CN106833542A - A kind of transformation temperature is between 2 DEG C 8 DEG C cool storage material and preparation method thereof - Google Patents
A kind of transformation temperature is between 2 DEG C 8 DEG C cool storage material and preparation method thereof Download PDFInfo
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- CN106833542A CN106833542A CN201710131740.2A CN201710131740A CN106833542A CN 106833542 A CN106833542 A CN 106833542A CN 201710131740 A CN201710131740 A CN 201710131740A CN 106833542 A CN106833542 A CN 106833542A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K5/00—Heat-transfer, heat-exchange or heat-storage materials, e.g. refrigerants; Materials for the production of heat or cold by chemical reactions other than by combustion
- C09K5/02—Materials undergoing a change of physical state when used
- C09K5/06—Materials undergoing a change of physical state when used the change of state being from liquid to solid or vice versa
- C09K5/066—Cooling mixtures; De-icing compositions
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/14—Thermal energy storage
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Abstract
The invention discloses a kind of transformation temperature between 2 DEG C 8 DEG C cool storage material and preparation method thereof, wherein, preparation method is comprised the following steps：At room temperature, certain herbaceous plants with big flowers alkane, hendecane, dodecane, tridecane, the tetradecane, pentadecane and hexadecane are mixed, stirs 10min, obtain liquid A；At room temperature, to the copper powder that 4 nitrophenols, trimethyl cetyl ammonium bromide and 800 mesh are added in above-mentioned liquid A, 1 2h is stirred, filtering removes filter residue, collects filtrate, obtains final product the cool storage material that transformation temperature is between 28 DEG C.The present invention is advantageous in that：(1) transformation temperature is between 2 DEG C 8 DEG C, and phase transition temperature is suitable, and evaporation latent heat is big, and cold accumulation effects are good；(2) process is simple, by the regulation and control that phase transition temperature is easily realized by the ratio for adjusting each component in preparation process；(3) using it is preceding freeze under less than cool storage material transformation temperature, higher than desired minimum temperature after i.e. can be used, it is not necessary to " balancing ", simplify operation, greatly improve operating efficiency.
Description
Technical field
The present invention relates to a kind of cool storage material and preparation method thereof, and in particular to a kind of transformation temperature is between 2 DEG C -8 DEG C of storage
Cold material and preparation method thereof, belongs to technical field of chemistry.
Background technology
The biological products such as vaccine, diagnostic reagent are the important leverage means for preventing disease from infecting, safeguarding human life and health.
With the development of modern society, more and more biological products need refrigeration, heat insulation transportation.Large batch of product can be by cold
Hide car fuel oil, energization and realize refrigerated transport.The product of small lot is then more universal by highway, railway, air transportation, and is based on
Economic consideration, in a short time such transport can not be transported by refrigerator car and replaced completely.It is still to ensure by phase-change material for cold storage
The important channel of quality of the small lot biological products in transportation.Therefore, in recent years, novel phase-change material for cold storage is developed
Become one, field important research direction.
At present, market is still, with water as solvent, and to add other materials with wide phase-change material for cold storage, such as inorganic
Salt (Huang Yan, chapter comes research Refrigeration Technique of the Cold Chain Logistics with compound cool storage material, 2016,36,33-35.).This kind of material
The advantage of material is cheap, simple production process, thus is employed for the cold-storage heat-preserving of many kind biological products.Such coolness storing material
Material is using preceding needing precooling to freeze (be normally placed at -18 DEG C freeze storehouses in), and the storage of vaccine kind biological product, cold chain transportation temperature
Degree requirement is 2 DEG C -8 DEG C, therefore, by with the transport process of the phase-change material for cold storage of water as solvent, can frequently result in vaccine etc.
