CN106836717B - Environmental protection glass floor made of a kind of post-consumer glass - Google Patents
Environmental protection glass floor made of a kind of post-consumer glass Download PDFInfo
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- CN106836717B CN106836717B CN201710100998.6A CN201710100998A CN106836717B CN 106836717 B CN106836717 B CN 106836717B CN 201710100998 A CN201710100998 A CN 201710100998A CN 106836717 B CN106836717 B CN 106836717B
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- 239000011521 glass Substances 0.000 title claims abstract description 103
- 230000007613 environmental effect Effects 0.000 title claims abstract description 13
- 230000000844 anti-bacterial effect Effects 0.000 claims abstract description 24
- 239000004744 fabric Substances 0.000 claims abstract description 15
- 239000011347 resin Substances 0.000 claims abstract description 11
- 229920005989 resin Polymers 0.000 claims abstract description 11
- 238000009413 insulation Methods 0.000 claims abstract description 7
- 239000000243 solution Substances 0.000 claims description 29
- 238000005260 corrosion Methods 0.000 claims description 22
- 230000007797 corrosion Effects 0.000 claims description 22
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 19
- 239000011248 coating agent Substances 0.000 claims description 19
- 238000000576 coating method Methods 0.000 claims description 19
- HNDVDQJCIGZPNO-YFKPBYRVSA-N L-histidine Chemical compound OC(=O)[C@@H](N)CC1=CN=CN1 HNDVDQJCIGZPNO-YFKPBYRVSA-N 0.000 claims description 18
- 239000000758 substrate Substances 0.000 claims description 16
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 15
- 239000003292 glue Substances 0.000 claims description 12
- 239000004005 microsphere Substances 0.000 claims description 11
- 239000012498 ultrapure water Substances 0.000 claims description 10
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 9
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 9
- 229960002885 histidine Drugs 0.000 claims description 9
- 238000003756 stirring Methods 0.000 claims description 9
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 8
- 239000000463 material Substances 0.000 claims description 8
- 229910052757 nitrogen Inorganic materials 0.000 claims description 8
- 239000000377 silicon dioxide Substances 0.000 claims description 8
- 239000002109 single walled nanotube Substances 0.000 claims description 8
- 239000011787 zinc oxide Substances 0.000 claims description 8
- 239000007788 liquid Substances 0.000 claims description 7
- 238000000034 method Methods 0.000 claims description 7
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 6
- 238000005299 abrasion Methods 0.000 claims description 6
- 238000005119 centrifugation Methods 0.000 claims description 6
- 229910052681 coesite Inorganic materials 0.000 claims description 6
- 229910052906 cristobalite Inorganic materials 0.000 claims description 6
- 238000010438 heat treatment Methods 0.000 claims description 6
- 238000003760 magnetic stirring Methods 0.000 claims description 6
- 238000002360 preparation method Methods 0.000 claims description 6
- 238000004062 sedimentation Methods 0.000 claims description 6
- 235000012239 silicon dioxide Nutrition 0.000 claims description 6
- 238000004528 spin coating Methods 0.000 claims description 6
- 229910052682 stishovite Inorganic materials 0.000 claims description 6
- 239000000725 suspension Substances 0.000 claims description 6
- 229910052905 tridymite Inorganic materials 0.000 claims description 6
- 229910021642 ultra pure water Inorganic materials 0.000 claims description 6
- 239000002105 nanoparticle Substances 0.000 claims description 5
- 229910001868 water Inorganic materials 0.000 claims description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 4
- 239000007864 aqueous solution Substances 0.000 claims description 4
- 239000002041 carbon nanotube Substances 0.000 claims description 4
- 229910021393 carbon nanotube Inorganic materials 0.000 claims description 4
- 230000036541 health Effects 0.000 claims description 4
- 239000003112 inhibitor Substances 0.000 claims description 4
- 239000006210 lotion Substances 0.000 claims description 4
- 238000006116 polymerization reaction Methods 0.000 claims description 4
- 238000006243 chemical reaction Methods 0.000 claims description 3
- 229920001971 elastomer Polymers 0.000 claims description 3
- 239000003365 glass fiber Substances 0.000 claims description 3
- 238000005498 polishing Methods 0.000 claims description 3
- 230000008569 process Effects 0.000 claims description 3
- 238000012545 processing Methods 0.000 claims description 3
- 239000000741 silica gel Substances 0.000 claims description 3
- 229910002027 silica gel Inorganic materials 0.000 claims description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 3
