CN106834828A - A kind of standby aluminium alloy of extra large frock and preparation method thereof - Google Patents

A kind of standby aluminium alloy of extra large frock and preparation method thereof Download PDF

Info

Publication number
CN106834828A
CN106834828A CN201710105942.XA CN201710105942A CN106834828A CN 106834828 A CN106834828 A CN 106834828A CN 201710105942 A CN201710105942 A CN 201710105942A CN 106834828 A CN106834828 A CN 106834828A
Authority
CN
China
Prior art keywords
aluminium alloy
extra large
alloys
standby
frock
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN201710105942.XA
Other languages
Chinese (zh)
Other versions
CN106834828B (en
Inventor
罗铭强
王顺成
陈树钦
陈文泗
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
GUANGDONG XINGFA ALUMINIUM CO Ltd
Original Assignee
GUANGDONG XINGFA ALUMINIUM CO Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by GUANGDONG XINGFA ALUMINIUM CO Ltd filed Critical GUANGDONG XINGFA ALUMINIUM CO Ltd
Priority to CN201710105942.XA priority Critical patent/CN106834828B/en
Publication of CN106834828A publication Critical patent/CN106834828A/en
Application granted granted Critical
Publication of CN106834828B publication Critical patent/CN106834828B/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C21/00Alloys based on aluminium
    • C22C21/06Alloys based on aluminium with magnesium as the next major constituent
    • C22C21/08Alloys based on aluminium with magnesium as the next major constituent with silicon
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C1/00Making non-ferrous alloys
    • C22C1/02Making non-ferrous alloys by melting
    • C22C1/026Alloys based on aluminium
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C1/00Making non-ferrous alloys
    • C22C1/02Making non-ferrous alloys by melting
    • C22C1/03Making non-ferrous alloys by melting using master alloys
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22FCHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS
    • C22F1/00Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working
    • C22F1/002Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working by rapid cooling or quenching; cooling agents used therefor
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22FCHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS
    • C22F1/00Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working
    • C22F1/04Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of aluminium or alloys based thereon
    • C22F1/047Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of aluminium or alloys based thereon of alloys with magnesium as the next major constituent

Abstract

A kind of standby aluminium alloy of extra large frock and preparation method thereof, the extra large standby aluminium alloy of frock is made up of following component and mass percent:Mg 4.1~4.5%, Mn 0.3~0.5%, Si 0.4~0.6%, Li 0.5~0.7%, Zr 0.005~0.015%, C 0.001~0.003%, Re 0.03~0.05%, Fe≤0.15%, Cr≤0.1%, balance of Al and inevitable impurity, impurity is single≤0.05%, total amount≤0.15%.The sea standby aluminium alloy of frock of the invention has the advantages that intensity is high, plasticity is good, corrosion-resistant, welding performance is excellent, it is suitable for the standby aluminium alloy pipe of the extra large frock such as manufacture sea fishery, oil and gas development, communications and transportation, tourism, electric power, offshore construction, bar and section bar, with wide market application foreground.