There is the phenomenon of supercooling in biological products, thus cause these biological products activity, function reduction, even lose.When people use
These lose activity or function biological products, it will there is unpredictable consequence, the lighter has adverse reaction, and severe one can disable
Or it is lethal.Although once trial certain methods (term " balancing " such as in industry, i.e., after freezing in cold chain transportation industry
Cool storage material is absorbed heat under normal temperature or refrigerated storage temperature, and temperature is reused after rising) such issues that solve, but effect pays no attention to always
Think.
Therefore, exploitation phase-change material for cold storage of the transformation temperature between 2 DEG C -8 DEG C, urgent as technical field of biological material is essential
Will.
The content of the invention
In for the existing biological products transportation of solution, lack suitable cool storage material, thus result in the easy mistake of biological products
Cold technical problem, it is an object of the invention to provide a kind of transformation temperature between 2 DEG C -8 DEG C cool storage material and preparation method thereof.
In order to realize above-mentioned target, the present invention is adopted the following technical scheme that：
Preparation method of a kind of transformation temperature between 2 DEG C -8 DEG C of cool storage material, it is characterised in that comprise the following steps：
Step1：At room temperature, certain herbaceous plants with big flowers alkane, hendecane, dodecane, tridecane, the tetradecane, pentadecane and hexadecane are mixed, is stirred
10min is mixed, liquid A is obtained, wherein, foregoing certain herbaceous plants with big flowers alkane, hendecane, dodecane, tridecane, the tetradecane, pentadecane and hexadecane
Volume fraction is respectively 1%-20%, 1%-20%, 5%-20%, 5%-30%, 5%-65%, 1%-20% and 1%-
20%；
Step2：At room temperature, to addition 4- nitrophenols, trimethyl cetyl ammonium bromide and 800 mesh in above-mentioned liquid A
Copper powder, stir 1-2h, filtering, remove filter residue, collect filtrate, obtain final product the cool storage material that transformation temperature is between 2-8 DEG C, wherein, it is preceding
The mass ratio for stating liquid A, 4- nitrophenols, trimethyl cetyl ammonium bromide and copper powder is 1000：10：1：1.
Foregoing preparation method, it is characterised in that in Step1, foregoing certain herbaceous plants with big flowers alkane, hendecane, dodecane, tridecane, ten
The volume fraction of four alkane, pentadecane and hexadecane is respectively 18%, 5%, 5%, 5%, 65%, 1% and 1%.
Foregoing preparation method, it is characterised in that in Step1, foregoing certain herbaceous plants with big flowers alkane, hendecane, dodecane, tridecane, ten
The volume fraction of four alkane, pentadecane and hexadecane is respectively 20%, 4%, 20%, 11%, 5%, 20% and 20%.
Foregoing preparation method, it is characterised in that in Step1, foregoing certain herbaceous plants with big flowers alkane, hendecane, dodecane, tridecane, ten
The volume fraction of four alkane, pentadecane and hexadecane is respectively 16%, 8%, 7%, 7%, 50%, 10% and 2%.
Foregoing preparation method, it is characterised in that in Step1, foregoing certain herbaceous plants with big flowers alkane, hendecane, dodecane, tridecane, ten
The volume fraction of four alkane, pentadecane and hexadecane is respectively 8%, 3%, 9%, 30%, 10%, 20% and 20%.
Foregoing preparation method, it is characterised in that in Step1, foregoing certain herbaceous plants with big flowers alkane, hendecane, dodecane, tridecane, ten
The volume fraction of four alkane, pentadecane and hexadecane is respectively 15%, 5%, 12%, 15%, 40%, 5% and 8%.
Foregoing preparation method, it is characterised in that in Step1, foregoing certain herbaceous plants with big flowers alkane, hendecane, dodecane, tridecane, ten
The volume fraction of four alkane, pentadecane and hexadecane is respectively 1%, 20%, 5%, 5%, 31%, 19% and 19%.
