CN106835836A - A kind of paper wood sealing wax and preparation method thereof - Google Patents
A kind of paper wood sealing wax and preparation method thereof Download PDFInfo
- Publication number
- CN106835836A CN106835836A CN201710093772.8A CN201710093772A CN106835836A CN 106835836 A CN106835836 A CN 106835836A CN 201710093772 A CN201710093772 A CN 201710093772A CN 106835836 A CN106835836 A CN 106835836A
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- China
- Prior art keywords
- paper wood
- sealing wax
- agent
- wood sealing
- thickener
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Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/10—Coatings without pigments
- D21H19/14—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12
- D21H19/24—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12 comprising macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/10—Coatings without pigments
- D21H19/14—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/10—Coatings without pigments
- D21H19/14—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12
- D21H19/18—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12 comprising waxes
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/10—Coatings without pigments
- D21H19/14—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12
- D21H19/20—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12 comprising macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
- D21H21/36—Biocidal agents, e.g. fungicidal, bactericidal, insecticidal agents
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Paper (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses a kind of paper wood sealing wax and preparation method thereof, the paper wood includes the following component of following percentage by weight with sealing wax:AA emulsion 45 75%, pH adjusting agent 0.4 0.7%, defoamer 0.1 0.5%, nano silicon dioxide dispersion 0 15%, emulsified wax 0 20%, flatting silica 0 4%, coalescents 2 5%, wetting agent 0.1 0.5%, levelling agent 0.1 0.5%, anticorrosion and bactericidal agent 0.1 0.5%, thickener 0.1 1.2%, deionized water 6 16%.Coating of the invention easily increases thickness, and the transparency is good, and coating surface is smooth, and hardness is good, with the printing that excellent corrosion resistance, resistance to chalking, wearability are become reconciled.
Description
Technical field
The present invention relates to paper wood matter sealing wax field, more particularly to a kind of paper wood sealing wax and preparation method thereof.
Background technology
In various product packaging, the ratio shared by packaging paper product is maximum.For example:Carton, carton, paper bag, fiber drum, honeybee
Nest cardboard etc., with it is widely used, easily reclaim cycling and reutilization, meet environmental requirement and be considered as green package, enjoy people's
Favor.But paper wrapper material is afraid of wet fragile, and to storing and using very big inconvenience is brought, loss is serious.But if making
With paint for papers, so that it may be avoided that these lose.Paper surface apply a coating so as to make it have prevent water, water vapour,
Oxygen and fat migration, prevent the aroma and flavor of food from changing, the advantages of acid-proof, alkali or organic solvent.In paper surface shape
Into one layer of special coating structure, the friction between paper can be reduced, increase the service life of packaging.
It is solvent type coating that overwhelming majority paper wrapper corporate boss will use at present.As people are to environment and the day of health
Benefit is paid attention to, and water paint is increasingly widely applied, and traditional solvent-borne coating is released during production and use
The pollution that the volatile organic content (VolatileOrganic Compounds, VOC) put is produced, turns into come automobile at present
City primary pollution source afterwards, with the constantly improve and sound, forced use environment-friendly type work of Environmental Protection in China laws and regulations
Industry coating has become trend of the times.And aqueous industrial coating is used as the prior development direction of environment-friendly type coating, in paper wood matter row
Application in industry has boundless market.Water paint, it is not only environmentally friendly using water as solvent, and can be compared to molten
Agent coating price is cheap.But current water paint prints ability and caking property again due to what the presence of water can not only reduce carton,
And influence carton is attractive in appearance firm.It is the environmental protection act and the Policy Conditions of energy-saving and emission-reduction of response country, for paper wood matter
Coating specification, develop the discharge of a low VOC (VOC), quick-drying and the aqueous industrial coating of function admirable and with
Propulsion water paint product makes the moisture effect of packaging paper product more preferably in the extensive use in packaging paper product field, and cost is more
Low, economic benefit is significantly significant.
Existing aqueous paper wood matter coating exist low hardness, poor water resistance, dry it is slow, reduce base material caking property, robustness
Problem.
At present, a kind of paper wood sealing wax with excellent anticorrosive wear-resistant and preparation method thereof is lacked.
The content of the invention
Regarding the issue above, the present invention provides a kind of paper wood sealing wax with excellent anticorrosive wear-resistant
And preparation method thereof.