Description

A kind of standby aluminium alloy of extra large frock and preparation method thereof
Technical field
The invention belongs to technical field of aluminum alloy technology, a kind of standby aluminium alloy of extra large frock and preparation method thereof is specifically related to.
Background technology
Ocean power is built, marine resources development ability is improved, Development of Marine economy is protected the marine eco-environment, safeguarded National marine rights and interests, are the significant development strategies of China.The standby important leverage for being to build ocean power of extra large frock, extra large work kit Include sea fishery equipment, offshore and gas development equipment, maritime transportation equipment, marine tourism equipment, ocean electrical circuitry equipment, Offshore construction equipment etc..Traditional sea frock is mainly ferrous materials for material, though ferrous materials have the advantages that intensity is high, Weight is big, and decay resistance is poor, causes the standby transport of extra large frock and maintenance cost all higher.Aluminium alloy have it is lightweight, into Shape processability is good, it is corrosion-resistant the advantages of, replace existing ferrous materials to manufacture extra large frock using aluminum alloy materials standby, can improve The standby decay resistance of extra large frock, reduces maintenance cost, while the standby weight of extra large frock can also significantly be mitigated, improves extra large frock standby Maneuverability and carrying capacity, and obtain the effect of energy-saving and emission-reduction.
5xxx line aluminium alloys belong to the middle strength aluminium alloy of not heat-treatable strengthened type, with good decay resistance and Welding performance, is widely used in ship, pressure vessel, refrigerating plant, television tower, plate armour, missile parts etc., such as ship and railcar Sheet metal component, automobile and aircraft weldment, liquid tank car, refrigerator car, the fuel tank oil pipe of aircraft and electric appliance casing etc..But mesh Preceding conventional 5xxx line aluminium alloys, such as 5005,5052,5083, though have the advantages that decay resistance and welding performance are excellent, That due to not heat-treatable strengthened, its intensity is still relatively low, cause the 5xxx line aluminium alloys of these trades mark in use its The problem that intensity is not enough, shock resistance is poor becomes increasingly conspicuous, it is impossible to meet the standby demand for development of modern sea frock.
The content of the invention
Above-mentioned there is problem and shortage it is an object of the invention to be directed to, there is provided a kind of intensity is high, plasticity is good, corrosion-resistant, Excellent standby aluminium alloy of extra large frock of welding performance and preparation method thereof.
The technical proposal of the invention is realized in this way:
The standby aluminium alloy of extra large frock of the present invention, is characterized in being made up of following component and mass percent:Mg 4.1~ 4.5%, Mn 0.3~0.5%, Si 0.4~0.6%, Li 0.5~0.7%, Zr 0.005~0.015%, C 0.001~0.003%, Re 0.03~0.05%, Fe≤0.15%, Cr≤0.1%, balance of Al and inevitable impurity, impurity is single≤and 0.05%, Total amount≤0.15%, wherein the Re into being grouped into and mass percent is:Pr 16.3%, Nd 23.4%, Pm 10.2%, Sm 16.5%, Eu 14.9%, Gd 18.7%.
Preferably, the standby aluminium alloy of extra large frock of the present invention, is made up of following component and mass percent:Mg 4.3%, Mn 0.4%, Si 0.5%, Li 0.6%, Zr 0.01%, C 0.002%, Re 0.04%, Fe≤0.15%, Cr≤0.1%, Balance of Al and inevitable impurity, impurity is single≤0.05%, total amount≤0.15%, wherein the Re into being grouped into and matter Measuring percentage is:Pr 16.3%, Nd 23.4%, Pm 10.2%, Sm 16.5%, Eu 14.9%, Gd 18.7%.
The preparation method of the standby aluminium alloy of extra large frock of the present invention, is characterized in comprising the following steps:
The first step:From technical pure aluminium ingot, pure magnesium ingot, instant silicon, Al20Mn alloys, Al20Li alloys, Al5Zr1C alloys and mixed Rare earth Re is closed as raw material;
Second step:By aluminium ingot in 720~760 DEG C of heating fusings, and add account for magnesium ingot that raw material gross weight is 4.1~4.5%, 0.4~0.6% instant silicon, 1.5~2.5% Al20Mn alloys and 2.5~3.5% Al20Li alloys, stirring are fused into aluminium conjunction Golden liquid;
3rd step:After to aluminum alloy melt refining degasification slagging-off, the Al5Zr1C for accounting for that raw material gross weight is 0.1~0.3% is added Alloy and 0.03~0.05% mischmetal Re, the composition that stirring enables aluminum alloy to liquid are uniform;
