CN106833361A - A kind of antibacterial aqueous polyurethane coating glue of silver ion deodorizing - Google Patents

A kind of antibacterial aqueous polyurethane coating glue of silver ion deodorizing Download PDF

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Publication number
CN106833361A
CN106833361A CN201710100861.0A CN201710100861A CN106833361A CN 106833361 A CN106833361 A CN 106833361A CN 201710100861 A CN201710100861 A CN 201710100861A CN 106833361 A CN106833361 A CN 106833361A
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parts
silver ion
aqueous polyurethane
polyurethane coating
coating glue
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CN106833361B (en
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李煌宝
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Guangzhou Yourui Plastic Co Ltd
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Guangzhou Yourui Plastic Co Ltd
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    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
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    • C09D175/00Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04Polyurethanes
    • C09D175/14Polyurethanes having carbon-to-carbon unsaturated bonds
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    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30Low-molecular-weight compounds
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    • C08G18/65Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen
    • C08G18/66Compounds of groups C08G18/42, C08G18/48, or C08G18/52
    • C08G18/6633Compounds of group C08G18/42
    • C08G18/6637Compounds of group C08G18/42 with compounds of group C08G18/32 or polyamines of C08G18/38
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    • C08G18/74Polyisocyanates or polyisothiocyanates cyclic
    • C08G18/75Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic
    • C08G18/751Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring
    • C08G18/752Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring containing at least one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group
    • C08G18/753Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring containing at least one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group containing one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group having a primary carbon atom next to the isocyanate or isothiocyanate group
    • C08G18/755Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring containing at least one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group containing one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group having a primary carbon atom next to the isocyanate or isothiocyanate group and at least one isocyanate or isothiocyanate group linked to a secondary carbon atom of the cycloaliphatic ring, e.g. isophorone diisocyanate
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    • C08G18/74Polyisocyanates or polyisothiocyanates cyclic
    • C08G18/76Polyisocyanates or polyisothiocyanates cyclic aromatic
    • C08G18/7657Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings
    • C08G18/7664Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings containing alkylene polyphenyl groups
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Abstract

The invention discloses a kind of antibacterial aqueous polyurethane coating glue of silver ion deodorizing, including:IPDI(IPDI)/ methyl diphenylene diisocyanate(MDI), polyester diol(XH‑111), trimethylolpropane(TMP), Isosorbide-5-Nitrae butanediol(BDO), hydroxy-ethyl acrylate(HEA), acrylic resin monomer, Ludox, medical stone powder, mica powder, dispersant, antiseptic, defoamer, wetting agent, silver ion agent, pure water.The present invention has excellent adhesive force, hardness high, anti-corrosion, water resistance, and weather-proof, wear-resisting, heat-proof combustion-resistant performance is outstanding, process industrial art performance is excellent, coating excellent in mechanical performance after film-forming, deodorizing sterilizing is carried out using silver ion, and with good antibacterial ability, side effect will not be produced to human body.