To reach above-mentioned purpose, present invention employs following technical proposal:A kind of paper wood sealing wax of the invention, the paper
Timber-used sealing wax includes the following component of following percentage by weight:
Further, described AA emulsion is pure acrylic acid copolymer emulsion or cinnamic acid copolymer breast
The combination of one or more in liquid.Such as moral WPA5812;
Further, described pH adjusting agent is any one in dimethylethanolamine, multifunction amine AMP-95.
Further, described defoamer is organic silicon defoamer.Such as BYK028.
Further, described coalescents are alcohol ester -12, propylene glycol monomethyl ether, dipropylene glycol methyl ether, dipropylene
In the combination of one or more.
Further, described emulsified wax is oxidation modification polyethylene hard wax;Described wetting agent has for polyether-modified
Machine silicon class compound, described levelling agent is the Tego270 of Di Gao companies, and described anticorrosion and bactericidal agent is isothiazoline class anti-corrosion
Bactericide.
Further, described anticorrosion and bactericidal agent is YN-188 the or Troy Troys company as sent out chemical company
K9N。
Further, described thickener is the one kind in hydrophobically-modified alkali swelling type thickener or polyurethane-type thickener
Or several combinations.
The preparation method of paper wood sealing wax of the present invention, comprises the following steps:
(1) each component is accurately weighed in a ratio;
Prepare delustring slurry:Portions of de-ionized water is added in a reservoir, is added under the mixing speed of 400-600r/min
Flatting silica, the flatting silica is made into the delustring slurry of 16wt%, is then ground, and is ground to fineness micro- less than or equal to 25
Rice;
(2) under 400-600r/min stirrings, described AA emulsion, deionized water, film forming are helped
Agent, pH adjusting agent, defoamer, emulsified wax, nano silicon dioxide dispersion, delustring slurry, wetting agent, levelling agent and anti-corrosion are killed
Microbial inoculum is sequentially added in pot of getting the raw materials ready, and the speed of 1000-1500r/min is stirred 10 minutes, until forming uniform mill base;
(3) viscosity for painting liquid is transferred to 60-85S at 25 DEG C with thickener under 800-1000r/min stirring conditions,
The speed of 1000r/min is stirred 10 minutes;Semi-finished product are obtained, the semi-finished product are filtered through 200 mesh gauzes, prepared paper wood water
Paint.
Further, in step (1), the container is cylinder, and in step (3), viscosity is-four glasss of viscosity of painting.
Beneficial effect:Coating of the invention easily increases thickness, and the transparency is good, and coating surface is smooth, and hardness is good, with excellent
The printing that different corrosion resistance, resistance to chalking, wearability are become reconciled, can make the coated face of paper has stronger water-resistance, thoroughly
Gas and wet strength.
Compared with prior art, the invention has the advantages that:
(1) not only coating weight is few for this varnish, and have substantially no effect on carton print ability and caking property again, make our paper
Case is attractive in appearance firm.
The present invention is nontoxic without benzene,toluene,xylene, formaldehyde, toxic heavy metal without organic solvent with diluent water
Non-stimulated smell, it is harmless, it is free from environmental pollution.Product film forming fast drying, is applicable paper products production line balance, coating transparent
Uniformly, can print, bond.Increase the pliability and hardness of coating by adding Nano filling, product cost is low, performance is excellent, ring
Guarantor property is good, and without changing existing paper making process.
(2) nano silicon is a kind of spheroidal particle for reaching Nano grade, by after surface treatment, surface is contained very
Multi-model group can have good compatibility with macromolecular material, and having can play increasing well in the composite for preparing
The effect of strong toughness reinforcing.The addition of nano silicon dioxide dispersion, can smooth paint film, improve the moisture-proof intensity of paper product, have
Stability higher, and the addition of paraffin wax emulsions, can improve the rub resistance energy of film and base material, improve the light slippage on surface
Degree.
(3) present invention is attractive in appearance with coating surface cleaning, and gloss is high, and moistureproof and mildewproof ability is protruded, with room temperature rapid-drying properties
Can, it is not necessary to increase extras.Inventive formulation is simple, not only environmentally friendly but also cheap, with good recoating performance, can root
It is adjusted according to gloss requirement.Hardness of the present invention is high, from dry up to H;Sanding property is particularly pertinent;Coating transparent is uniform, has
The chemical properties such as splendid water-fast, solvent resistant, acid and alkali-resistance, in south, even more damp and hotter coastal area is able to maintain that 2 years
The use time of left and right.Sealing wax VOC content is extremely low, < 35g/L.