4th step:Aluminum alloy melt is cooled to 700~740 DEG C and 1~2 hour is stood, aluminium alloy is then cast as;
5th step:By aluminium alloy in 480~500 DEG C of solution treatment 2~3 hours, after water quenching, in 130~150 DEG C of Ageing Treatments 4 ~8 hours, the standby aluminium alloy of extra large frock is obtained after furnace cooling.
The present invention compared with prior art, with advantages below:
The room temperature tensile intensity of the sea standby aluminium alloy of frock of the invention is more than 430MPa, and yield strength is more than 390MPa, elongation More than 15%, have the advantages that intensity is high, plasticity is good, corrosion-resistant, welding performance is excellent, be suitable for manufacture sea fishery, oil gas and open The standby aluminium alloy pipe of the sea frock such as hair, communications and transportation, tourism, electric power, offshore construction, bar and section bar, with wide Market application foreground.
Specific embodiment
To make the purpose of the present invention, technical scheme and effect clearer, clear and definite, make further detailed to the present invention below Describe in detail bright.
The standby aluminium alloy of extra large frock of the present invention, is made up of following component and mass percent:Mg 4.1~4.5%, Mn 0.3~0.5%, Si 0.4~0.6%, Li 0.5~0.7%, Zr 0.005~0.015%, C 0.001~0.003%, Re 0.03~0.05%, Fe≤0.15%, Cr≤0.1%, balance of Al and inevitable impurity, impurity is single≤and 0.05%, always Amount≤0.15%.
Preferably, the composition of the standby aluminium alloy of extra large frock and mass percent composition are:Mg 4.3%, Mn 0.4%, Si 0.5%, Li 0.6%, Zr 0.01%, C 0.002%, Re 0.04%, Fe≤0.15%, Cr≤0.1%, balance of Al and not Evitable impurity, impurity is single≤0.05%, total amount≤0.15%.
The Re into being grouped into and mass percent is:Pr 16.3%, Nd 23.4%, Pm 10.2%, Sm 16.5%, Eu 14.9%, Gd 18.7%.
Wherein, Mg is the main alloy element of the sea standby aluminium alloy of frock of the invention, and Mg solubility in aluminium alloy is very big, Mainly rise solution strengthening effect, in addition, Mg is formed in the ageing process of aluminium alloy of the present invention strengthen effect it is extremely notable Mg2Si phases, strengthen the intensity of aluminium alloy.With the increase of Mg contents, the intensity of aluminium alloy is higher.But Mg contents are too high, aluminium The hot cracking tendency and plasticity of alloy cast ingot can also decline, and forming performance degenerates.In order to ensure aluminium alloy have it is enough strong Degree, plasticity and forming performance, the selection of Mg contents is 4.1~4.5%, it is preferred that Mg contents are Mg 4.3%.
Mn can form MnAl in the sea standby aluminium alloy of frock of the invention6Compound disperses particle, can prevent aluminium alloy Recrystallization process, improves recrystallization temperature, and can significantly refine recrystal grain.Mn in aluminium alloy can also dissolved impurity Fe, Formed(Fe、Mn)Al6, reduce the adverse effect of iron, improve the corrosion resistance and welding performance of aluminium alloy.But Mn contents are too high Also element segregation is easily caused, therefore, the Mn of selection addition 0.3~0.5%, it is preferred that Mn contents are 0.4%.
Li is most light metallic element, and Li is added in the standby aluminium alloy of extra large frock, and the close of aluminium alloy can be reduced first Degree, improves the specific strength and specific stiffness of aluminium alloy, reaches light-weighted effect.Secondly, Li can also separate out nanometer in ag(e)ing process The Al of size3Li、Al2The hardening constituents such as MgLi, these hardening constituents can pinning dislocation, subgrain and crystal boundary, suppress alloy recrystallization, carry The intensity of high-aluminium alloy, plasticity and welding performance, the micro Li of addition 0.5~0.7% can produce obvious reinforcing to aluminium alloy Effect, it is preferred that Li additions are 0.6%.
Zr, C are that Al5Zr1C alloys are by potassium fluorozirconate and carbon dust in being added to aluminium alloy in the form of Al5Zr1C alloys The reaction of mixture and aluminium liquid obtain, substantial amounts of ZrC particles are contained in inside.Al5Zr1C alloys are that a kind of new aluminium alloy is brilliant Grain fining agent, inventor experimental results demonstrate the existing Al5Ti1B and Al5Ti1C alloys of Al5Zr1C alloy ratios have stronger Grain refining capability, the Al5Zr1C alloys of addition 0.1~0.3%, in aluminium alloy containing 0.005~0.015% Zr and 0.001~0.003% C, can notable refining aluminum alloy crystal grain, improve the structural homogenity of aluminium alloy, improve the modeling of aluminium alloy Property deformability, it is preferred that Al5Zr1C alloy addition levels be 0.2%, the C of 0.01% Zr and 0.002% is contained in aluminium alloy.