- 238000005303 weighing Methods 0.000 claims description 3
- -1 2- methyl-propyl amidine Chemical class 0.000 claims description 2
- AGSFLAWGTNCBFT-UHFFFAOYSA-N C(CC)[SiH2]OC.[O].C(C1CO1)OCC1CO1 Chemical compound C(CC)[SiH2]OC.[O].C(C1CO1)OCC1CO1 AGSFLAWGTNCBFT-UHFFFAOYSA-N 0.000 claims description 2
- 244000137852 Petrea volubilis Species 0.000 claims description 2
- 239000004793 Polystyrene Substances 0.000 claims description 2
- 238000013019 agitation Methods 0.000 claims description 2
- 238000007664 blowing Methods 0.000 claims description 2
- 238000009833 condensation Methods 0.000 claims description 2
- 230000005494 condensation Effects 0.000 claims description 2
- 238000007598 dipping method Methods 0.000 claims description 2
- 238000000703 high-speed centrifugation Methods 0.000 claims description 2
- 238000002347 injection Methods 0.000 claims description 2
- 239000007924 injection Substances 0.000 claims description 2
- 239000000203 mixture Substances 0.000 claims description 2
- 239000000178 monomer Substances 0.000 claims description 2
- 239000012299 nitrogen atmosphere Substances 0.000 claims description 2
- 239000002245 particle Substances 0.000 claims description 2
- 239000005011 phenolic resin Substances 0.000 claims description 2
- 229920002223 polystyrene Polymers 0.000 claims description 2
- 230000001376 precipitating effect Effects 0.000 claims description 2
- 238000010992 reflux Methods 0.000 claims description 2
- 238000000926 separation method Methods 0.000 claims description 2
- 238000005406 washing Methods 0.000 claims description 2
- 239000003643 water by type Substances 0.000 claims description 2
- 238000001035 drying Methods 0.000 claims 2
- 206010013786 Dry skin Diseases 0.000 claims 1
- 150000001336 alkenes Chemical class 0.000 claims 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 claims 1
- 239000004816 latex Substances 0.000 claims 1
- 229920000126 latex Polymers 0.000 claims 1
- 239000011806 microball Substances 0.000 claims 1
- 229920006389 polyphenyl polymer Polymers 0.000 claims 1
- 239000002994 raw material Substances 0.000 abstract description 4
- 238000004519 manufacturing process Methods 0.000 abstract description 2
- 230000009967 tasteless effect Effects 0.000 abstract description 2
- 229910001385 heavy metal Inorganic materials 0.000 abstract 1
- 238000009434 installation Methods 0.000 abstract 1
- 230000005855 radiation Effects 0.000 abstract 1
- 229960001296 zinc oxide Drugs 0.000 description 5
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 4
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
- 230000001408 fungistatic effect Effects 0.000 description 3
- 230000008439 repair process Effects 0.000 description 3
- 230000004044 response Effects 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- 241000894006 Bacteria Species 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- 241000588724 Escherichia coli Species 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- 238000002835 absorbance Methods 0.000 description 2
- 230000002528 anti-freeze Effects 0.000 description 2
- 238000005034 decoration Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 239000011780 sodium chloride Substances 0.000 description 2
- 239000010959 steel Substances 0.000 description 2
- 230000001629 suppression Effects 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 229940024606 amino acid Drugs 0.000 description 1
- 150000001413 amino acids Chemical class 0.000 description 1
- 230000000845 anti-microbial effect Effects 0.000 description 1
- 230000000840 anti-viral effect Effects 0.000 description 1
- 230000002155 anti-virotic effect Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 230000000959 cryoprotective effect Effects 0.000 description 1
- 230000003111 delayed effect Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000005284 excitation Effects 0.000 description 1
- 238000009408 flooring Methods 0.000 description 1
- 231100001261 hazardous Toxicity 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 239000004579 marble Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 238000005728 strengthening Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Classifications
-
- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04F—FINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
- E04F15/00—Flooring
- E04F15/02—Flooring or floor layers composed of a number of similar elements
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B15/00—Layered products comprising a layer of metal
- B32B15/18—Layered products comprising a layer of metal comprising iron or steel
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B3/00—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form
- B32B3/10—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by a discontinuous layer, i.e. formed of separate pieces of material