(4) present invention base-material used is acrylic acid modified epoxy resin while having epoxy resin and acrylic acid excellent concurrently
Characteristic, the water paint that it is prepared can normal temperature self-drying, can also dry, and be one-component, and storage stability is good, with excellent
Humidity resistance, fungicidal properties, quick-drying and excellent filming performance and adhesive force.Reasonably combined coalescents, nanometer titanium dioxide
Silicon dispersion liquid and paraffin wax emulsions, had both improve the film forming of coating, coating is had good water resistant, grease resistance, improve again
The wear resistance and tensile property of coating.
Specific embodiment
Following examples only exist in illustrative purpose, without being intended to limit the scope of the present invention.
Embodiment 1
A kind of paper wood sealing wax of the invention, the paper wood includes the following component of following percentage by weight with sealing wax:
Described AA emulsion is pure acrylic acid copolymer emulsion.Such as moral WPA5812;
Described pH adjusting agent is multifunction amine AMP-95.
Described defoamer is organic silicon defoamer.Such as BYK028.
Described coalescents are alcohol ester -12.
Described emulsified wax is oxidation modification polyethylene hard wax;Described wetting agent is organic silicon modified by polyether class chemical combination
Thing, described levelling agent is the Tego270 of Di Gao companies, and described anticorrosion and bactericidal agent is isothiazoline class anticorrosion and bactericidal agent.
Described anticorrosion and bactericidal agent is the YN-188 as sent out chemical company.
Described thickener is hydrophobically-modified alkali swelling type thickener.
The preparation method of paper wood sealing wax of the present invention, comprises the following steps:
(1) each component is accurately weighed in a ratio;
Prepare delustring slurry:Portions of de-ionized water is added in a reservoir, and delustring is added under the mixing speed of 500r/min
Powder, the flatting silica is made into the delustring slurry of 16wt%, is then ground, and is ground to fineness less than or equal to 25 microns;
(2) under 500r/min stirrings, by described AA emulsion, deionized water, coalescents, pH
Conditioning agent, defoamer, emulsified wax, nano silicon dioxide dispersion, delustring slurry, wetting agent, levelling agent and anticorrosion and bactericidal agent
Sequentially add in pot of getting the raw materials ready, the speed of 1300r/min is stirred 10 minutes, until forming uniform mill base;
(3) viscosity for painting liquid is transferred to 85S, 1000r/min at 25 DEG C with thickener under 1000r/min stirring conditions
Speed stir 10 minutes;Semi-finished product are obtained, the semi-finished product are filtered through 200 mesh gauzes, prepared paper wood sealing wax.The appearance
Device is cylinder, and viscosity is-four glasss of viscosity of painting.
Embodiment 2
Embodiment 2 is with the difference of embodiment 1:A kind of paper wood sealing wax of the invention, the paper wood is included with sealing wax
The following component of following percentage by weight:
Described AA emulsion is two kinds in pure acrylic acid copolymer emulsion, cinnamic acid copolymer emulsion
Combination.Such as moral WPA5812;
Described pH adjusting agent is dimethylethanolamine.Described coalescents are propylene glycol monomethyl ether.Described thickener
It is polyurethane-type thickener.Described anticorrosion and bactericidal agent is the K9N of Troy Troys company.
The preparation method of paper wood sealing wax of the present invention, comprises the following steps:
(1) each component is accurately weighed in a ratio;
Prepare delustring slurry:Portions of de-ionized water is added in cylinder, flatting silica is added under the mixing speed of 400r/min,
The flatting silica is made into the delustring slurry of 16wt%, is then ground, be ground to fineness less than or equal to 25 microns;
(2) under 600r/min stirrings, by described AA emulsion, deionized water, coalescents, pH
Conditioning agent, defoamer, emulsified wax, nano silicon dioxide dispersion, delustring slurry, wetting agent, levelling agent and anticorrosion and bactericidal agent
Sequentially add in pot of getting the raw materials ready, the speed of 1000r/min is stirred 10 minutes, until forming uniform mill base;
(3) viscosity for painting liquid is transferred to 60S, 1000r/min at 25 DEG C with thickener under 800r/min stirring conditions
Speed stir 10 minutes;Semi-finished product are obtained, the semi-finished product are filtered through 200 mesh gauzes, prepared paper wood sealing wax.The appearance
Device is cylinder, and viscosity is-four glasss of viscosity of painting.