Re is to contain Pr, Nd, Pm, Sm, Eu, Gd totally six kinds of mischmetals of LREE, the physics of LREE Chemical property is active, can be with impurity element reaction generation high-melting-point, the high stable such as the hydrogen in aluminum alloy melt, oxygen, iron, zinc, copper, chromium The rare earth compound of property, has deep purifying to act on aluminum alloy melt, the adverse effect of impurity element can be eliminated, while rare earth is first Element can also improve the corrosion potential of aluminium alloy and form the rare-earth oxidation film of densification in aluminum alloy surface, improve the anti-crystalline substance of aluminium alloy Between corrosion and stress corrosion resistant ability.The experimental study of inventor shows that addition contains totally six kinds of Pr, Nd, Pm, Sm, Eu, Gd The effect of the mixed light rare earth of LREE is all more preferable than adding a kind of or a few LREE effect, therefore, The mischmetal of selection addition 0.03~0.05%, it is preferred that mischmetal addition is 0.04%.
Present invention also offers the preparation method of the extra large standby aluminium alloy of frock, following steps are specifically included:
The first step:From technical pure aluminium ingot, pure magnesium ingot, instant silicon, Al20Mn alloys, Al20Li alloys, Al5Zr1C alloys and mixed Rare earth Re is closed as raw material;
Second step:By aluminium ingot in 720~760 DEG C of heating fusings, and add account for magnesium ingot that raw material gross weight is 4.1~4.5%, 0.4~0.6% instant silicon, 1.5~2.5% Al20Mn alloys and 2.5~3.5% Al20Li alloys, stirring are fused into aluminium conjunction Golden liquid;
3rd step:After to aluminum alloy melt refining degasification slagging-off, the Al5Zr1C for accounting for that raw material gross weight is 0.1~0.3% is added Alloy and 0.03~0.05% mischmetal Re, the composition that stirring enables aluminum alloy to liquid are uniform;
4th step:Aluminum alloy melt is cooled to 700~740 DEG C and 1~2 hour is stood, aluminium alloy is then cast as;
5th step:By aluminium alloy in 480~500 DEG C of solution treatment 2~3 hours, after water quenching, in 130~150 DEG C of Ageing Treatments 4 ~8 hours, the standby aluminium alloy of extra large frock is obtained after furnace cooling.
Preparation method of the invention, from technical pure aluminium ingot, pure magnesium ingot, instant silicon, Al20Mn alloys, Al20Li alloys, Al5Zr1C alloys and mischmetal Re as raw material, by optimizing the content of main alloying element Mg, add instant silicon, Al20Mn alloys, Al20Li alloys carry out microalloying, after refined degasification, slagging-off, add Al5Zr1C alloys and mixing is dilute Native Re, can give full play to crystal grain refinement and the deep purifying effect of Al5Zr1C alloys and mischmetal Re to aluminum alloy melt, really The extra large standby aluminium alloy of frock of the invention that breaks even obtains high intensity, high-ductility and excellent decay resistance and welding performance.
In order to more describe present invention sea standby aluminium alloy of frock and preparation method thereof in detail, several embodiments are exemplified below It is further described.
Embodiment 1:
The standby aluminium alloy of extra large frock of the present invention, is made up of following component and mass percent:Mg 4.1%, Mn 0.3%, Si 0.4%, Li 0.5%, Zr 0.005%, C 0.001%, Re 0.03%, Fe≤0.15%, Cr≤0.1%, balance of Al and not Evitable impurity, impurity is single≤0.05%, total amount≤0.15%, wherein the Re into being grouped into and mass percent is: Pr 16.3%, Nd 23.4%, Pm 10.2%, Sm 16.5%, Eu 14.9%, Gd 18.7%.Preparation method is comprised the steps of:
The first step:From technical pure aluminium ingot, pure magnesium ingot, instant silicon, Al20Mn alloys, Al20Li alloys, Al5Zr1C alloys and mixed Rare earth Re is closed as raw material;
Second step:By aluminium ingot in 720 DEG C of heating fusings, and add the instant of the magnesium ingot, 0.4% for accounting for that raw material gross weight is 4.1% Silicon, 1.5% Al20Mn alloys and 2.5% Al20Li alloys, stirring are fused into aluminum alloy melt;
3rd step:After degasification slagging-off is refined to aluminum alloy melt with carbon trichloride, it is 0.1% to add and account for raw material gross weight Al5Zr1C alloys and 0.03% mischmetal Re, the composition that stirring enables aluminum alloy to liquid are uniform;
4th step:Aluminum alloy melt is cooled to 700 DEG C and 2 hours are stood, aluminium alloy is then cast as;
5th step:By aluminium alloy in 500 DEG C of solution treatment 2 hours, after water quenching, in 130 DEG C of Ageing Treatments 8 hours, furnace cooling After obtain the standby aluminium alloy of extra large frock.