- B32B3/12—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by a discontinuous layer, i.e. formed of separate pieces of material characterised by a layer of regularly- arranged cells, e.g. a honeycomb structure
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B33/00—Layered products characterised by particular properties or particular surface features, e.g. particular surface coatings; Layered products designed for particular purposes not covered by another single class
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/70—Other properties
- B32B2307/714—Inert, i.e. inert to chemical degradation, corrosion
- B32B2307/7145—Rot proof, resistant to bacteria, mildew, mould, fungi
Landscapes
- Engineering & Computer Science (AREA)
- Architecture (AREA)
- Civil Engineering (AREA)
- Structural Engineering (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
- Laminated Bodies (AREA)
Abstract
This application involves environmental protection glass floors made of a kind of post-consumer glass, including anticorrosion antiwear layer, antibacterial freeze proof layer, glass, fire-proof sound insulation layer, waterproof layer, reinforced mesh, grid cloth, resin layer, base and finger pressure layer.The present invention uses raw material of the post-consumer glass as floor, and glass is a kind of raw material colorless and transparent, tasteless, without heavy metal and radiation, so itself is safe and reliable, the structure of the application is simply and production installation is more convenient.
Description
Technical field
This application involves environmental protection glass floors made of technical field of floor more particularly to a kind of post-consumer glass.
Background technique
Currently, especially flooring decoration is based on ceramic tile, marble and wood floors in building decoration area.So
And there is the also harmful substance such as formaldehyde in these above-mentioned ornament materials colors, hang up one's hat in these environment, to human body
Health cause it is potentially hazardous.
Summary of the invention
To solve the problems, such as above-mentioned background technique, the application is with providing environmental protection glass made of a kind of post-consumer glass
Plate.
Provide environmental protection glass floor made of a kind of post-consumer glass in the embodiment of the present invention, including anticorrosion antiwear layer,
Antibacterial freeze proof layer, glass, fire-proof sound insulation layer, waterproof layer, reinforced mesh, grid cloth, resin layer, base and finger pressure layer；The glass
The anticorrosion antiwear layer and the antibacterial freeze proof layer are sequentially coated with respectively from top to bottom above glass；Successively divide below the glass
It is not laid with the fire-proof sound insulation layer and the waterproof layer；It is the reinforced mesh, the reinforced mesh below the waterproof layer
Lower section is the grid cloth, and cloth is set as the resin layer below the grid cloth, is the base below the resin layer；Its
In, it is additionally provided with the finger pressure layer above the glass, the finger pressure layer is made of silica gel and glass fiber material, plays massage
The effect of health care.
The technical solution that embodiments herein provides can include the following benefits:
Compared with the existing technology, beneficial effects of the present invention:
1, the present invention uses raw material of the post-consumer glass as floor, and glass is that one kind is colorless and transparent, tasteless, is free of a huge sum of money
The raw material for belonging to and radiating, so itself is safe and reliable, the structure of the application is simply installed with production more convenient.By
The surface of glass floor is coated with anticorrosion antiwear layer, prevents and delayed the corrosion of glass floor, and have freeze proof antibacterial work
With；It is that hollow mesoporous silica microsphere adsorbs amino acid and carbon nanotube in the coating that the surface of glass coats, in glass
The surface of plate forms intelligent response layer, and when the surface of glass floor is by corroding, intelligent response layer film can sense glass
PH value ion (the H of glass floor surface+Or OH-) concentration variation, the L-Histidine adsorbed in hollow mesoporous silica microsphere
Corrosion inhibiter and carbon nanotube, which flow out voluntarily excitation, repairs in substrate by the place corroded, and extends the use of glass floor
Service life has saved the cost generated and rehabilitation cost, meanwhile, a large amount of manpower and material resources are also saved, therefore, the application has good
Good business use value.
