CN106835698A - softener composition - Google Patents
softener composition Download PDFInfo
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- CN106835698A CN106835698A CN201710078407.XA CN201710078407A CN106835698A CN 106835698 A CN106835698 A CN 106835698A CN 201710078407 A CN201710078407 A CN 201710078407A CN 106835698 A CN106835698 A CN 106835698A
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- Prior art keywords
- starch
- softener composition
- composition according
- hydroxypropyl
- cationic starch
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Classifications
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/46—Compounds containing quaternary nitrogen atoms
- D06M13/463—Compounds containing quaternary nitrogen atoms derived from monoamines
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/46—Compounds containing quaternary nitrogen atoms
- D06M13/47—Compounds containing quaternary nitrogen atoms derived from heterocyclic compounds
- D06M13/473—Compounds containing quaternary nitrogen atoms derived from heterocyclic compounds having five-membered heterocyclic rings
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/46—Compounds containing quaternary nitrogen atoms
- D06M13/47—Compounds containing quaternary nitrogen atoms derived from heterocyclic compounds
- D06M13/477—Compounds containing quaternary nitrogen atoms derived from heterocyclic compounds having six-membered heterocyclic rings
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
- D06M15/03—Polysaccharides or derivatives thereof
- D06M15/11—Starch or derivatives thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/50—Modified hand or grip properties; Softening compositions
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
The present invention relates to a kind of softener composition, including following weight percentage component：Quat active 3 7%, cationic starch 0.02 0.5%, thickener 0.01~1.5%, additive 0~2%, balance of water；The cationic starch is prepared by starch and 2,3 epoxypropyltrimethylchloride chlorides, the hydroxypropyl-trimethyl ammonium chloride of 3 chlorine 2, the dimethyldodecyl ammonium chloride of 3 chlorine 2 or the hydroxypropyl dimethyl octadecyl ammonium chloride of 3 chlorine 2.Above-mentioned softener composition is compounded cationic starch with quat active, cationic starch (based on composition weight 0.02~0.5%) under less addition, quaternary ammonium salt is coordinated to use, softening fabrics effect is better than exclusive use quaternary ammonium salt, can to a certain extent mitigate the partially greasy feel that saturation degree quaternary ammonium salt higher brings simultaneously, bring more smooth experience.
Description
Technical field
The present invention relates to household chemicals technical field, more particularly to a kind of softener composition.
Background technology
Fabric during Reusability, cyclic washing, according to different material and textile technology, the fiber in fabric,
Especially fiber fines often mutually wind, intertwine, or even fracture occur and comes off.The outward appearance of fabric is influenceed, makes to knit
Thing is hardened, roughening, the overall feel of influence.Fabric softening agent can form cation diaphragm on fabric fibre surface, reduce fine
Dimension friction, makes clothes soft submissive.
The raw material of fabric softening agent is mainly quaternary cationics, and the cationoid product is more, but very
Just can be used for the quaternary ammonium product salt of the still double long chain alkyl groups in terms of fabric sofetening, its representative products such as double hexadecyldimethylamines
Ammonium chloride (D1821), alkyl ester quat (TE) and imidazoline quaternary ammonium salt (OM) etc..Existing for wherein typical D1281
Low biodegradable problem turns into the principal element of its development of restriction.With the enhancing of people's environmental consciousness, alkyl ester quat and
Imidazoline quaternary ammonium salt turns into the fashion trend in market.Increasing manufacturer uses it as the main component of fabric-softening.
Representational alkyl ester quat compatibility, dispersiveness, biological degradability, non-yellowing properties and rewettability are better than D1281, but
There is certain gap compared with D1281 in flexibility.
With reference to the service condition of domestic market, the present invention is matched somebody with somebody using substitution value cationic starch higher with specific quaternary ammonium salt
Conjunction is applied in softener, and finer research has been carried out for its auxiliary cushion effect.Optimization cationic starch addition scope
And preferably go out preferably combination.
