CN106835492B - A kind of production method of cashmere protein cellulose fiber spunlace non-woven cloth - Google Patents
A kind of production method of cashmere protein cellulose fiber spunlace non-woven cloth Download PDFInfo
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- CN106835492B CN106835492B CN201611163223.5A CN201611163223A CN106835492B CN 106835492 B CN106835492 B CN 106835492B CN 201611163223 A CN201611163223 A CN 201611163223A CN 106835492 B CN106835492 B CN 106835492B
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- cashmere
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- woven cloth
- cellulose fiber
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- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/42—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
- D04H1/425—Cellulose series
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/10—Other agents for modifying properties
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F2/00—Monocomponent artificial filaments or the like of cellulose or cellulose derivatives; Manufacture thereof
- D01F2/06—Monocomponent artificial filaments or the like of cellulose or cellulose derivatives; Manufacture thereof from viscose
- D01F2/08—Composition of the spinning solution or the bath
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/42—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
- D04H1/425—Cellulose series
- D04H1/4258—Regenerated cellulose series
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/44—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties the fleeces or layers being consolidated by mechanical means, e.g. by rolling
- D04H1/46—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties the fleeces or layers being consolidated by mechanical means, e.g. by rolling by needling or like operations to cause entanglement of fibres
- D04H1/492—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties the fleeces or layers being consolidated by mechanical means, e.g. by rolling by needling or like operations to cause entanglement of fibres by fluid jet
- D04H1/495—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties the fleeces or layers being consolidated by mechanical means, e.g. by rolling by needling or like operations to cause entanglement of fibres by fluid jet for formation of patterns, e.g. drilling or rearrangement
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- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Mechanical Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
Abstract
The invention discloses a kind of cashmere protein cellulose fiber spunlace non-woven cloth and its production methods, it is related to functional spunlace non-woven cloth preparation field, the spunlace non-woven cloth is made of the fiber of following weight percent: the cashmere albumen of 5-15%, the cotton fiber or synthetic fibers of 85-95%, cashmere albumen is grafted on cellulose by silane coupling agent, the fiber number of fiber is 1.33-1.67dtex, production method is combined with the preparation process of cashmere protein cellulose fiber, the content of cashmere albumen in non-woven fabrics is up to 5-15%, cashmere albumen and cotton fiber are to be covalently keyed, cashmere albumen becomes a part of cotton fiber (viscose rayon), since cashmere albumen and cotton fiber are to be covalently keyed, the original mechanical property of cotton fiber is not influenced, in the base for keeping the excellent textile performance of cellulose fibre Feel and correlation properties smooth, soft as its cashmere are assigned on plinth, cashmere (wool) complex fiber material surface is smooth made from such cashmere protein cellulose fiber, is not easy pilling.
Description
Technical field
The present invention relates to functional spunlace non-woven cloth preparation fields, and in particular to a kind of cashmere protein cellulose fiber spun lacing
The production method of non-woven fabrics.
Background technique
Wool is the important source material of textile industry, it has many advantages, such as, and elasticity is good, hygroscopicity is strong, warmth retention property is good, and wool is spun
Fabric is famous with its luxurious graceful, natural style comfortable and easy to wear, especially the cashmere good name that has " soft gold ", but due to
Price is high, for the production of non-woven cloth, using few, using the non-woven cloth of good woool production, is only limitted to needle thorn manufacture
Few some advanced industrial cloth such as woollen blanket, advanced Nomex, undercoat, the coarse wool being generally adopted by wool processing, lead to
Cross the products such as the pad cloth of the methods of needle thorn, loop bonding production carpet, the sandwich of layers of needle punched carpet, insulation heat insulating material, this kind of sheep
The length of hair is different, contains miscellaneous height, and spinnability is poor, and processing is more difficult, and product can pass through chemical processing, to improve quality.
In order to increase the utilization of cashmere, modern industry combines cashmere with viscose rayon, under certain condition will be certain
The protein hydrolysate stoste and cellulose (viscose glue) stoste of concentration carry out spinning, and post-treated processing by certain proportion mixing
Ideal regenerated protein is made, in the peptide bond (- CO-NH -) among such protein fibre and cellulose-OH shape
At hydrogen bond, stronger molecular binding affinities are generated, to form the composite fibre of novel protein, but substantially hydrogen bond is still fallen within
Molecular separating force, not enough in conjunction with dynamics, by repeatedly washing, protein falls off, and related performance decline is obvious, and for power
For learning performance, such composite fibre is still less than viscose rayon.
Summary of the invention
It is an object of the present invention to provide a kind of production methods of cashmere protein cellulose fiber spunlace non-woven cloth, provide good
It is thick to solve cashmere (wool) the complex fiber material surface that the prior art is produced containing cashmere (wool) complex fiber material
The problem of rough, easy pilling.