Embodiment 2:
The standby aluminium alloy of extra large frock of the present invention, is made up of following component and mass percent:Mg 4.3%, Mn 0.4%, Si 0.5%, Li 0.6%, Zr 0.01%, C 0.002%, Re 0.04%, Fe≤0.15%, Cr≤0.1%, balance of Al and not Evitable impurity, impurity is single≤0.05%, total amount≤0.15%, wherein the Re into being grouped into and mass percent is: Pr 16.3%, Nd 23.4%, Pm 10.2%, Sm 16.5%, Eu 14.9%, Gd 18.7%.Preparation method is comprised the steps of:
The first step:From technical pure aluminium ingot, pure magnesium ingot, instant silicon, Al20Mn alloys, Al20Li alloys, Al5Zr1C alloys and mixed Rare earth Re is closed as raw material;
Second step:By aluminium ingot in 740 DEG C of heating fusings, and add the instant of the magnesium ingot, 0.5% for accounting for that raw material gross weight is 4.3% Silicon, 2% Al20Mn alloys and 3% Al20Li alloys, stirring are fused into aluminum alloy melt;
3rd step:Degasification is refined with carbon trichloride to aluminum alloy melt to remove the gred, it is 0.2% to add and account for raw material gross weight Al5Zr1C alloys and 0.04% mischmetal Re, the composition that stirring enables aluminum alloy to liquid are uniform;
4th step:Aluminum alloy melt is cooled to 720 DEG C and 1.5 hours are stood, aluminium alloy is then cast as;
5th step:It is cold with stove in 140 DEG C of Ageing Treatments 6 hours after water quenching by aluminium alloy in 490 DEG C of solution treatment 2.5 hours But the standby aluminium alloy of extra large frock is obtained afterwards.
Embodiment 3:
The standby aluminium alloy of extra large frock of the present invention, is made up of following component and mass percent:Mg 4.5%, Mn 0.5%, Si 0.6%, Li 0.7%, Zr 0.015%, C 0.003%, Re 0.05%, Fe≤0.15%, Cr≤0.1%, balance of Al and not Evitable impurity, impurity is single≤0.05%, total amount≤0.15%, wherein the Re into being grouped into and mass percent is: Pr 16.3%, Nd 23.4%, Pm 10.2%, Sm 16.5%, Eu 14.9%, Gd 18.7%.Preparation method is comprised the steps of:
The first step:From technical pure aluminium ingot, pure magnesium ingot, instant silicon, Al20Mn alloys, Al20Li alloys, Al5Zr1C alloys and mixed Rare earth Re is closed as raw material;
Second step:By aluminium ingot in 760 DEG C of heating fusings, and add the instant of the magnesium ingot, 0.6% for accounting for that raw material gross weight is 4.5% Silicon, 2.5% Al20Mn alloys and 3.5% Al20Li alloys, stirring are fused into aluminum alloy melt;
3rd step:Degasification is refined with carbon trichloride to aluminum alloy melt to remove the gred, it is 0.3% to add and account for raw material gross weight Al5Zr1C alloys and 0.05% mischmetal Re, the composition that stirring enables aluminum alloy to liquid are uniform;
4th step:Aluminum alloy melt is cooled to 740 DEG C and 1 hour is stood, aluminium alloy is then cast as;
5th step:By aluminium alloy in 480 DEG C of solution treatment 3 hours, after water quenching, in 150 DEG C of Ageing Treatments 4 hours, furnace cooling After obtain the standby aluminium alloy of extra large frock.
By National Standard of the People's Republic of China GB/T16865-2013, by the standby aluminium alloy of extra large frock of embodiment 1-3 Standard tensile specimen is processed into, room temperature tensile is carried out on DNS200 type electronic tensile test machines, rate of extension is 2 millis m/min Clock, tensile mechanical properties are as shown in table 1.
The tensile mechanical properties of the embodiment 1-3 of the table 1 seas standby aluminium alloy of frock
Embodiment sequence number Tensile strength/MPa Yield strength/MPa Elongation/%
Embodiment 1 431.5 391.7 18.9
Embodiment 2 458.7 414.4 16.5
Embodiment 3 489.1 445.3 14.5
From the testing result of table 1, the room temperature tensile intensity of the present invention sea standby aluminium alloy of frock is more than 430MPa, and surrender is strong Degree is more than 390MPa, and elongation is more than 14%, has the advantages that intensity is high, plasticity is good, corrosion-resistant, welding performance is excellent, is suitable for The standby aluminium alloy pipe of the extra large frock such as manufacture sea fishery, oil and gas development, communications and transportation, tourism, electric power, offshore construction, Bar and section bar, with wide market application foreground.
The present invention is described by embodiment, but is not limited the invention, with reference to description of the invention, institute Other changes of disclosed embodiment, such as the professional person for this area is readily apparent that, such change should belong to Within the scope of the claims in the present invention are limited.