It is submissive that patent CN200910242913.3 discloses a kind of fabric maintenance comprising cationic polymer and quaternary ammonium salt
Agent, the patent only gives a kind of structural formula of modified starch, and the other sides such as substitution value, starch source are not carried out in detail
Thin description.
Patent 201510960094.1 discloses a kind of containing environment-friendly type fabric softeners such as ester based quaternary ammonium salt, thickeners.Its
In only include ester based quaternary ammonium salt cationic surfactant, cationic starch is not compounded.
The content of the invention
Based on this, it is an object of the invention to provide a kind of softener composition.
Specific technical scheme is as follows：
A kind of softener composition, is characterised by, including following weight percentage component：
Wherein in some embodiments, the quat active is selected from：
A. there is following chemical structural formula：
{R4-m-N+-[(CH2)n-Y-R1]m}A-
Wherein, m is 1,2, or 3；
N is 2 or 3；
R1It is C12~C22 alkyl, the alkyl is insatiable hunger and/or saturation, straight or branched；R is C1~C6 alkyl
Or hydroxyalkyl；
Y is-COO- or-CONH-；
A-Selected from chlorion, bromide ion, sulfate radical or methylsulfate；
B. there is following chemical structural formula：
A-, R and R1It is as defined above, R2It is C1~C6 alkylidenes, G is O or-NR-；C. there is following chemical structural formula：
R1、R2And A-It is as defined above；
D. there is following chemical structural formula：
R1And A-It is as defined above；
E. there is following chemical structural formula：
Wherein R3Optionally from the alkyl of C1-C2, R4、R5、R6It is independently selected from alkyl, the CH of C1-C22CH
(COOCnH2n-1)CH3、CH2CH(COOCnH2n)CH3、CH(CH2COOCnH2n-1)CH3Or CH (CH2COOCnH2n)CH3, wherein 5≤n
≤17；A-It is as defined above.
Wherein in some embodiments, the quat active is selected from：Bis-fatty acid ethoxycarbonyl hydroxyethyl methyl sulfuric acid
Ammonium methyl, bis-fatty acid ethoxycarbonyl dimethyl sulfate ammonium methyl or bis-fatty acid isopropyl ester group dimethyl sulfate ammonium methyl.
Wherein in some embodiments, the cationic starch is by starch and 2,3- epoxypropyltrimethylchloride chloride, 3-
The chloro- 2- hydroxypropyl dimethyls-lauryl ammonium chloride of chloro-2-hydroxypropyl-trimethyl ammonium chloride, 3- or the chloro- 2- hydroxypropyls diformazans of 3-
Base-octadecyl ammonium chloride is prepared.
Wherein in some embodiments, the amylose comprising 20~50wt% in the cationic starch.
Wherein in some embodiments, the amylose comprising 20~30wt% in the cationic starch.
Wherein in some embodiments, the cationic starch performance is as follows：Substitution value is 0.07~0.5,20wt% water
Solution viscosity is 20mPas~500mPas.
Wherein in some embodiments, the cationic starch is Starch hydroxypropyl-trimethyl ammonium chloride, dimethyl tristearin
One or more in base hydroxypropyl ammonium chloride or dimethyl dodecyl base hydroxypropyl ammonium chloride.
Wherein in some embodiments, the starch be selected from tapioca, farina, starch from sweet potato, cornstarch,
One or more in wheaten starch, sago starch, waxy corn starch or rice starch.
Wherein in some embodiments, the thickener be selected from cation cellulose ether, cation guar gum, shitosan,
One kind or several in polyacrylamide homo polymer, polyacrylamide copolymer, polyquaternium, polyvinylamine or polyethyleneimine
Kind.
Wherein in some embodiments, the additive is selected from silicone oil, essence, parcel essence, preservative and pigment
One or more.