2, the present invention is also laid with reinforced mesh on the surface of glass and grid cloth is used cooperatively, and enhances glass floor sheet
While the mechanical strength of body, steel are also ad save, protect environment, save the cost, non-ignitable rank is high, therefore, Environmental Safety.
3, the present invention is during the preparation process, simple and easy for the polishing mode of glass surface, not only increases glass table
The roughness in face increases the contact area of substrate and coating, and then extends the out-of-service time of coating, it is ensured that glass floor
Long-time service life.
4, the present invention is also coated with antibacterial freeze proof layer on glass floor, has zinc-oxide nano in the antibacterial freeze proof layer
Grain, antibacterium and antiviral effect due to Zinc oxide nanoparticle are combined with intelligent response layer, not only realize intelligence
It repairs, also adds the service life and anti-bacteria and anti-virus performance of glass floor.
5, the glass pretreatment mode of the application use and the reagent for preparing film use have environmentally protective performance,
Product withdraw not will cause the secondary pollution of environment into environment, therefore be a kind of generation technique of green.
Detailed description of the invention
Fig. 1 is structural schematic diagram of the invention.
Fig. 2 is the cross-sectional view of Fig. 1.
Fig. 3 is corrosion-resistant painting in a kind of environmentally friendly glass for substation of the application shown according to an exemplary embodiment
The preparation method flow chart of material.
Wherein: 1- anticorrosion antiwear layer, the antibacterial freeze proof layer of 2-, 3- glass, 4- fire-proof sound insulation layer, 5- waterproof layer, 6- steel mesh
Piece, 7- grid cloth, 8- resin layer, 9- base, 10- finger pressure layer.
Specific embodiment
Figures 1 and 2 show that environmental protection glass floor made of a kind of post-consumer glass that embodiments herein is related to.Such as figure
1 to shown in Fig. 2, including anticorrosion antiwear layer 1, antibacterial freeze proof layer 2, glass 3, fire-proof sound insulation layer 4, waterproof layer 5, reinforced mesh 6, net
Lattice cloth 7, resin layer 8, base 9 and finger pressure layer 10.3 top of glass is sequentially coated with anticorrosion antiwear layer 1 and suppression respectively from top to bottom
The freeze proof layer 2 of bacterium.3 lower section of glass is successively laid with fire-proof sound insulation layer 4 and waterproof layer 5 respectively；It is reinforced mesh 6 below waterproof layer 5,
It is grid cloth 7 below reinforced mesh 6, it is base 9 below resin layer 8 that 7 lower section cloth of grid cloth, which is set as resin layer 8,；Wherein, glass 3
Top is additionally provided with finger pressure layer 10, which is made of silica gel and glass fiber material, plays the role of health care massage.
The application is coated with corrosion resistant coating on the surface of the environmentally friendly glass floor, enhance the wear-resisting of glass floor and
Corrosion resistance can prevent the corrosion of environmentally friendly glass, and can intelligently repair, cryoprotective effects it is good.
Further, the anticorrosion antiwear layer 1 is coated by corrosion-resistant abrasion coating, with a thickness of 10~100 μm；Suppression
The freeze proof layer 2 of bacterium in corrosion-resistant abrasion coating by adding isopropanol material and coating, with a thickness of 10~50 μm.Some
In other embodiments, the anticorrosion antiwear layer 1 with a thickness of 50~80 μm；The antibacterial freeze proof layer 2 with a thickness of 20~40 μ
m.In the present embodiment, the anticorrosion antiwear layer 1 with a thickness of 65 μm；The antibacterial freeze proof layer 2 with a thickness of 30 μm.
Further, Nano-ZnO particle is contained in the corrosion-resistant abrasion coating used in the anticorrosion antiwear layer 1.
Further, isopropanol and hollow mesoporous SiO2- carbon nanotube microballoon are contained in the antibacterial freeze proof layer 2.
Further, the anticorrosion antiwear layer 1 and antibacterial freeze proof layer 2 coated on environmentally friendly glass floor described herein is logical
Technical solution as shown in Figure 3 is crossed to be able to be prepared and realize.