Claims (3)

1. a kind of standby aluminium alloy of extra large frock, it is characterised in that be made up of following component and mass percent:Mg 4.1~4.5%, Mn 0.3~0.5%, Si 0.4~0.6%, Li 0.5~0.7%, Zr 0.005~0.015%, C 0.001~0.003%, Re 0.03~0.05%, Fe≤0.15%, Cr≤0.1%, balance of Al and inevitable impurity, impurity is single≤and 0.05%, always Amount≤0.15%, wherein the Re into being grouped into and mass percent is:Pr 16.3%, Nd 23.4%, Pm 10.2%, Sm 16.5%, Eu 14.9%, Gd 18.7%.
2. the standby aluminium alloy of extra large frock according to claim 1, it is characterised in that by following component and mass percent group Into:Mg 4.3%, Mn 0.4%, Si 0.5%, Li 0.6%, Zr 0.01%, C 0.002%, Re 0.04%, Fe≤0.15%, Cr ≤ 0.1%, balance of Al and inevitable impurity, impurity is single≤0.05%, total amount≤0.15%, wherein the composition of the Re Composition and mass percent are:Pr 16.3%, Nd 23.4%, Pm 10.2%, Sm 16.5%, Eu 14.9%, Gd 18.7%.
3. a kind of method for preparing as described in above-mentioned any claim the standby aluminium alloy of extra large frock, it is characterised in that including following Step:
The first step:From technical pure aluminium ingot, pure magnesium ingot, instant silicon, Al20Mn alloys, Al20Li alloys, Al5Zr1C alloys and mixed Rare earth Re is closed as raw material;
Second step:By aluminium ingot in 720~760 DEG C of heating fusings, and add account for magnesium ingot that raw material gross weight is 4.1~4.5%, 0.4~0.6% instant silicon, 1.5~2.5% Al20Mn alloys and 2.5~3.5% Al20Li alloys, stirring are fused into aluminium conjunction Golden liquid;
3rd step:After to aluminum alloy melt refining degasification slagging-off, the Al5Zr1C for accounting for that raw material gross weight is 0.1~0.3% is added Alloy and 0.03~0.05% mischmetal Re, the composition that stirring enables aluminum alloy to liquid are uniform;
4th step:Aluminum alloy melt is cooled to 700~740 DEG C and 1~2 hour is stood, aluminium alloy is then cast as;
5th step:By aluminium alloy in 480~500 DEG C of solution treatment 2~3 hours, after water quenching, in 130~150 DEG C of Ageing Treatments 4 ~8 hours, the standby aluminium alloy of extra large frock is obtained after furnace cooling.
CN201710105942.XA 2017-02-27 2017-02-27 A kind of offshore equipment aluminium alloy and preparation method thereof Active CN106834828B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710105942.XA CN106834828B (en) 2017-02-27 2017-02-27 A kind of offshore equipment aluminium alloy and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201710105942.XA CN106834828B (en) 2017-02-27 2017-02-27 A kind of offshore equipment aluminium alloy and preparation method thereof