Above-mentioned softener composition is compounded cationic starch with quat active, is added cationic starch is less
Under dosage (based on composition weight 0.05~0.5%), coordinate quaternary ammonium salt to use, the energy of single quaternary ammonium salt softening fabrics can be improved
Power.The smooth feel of fabric has been taken into account simultaneously, and alleviate that saturation degree quaternary ammonium salt higher brings to a certain extent is partially greasy
Feel, bring more smooth feel to experience.
Specific embodiment
For the ease of understanding the present invention, the present invention will be described more fully below.But, the present invention can be with perhaps
More different form is realized, however it is not limited to embodiment described herein.On the contrary, the purpose for providing these embodiments is to make
Understanding to the disclosure is more thorough comprehensive.
Unless otherwise defined, all of technologies and scientific terms used here by the article with belong to technical field of the invention
The implication that technical staff is generally understood that is identical.The term for being used in the description of the invention herein is intended merely to description tool
The purpose of the embodiment of body, it is not intended that in the limitation present invention.Term as used herein "and/or" includes one or more phases
The arbitrary and all of combination of the Listed Items of pass.
Embodiment 1~8
See Tables 1 and 2.
Table 1
The quat active is double ethyl palmitate base hydroxyethyl methyl Methylsulfate amine；
The thickener is：Acrylamide/acrylyl oxy-ethyl-trimethyl salmiac copolymer；
The cationic starch is Starch hydroxypropyl-trimethyl ammonium chloride.Design parameter such as table 2.
Table 2
According to the raw material proportioning of table 1, softener composition is prepared by method well known in the art.
Comparative example 1
A kind of softener composition of this comparative example, raw material proportioning is same as Example 5, and difference is not add cation
Starch.
Comparative example 2
A kind of softener composition of this comparative example, raw material proportioning is same as Example 5, and difference is the sun employed in it
Substitution value is 0.03 in ionic starch.
Measure of merit：
(1) test cotton towel is cleaned with regular powder, respectively with above-described embodiment 5, comparative example 1 and comparative example
The 2 softener compositions for preparing are configured to 5% solution, soak, dry.
(2) the submissive effect of clothing is detected, 50 people group hand touches manner of comparison assessment, and soft effect is up to 5 points, minimum
It is 1 point.Sliding sense effect is preferably 5 points, minimum 1 point.
The performance test results of table 3
| Evaluation index | Embodiment 5 | Comparative example 1 | Comparative example 2 |
| Soft effect | 4.6 | 3.6 | 3.8 |
| Sliding sense | 3.7 | 2.9 | 3.1 |
Knowable to above-mentioned test result, the fabric softening agent that cationic starch of the invention is compounded with quaternary ammonium salt activating agent
Composition, its soft effect better than being used alone quaternary ammonium salt softening agent, the sun of cationic starch of the invention and low degree of substitution from
Sub- starch is compared, and has the effect that preferably auxiliary softens.
Embodiment 9-13
A kind of softener composition of the present embodiment, raw material proportioning is same as Example 5, and difference is used quaternary ammonium salt
Active matter is different.Refer to table 4.
Table 4
The cationic starch is Starch hydroxypropyl-trimethyl ammonium chloride.Substitution value is 0.25,20wt% solution viscosities
It is 200mPas, amylose content is 25wt%；
Comparative example 3-7
Table 5
Contrast properties are tested：
Table 6
| Evaluation index | Comparative example 3 | Embodiment 9 | Comparative example 4 | Embodiment 10 | Comparative example 5 |
| Soft effect | 3.6 | 4.6 | 3.6 | 4.7 | 3.3 |
| Sliding sense | 2.9 | 3.8 | 2.8 | 3.6 | 2.6 |
Table 7
| Evaluation index | Embodiment 11 | Comparative example 6 | Embodiment 12 | Comparative example 7 | Embodiment 13 |
| Soft effect | 4.5 | 3.7 | 4.5 | 4.7 | 4.8 |
| Sliding sense | 3.2 | 2.8 | 3.4 | 3.7 | ]3.8 |
Knowable to above-mentioned test result, cationic starch of the invention with double ethyl palmitate base hydroxyethyl methyl sulphur
Sour methyl esters amine, double ethyl palmitate base dimethyl sulfate ammonium methyls, double ethyl palmitate base dimethyl sulfate ammonium methyl this kind of seasons
Ammonium salt compounding can significantly improve fabric sofetening performance.