A. glass substrate pre-processes: the hydrochloric acid solution of 0.5mol/L is prepared, by wherein 100~120 points of glass substrate dipping
Clock polishes to the surface of glass after taking-up, and polishing successively uses 16 mesh, 80 mesh and 800 mesh sand paper, using 60wt% hydrogen-oxygen
Change sodium solution to impregnate 120 minutes, then uses hot water injection 10 minutes of 80 DEG C, dried up using blowing apparatus；By by glass
Surface is polished into the mode of rough surface, and the surface of glass is showed to rough surface, increases the roughness of glass surface, increases
Contact area that is big and strengthening glass and coating, and then extend the out-of-service time of coating；
B. the preparation of hollow mesoporous SiO2 microballoon:
I. it prepares 10wt% sodium hydroxide solution and washs C8H8Monomer removes polymerization inhibitor with separatory funnel liquid separation, is repeated 3 times,
Then with ultrapure water to pH=6.8~7.5；
0.20g C is dissolved in II.80mL ultrapure water15H34NCl loads onto reflux condensation mode system, leads to nitrogen, is added dropwise dropwise
8g is through step I treated C8H8, 40 DEG C magnetic agitation 60 minutes, be added 5wt%2, the water of 2'- azo (2- methyl-propyl amidine)
It 25 milliliters of solution, is subsequently placed in 50 DEG C of vacuum oven 5 minutes, continues magnetic force heating stirring after taking-up, heating temperature is
50 DEG C and polymerization reaction 24 hours in N2 atmosphere are placed in, obtain polystyrene rubber microspheres solution；
III. N, N are weighed, N- trimethyl -1- cetyl ammonium bromide 1.0g is dissolved in 49 ml deionized waters, adds
The dense NH of 10g EtOH, 1.0mL3·H2O, revolving speed be 1000rpm/min magnetic stirring apparatus on stir 10 minutes；Then 10g is gathered
Styrene rubber microballoon lotion is added dropwise above-mentioned N dropwise, N, in N- trimethyl -1- cetyl ammonium bromide mixed liquor, ultrasonic disperse
0.5 hour, 4.5gCH is added dropwise3CH2OSi(OCH2CH3)3, magnetic stirring apparatus temperature is risen to 45 DEG C, it is small persistently to stir 10
When；
IV. centrifugal sedimentation handles resulting lotion through step III, and centrifugal sedimentation speed is set as 9000 revs/min, centrifugation
The temperature of sedimentation is 0~3 DEG C, and after precipitating is using EtOH washing, repeated centrifugation is washed 5 times, vacuum oven 50KPa, 40 DEG C it is dry
Dry 3 hours, desciccate was calcined 5 hours for 1400 DEG C in Muffle furnace；
C. corrosion inhibitor solution is prepared: being weighed hollow mesoporous SiO2 microballoon 0.5g made from step B, is dissolved in L-Histidine saturation
In aqueous solution, ultrasonic disperse 0.25 hour；Weighing 0.60mg SWCNTs, to be dissolved in ultrasonic disperse 0.25 in 0.01L ultrapure water small
When, then SWCNTs solution is added into the L-Histidine aqueous solution of mesoporous SiO2 microballoon hollow containing in, then at 25 ± 5 DEG C
Vacuum oven in 0.4~0.55MPa negative reaction 24 hours, vacuum cooled high speed centrifugation, centrifuging temperature is 1~2 DEG C,
Centrifugal speed is 8000 revs/min, and centrifugation gained, which is deposited in 80 DEG C of vacuum tanks, to be dried overnight to get L-Histidine has been adsorbed
Hollow mesoporous SiO2-SWCNTs microballoon；
D. prepared by glass substrate coating liquid:
The first, prepared by solution A: 0.02 liter of CH being added in 0.08 liter of ultrapure water3OH is placed on magnetic stirring apparatus and adds for 40 DEG C
Heat, 100rpm/min stir 5min, are slowly added to glycidyl ether oxygen propyl-methoxy silane, and 0.1M HCl adjusts pH to 6.1
~6.8,10min is stirred at room temperature；
The second, prepared by solution B: 35 milliliters of (CH3)21.0mg Zinc oxide nanoparticle is added in CHOH, 50 DEG C of sides of water-bath add
Hot side is stirred 0.5 hour and is uniformly mixed；The antifreeze isopropanol of addition ensure that in machine of the temperature compared with coating under low environment
Tool is good；
Third will mix in solution B addition solution A, obtain substrate coating liquid；