Publications (2)

Publication Number Publication Date
CN106834828A true CN106834828A (en) 2017-06-13
CN106834828B CN106834828B (en) 2018-11-20

Family

ID=59134231

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201710105942.XA Active CN106834828B (en) 2017-02-27 2017-02-27 A kind of offshore equipment aluminium alloy and preparation method thereof

Country Status (1)

Country Link
CN (1) CN106834828B (en)

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2001049375A (en) * 1999-08-06 2001-02-20 Res Inst Electric Magnetic Alloys Al ALLOY HAVING EXCELLENT VIBRATION ABSORBABILITY AND ITS PRODUCTION
CN101538668A (en) * 2009-04-28 2009-09-23 中铝河南铝业有限公司 Production process of aluminum alloy hot rolling medium plate
CN101805854A (en) * 2009-09-23 2010-08-18 贵州华科铝材料工程技术研究有限公司 Li-W-RE high-strength heat resistant aluminum alloy material modified with C and preparation method thereof
US20120291925A1 (en) * 2011-05-20 2012-11-22 Constellium France Aluminum magnesium lithium alloy with improved fracture toughness
CN104451272A (en) * 2014-11-21 2015-03-25 上海交通大学 Light-weight and high-strength cast aluminum lithium alloy and preparation method thereof
CN104711463A (en) * 2015-03-17 2015-06-17 中南大学 Al-Mg-Zn-Li alloy and preparation method for alloy plate
CN105200284A (en) * 2015-09-18 2015-12-30 霍山县龙鑫金属制品有限公司 Magnesium-aluminum alloy