Foregoing preparation method, it is characterised in that in Step1, foregoing certain herbaceous plants with big flowers alkane, hendecane, dodecane, tridecane, ten
The volume fraction of four alkane, pentadecane and hexadecane is respectively 1%, 1%, 5%, 18%, 35%, 20% and 20%.
The present invention is advantageous in that：
(1) cool storage material of the invention, transformation temperature is between 2 DEG C -8 DEG C, and phase transition temperature is suitable, and evaporation latent heat is big, cold-storage effect
It is really good, for needing to refrigerate, being incubated and temperature range includes 2 DEG C of products in -8 DEG C of intervals, using cool storage material of the invention not
The phenomenon of supercooling or overheat occurs, i.e., had both been not in 2 DEG C of the minimum temperature less than product requirement, be also not in higher than product
8 DEG C of the maximum temperature of product requirement, realizes 2 DEG C of -8 DEG C of temperature controls well；
(2) cool storage material of the invention, using preceding cold under less than cool storage material transformation temperature, higher than desired minimum temperature
Be can be used after freezing, it is not necessary to " balancing " so-called in industry, simplify operation difficulty, greatly improve work effect
Rate；
(3) preparation method of the invention, by physics and the effect of chemistry, has given full play to the collaboration work of kinds of ingredients
With promoting material integrally to give play to good cold-storage and act on；
(4) preparation method of the invention, process is simple, by the ratio for adjusting each component in preparation process, you can easily
The regulation and control of phase transition temperature are realized, is suitable for prepare with scale.
Specific embodiment
Make specific introduction to the present invention below in conjunction with specific embodiment.
First, liquid A is prepared
With volume percentage, prepare each component for preparing liquid A, refer to table 1.
Table 1 is used to prepare each component and proportioning of liquid A
Preparation method：At room temperature, certain herbaceous plants with big flowers alkane, hendecane, dodecane, tridecane, the tetradecane, pentadecane and hexadecane are mixed
Close, stir 10min, that is, obtain liquid A.
Certain herbaceous plants with big flowers alkane, hendecane, dodecane, tridecane, the tetradecane, pentadecane and hexadecane are homologue, and they have similar
But incomplete same physics and chemical property.The liquid A being made up of these homologues, is to prepare in the cool storage material later stage
During involved chemical reaction provide necessary reacting environment and material base.Meanwhile, themselves it is also coolness storing material
The important component of material.
2nd, cool storage material is prepared
At room temperature, to the copper powder that 4- nitrophenols, trimethyl cetyl ammonium bromide and 800 mesh are added in above-mentioned liquid A,
Stirring 1-2h, filtering removes filter residue, collects filtrate, obtains final product the cool storage material that transformation temperature is between 2-8 DEG C.Wherein, liquid A, 4- nitre
The mass ratio of base phenol, trimethyl cetyl ammonium bromide and copper powder is 1000：10：1：1.
After the copper powder of 4- nitrophenols, trimethyl cetyl ammonium bromide and 800 mesh is added in liquid A, change
Reaction is learned, fragrant amine substance is produced, they are the another important component of cool storage material, these fragrant amine substances and liquid A
Middle kinds of ingredients synergy, can promote cool storage material integrally to give play to good cold-storage and act on.
As can be seen here, cool storage material of the invention has given full play to the association of kinds of ingredients by physics and the effect of chemistry
Same-action, promotes material integrally to give play to good cold-storage and acts on.
3rd, transformation temperature is tested
After tested, the transformation temperature of each group cool storage material corresponding with table 1 is shown in Table 2.