E. microsphere suspensions are prepared: weighing 0.1g through having adsorbed the hollow mesoporous SiO2- of L-Histidine made from step C
SWCNTs microballoon is dissolved in 0.1 liter of ultrapure water, is stirred at room temperature 10 minutes, and 0.3g phenol resin solution, stirring 10 is then added dropwise
Minute, obtain microsphere suspensions；
F. drop glue forms a film: the microsphere suspensions prepared in step E are added dropwise dropwise by the way of dripping glue through processing of step A
In the glass substrate crossed, the speed for dripping glue is 800 revolutions per seconds, and the drop glue time is 4 seconds, and spin coating speed is 800 revolutions per seconds, spin coating 20
Second, it repeats to drip glue and spin coating 4 times；The glass substrate for having dripped glue is placed in 100 DEG C of baking oven and is dried overnight, forms anticorrosion antiwear
Layer；
G. Best-Effort request forms a film: the solution configured in step D is coated on by the way of Best-Effort request by step F
On the glass of reason, glass substrate is placed in baking oven and is heated 8 minutes for 130 DEG C, forms transparent freeze proof layer in glass surface.
Experiment test: environmental protection glass floor made of a kind of post-consumer glass described herein is tested for the property: general
The glass floor of uncoated anticorrosion antiwear layer is as blank control；By the glass of blank control glass floor and coating anticorrosion antiwear layer
Glass floor, which is placed in the sodium chloride solution of 1.0 mol/Ls, impregnates, after different time corrosion test, two kinds of glass floors
Electrochemical parameter is as shown in Table 1 and Table 2.
The corrosion potentials value (unit: mv) of 1 two kinds of glass floors of table
| 1 hour | 12 hours | 24 hours | 48 hours | 72 hours | |
| Blank control | -982.00 | -1042.32 | -1500.10 | -2015.26 | -2089.56 |
| The application | -369.12 | -412.21 | -399.56 | -500.78 | -600.89 |
Corrosion electric current density value (the unit: nA/cm of 2 two kinds of glass floors of table2)
| 1 hour | 12 hours | 24 hours | 48 hours | 72 hours | |
| Blank control | 5600.00 | 6800.22 | 7856.32 | 8900.56 | 9000.78 |
| The application | 15.30 | 15.30 | 17.20 | 19.21 | 50.26 |
It can be seen that the corrosion electric current density of the glass floor of blank control with corrosion potentials from the end value of Tables 1 and 2
Increase and increased dramatically, illustrate that the glass floor as blank control is substantial in sodium chloride solution.And this
Invention is compared with the glass floor of blank control, and with the increase of corrosion potentials, corrosion electric current density increasess slowly, and illustrates this
The corrosion reaction of the application glass floor occurs more slow, or even will not corrode within a certain period of time.
The anti-microbial property test of glass floor described herein: absorbance method is used, glass described herein is detected
Fungistatic effect of the floor to Escherichia coli.The results are shown in Table 3.
Antibacterial absorbance value of 3 glass floor of table to Escherichia coli
Experiments have shown that glass floor described herein has significant fungistatic effect, this in preparation the application process
In be added to that Zinc oxide nanoparticle is related in the antibacterial freeze proof layer that is coated on glass floor, due to Zinc oxide nanoparticle
Addition, so that the glass floor has fungistatic effect.Moreover, it has been found that glass floor described herein its at -10 DEG C, resist
Corrosive effect difference is obvious, this in antibacterial freeze proof layer during the preparation process be added with (CH3)2CHOH antifreeze is related.
It should be understood that the present invention is not limited to the precise structure already described above and shown in the accompanying drawings, and
And various modifications and changes may be made without departing from the scope thereof.The scope of the present invention is limited only by the attached claims.