Embodiment 3
Embodiment 3 is with the difference of embodiment 1:A kind of paper wood sealing wax of the invention, the paper wood is included with sealing wax
The following component of following percentage by weight:
Described AA emulsion is cinnamic acid copolymer emulsion.Such as moral WPA5812;
Described coalescents are the combination of three kinds in propylene glycol monomethyl ether, dipropylene glycol methyl ether, dipropylene.
Described thickener is the combination in hydrophobically-modified alkali swelling type thickener or polyurethane-type thickener.
The preparation method of paper wood sealing wax of the present invention, comprises the following steps:
(1) each component is accurately weighed in a ratio;
Prepare delustring slurry:Portions of de-ionized water is added in a reservoir, and delustring is added under the mixing speed of 600r/min
Powder, the flatting silica is made into the delustring slurry of 16wt%, is then ground, and is ground to fineness less than or equal to 25 microns;
(2) under 400r/min stirrings, by described AA emulsion, deionized water, coalescents, pH
Conditioning agent, defoamer, emulsified wax, nano silicon dioxide dispersion, delustring slurry, wetting agent, levelling agent and anticorrosion and bactericidal agent
Sequentially add in pot of getting the raw materials ready, the speed of 1500r/min is stirred 10 minutes, until forming uniform mill base;
(3) viscosity for painting liquid is transferred to 75S, 1000r/min at 25 DEG C with thickener under 900r/min stirring conditions
Speed stir 10 minutes;Semi-finished product are obtained, the semi-finished product are filtered through 200 mesh gauzes, prepared paper wood sealing wax.
Experiment 1
The product paper wood of embodiment 1 to embodiment 3 is detected that its detection data is as shown in table 1 with sealing wax:
Table 1
As shown in table 1:Embodiments of the invention 1:Coating easily increases thickness, and the transparency is good, and hardness is moderate, grinability
It is good.Embodiment 2:Hardness is good, coating surface is smooth, wearability is good, water-tolerant.Embodiment 3:Compared to the first two scheme, beat
Mill property is good, and the transparency is good, but coating smooth degree is not good enough, hardness is more slightly worse than embodiment 1 and embodiment 2.
Experiment 2
Paper wood sealing wax of the invention and common paper water varnish performance comparison, its detection data are as shown in table 2:
Table 2
As shown in table 2, the special sealing wax of paper wood matter that prepared by the present invention passes through the collective effects such as film forming matter, coalescents,
Making the sealing wax of preparation has following innovative point:With the printing that excellent corrosion resistance, resistance to chalking, wearability are become reconciled,
The coated face of paper can be made has stronger water-resistance, gas permeability and wet strength.1st, hardness is high, from dry up to H;2nd, sanding property
It is particularly pertinent, it is non-sticky glutinous;3rd, coating transparent is uniform, with chemical properties such as splendid water-fast, solvent resistant, acid and alkali-resistances, in south
Even more damp and hotter coastal area is able to maintain that the use time of 2 years or so.4th, sealing wax VOC content is extremely low, < 35g/L.
Specific embodiment described herein is only to the spiritual explanation for example of the present invention.Technology neck belonging to of the invention
The technical staff in domain can be made various modifications or supplement to described specific embodiment or be replaced using similar mode
Generation, but without departing from spirit of the invention or surmount scope defined in appended claims.
Claims (10)
1. a kind of paper wood sealing wax, it is characterised in that:The paper wood includes the following component of following percentage by weight with sealing wax:
2. paper wood sealing wax according to claim 1, it is characterised in that:Described AA emulsion is pure propylene
The combination of one or more in acid copolymer emulsion or cinnamic acid copolymer emulsion.
3. paper wood sealing wax according to claim 1, it is characterised in that:Described pH adjusting agent be dimethylethanolamine,
Any one in multifunction amine AMP-95.
4. paper wood sealing wax according to claim 1, it is characterised in that:Described defoamer is organic silicon defoamer.
5. paper wood sealing wax according to claim 1, it is characterised in that:Described coalescents are alcohol ester -12, propane diols
The combination of one or more in methyl ether, dipropylene glycol methyl ether, dipropylene.