With two (butter buserelin) polyethoxy methylsulfuric acid ammonium methyls, 1- methyl -2- butter -3- buserelins-miaow
Oxazoline sulfate methyl ammonium compounding also has the effect of certain softness.
Dioctadecyl dimethyl ammonium chloride (D1821) although having preferably softness, because it is biodegradable
Poor, the antistatic difference of property, is difficult to be configured to the product of high concentration, and production cost is higher, easily by sludge absorption in sewage disposal
And environmental pollution is caused, the Western European countries such as Germany have stopped using.Both at home and abroad, it is especially external progressively with easily biological drop
The quaternary ammonium salt of solution substitutes D1821, alkyl ester quat (bis-fatty acid ethoxycarbonyl hydroxyethyl methyl sulfuric acid first of the present invention
Ester amine, bis-fatty acid ethoxycarbonyl dimethyl sulfate ammonium methyl or bis-fatty acid isopropyl ester group dimethyl sulfate ammonium methyl) compatibility,
Dispersiveness, biological degradability, non-yellowing properties and rewettability are better than D1281.Present invention discover that using the height substitution of the application
Cationic starch is compounded with the quaternary ammonium salt of the application, is remarkably improved the soft effect of softener, and flexibility is approached with D1281.
Each technical characteristic of embodiment described above can be combined arbitrarily, to make description succinct, not to above-mentioned reality
Apply all possible combination of each technical characteristic in example to be all described, as long as however, the combination of these technical characteristics is not deposited
In contradiction, the scope of this specification record is all considered to be.
Embodiment described above only expresses several embodiments of the invention, and its description is more specific and detailed, but simultaneously
Can not therefore be construed as limiting the scope of the patent.It should be pointed out that coming for one of ordinary skill in the art
Say, without departing from the inventive concept of the premise, various modifications and improvements can be made, these belong to protection of the invention
Scope.Therefore, the protection domain of patent of the present invention should be determined by the appended claims.
Claims (11)
1. a kind of softener composition, it is characterised in that the component including following weight percentage：
2. softener composition according to claim 1, it is characterised in that the quat active is selected from：
A. there is following chemical structural formula：
{R4-m-N+-[(CH2)n-Y-R1]m}A-
Wherein, m is 1,2, or 3；
N is 2 or 3；
R1It is C12~C22 alkyl, the alkyl is insatiable hunger and/or saturation, straight or branched；
R is C1~C6 alkyl or hydroxyalkyl；
Y is-COO- or-CONH-；
A-Selected from chlorion, iodide ion, bromide ion, ethyl ester sulfate radical or methylsulfate；
B. there is following chemical structural formula：
A-, R and R1It is as defined above, R2It is C1~C6 alkylidenes, G is O or-NR-；
C. there is following chemical structural formula：
R1、R2And A‐It is as defined above；
D. there is following chemical structural formula：
R1And A‐It is as defined above；
E. there is following chemical structural formula：
Wherein R3Optionally from the alkyl of C1-C2, R4、R5、R6It is independently selected from alkyl, the CH of C1-C22CH(OOCCnH2n-1)
CH3、CH2CH(OOCCnH2n)CH3、CH(CH2OOCCnH2n-1)CH3Or CH (CH2OOCCnH2n)CH3, wherein 5≤n≤17；A-As above
State and defined.
3. softener composition according to claim 2, it is characterised in that the quat active is selected from：Double fat
Acetoacetic ester base hydroxyethyl methyl sulfate methyl ammonium, bis-fatty acid ethoxycarbonyl dimethyl sulfate ammonium methyl or bis-fatty acid isopropyl ester group
Dimethyl sulfate ammonium methyl.