To solve the above problems, technical solution provided by the invention are as follows:
A kind of cashmere protein cellulose fiber spunlace non-woven cloth, is made of: 5-15%'s the fiber of following weight percent
The cotton fiber or synthetic fibers of cashmere protein cellulose fiber, 85-95%, cashmere albumen are grafted on fiber by silane coupling agent
On element, the fiber number of fiber is 1.33-1.67dtex.
A kind of production method of cashmere protein cellulose fiber spunlace non-woven cloth, includes the following steps:
(1) prepare cashmere protein cellulose fiber: prepare mass fraction be 5-15%, the cashmere albumen that pH value is 11-12
Cashmere albumen alkaline aqueous solution is heated to 55-65 DEG C, silane coupling agent is added dropwise under agitation by alkaline aqueous solution, is added dropwise
System temperature is risen to 100-110 DEG C after complete, cashmere albumen pretreatment fluid is obtained after maintaining reaction 2-3 hours, then drops to
The cashmere albumen pretreatment fluid of preparation is added according to the ratio of cashmere albumen pretreatment fluid and viscose glue volume ratio 1:10 after room temperature
In viscose glue, bucket among maturation is entered after being sufficiently mixed, is always maintained at stirring among maturation in bucket, maintains reaction 6-10 hours
Spinning is directly carried out afterwards obtains wet cashmere protein cellulose fiber；
(2) the wet cashmere protein cellulose fiber for obtaining step (1) carries out mixing combing with cotton fiber or synthetic fibers
Obtain wet non-woven fabrics fiber net；
(3) it carries out 360 degree of full dimension spun lacings to the wet non-woven fabrics fiber net that step (2) obtains with clear water to consolidate, totally 11
Spun lacing process, spun lacing pressure are stepped up at spiral gradient；Last in spun lacing process punches skill by high-pressure water-jet together
Art forms non-woven fabrics cloth cover every square centimeter while being evenly distributed 60 deflector holes when shaping；
(4) spunlace non-woven cloth made from step (3) is moved into tunnel drier, is in 80~100 DEG C, transmission speed
Under conditions of 0.1~0.5r/min, 2~3h, the aqueous humidity 7.5%-9.5% of final non-woven fabrics are handled.
Further, in step (1), the dosage of silane coupling agent is the 30-40% of cashmere albumen quality, and it is even that silane is added dropwise
The time for joining agent is 20-30min.
Still further, the silane coupling agent is γ-(2,3- the third oxygen of epoxy) propyl trimethoxy silicane or γ-shrink
Glycerol ether oxygen propyl trimethoxy silicane.
The invention has the following advantages over the prior art:
(1) present invention is combined with the preparation process of cashmere protein cellulose fiber, and the cashmere albumen in non-woven fabrics contains
Amount is up to 5-15%, and to be covalently keyed, cashmere albumen becomes one of cotton fiber (viscose rayon) for cashmere albumen and cotton fiber
Point, since cashmere albumen and cotton fiber are to be covalently keyed, the original mechanical property of cotton fiber is not influenced, is keeping cellulose fiber
It ties up and assigns feel and correlation properties smooth, soft as its cashmere, such cashmere protein fiber on the basis of excellent textile performance
(wool) complex fiber material of cashmere made from cellulose fiber surface is smooth, is not easy pilling；
(2) cashmere albumen and cotton fiber are grafted on cellulose with covalent bond, are existed without free cashmere, are usually used
Cheng Zhong, cashmere albumen is without departing from will not come to harm to the people of cashmere allergy；
(3) clear water is used when spun lacing, has not only played spun lacing consolidation, but also swim adhering to above cashmere protein cellulose fiber
From cashmere rinse out, be not necessarily to washing operation after the completion of spun lacing, only operated with first drying, energy consumption, water consume are low.
(4) it is organically combined by the grafting of cashmere albumen, front end spinning technique and spun lacing process, obtained fiber is without drying
It is dry to be directly entered spun lacing step, and without exclusively carrying out spun lacing pretreatment, integration production substantially reduces process flow,
Technique is simplified, method is easy, is easy to large-scale production.
