CN106835189B - A kind of sodium hypochlorite electrolytic cell assembly of multi-channel structure - Google Patents

A kind of sodium hypochlorite electrolytic cell assembly of multi-channel structure Download PDF

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Publication number
CN106835189B
CN106835189B CN201710092968.5A CN201710092968A CN106835189B CN 106835189 B CN106835189 B CN 106835189B CN 201710092968 A CN201710092968 A CN 201710092968A CN 106835189 B CN106835189 B CN 106835189B
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China
Prior art keywords
electrolytic cell
plate
cell assembly
sodium hypochlorite
channel structure
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CN201710092968.5A
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CN106835189A (en
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刘齐鑫
石角
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Guangzhou new Olympic Environment Technology Co., Ltd.
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Guangzhou Xin Ao Environmental Protection Equipment Engineering Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25BELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B9/00Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
    • C25B9/70Assemblies comprising two or more cells
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25BELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B1/00Electrolytic production of inorganic compounds or non-metals
    • C25B1/01Products
    • C25B1/24Halogens or compounds thereof
    • C25B1/26Chlorine; Compounds thereof
    • C25B1/265Chlorates

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)

Abstract

A kind of sodium hypochlorite electrolytic cell assembly of multi-channel structure, it is characterised in that:The electrolytic cell assembly includes multichannel buffer tank, the pipe being connected to multichannel buffer tank dress electrolytic cell;The pipe fills the electrolyte chamber that electrolytic cell includes several mutually isolated, and the multichannel buffer tank corresponds to each electrolyte chamber and is provided with independent exhalant canal;The multichannel buffer tank is provided with electrolyte feeding opening, each electrolyte chamber is provided with finished fluid outlet, pipe dress electrolytic cell in the present invention is provided with several independent electrolyte chambers, multichannel buffer tank corresponds to each electrolyte chamber and is provided with independent exhalant canal, makes electrolyte evenly into each electrolyte chamber, and the utilization rate of electric energy is high in electrolytic process, electrolytic process calorific value is low, hydrogen in pipe dress electrolytic cell can be discharged in time, reduce the heat of pipe dress electrolytic cell, improve electrolytic efficiency.