Claims (4)
1. environmental protection glass floor made of a kind of post-consumer glass, which is characterized in that including anticorrosion antiwear layer, antibacterial freeze proof layer, glass
Glass, fire-proof sound insulation layer, waterproof layer, reinforced mesh, grid cloth, resin layer, base and finger pressure layer；Above the glass from top to bottom
It is sequentially coated with the anticorrosion antiwear layer and the antibacterial freeze proof layer respectively；It is successively laid with respectively below the glass described anti-
Fire screen sound-absorbing layer and the waterproof layer；It is the reinforced mesh below the waterproof layer, is the grid below the reinforced mesh
Cloth, grid cloth lower section cloth are set as the resin layer, are the base below the resin layer；Wherein, above the glass
It is additionally provided with the finger pressure layer, the finger pressure layer is made of silica gel and glass fiber material, plays the role of health care massage；It is described
Anticorrosion antiwear layer is coated by corrosion-resistant abrasion coating；The antibacterial freeze proof layer in corrosion-resistant abrasion coating by adding isopropyl
It alcohol material and coats；Contain nano zinc oxide particles in the corrosion-resistant abrasion coating used in the anticorrosion antiwear layer；Institute
Contain isopropanol and hollow mesoporous SiO2- carbon nanotube microballoon in the antibacterial freeze proof layer stated；It is applied on the environmentally friendly glass floor
The anticorrosion antiwear layer and antibacterial freeze proof layer covered is prepared by following steps:
A. glass substrate pre-processes: preparing the hydrochloric acid solution of 0.5mol/L, glass substrate dipping wherein 100~120 minutes take
It polishes after out the surface of glass, polishing successively uses 16 mesh, 80 mesh and 800 mesh sand paper, using 60wt% sodium hydroxide
Solution impregnates 120 minutes, then uses hot water injection 10 minutes of 80 DEG C, is dried up using blowing apparatus；
B. the preparation of hollow mesoporous SiO2 microballoon:
I. it prepares 10wt% sodium hydroxide solution and washs C8H8Monomer removes polymerization inhibitor with separatory funnel liquid separation, is repeated 3 times, then
With ultrapure water to pH=6.8~7.5；
0.20g C is dissolved in II.80mL ultrapure water15H34NCl loads onto reflux condensation mode system, leads to nitrogen, and 8g is added dropwise dropwise through step
Rapid I treated C8H8, 40 DEG C magnetic agitation 60 minutes, be added 5wt%2, the aqueous solution 25 of 2'- azo (2- methyl-propyl amidine)
Milliliter, be subsequently placed in 50 DEG C of vacuum oven 5 minutes, after taking-up continue magnetic force heating stirring, heating temperature be 50 DEG C and
Polymerization reaction 24 hours in N2 atmosphere are placed in, polystyrene rubber microspheres solution is obtained；
III. N, N are weighed, N- trimethyl -1- cetyl ammonium bromide 1.0g is dissolved in 49 ml deionized waters, adds 10g
The dense NH of EtOH, 1.0mL3·H2O, revolving speed be 1000rpm/min magnetic stirring apparatus on stir 10 minutes；Then by 10g polyphenyl second
Alkene latex microspheres lotion is added dropwise above-mentioned N dropwise, N, and in N- trimethyl -1- cetyl ammonium bromide mixed liquor, ultrasonic disperse 0.5 is small
When, 4.5g CH is added dropwise3CH2OSi(OCH2CH3)3, magnetic stirring apparatus temperature is risen to 45 DEG C, is persistently stirred 10 hours；
IV. centrifugal sedimentation handles resulting lotion through step III, and centrifugal sedimentation speed is set as 9000 revs/min, centrifugal sedimentation
Temperature be 0~3 DEG C, precipitating using EtOH washing after, repeated centrifugation wash 5 times, vacuum oven 50KPa, 40 DEG C of dryings 3 are small
When, desciccate is calcined 5 hours for 1400 DEG C in Muffle furnace；
C. corrosion inhibitor solution is prepared: weighing hollow mesoporous SiO2 microballoon 0.5g made from step B, it is water-soluble to be dissolved in L-Histidine saturation
In liquid, ultrasonic disperse 0.25 hour；It weighs 0.60mg SWCNTs and is dissolved in ultrasonic disperse 0.25 hour in 0.01L ultrapure water, so
SWCNTs solution is added into the L-Histidine aqueous solution of mesoporous SiO2 microballoon hollow containing in afterwards, it is then true at 25 ± 5 DEG C