Description

A kind of antibacterial aqueous polyurethane coating glue of silver ion deodorizing
Technical field
The present invention relates to technical field of coatings, specially a kind of antibacterial aqueous polyurethane coating glue of silver ion deodorizing.
Background technology
Aqueous polyurethane using water as decentralized medium, with advantages such as environment-protecting asepsis, difficult to burn, and can by change Soft and hard segments species and ratio adjust the combination property of resin material.Market is introduced into from end of the sixties in last century aqueous polyurethane Afterwards, aqueous polyurethane is with excellent cementitiousness, outstanding temperature-change resistance energy, excellent resistance to low temperature, good biofacies The characteristic of capacitive and environment-protecting asepsis and be widely used in multiple fields.In recent years with the development of science and technology, people are to being both resistant to The water paint demand of water and energy heat-proof combustion-resistant is growing, and how to prepare a kind of water-fast, heat-resisting, fire-retardant water paint turns into The current technical issues that need to address, and existing aqueous polyurethane coating glue does not have deodorant function, is asked for above-mentioned Topic, spy proposes a kind of antibacterial aqueous polyurethane coating glue of silver ion deodorizing.
The content of the invention
It is an object of the invention to provide a kind of alarm of logistics equipment automatic fault diagnosis and long distance control system, to solve The problem proposed in above-mentioned background technology.
To achieve the above object, the present invention provides following technical scheme:A kind of antibacterial aqueous polyurethane of silver ion deodorizing is applied Layer glue, raw material includes by weight:IPDI(IPDI)/ methyl diphenylene diisocyanate(MDI)40 to 42 parts, polyester diol(XH-111)5 to 8 parts, trimethylolpropane(TMP)3 to 6 parts, BDO(BDO)12 to 15 Part, hydroxy-ethyl acrylate(HEA)35 to 37 parts, 32 to 35 parts of acrylic resin monomer, 15 to 18 parts of Ludox, medical stone powder 18 To 21 parts, 13 to 16 parts of mica powder, 6 to 9 parts of dispersant, 3 to 4 parts of antiseptic, 3 to 4 parts of defoamer, 6 to 8 parts of wetting agent, silver 3 to 4 parts of ionic agent, 120 to 150 parts of pure water.
Preferably, raw material includes by weight:IPDI(IPDI)/ methyl diphenylene diisocyanate (MDI)40.5 to 41.5 parts, polyester diol(XH-111)5.5 to 7.5 parts, trimethylolpropane(TMP)3.5 to 5.5 parts, 1, 4- butanediols(BDO)12.5 to 14.5 parts, hydroxy-ethyl acrylate(HEA)35.5 to 36.5 parts, acrylic resin monomer 32.5 to 34.5 parts, 15.5 to 17.5 parts of Ludox, 18.5 to 20.5 parts of medical stone powder, 13.5 to 15.5 parts of mica powder, dispersant 6.5 to 8.5 parts, 3.3 to 3.7 parts of antiseptic, 3.3 to 3.7 parts of defoamer, 6.5 to 7.5 parts of wetting agent, 3.3 to 3.5 parts of silver ion agent, 120 to 150 parts of pure water.
Preferably, silver ion agent includes 0.6 part of high-efficiency activated silver ion solution by weight ratio, the type 6 of card nurse ripple 940 Part, 100 parts of glycerine, 15 parts of menthol, 1 part of ethyl hydroxy benzoate, 1000 parts of pure water.
Preferably, phosphorous diamines based flame retardant is additionally added in raw material.
Preferably, phosphorous diamines based flame retardant is 3,9- bis-(3- aminophenyls)The phosphorus spiral shells of four oxygen -3,9- of -2,4,8,10- two Ring [5.5] hendecane -3,9- dioxies.
Compared with prior art, the beneficial effects of the invention are as follows:A kind of logistics equipment automatic fault diagnosis are alarmed and long-range Monitoring system, anti-corrosion, water resistance high with excellent adhesive force, hardness, and also weather-proof, wear-resisting, heat-proof combustion-resistant performance is excellent Show, process industrial art performance is excellent, the coating excellent in mechanical performance after film-forming, and deodorizing sterilizing is carried out using silver ion, and With good antibacterial ability, side effect will not be produced to human body.
Specific embodiment
The technical scheme in the embodiment of the present invention will be clearly and completely described below, it is clear that described implementation Example is only a part of embodiment of the invention, rather than whole embodiments.Based on the embodiment in the present invention, this area is common The every other embodiment that technical staff is obtained under the premise of creative work is not made, belongs to the model of present invention protection Enclose.
The first technical scheme that the present invention is provided:A kind of antibacterial aqueous polyurethane coating glue of silver ion deodorizing, raw material is pressed Weight portion includes:IPDI(IPDI)40 to 42 parts, polyester diol(XH-111)5 to 8 parts, trihydroxy methyl Propane(TMP)3 to 6 parts, BDO(BDO)12 to 15 parts, hydroxy-ethyl acrylate(HEA)35 to 37 parts, acrylic resin 32 to 35 parts of monomer, 15 to 18 parts of Ludox, 18 to 21 parts of medical stone powder, 13 to 16 parts of mica powder, 6 to 9 parts of dispersant, antibacterial 3 to 4 parts of agent, 3 to 4 parts of defoamer, 6 to 8 parts of wetting agent, 3 to 4 parts of silver ion agent, 120 to 150 parts of pure water, silver ion agent bag Include 0.6 part of high-efficiency activated silver ion solution by weight ratio, 6 parts of 940 type of card nurse ripple, 100 parts of glycerine, 15 parts of menthol, 1 part of ethyl hydroxy benzoate, 1000 parts of pure water is additionally added phosphorous diamines based flame retardant in raw material, phosphorous diamines based flame retardant is 3,9- Two(3- aminophenyls)- 2,4,8,10- four oxygen -3,9- hosphospiro [5.5] hendecane -3,9- dioxies.