Description

A kind of sodium hypochlorite electrolytic cell assembly of multi-channel structure
Technical field
The present invention relates to a kind of sodium hypochlorite electrolytic cell assemblies of multi-channel structure, belong to chemical field.
Background technology
In the prior art, electrolysis sodium hypochlorite electrolytic cell is broadly divided into pipe loading board formula structure electrolysis slot and square plate type electrolysis Slot, it is strip tubular type that Large Tube, which fills cell construction, and weak brine water inlet pipe is arranged in the leading portion of pipe, and finished product drug is arranged in the end of pipe Pipe is provided with multistage partition board in electrolytic cell, and weak brine is all entered by a water inlet in electrolytic cell, then by multistage every Plate flows out finally by finished product drug discharging tube, due to being only equipped with the medicine storing pot of a water inlet, causes electrolyte in the process of electrolysis In be unevenly distributed, electrolytic efficiency is low, and due in electrolytic process salinity reducing always, arrived electrolytic cell end, energy consumption Using very low, entire to be electrolysed calorific value big, and hydrogen cannot be discharged in time, and the hydrogen retained in electrolytic cell is more, danger system Number is high.
Therefore, it is necessary to be further improved.
Invention content
It is an object of the invention to overcome above-mentioned the shortcomings of the prior art, and provide a kind of secondary chlorine of multi-channel structure Sour natrium electrolytic cell device, middle pipe dress electrolytic cell are provided with several independent electrolyte chambers, and multichannel buffer tank corresponds to each electrolysis Chamber is provided with independent exhalant canal, makes electrolytic efficiency higher.
The object of the present invention is achieved like this:
A kind of sodium hypochlorite electrolytic cell assembly of multi-channel structure, the electrolytic cell assembly include multichannel buffer tank, with The pipe of multichannel buffer tank connection fills electrolytic cell;The pipe fills the electrolyte chamber that electrolytic cell includes several mutually isolated, described mostly logical Road surge tank corresponds to each electrolyte chamber and is provided with independent exhalant canal;The multichannel buffer tank is provided with electrolyte into medicine Mouthful, each electrolyte chamber is provided with finished fluid outlet.
Several spacing boards are provided in the pipe dress electrolytic cell, pipe dress electrolytic cell is separated into several mutually independent electrolysis Chamber.
Several electrode plates are provided in the pipe dress electrolytic cell, pipe dress electrolytic cell both sides are respectively arranged with fixed plate electrode Cathode terminal, anode terminal.
The electrode plate includes anode plate, cathode plate;The anode plate is arranged on anode terminal, and cathode plate setting exists On cathode terminal.
The electrolytic cell assembly includes electrolysis power, the electrolysis power anode jointed anode binding post, and electrolysis power is negative Pole connects cathode terminal.
The cushion block for spaced electrodes plate is provided between two adjacent electrode plates, electrode plate is fixed by screw arbor assembly Connection.
The pipe dress electrolytic cell further includes electrolytic zinc-coated steel sheet, and the electrolytic zinc-coated steel sheet includes anode electrolysis plate, catholyte plate, the sun Pole electrolytic zinc-coated steel sheet is arranged on anode plate, and catholyte plate is arranged on cathode plate.
The electrode plate is fabricated by titanium-base, and the anode plate surface is protected coated with nano level ruthenium iridium oxide Layer.
The pipe dress electrolytic cell and spacing board are fabricated by hard polyvinyl chloride or organic glass.
The electrolytic cell assembly is provided with the metering pump being connected to electrolyte feeding opening.
Beneficial effects of the present invention are as follows:
Pipe dress electrolytic cell is provided with several independent electrolyte chambers, and multichannel buffer tank corresponds to each electrolyte chamber and is provided with independence Exhalant canal, make electrolyte evenly into each electrolyte chamber, the utilization rate of electric energy is high in electrolytic process, electrolytic process fever Measure it is low, pipe dress electrolytic cell in hydrogen can be discharged in time, reduce pipe dress electrolytic cell heat, improve electrolytic efficiency.
Description of the drawings
Fig. 1 is the structural schematic diagram of one embodiment of the invention.
Specific implementation mode
The invention will be further described with reference to the accompanying drawings and embodiments.