Specific embodiment
Embodiment 1
Carry out the operation of following steps:
(1) it is pumped into 50L water to glassed steel reaction vessels, opens stirring, and the cashmere albumen of 10Kg is added, dilute hydroxide is added dropwise
System pH is adjusted to the cashmere albumen alkaline aqueous solution sufficiently dissolved after 11-12 by sodium solution, then by cashmere albumen
Alkaline aqueous solution is heated to 55-65 DEG C, 55-65 DEG C of maintenance system temperature under agitation in 20~30min in system
3.5L γ-(2,3- the third oxygen of epoxy) propyl trimethoxy silicane is added dropwise, system temperature is risen to 100-110 DEG C after dripping, dimension
Cashmere albumen pretreatment fluid is obtained after holding 100-110 DEG C of system temperature reaction 2.5 hours, uses injecting systems after then dropping to room temperature
The cashmere albumen pretreatment fluid of preparation is added in viscose glue according to the ratio of cashmere albumen pretreatment fluid and viscose glue volume ratio 1:10,
Enter bucket among maturation after static mixer mixes, be always maintained at stirring among maturation in bucket, maintains reaction 6 hours
Spinning is directly carried out afterwards obtains wet cashmere protein cellulose fiber；
(2) the wet cashmere protein cellulose fiber for obtaining step (1) carries out mixing combing with cotton fiber or synthetic fibers
Obtain wet non-woven fabrics fiber net；
(3) it carries out 360 degree of full dimension spun lacings to the wet non-woven fabrics fiber net that step (2) obtains with clear water to consolidate, totally 11
Spun lacing process, spun lacing pressure are stepped up at spiral gradient；Last in spun lacing process punches skill by high-pressure water-jet together
Art forms non-woven fabrics cloth cover every square centimeter while being evenly distributed 60 deflector holes when shaping；
(4) spunlace non-woven cloth made from step (3) is moved into tunnel drier, is in 80~100 DEG C, transmission speed
Under conditions of 0.1~0.5r/min, 2~3h, the aqueous humidity 7.5%-9.5% of final non-woven fabrics are handled.
Final cashmere protein cellulose fiber spunlace non-woven cloth obtained is made of the fiber of following weight percent:
11.56% cashmere albumen, 88.44% cotton fiber or synthetic fibers, wherein cashmere albumen pass through γ-(2,3- the third oxygen of epoxy)
Propyl trimethoxy silicane is grafted on cellulose, and the fiber number of fiber is 1.33dtex.
The present embodiment is organically combined by the grafting of cashmere albumen, front end spinning technique and spun lacing process, integration production,
Process flow is substantially reduced, technique is simplified, method is easy, is easy to large-scale production, the compound fibre of cashmere (wool) obtained
Dimension surface of cloth is smooth, is not easy pilling.
Cashmere protein content is measured using Kjeldahl's method, the items through spunlace non-woven cloth made from this instance method are specific
Index such as table 1:
1 cashmere protein cellulose fiber spunlace non-woven cloth product parameters of table
1 cashmere protein cellulose fiber spunlace non-woven cloth product parameters of table
As shown in table 1, spunlace non-woven cloth manufactured in the present embodiment imparts non-woven fabrics on the basis of guaranteeing standard quality
Smooth, soft characteristic, and cashmere albumen is grafted on cellulose with covalent bond, it is stable, not easily to fall off, it is a kind of novel
Multifunctional composite is suitable for film cloth base material and garment lining etc..
Embodiment 2
Carry out the operation of following steps:
(1) it is pumped into 50L water to glassed steel reaction vessels, opens stirring, and the cashmere albumen of 10Kg is added, dilute hydroxide is added dropwise
System pH is adjusted to the cashmere albumen alkaline aqueous solution sufficiently dissolved after 11-12 by sodium solution, then by cashmere albumen
Alkaline aqueous solution is heated to 55-65 DEG C, 55-65 DEG C of maintenance system temperature under agitation in 20~30min in system
3.5L γ-glycidyl ether oxygen propyl trimethoxy silicane is added dropwise, system temperature is risen to 100-110 DEG C after dripping, maintains
100-110 DEG C of system temperature obtains cashmere albumen pretreatment fluid after reaction 2.5 hours, and then dropping to after room temperature will with injecting systems
The cashmere albumen pretreatment fluid of preparation is added in viscose glue according to the ratio of cashmere albumen pretreatment fluid and viscose glue volume ratio 1: 10, warp
Enter bucket among maturation after crossing static mixer mixing, stirring is always maintained among maturation in bucket, after maintaining reaction 6 hours
It directly carries out spinning and obtains wet cashmere protein cellulose fiber；
(2) the wet cashmere protein cellulose fiber for obtaining step (1) carries out mixing combing with cotton fiber or synthetic fibers
Obtain wet non-woven fabrics fiber net；
(3) it carries out 360 degree of full dimension spun lacings to the wet non-woven fabrics fiber net that step (2) obtains with clear water to consolidate, totally 11
Spun lacing process, spun lacing pressure are stepped up at spiral gradient；Last in spun lacing process punches skill by high-pressure water-jet together
Art forms non-woven fabrics cloth cover every square centimeter while being evenly distributed 60 deflector holes when shaping；
(4) spunlace non-woven cloth made from step (3) is moved into tunnel drier, is in 80~100 DEG C, transmission speed
Under conditions of 0.1~0.5r/min, 2~3h, the aqueous humidity 7.5%-9.5% of final non-woven fabrics are handled.