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2001049375A (en) * 1999-08-06 2001-02-20 Res Inst Electric Magnetic Alloys Al ALLOY HAVING EXCELLENT VIBRATION ABSORBABILITY AND ITS PRODUCTION
CN101538668A (en) * 2009-04-28 2009-09-23 中铝河南铝业有限公司 Production process of aluminum alloy hot rolling medium plate
CN101805854A (en) * 2009-09-23 2010-08-18 贵州华科铝材料工程技术研究有限公司 Li-W-RE high-strength heat resistant aluminum alloy material modified with C and preparation method thereof
US20120291925A1 (en) * 2011-05-20 2012-11-22 Constellium France Aluminum magnesium lithium alloy with improved fracture toughness
CN104451272A (en) * 2014-11-21 2015-03-25 上海交通大学 Light-weight and high-strength cast aluminum lithium alloy and preparation method thereof
CN104711463A (en) * 2015-03-17 2015-06-17 中南大学 Al-Mg-Zn-Li alloy and preparation method for alloy plate
CN105200284A (en) * 2015-09-18 2015-12-30 霍山县龙鑫金属制品有限公司 Magnesium-aluminum alloy

Also Published As

Publication number Publication date
CN106834828B (en) 2018-11-20

Similar Documents

Publication Publication Date Title
CN104975196B (en) A kind of regenerated high-silicon aluminium alloy ingots manufacturing process
CN111001800B (en) 3D printing high-strength Al-Cr-Sc alloy
CN105648285B (en) Formula for casting aluminum alloy hubs
CN101532861B (en) A method for manufacturing water meter housing by high strength cast aluminum alloy and a product thereof
CN106893911B (en) A kind of high-strength temperature-resistant Al-Cu line aluminium alloys and preparation method thereof
CN110643862A (en) Aluminum alloy for new energy automobile battery shell and pressure casting preparation method thereof
CN103276323B (en) The preparation method of high-strength corrosion-resisting compound thermal exchanging tube
CN108300884B (en) A kind of hypoeutectic Al-Mg2The rotten and thinning method of Si alloy
CN106399781A (en) Novel high-strength corrosion-resistant rare earth aluminum alloy material and preparation method
CN107739947A (en) A kind of Mg Y Mn Sc heat resistance magnesium alloys and preparation method thereof
CN108118240A (en) A kind of crude oil carrier Cargo Oil Ceiling anti-corrosion steel plate and its manufacturing method
CN106967910B (en) A kind of high intensity Al-Zn-Mg line aluminium alloys and preparation method thereof
CN107245614B (en) A kind of wear-resistant aluminum alloy and application thereof
CN107881370A (en) A kind of five layers of aluminum alloy composite board and complex method
CN106834834A (en) A kind of use for electronic products high-strength aluminum alloy and preparation method thereof
CN106834829B (en) A kind of ship anticorodal and preparation method thereof
WO2012113241A1 (en) Multi-combinational degenerated low-zinc hot-dipped aluminum-galvanized alloy plating material containing mg, and preparation method therefor
CN106967908B (en) A kind of high strength anti-corrosion Al-Mg line aluminium alloys and preparation method thereof
CN108504973A (en) A kind of heat treatment method of naval vessel Al-Mg-Si alloy
CN106917015B (en) One kind tough aluminium alloy of height used for vehicle and preparation method thereof
CN105063393B (en) A kind of Mg2The method of Si/Al based composites and its composite optimization
CN106967909B (en) A kind of high tough Al-Mg-Si-type aluminum alloy and preparation method thereof
CN106834828B (en) A kind of offshore equipment aluminium alloy and preparation method thereof
CN114875302B (en) Low-alloy steel and preparation method and application thereof
CN107177755B (en) High-strength, high-anti-friction zinc-containing alloy, its casting preparation method and dedicated unit

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant
CP02 Change in the address of a patent holder
CP02 Change in the address of a patent holder

Address after: 528137 F22, first floor, building 23, No. 23, qiangye Avenue, Leping Town, Sanshui District, Foshan City, Guangdong Province (residence declaration)

Patentee after: GUANGDONG XINGFA ALUMINIUM Co.,Ltd.

Address before: No.23 Renhe Road, Nanzhuang Town, Chancheng District, Foshan City, Guangdong Province

Patentee before: GUANGDONG XINGFA ALUMINIUM Co.,Ltd.