Referring to Fig. 1, the sodium hypochlorite electrolytic cell assembly of this multi-channel structure, the electrolytic cell assembly includes multichannel buffer Tank 2, the pipe being connected to multichannel buffer tank 2 fill electrolytic cell 3;The pipe dress electrolytic cell 3 includes several mutually isolated electrolyte chamber 31, the multichannel buffer tank 2 corresponds to each electrolyte chamber 31 and is provided with independent exhalant canal 21;The multichannel buffer tank 2 It is provided with electrolyte feeding opening 1, each electrolyte chamber 31 is provided with finished fluid outlet 6, and hydrogen equally exports 6 rows from finished fluid Go out, multiple finished fluid outlets 6 ensure that the timely discharge of hydrogen, ensure that production safety, and the interpolar that need not be additionally arranged Hydrogen gas segregator reduces the production cost of electrolytic cell assembly.
One multichannel buffer tank 2 is set before pipe fills electrolytic cell 3, and pipe dress electrolytic cell 3 is provided with several independent electricity Solve chamber 31, multichannel buffer tank 2 corresponds to each electrolyte chamber 31 and is provided with independent exhalant canal 21, make electrolyte evenly into Each electrolyte chamber 31, keeps the concentration of electrolyte gradient in each electrolyte chamber 31 low, i.e., each position electrolyte is dense in electrolyte chamber 31 Degree is not much different, and the utilization rate of electric energy is high in electrolytic process, and electrolytic process calorific value is low, reduces the heat of pipe dress electrolytic cell 3, carries High electrolytic efficiency.
Multichannel buffer tank 2 must can guarantee that electrolyte stablizes outflow, and the quantity of exhalant canal 21, and size must be through Stringent calculating is crossed, electrolyte various concentration is measured and is electrolysed consumed electric energy, the heat of generation obtains water outlet by measuring and calculation The quantity and size in channel 21, which must assure that, is in that energy consumption is minimum in electrolyte electrolytic process, each under the operating mode of heat minimum The product of kind specification is required for completing after stringent test.
Recirculated cooling water, the electrolytic cell in the present invention is arranged due to the excessive needs of heat in conventional electrolytic cell in electrolytic cell Device need not be filled in pipe is arranged cooling device in electrolytic cell 3, simplify the internal structure of pipe dress electrolytic cell 3, reduce electrolytic cell The production cost of device.
Further, several spacing boards 8 are provided in the pipe dress electrolytic cell 3, pipe dress electrolytic cell 3 is separated into several phases Mutual independent electrolyte chamber 31.
Further, several electrode plates 4 are provided in the pipe dress electrolytic cell 3,3 both sides of pipe dress electrolytic cell are respectively arranged with Cathode terminal 7, the anode terminal 5 of fixed plate electrode 4.
Further, the electrode plate 4 includes anode plate, cathode plate;The anode plate is arranged on anode terminal 5, Cathode plate is arranged on cathode terminal 7.
Further, the electrolytic cell assembly includes electrolysis power, the electrolysis power anode jointed anode binding post 5, Electrolysis power cathode connects cathode terminal 7.
Further, the cushion block for spaced electrodes plate 4 is provided between two adjacent electrode plates 4, electrode plate 4 passes through Screw arbor assembly 9 is fixedly connected, and 9 each component of screw arbor assembly is fabricated by Kynoar, the corrosion resistance of Kynoar By force, oxidation resistance is strong, is suitable for sodium hypochlorite electrolysis production.
Further, the pipe dress electrolytic cell 3 further includes electrolytic zinc-coated steel sheet, and the electrolytic zinc-coated steel sheet includes anode electrolysis plate, cathode electricity Plate is solved, the anode electrolysis plate is arranged on anode plate, and catholyte plate is arranged on cathode plate.
Further, the electrode plate 4 is fabricated by titanium-base, and the anode plate surface is coated with nano level ruthenium iridium Protective oxide film.
Further, the pipe dress electrolytic cell 3 and spacing board 8 are fabricated by hard polyvinyl chloride or organic glass, firmly Polyvinyl chloride, the corrosion resistance of organic glass are strong, and oxidation resistance is strong, and have certain intensity, are suitable for sodium hypochlorite Electrolysis production.
Further, the electrolytic cell assembly is provided with the metering pump being connected to electrolyte feeding opening 1.
Specific production stage is as follows:
Electrolyte is conveyed by metering pump to be entered through electrolyte feeding opening 1 in multichannel buffer tank 2, multichannel buffer tank 2 Each exhalant canal 21 to 31 conveying electrolyte of corresponding electrolyte chamber, electrolyte is electrolysed in independent electrolyte chamber 31, Finished fluid and hydrogen are discharged in time by the finished product medicine outlet 6 of respective electrolyte chamber 31.
Above-described embodiment is the preferred embodiment of the present invention, and the present invention can also have other embodiments.The technology of this field Personnel can also make equivalent variations or replacement under the premise of without prejudice to spirit of that invention, these equivalent modifications or replacement are wrapped It is contained in the range set by the application claim.