Final cashmere protein cellulose fiber spunlace non-woven cloth obtained is made of the fiber of following weight percent:
11.51% cashmere albumen, 88.49% cotton fiber or synthetic fibers, wherein cashmere albumen pass through γ-glycidyl ether oxygen third
Base trimethoxy silane is grafted on cellulose, and the fiber number of fiber is 1.67dtex.
The specific embodiment of the application above described embodiment only expresses, the description thereof is more specific and detailed, but simultaneously
The limitation to the application protection scope therefore cannot be interpreted as.It should be pointed out that for those of ordinary skill in the art
For, under the premise of not departing from technical scheme design, various modifications and improvements can be made, these belong to this
The protection scope of application.
Claims (3)
1. a kind of production method of cashmere protein cellulose fiber spunlace non-woven cloth, which is characterized in that cashmere protein cellulose is fine
Dimension spunlace non-woven cloth is made of the fiber of following weight percent: the cotton of the cashmere protein cellulose fiber of 5-15%, 85-95%
Fiber or synthetic fibers, cashmere albumen are grafted on cellulose by silane coupling agent, and the fiber number of fiber is 1.33-
1.67dtex；Production method includes the following steps:
(1) it prepares cashmere protein cellulose fiber: preparing the cashmere albumen alkalinity that mass fraction is 5-15%, pH value is 11-12
Cashmere albumen alkaline aqueous solution is heated to 55-65 DEG C, silane coupling agent is added dropwise under agitation, after dripping by aqueous solution
System temperature is risen to 100-110 DEG C, cashmere albumen pretreatment fluid is obtained after maintaining reaction 2-3 hours, then drops to room temperature
Viscose glue is added according to the ratio of cashmere albumen pretreatment fluid and viscose glue volume ratio 1:10 in the cashmere albumen pretreatment fluid of preparation afterwards
In, bucket among maturation is entered after being sufficiently mixed, is always maintained at stirring among maturation in bucket, it is straight after maintaining reaction 6-10 hours
It taps into row spinning and obtains wet cashmere protein cellulose fiber；
(2) the wet cashmere protein cellulose fiber that step (1) obtains mix combing with cotton fiber or synthetic fibers and be obtained
Wet non-woven fabrics fiber net；
(3) it carries out 360 degree of full dimension spun lacings to the wet non-woven fabrics fiber net that step (2) obtains with clear water to consolidate, totally 11 spun lacing
Process, spun lacing pressure are stepped up at spiral gradient；Last in spun lacing process passes through high-pressure water-jet cheesing techniques, shape together
60 deflector holes are evenly distributed when shaping simultaneously at non-woven fabrics cloth cover every square centimeter；
(4) spunlace non-woven cloth made from step (3) is moved into tunnel drier, in 80~100 DEG C, transmission speed 0.1
Under conditions of~0.5r/min, 2~3h, the aqueous humidity 7.5%-9.5% of final non-woven fabrics are handled.
2. a kind of production method of cashmere protein cellulose fiber spunlace non-woven cloth as described in claim 1, which is characterized in that
In step (1), the dosage of silane coupling agent is the 30-40% of cashmere albumen quality, and the time that silane coupling agent is added dropwise is 20-
30min。
3. a kind of production method of cashmere protein cellulose fiber spunlace non-woven cloth according to claim 1 or 2, feature
It is, the silane coupling agent is γ-(2,3- the third oxygen of epoxy) propyl trimethoxy silicane or γ-glycidyl ether oxygen propyl three
Methoxy silane.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201611163223.5A CN106835492B (en) | 2016-12-15 | 2016-12-15 | A kind of production method of cashmere protein cellulose fiber spunlace non-woven cloth |
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| CN201611163223.5A CN106835492B (en) | 2016-12-15 | 2016-12-15 | A kind of production method of cashmere protein cellulose fiber spunlace non-woven cloth |
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| CN106835492B true CN106835492B (en) | 2019-07-16 |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| DE102004030393A1 (en) * | 2004-06-23 | 2006-01-26 | Carl Freudenberg Kg | Production of 3-dimensional molded fleece, used as thermal insulation or reinforcement, involves molding mechanically consolidated fleece in z-direction by treating one side with high-pressure fluid jets on small-mesh perforated screen |
| CN1896358A (en) * | 2005-07-12 | 2007-01-17 | 欣龙控股（集团）股份有限公司 | Woolen fibre water-penetrated non-fabric sanitary material and its production |
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| CN106835492A (en) | 2017-06-13 |
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