6. paper wood sealing wax according to claim 1, it is characterised in that:Described emulsified wax is oxidation modification polyethylene
Hard wax;Described wetting agent is organic silicon modified by polyether class compound, and described levelling agent is the Tego270 of Di Gao companies, institute
The anticorrosion and bactericidal agent stated is isothiazoline class anticorrosion and bactericidal agent.
7. paper wood sealing wax according to claim 6, it is characterised in that:Described anticorrosion and bactericidal agent is such as hair chemical company
YN-188 or Troy Troys company K9N.
8. paper wood sealing wax according to claim 1, it is characterised in that:Described thickener is hydrophobically-modified alkali swelling type
The combination of one or more in thickener or polyurethane-type thickener.
9. the preparation method of the paper wood sealing wax described in any one of claim 1 to 8, comprises the following steps:
(1) each component is accurately weighed in the ratio described in claim 1;
Prepare delustring slurry:Portions of de-ionized water is added in a reservoir, and delustring is added under the mixing speed of 400-600r/min
Powder, the flatting silica is made into the delustring slurry of 16wt%, is then ground, and is ground to fineness less than or equal to 25 microns;
(2) under 400-600r/min stirrings, by described AA emulsion, deionized water, coalescents, pH
Conditioning agent, defoamer, emulsified wax, nano silicon dioxide dispersion, delustring slurry, wetting agent, levelling agent and anticorrosion and bactericidal agent
Sequentially add in pot of getting the raw materials ready, the speed of 1000-1500r/min is stirred 10 minutes, until forming uniform mill base;
(3) viscosity for painting liquid is transferred to 60-85S, 1000r/ at 25 DEG C with thickener under 800-1000r/min stirring conditions
The speed of min is stirred 10 minutes;Semi-finished product are obtained, the semi-finished product are filtered through 200 mesh gauzes, prepared paper wood sealing wax.
10. the preparation method of paper wood sealing wax according to claim 9, it is characterised in that:In step (1), the appearance
Device is cylinder, and in step (3), viscosity is-four glasss of viscosity of painting.
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
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CN111114013A (en) * | 2020-01-03 | 2020-05-08 | 保定乐凯包装材料有限公司 | Preparation method of seamless polished paper tube and product |
CN114481687A (en) * | 2021-12-29 | 2022-05-13 | 台昌树脂(佛山)有限公司 | Acrylic acid copolymer emulsion for water-based toner paper and preparation method thereof |
CN115960501A (en) * | 2022-11-03 | 2023-04-14 | 上海君子兰新材料股份有限公司 | Water-based door and window varnish and preparation method thereof |
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CN101560354A (en) * | 2008-04-15 | 2009-10-21 | 湖州百胜涂料有限公司 | Nanometer environmental protection water-borne woodwork coating and preparation method thereof |
US20100285258A1 (en) * | 2007-09-28 | 2010-11-11 | Avery Dennison Corporation | Opacifying label |
CN102964947A (en) * | 2012-11-02 | 2013-03-13 | 广东巴德士化工有限公司 | One-component water-borne semi-matt wood finishing varnish |
CN104631207A (en) * | 2015-01-08 | 2015-05-20 | 湖南华望科技股份有限公司 | Waterproof coating for water-based paperboards and preparation method thereof |
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Publication number | Priority date | Publication date | Assignee | Title |
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US20100285258A1 (en) * | 2007-09-28 | 2010-11-11 | Avery Dennison Corporation | Opacifying label |
CN101560354A (en) * | 2008-04-15 | 2009-10-21 | 湖州百胜涂料有限公司 | Nanometer environmental protection water-borne woodwork coating and preparation method thereof |
CN102964947A (en) * | 2012-11-02 | 2013-03-13 | 广东巴德士化工有限公司 | One-component water-borne semi-matt wood finishing varnish |
CN104631207A (en) * | 2015-01-08 | 2015-05-20 | 湖南华望科技股份有限公司 | Waterproof coating for water-based paperboards and preparation method thereof |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN111114013A (en) * | 2020-01-03 | 2020-05-08 | 保定乐凯包装材料有限公司 | Preparation method of seamless polished paper tube and product |
CN114481687A (en) * | 2021-12-29 | 2022-05-13 | 台昌树脂(佛山)有限公司 | Acrylic acid copolymer emulsion for water-based toner paper and preparation method thereof |
CN115960501A (en) * | 2022-11-03 | 2023-04-14 | 上海君子兰新材料股份有限公司 | Water-based door and window varnish and preparation method thereof |
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Application publication date: 20170613 |