4. softener composition according to claim 1, it is characterised in that the cationic starch is by starch and 2,3- ring
The chloro- 2- hydroxypropyl dimethyls-dodecyl chlorination of oxygen hydroxypropyltrimonium chloride, 3- chloro-2-hydroxypropyl-trimethyl ammonium chlorides, 3-
Ammonium or the chloro- 2- hydroxypropyl dimethyls-octadecyl ammonium chlorides of 3- are prepared.
5. softener composition according to claim 4, it is characterised in that in the cationic starch comprising 20~
The amylose of 50wt%.
6. softener composition according to claim 4, it is characterised in that in the cationic starch comprising 20~
The amylose of 30wt%.
7. softener composition according to claim 4, it is characterised in that the cationic starch performance is as follows：Substitution
Spend is that 0.07~0.5,20wt% solution viscosities are 20~500mPas.
8. softener composition according to claim 7, it is characterised in that the cationic starch is starch hydroxypropyl three
One kind or several in ammonio methacrylate, dimethyl stearyl hydroxypropyl ammonium chloride or dimethyl dodecyl base hydroxypropyl ammonium chloride
Kind.
9. the softener composition according to claim any one of 1-8, it is characterised in that the starch is selected from para arrowroot
In powder, farina, starch from sweet potato, cornstarch, wheaten starch, sago starch, waxy corn starch or rice starch
One or more.
10. the softener composition according to claim any one of 1-8, it is characterised in that the thickener be selected from sun from
Subbundle element ether, cation guar gum, shitosan, it is polyacrylamide homo polymer, polyacrylamide copolymer, polyquaternium, poly-
One or more in vinylamine or polyethyleneimine.
The 11. softener composition according to claim any one of 1-8, it is characterised in that the additive be selected from silicone oil,
One or more in essence, parcel essence, preservative and pigment.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201710078407.XA CN106835698B (en) | 2017-02-14 | 2017-02-14 | Softener composition |
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|---|---|---|---|
| CN201710078407.XA CN106835698B (en) | 2017-02-14 | 2017-02-14 | Softener composition |
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| CN106835698B CN106835698B (en) | 2019-12-10 |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108755114A (en) * | 2018-04-30 | 2018-11-06 | 安徽恒益纺织科技有限公司 | A kind of care agent for textile fabric |
| CN108914592A (en) * | 2018-07-02 | 2018-11-30 | 汪涛 | A kind of dacron afterfinish softening agent |
| CN113417142A (en) * | 2021-06-22 | 2021-09-21 | 杭州萧山凤凰纺织有限公司 | Antibacterial non-woven fabric and preparation method thereof |
| CN113980745A (en) * | 2021-08-19 | 2022-01-28 | 广州南顺清洁用品有限公司 | Color-locking care laundry detergent and preparation method thereof |
| CN113980744A (en) * | 2021-08-19 | 2022-01-28 | 广州南顺清洁用品有限公司 | Color fixing softener and preparation method thereof |
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| CN108755114A (en) * | 2018-04-30 | 2018-11-06 | 安徽恒益纺织科技有限公司 | A kind of care agent for textile fabric |
| CN108914592A (en) * | 2018-07-02 | 2018-11-30 | 汪涛 | A kind of dacron afterfinish softening agent |
| CN113417142A (en) * | 2021-06-22 | 2021-09-21 | 杭州萧山凤凰纺织有限公司 | Antibacterial non-woven fabric and preparation method thereof |
| CN113980745A (en) * | 2021-08-19 | 2022-01-28 | 广州南顺清洁用品有限公司 | Color-locking care laundry detergent and preparation method thereof |
| CN113980744A (en) * | 2021-08-19 | 2022-01-28 | 广州南顺清洁用品有限公司 | Color fixing softener and preparation method thereof |
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| Publication number | Publication date |
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| CN106835698B (en) | 2019-12-10 |
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