In 0.4~0.55MPa negative reaction 24 hours in empty drying box, vacuum cooled high speed centrifugation, centrifuging temperature is 1~2 DEG C, centrifugation
Speed is 8000 revs/min, and centrifugation gained, which is deposited in 80 DEG C of vacuum tanks, to be dried overnight to get the hollow of L-Histidine has been adsorbed
Mesoporous SiO2-SWCNTs microballoon；
D. prepared by glass substrate coating liquid:
The first, prepared by solution A: 0.02 liter of CH being added in 0.08 liter of ultrapure water3OH, be placed on magnetic stirring apparatus 40 DEG C of heating,
100rpm/min stirs 5min, is slowly added to glycidyl ether oxygen propyl-methoxy silane, 0.1M HCl adjust pH to 6.1~
6.8,10min is stirred at room temperature；
The second, prepared by solution B: 35 milliliters of (CH3)21.0mg Zinc oxide nanoparticle is added in CHOH, 50 DEG C of water-bath in heating
It is stirred 0.5 hour and is uniformly mixed；
Third will mix in solution B addition solution A, obtain substrate coating liquid；
E. microsphere suspensions are prepared: weigh 0.1g adsorbed made from step C L-Histidine hollow mesoporous SiO2-SWCNTs it is micro-
Ball is dissolved in 0.1 liter of ultrapure water, is stirred at room temperature 10 minutes, 0.3g phenol resin solution is then added dropwise, stir 10 minutes, obtain
To microsphere suspensions；
F. drop glue film forming: the microsphere suspensions prepared in step E are added dropwise dropwise by the way of dripping glue and are being crossed through processing of step A
In glass substrate, the speed for dripping glue is 800 revolutions per seconds, and the drop glue time is 4 seconds, and spin coating speed is 800 revolutions per seconds, spin coating 20 seconds, heavy
Glue and spin coating 4 times are dripped again；The glass substrate for having dripped glue is placed in 100 DEG C of baking oven and is dried overnight, forms anticorrosion antiwear layer；
G. Best-Effort request forms a film: the solution configured in step D is coated on by step F processing by the way of Best-Effort request
On glass, glass substrate is placed in baking oven and is heated 8 minutes for 130 DEG C, forms transparent freeze proof layer in glass surface.
2. environmental protection glass floor according to claim 1, which is characterized in that the anticorrosion antiwear layer with a thickness of 10~
100μm；The antibacterial freeze proof layer with a thickness of 10~50 μm.
3. it is according to claim 2 environmental protection glass floor, which is characterized in that the anticorrosion antiwear layer with a thickness of 50~80
μm；The antibacterial freeze proof layer with a thickness of 20~40 μm.
4. it is according to claim 3 environmental protection glass floor, which is characterized in that the anticorrosion antiwear layer with a thickness of 65 μm；
The antibacterial freeze proof layer with a thickness of 30 μm.
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| CN201710100998.6A CN106836717B (en) | 2017-02-23 | 2017-02-23 | Environmental protection glass floor made of a kind of post-consumer glass |
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| CN201710100998.6A CN106836717B (en) | 2017-02-23 | 2017-02-23 | Environmental protection glass floor made of a kind of post-consumer glass |
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| CN106836717B true CN106836717B (en) | 2019-01-15 |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| US10494822B2 (en) * | 2014-07-07 | 2019-12-03 | Zhangjiagang Elegant Plastics Co., Ltd. | Elastic plastic floor which is with the functions of moisture proof and sound insulation, and its production method |
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|---|---|---|---|---|
| EP2088131A1 (en) * | 2006-10-16 | 2009-08-12 | Nippon Sheet Glass Company Limited | Antibacterial substratum and process for producing the same |
| JP2010018458A (en) * | 2008-07-08 | 2010-01-28 | Sanshiba Shozai Kk | Plate glass |
| JP2010168873A (en) * | 2009-01-20 | 2010-08-05 | Juko:Kk | Heat-generating floor member |
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| CN205502483U (en) * | 2016-03-31 | 2016-08-24 | 上海傲胜科创实业有限公司 | Antiseptic floor |
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| CN106836717A (en) | 2017-06-13 |
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