The transformation temperature of each cool storage material under the different formulations of table 2
| Group number | 1 | 2 | 3 | 4 | 5 | 6 | 7 |
| Transformation temperature | 2.0℃ | 3.0℃ | 5.0℃ | 7.0℃ | 8.0℃ | 4.0℃ | 6.0℃ |
As can be seen here：
(1) cool storage material transformation temperature of the invention is between 2 DEG C -8 DEG C, and phase transition temperature is suitable, and evaporation latent heat is big, cold accumulation effects
It is good, for needing to refrigerate, being incubated and temperature range includes 2 DEG C of products in -8 DEG C of intervals, will not using cool storage material of the invention
There is the phenomenon of supercooling or overheat, i.e., be both not in 2 DEG C of the minimum temperature less than product requirement, be also not in higher than product
It is required that 8 DEG C of maximum temperature, 2 DEG C of -8 DEG C of temperature controls are realized well；
(2) ratio by adjusting each component in preparation process of the invention, you can easily realize the regulation and control of phase transition temperature, fit
Together in prepare with scale.
4th, application method
Vaccine cold chain temperature is 2 DEG C -8 DEG C, cold storage insulation box cold chain transportation dispatching vaccine, it is only necessary to by cold-storage of the invention
Then material is placed directly in inside incubator, uses around vaccine in 2 DEG C or 3 DEG C freezings, over time, stores
Cold material and vaccine temperature can be raised, and cool storage material and vaccine temperature can be higher than 8 DEG C, and vaccine has substantially from point of origin to receiving point
Time, arrival receiving point time vaccines temperature can be made still to be below 8 DEG C by adjusting the usage amount of cool storage material.
In temperature than especially northern area of relatively low winter etc., in order that incubator intradermal vaccine product temperature is not less than 2 DEG C,
Proper temperature (7 DEG C or 8 DEG C), appropriate cool storage material of the invention can be placed in incubator, vaccine periphery, to resist
Low temperature.
As can be seen here, cool storage material of the invention, using preceding less than cool storage material transformation temperature, higher than desired lowest temperature
The lower freezing of degree can be used after freezing, it is not necessary to " balancing " so-called in industry, simplify operation difficulty, greatly improve
Operating efficiency.
It should be noted that above-described embodiment the invention is not limited in any way, all use equivalents or equivalent change
The technical scheme that the mode changed is obtained, all falls within protection scope of the present invention.
Claims (9)
1. preparation method of a kind of transformation temperature between 2 DEG C -8 DEG C of cool storage material, it is characterised in that comprise the following steps：
Step1：At room temperature, certain herbaceous plants with big flowers alkane, hendecane, dodecane, tridecane, the tetradecane, pentadecane and hexadecane are mixed, stirring
10min, obtains liquid A, wherein, the body of the certain herbaceous plants with big flowers alkane, hendecane, dodecane, tridecane, the tetradecane, pentadecane and hexadecane
Fraction is respectively 1%-20%, 1%-20%, 5%-20%, 5%-30%, 5%-65%, 1%-20% and 1%-20%；
Step2：At room temperature, to the copper that 4- nitrophenols, trimethyl cetyl ammonium bromide and 800 mesh are added in above-mentioned liquid A
Powder, stirs 1-2h, and filtering removes filter residue, collects filtrate, obtains final product the cool storage material that transformation temperature is between 2-8 DEG C, wherein, the liquid
The mass ratio of body A, 4- nitrophenol, trimethyl cetyl ammonium bromide and copper powder is 1000：10：1：1.
2. preparation method according to claim 1, it is characterised in that in Step1, the certain herbaceous plants with big flowers alkane, hendecane, 12
The volume fraction of alkane, tridecane, the tetradecane, pentadecane and hexadecane is respectively 18%, 5%, 5%, 5%, 65%, 1% and
1%.
3. preparation method according to claim 1, it is characterised in that in Step1, the certain herbaceous plants with big flowers alkane, hendecane, 12
The volume fraction of alkane, tridecane, the tetradecane, pentadecane and hexadecane is respectively 20%, 4%, 20%, 11%, 5%, 20% and
20%.
4. preparation method according to claim 1, it is characterised in that in Step1, the certain herbaceous plants with big flowers alkane, hendecane, 12
The volume fraction of alkane, tridecane, the tetradecane, pentadecane and hexadecane is respectively 16%, 8%, 7%, 7%, 50%, 10% and
2%.
