablize Agent: oil-base fluid 40%:30%:5%:3%:2%:20%;
It is 5-8MPa that initial pressure, which is arranged, in supercritical carbon dioxide;
Preparation method is:
1. material mixes
Nano level metal magnetic fluid, carbon dioxide thickener, dispersing agent, stabilizer and oil-base fluid are mixed according to predetermined ratio It is even, and be stored in tank body (7);
2. injecting postcritical carbon dioxide
Postcritical carbon dioxide is injected to predetermined pressure;
3. fluid-mixing
It is to be mixed uniformly rear up to the high magnetic conduction fluid (A) of carbon dioxide-base nanometer mixed phase.
CN201710007019.2A 2017-01-05 2017-01-05 Low-temperature waste heat power generation system based on the high magnetic conduction fluid of carbon dioxide-base nanometer mixed phase Active CN106849607B (en)

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109274246A (en) * 2018-09-11 2019-01-25 技新(浙江)节能技术有限公司 A kind of low-temperature waste heat power generation system based on the high magnetic conduction fluid of carbon dioxide-base nanometer mixed phase
CN113037052B (en) * 2021-03-11 2022-04-22 中国科学院理化技术研究所 Multiphase thermoacoustic magnetohydrodynamic generator
CN115247227B (en) * 2022-07-18 2024-01-23 江苏士美机电装备有限公司 Automobile spare and accessory part processing device with waste heat recycling function

Citations (4)

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Publication number Priority date Publication date Assignee Title
CN101725489A (en) * 2009-12-03 2010-06-09 西安交通大学 Solar thermoelectricity combined utilization device
CN101800462A (en) * 2009-12-31 2010-08-11 浙江大学 Solar energy-driven magnetic fluid and steam turbine coupled power generating system
CN104578682A (en) * 2015-01-29 2015-04-29 东南大学 Method for closed-loop magnetic fluid power generation by making use of latent heat of vaporization and cyclic power generation system
CN105024522A (en) * 2015-07-27 2015-11-04 西安交通大学 Magnetohydrodynamic power generation system capable of directly converting heat energy into electric energy

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101725489A (en) * 2009-12-03 2010-06-09 西安交通大学 Solar thermoelectricity combined utilization device
CN101800462A (en) * 2009-12-31 2010-08-11 浙江大学 Solar energy-driven magnetic fluid and steam turbine coupled power generating system
CN104578682A (en) * 2015-01-29 2015-04-29 东南大学 Method for closed-loop magnetic fluid power generation by making use of latent heat of vaporization and cyclic power generation system
CN105024522A (en) * 2015-07-27 2015-11-04 西安交通大学 Magnetohydrodynamic power generation system capable of directly converting heat energy into electric energy

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