Second technical scheme that the present invention is provided:A kind of antibacterial aqueous polyurethane coating glue of silver ion deodorizing, raw material is pressed Weight portion includes:Methyl diphenylene diisocyanate(MDI)40 to 42 parts, polyester diol(XH-111)5 to 8 parts, three hydroxyl first Base propane(TMP)3 to 6 parts, BDO(BDO)12 to 15 parts, hydroxy-ethyl acrylate(HEA)35 to 37 parts, acrylic acid tree 32 to 35 parts of alicyclic monomer, 15 to 18 parts of Ludox, 18 to 21 parts of medical stone powder, 13 to 16 parts of mica powder, 6 to 9 parts of dispersant resists 3 to 4 parts of microbial inoculum, 3 to 4 parts of defoamer, 6 to 8 parts of wetting agent, 3 to 4 parts of silver ion agent, 120 to 150 parts of pure water, silver ion agent Including 0.6 part of high-efficiency activated silver ion solution by weight ratio, 6 parts of 940 type of card nurse ripple, 100 parts of glycerine, menthol 15 Part, 1 part of ethyl hydroxy benzoate, 1000 parts of pure water is additionally added phosphorous diamines based flame retardant in raw material, phosphorous diamines based flame retardant is 3, 9- bis-(3- aminophenyls)- 2,4,8,10- four oxygen -3,9- hosphospiro [5.5] hendecane -3,9- dioxies
The third technical scheme that the present invention is provided:A kind of antibacterial aqueous polyurethane coating glue of silver ion deodorizing, raw material is by weight Part includes:IPDI(IPDI)40.5 to 41.5 parts, polyester diol(XH-111)5.5 to 7.5 parts, three hydroxyls Methylpropane(TMP)3.5 to 5.5 parts, BDO(BDO)12.5 to 14.5 parts, hydroxy-ethyl acrylate(HEA)35.5 to 36.5 parts, 32.5 to 34.5 parts of acrylic resin monomer, 15.5 to 17.5 parts of Ludox, 18.5 to 20.5 parts of medical stone powder, cloud 13.5 to 15.5 parts of female powder, 6.5 to 8.5 parts of dispersant, 3.3 to 3.7 parts of antiseptic, 3.3 to 3.7 parts of defoamer, wetting agent 6.5 To 7.5 parts, 3.3 to 3.5 parts of silver ion agent, 120 to 150 parts of pure water, silver ion agent includes efficient work by weight ratio Property 0.6 part of silver ion solution, 6 parts of 940 type of card nurse ripple, 100 parts of glycerine, 15 parts of menthol, 1 part of ethyl hydroxy benzoate, pure water 1000 Part, phosphorous diamines based flame retardant is additionally added in raw material, phosphorous diamines based flame retardant is 3,9- bis-(3- aminophenyls)-2,4,8, 10- tetra- oxygen -3,9- hosphospiro [5.5] hendecane -3,9- dioxies.
The 4th kind of technical scheme that the present invention is provided:A kind of antibacterial aqueous polyurethane coating glue of silver ion deodorizing, raw material is pressed Weight portion includes:Methyl diphenylene diisocyanate(MDI)40.5 to 41.5 parts, polyester diol(XH-111)5.5 to 7.5 Part, trimethylolpropane(TMP)3.5 to 5.5 parts, BDO(BDO)12.5 to 14.5 parts, hydroxy-ethyl acrylate(HEA) 35.5 to 36.5 parts, 32.5 to 34.5 parts of acrylic resin monomer, 15.5 to 17.5 parts of Ludox, medical stone powder 18.5 to 20.5 Part, 13.5 to 15.5 parts of mica powder, 6.5 to 8.5 parts of dispersant, 3.3 to 3.7 parts of antiseptic, 3.3 to 3.7 parts of defoamer, wetting 6.5 to 7.5 parts of agent, 3.3 to 3.5 parts of silver ion agent, 120 to 150 parts of pure water, silver ion agent includes height by weight ratio 0.6 part of effect active silver ion solution, 6 parts of 940 type of card nurse ripple, 100 parts of glycerine, 15 parts of menthol, 1 part of ethyl hydroxy benzoate, pure water 1000 parts, phosphorous diamines based flame retardant is additionally added in raw material, phosphorous diamines based flame retardant is 3,9- bis-(3- aminophenyls)-2,4, 8,10- tetra- oxygen -3,9- hosphospiro [5.5] hendecane -3,9- dioxies.
The present invention substantially increases adhesive force, hardness, anti-corrosion, water resistance, but also with it is excellent it is heat-resisting, wear-resisting, Weather-proof, decay resistance, process industrial art performance is excellent, the coating excellent in mechanical performance after film-forming, greatly improves this hair Bright denseness and anti-thixotropy, film forming matter and packing strengthening agent in the present invention are evenly distributed, and substantially prolongs of the invention Service life and holding time, and the compactness of film can also be improved, further increase the water-fast of film, corrosion resistance and Adhesive force between ground;Medical stone powder and mica powder make the present invention have after hardening excellent as filler of the invention Intensity, toughness, waterproof, anti-aging, wear-resisting and corrosion resistance;Medical stone powder and mica powder have huge specific surface area and The many meso-hole structures in surface, so that the present invention has extremely strong adsorption capacity, and thermal conductivity factor of the present invention is low, can adjust bottom The temperature of material, and deodorizing sterilizing is carried out using silver ion agent, and with good antibacterial ability, pair will not be produced to human body Effect.
Although an embodiment of the present invention has been shown and described, for the ordinary skill in the art, can be with Understanding can carry out various changes, modification, replacement to these embodiments without departing from the principles and spirit of the present invention And modification, the scope of the present invention be defined by the appended.