5. preparation method according to claim 1, it is characterised in that in Step1, the certain herbaceous plants with big flowers alkane, hendecane, 12
The volume fraction of alkane, tridecane, the tetradecane, pentadecane and hexadecane is respectively 8%, 3%, 9%, 30%, 10%, 20% and
20%.
6. preparation method according to claim 1, it is characterised in that in Step1, the certain herbaceous plants with big flowers alkane, hendecane, 12
The volume fraction of alkane, tridecane, the tetradecane, pentadecane and hexadecane is respectively 15%, 5%, 12%, 15%, 40%, 5% and
8%.
7. preparation method according to claim 1, it is characterised in that in Step1, the certain herbaceous plants with big flowers alkane, hendecane, 12
The volume fraction of alkane, tridecane, the tetradecane, pentadecane and hexadecane is respectively 1%, 20%, 5%, 5%, 31%, 19% and
19%.
8. preparation method according to claim 1, it is characterised in that in Step1, the certain herbaceous plants with big flowers alkane, hendecane, 12
The volume fraction of alkane, tridecane, the tetradecane, pentadecane and hexadecane is respectively 1%, 1%, 5%, 18%, 35%, 20% and
20%.
9. a kind of transformation temperature prepared by claim 1 to 8 any one methods described is between 2-8 DEG C of cool storage material.
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107814034A (en) * | 2017-11-29 | 2018-03-20 | 杭州鲁尔新材料科技有限公司 | A kind of long timeliness medicine cold chain heat insulation box of low cost |
| CN107936928A (en) * | 2017-11-29 | 2018-04-20 | 杭州鲁尔新材料科技有限公司 | A kind of low-temperature phase-change material for medicine cold chain transportation |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1563252A (en) * | 2004-03-23 | 2005-01-12 | 南京大学 | Phase change cold accumulation material in use for air conditioning, and preparation method |
| CN1621483A (en) * | 2004-10-22 | 2005-06-01 | 清华大学 | Microcapsule type phase change cold accumulation agent for air conditioner cold accumulation and method for preparing same |
| CN105647481A (en) * | 2016-01-18 | 2016-06-08 | 北京理工大学 | Medium-low temperature phase change cold storage material and preparation method thereof |
-
2017
- 2017-03-07 CN CN201710131740.2A patent/CN106833542A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1563252A (en) * | 2004-03-23 | 2005-01-12 | 南京大学 | Phase change cold accumulation material in use for air conditioning, and preparation method |
| CN1621483A (en) * | 2004-10-22 | 2005-06-01 | 清华大学 | Microcapsule type phase change cold accumulation agent for air conditioner cold accumulation and method for preparing same |
| CN105647481A (en) * | 2016-01-18 | 2016-06-08 | 北京理工大学 | Medium-low temperature phase change cold storage material and preparation method thereof |
Non-Patent Citations (4)
| Title |
|---|
| 张明: "《纳米与新材料专辑 2》", 25 April 2004, 材料报道社 * |
| 朱洪法: "《催化剂手册》", 31 August 2008, 金盾出版社 * |
| 程青芳: "《有机化学实验》", 30 September 2006, 南京大学出版社 * |
| 饶中浩等: "《储能技术概论》", 31 January 2017, 中国矿业大学出版社 * |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107814034A (en) * | 2017-11-29 | 2018-03-20 | 杭州鲁尔新材料科技有限公司 | A kind of long timeliness medicine cold chain heat insulation box of low cost |
| CN107936928A (en) * | 2017-11-29 | 2018-04-20 | 杭州鲁尔新材料科技有限公司 | A kind of low-temperature phase-change material for medicine cold chain transportation |
| CN107814034B (en) * | 2017-11-29 | 2024-02-02 | 杭州鲁尔新材料科技有限公司 | Low-cost long-time-effect medicine cold chain insulation can |
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