Claims (10)

1. a kind of sodium hypochlorite electrolytic cell assembly of multi-channel structure, it is characterised in that:The electrolytic cell assembly includes multichannel Surge tank(2)And multichannel buffer tank(2)The pipe of connection fills electrolytic cell(3);The pipe fills electrolytic cell(3)Including several mutual The electrolyte chamber of isolation(31), the multichannel buffer tank(2)Corresponding each electrolyte chamber(31)It is provided with independent exhalant canal (21);The multichannel buffer tank(2)It is provided with electrolyte feeding opening(1), each electrolyte chamber(31)It is provided with finished fluid Outlet(6).
2. the sodium hypochlorite electrolytic cell assembly of multi-channel structure according to claim 1, it is characterised in that:The pipe dress electricity Solve slot(3)Inside it is provided with several spacing boards(8), pipe is filled into electrolytic cell(3)It is separated into several mutually independent electrolyte chambers(31).
3. the sodium hypochlorite electrolytic cell assembly of multi-channel structure according to claim 1, it is characterised in that:The pipe dress electricity Solve slot(3)Inside it is provided with several electrode plates(4), pipe dress electrolytic cell(3)Both sides are respectively arranged with fixed plate electrode(4)Cathode connect Terminal(7), anode terminal(5).
4. the sodium hypochlorite electrolytic cell assembly of multi-channel structure according to claim 3, it is characterised in that:The electrode plate (4)Including anode plate, cathode plate;The anode plate is arranged in anode terminal(5)On, cathode plate is arranged in cathode terminal (7)On.
5. the sodium hypochlorite electrolytic cell assembly of multi-channel structure according to claim 3, it is characterised in that:The electrolytic cell Device includes electrolysis power, the electrolysis power anode jointed anode binding post(5), electrolysis power cathode connection cathode terminal (7).
6. the sodium hypochlorite electrolytic cell assembly of multi-channel structure according to claim 3, it is characterised in that:Described two is adjacent Electrode plate(4)Between be provided with for spaced electrodes plate(4)Cushion block, electrode plate(4)Pass through screw arbor assembly(9)It is fixedly connected.
7. the sodium hypochlorite electrolytic cell assembly of multi-channel structure according to claim 4, it is characterised in that:The pipe dress electricity Solve slot(3)Further include electrolytic zinc-coated steel sheet, the electrolytic zinc-coated steel sheet includes anode electrolysis plate, catholyte plate, and the anode electrolysis plate setting exists On anode plate, catholyte plate is arranged on cathode plate.
8. the sodium hypochlorite electrolytic cell assembly of multi-channel structure according to claim 4, it is characterised in that:The electrode plate (4)It is fabricated by titanium-base, the anode plate surface is coated with nano level ruthenium iridium oxide protective layer.
9. the sodium hypochlorite electrolytic cell assembly of multi-channel structure according to claim 2, it is characterised in that:The pipe dress electricity Solve slot(3)And spacing board(8)It is fabricated by hard polyvinyl chloride or organic glass.
10. according to the sodium hypochlorite electrolytic cell assembly of claim 1 to 9 any one of them multi-channel structure, it is characterised in that: The electrolytic cell assembly is provided with and electrolyte feeding opening(1)The metering pump of connection.
CN201710092968.5A 2017-02-21 2017-02-21 A kind of sodium hypochlorite electrolytic cell assembly of multi-channel structure Active CN106835189B (en)

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CN108265312B (en) * 2018-02-11 2024-06-04 广东卓信环境科技股份有限公司 Electrolytic tank of hypochlorite generator
CN111893510B (en) * 2020-07-30 2023-05-26 福建铭麟科技有限公司 Electrolytic tank device with multichannel structure

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CN207276735U (en) * 2017-02-21 2018-04-27 广州市新奥环保设备工程有限公司 A kind of sodium hypochlorite electrolytic cell assembly of multi-channel structure

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JPS5350072A (en) * 1976-10-19 1978-05-08 Toagosei Chem Ind Co Ltd Multiple electrode type electrolytic cell with ion exchange membrane
JPS563689A (en) * 1979-06-26 1981-01-14 Chlorine Eng Corp Ltd Electrolytic apparatus for electrolysis of aqueous solution
KR100692331B1 (en) * 2005-03-09 2007-03-09 김진군 Dumpling with incense of live coals and preparation thereof
WO2011115370A2 (en) * 2010-03-15 2011-09-22 유니테크 주식회사 Electrolyzer for producing sodium hypochlorite
FR2976590B1 (en) * 2011-06-16 2014-06-13 Mp Technic DEVICE FOR MANUFACTURING OR PRODUCING SODIUM HYPOCHLORITE OR HYPOCHLOROUS ACID AND SYSTEM FOR TREATING WATER IN GENERAL
CN203429268U (en) * 2013-09-13 2014-02-12 重庆市亚太环保工程技术设计研究所有限公司 Electrolytic reactor of sodium hypochlorite

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CN207276735U (en) * 2017-02-21 2018-04-27 广州市新奥环保设备工程有限公司 A kind of sodium hypochlorite electrolytic cell assembly of multi-channel structure

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Address after: 510670 Third Floor, 119 Science Avenue, Science City, Guangzhou High-tech Industrial Development Zone, Guangdong Province

Patentee after: Guangzhou new Olympic Environment Technology Co., Ltd.

Address before: Room 31, No. 15 Chebi Road, Tianhe District, Guangzhou City, Guangdong Province

Patentee before: Guangzhou Xin Ao environmental protection equipment Engineering Co., Ltd

PE01 Entry into force of the registration of the contract for pledge of patent right
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Denomination of invention: A multichannel sodium hypochlorite electrolyzer

Effective date of registration: 20201021

Granted publication date: 20181113

Pledgee: China Co. truction Bank Corp Guangzhou economic and Technological Development Zone sub branch

Pledgor: NEAO GUANGZHOU ENVIRONMENTAL TECHNOLOGY Co.,Ltd.

Registration number: Y2020440000331