Claims (5)

1. the antibacterial aqueous polyurethane coating glue of a kind of silver ion deodorizing, it is characterised in that raw material includes by weight:Isophorone Diisocyanate(IPDI)/ methyl diphenylene diisocyanate(MDI)40 to 42 parts, polyester diol(XH-111)5 to 8 parts, Trimethylolpropane(TMP)3 to 6 parts, BDO(BDO)12 to 15 parts, hydroxy-ethyl acrylate(HEA)35 to 37 parts, third 32 to 35 parts of olefin(e) acid resin monomer, 15 to 18 parts of Ludox, 18 to 21 parts of medical stone powder, 13 to 16 parts of mica powder, dispersant 6 to 9 parts, 3 to 4 parts of antiseptic, 3 to 4 parts of defoamer, 6 to 8 parts of wetting agent, 3 to 4 parts of silver ion agent, 120 to 150 parts of pure water.
2. the antibacterial aqueous polyurethane coating glue of a kind of silver ion deodorizing according to claim 1, it is characterised in that raw material is pressed Weight portion includes:IPDI(IPDI)/ methyl diphenylene diisocyanate(MDI)40.5 to 41.5 parts, gather Ester dihydroxylic alcohols(XH-111)5.5 to 7.5 parts, trimethylolpropane(TMP)3.5 to 5.5 parts, BDO(BDO)12.5 to 14.5 parts, hydroxy-ethyl acrylate(HEA)35.5 to 36.5 parts, 32.5 to 34.5 parts of acrylic resin monomer, Ludox 15.5 to 17.5 parts, 18.5 to 20.5 parts of medical stone powder, 13.5 to 15.5 parts of mica powder, 6.5 to 8.5 parts of dispersant, antiseptic 3.3 to 3.7 parts, 3.3 to 3.7 parts of defoamer, 6.5 to 7.5 parts of wetting agent, 3.3 to 3.5 parts of silver ion agent, 120 to 150 parts of pure water.
3. the antibacterial aqueous polyurethane coating glue of a kind of silver ion deodorizing according to claim 1 and 2, it is characterised in that:Silver Ionic agent includes 0.6 part of high-efficiency activated silver ion solution by weight ratio, 6 parts of 940 type of card nurse ripple, 100 parts of glycerine, peppermint 15 parts of brain, 1 part of ethyl hydroxy benzoate, 1000 parts of pure water.
4. the antibacterial aqueous polyurethane coating glue of a kind of silver ion deodorizing according to claim 3, it is characterised in that:In raw material It is additionally added phosphorous diamines based flame retardant.
5. the antibacterial aqueous polyurethane coating glue of a kind of silver ion deodorizing according to claim 4, it is characterised in that:Phosphorous two Amine fire retardant is 3,9- bis-(3- aminophenyls)- 2,4,8,10- four oxygen -3,9- hosphospiro [5.5] hendecane -3,9- two Oxygen.
CN201710100861.0A 2017-02-23 2017-02-23 A kind of antibacterial aqueous polyurethane coating glue of silver ion deodorizing Expired - Fee Related CN106833361B (en)

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CN103724574A (en) * 2013-12-06 2014-04-16 四川达威科技股份有限公司 Preparation method of non-ionic waterborne polyurethane-polyacrylate composite emulsion for leather finishing
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CN102182069A (en) * 2010-12-30 2011-09-14 洪桂焕 Silver-carried antibacterial finishing agent and preparation method thereof
CN102212311A (en) * 2011-05-09 2011-10-12 中国工程物理研究院化工材料研究所 Colorful ultraviolet (UV) light solidifying paint
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