CN106833342A - A kind of preparation method of aqueous Stripable paint - Google Patents

A kind of preparation method of aqueous Stripable paint Download PDF

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Publication number
CN106833342A
CN106833342A CN201710098659.9A CN201710098659A CN106833342A CN 106833342 A CN106833342 A CN 106833342A CN 201710098659 A CN201710098659 A CN 201710098659A CN 106833342 A CN106833342 A CN 106833342A
Authority
CN
China
Prior art keywords
rotating speed
preparation
aqueous
agent
stripable paint
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710098659.9A
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Chinese (zh)
Inventor
李文峰
刘�文
苏永义
巩固
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Taoyuan Linyi Industrial Co Ltd
State Grid Corp of China SGCC
Linyi Power Supply Co of State Grid Shandong Electric Power Co Ltd
Original Assignee
Taoyuan Linyi Industrial Co Ltd
State Grid Corp of China SGCC
Linyi Power Supply Co of State Grid Shandong Electric Power Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Taoyuan Linyi Industrial Co Ltd, State Grid Corp of China SGCC, Linyi Power Supply Co of State Grid Shandong Electric Power Co Ltd filed Critical Taoyuan Linyi Industrial Co Ltd
Priority to CN201710098659.9A priority Critical patent/CN106833342A/en
Publication of CN106833342A publication Critical patent/CN106833342A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04Polyurethanes
    • C09D175/06Polyurethanes from polyesters
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08Anti-corrosive paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/20Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for coatings strippable as coherent films, e.g. temporary coatings strippable as coherent films
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/63Additives non-macromolecular organic
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/08Stabilised against heat, light or radiation or oxydation

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention discloses a kind of preparation method of aqueous Stripable paint, belong to paint field.It includes following operating procedure:Deionized water is added in container, wetting agent, dispersant, thickener are sequentially added under 200~600r/min of rotating speed stirrings, stir 5~10min;Inorganic filler is subsequently adding, 20~40min is disperseed under 1500~2500r/min of rotating speed;Regulation rotating speed is 700~1300r/min, adds polyaminoester emulsion and styrene-acrylic emulsion, stirs 15~20min;Regulation rotating speed is 200~600r/min, sequentially adds levelling agent, coalescents, silicone release agent, aqueous corrosion inhibiter, and it is 8~9 to adjust pH.Tensile strength of the present invention, elongation at break, 180 ° of peel strengths improve a lot, and drying time is short, and water resistance and the solution of resistance to 3%NaCl are more than 24h.

Description

A kind of preparation method of aqueous Stripable paint
Technical field
The invention belongs to a kind of preparation method of coating, specifically, more particularly to a kind of system of aqueous Stripable paint Preparation Method.
Background technology
Steel, parts and instrument and equipment are subject to from acid rain, steam, greasy dirt, micro- in transport and storage process, easily Many erosions such as biology and artificial friction, scratch etc., make its surface be damaged by different degrees of, and shortening uses the longevity Life.If covering one layer of provisional diaphragm in these materials or equipment surface, invading for extraneous undesirable element can either be completely cut off Erosion, reduces the generation of infringement, can be peeled off when material or equipment put back into again, and their outward appearance and property is not influenceed Energy.Have passed through the aspects such as the research of decades, product quality, kind and performance all to have a great development, because solvent-borne type can Release coating all shows outstanding in terms of intensity, elasticity and protective, thus as main product.But, solvent-borne type can Release coating needs to use substantial amounts of organic solvent, not only pollutes environment, and harm people's is healthy, and causes serious money Source wastes.
The content of the invention
It is an object of the present invention to provide a kind of preparation method of aqueous Stripable paint, to overcome the solvent-borne type in the prior art can Release coating needs to use substantial amounts of organic solvent, not only pollutes environment, and harm people's is healthy, and causes serious money The defect that source wastes.
The present invention is realized using following technical scheme:
A kind of preparation method of aqueous Stripable paint, including following operating procedure:
(1) deionized water is added in container, sequentially adding mass fraction under 200~600r/min of rotating speed stirrings is 0.1%~0.5% wetting agent, 1%~2% dispersant, 0.1%~0.5% thickener, stir 5~10min;
(2) be subsequently adding the inorganic filler of mass fraction 1%~8%, under 1500~2500r/min of rotating speed disperse 20~ 40min;
(3) regulation rotating speed be 700~1300r/min, add mass fraction be 45%~70% polyaminoester emulsion and 10%~30% styrene-acrylic emulsion, stirs 15~20min;
(4) regulation rotating speed is 200~600r/min, sequentially adds levelling agent, coalescents, silicone release agent, aqueous Corrosion inhibiter, and it is 8~9 to adjust pH.
The polyaminoester emulsion is 7: 3 with the mass ratio of styrene-acrylic emulsion.
The inorganic filler is mica powder.
Mass fraction shared by the mica powder is 5%.
Mass fraction shared by the silicone release agent is 0.8%~1.0%.
Compared with prior art, the beneficial effects of the invention are as follows:
(1) the aqueous Stripable paint developed selects the good anion aliphatic polyester of high intensity, rippability to gather Urethane emulsion is main film forming substance, and compounds appropriate styrene-acrylic emulsion, to improve the pliability and feel of paint film;
(2) with mica powder as inorganic filler, and make its consumption 5% or so, paint film has tensile strength higher and breaks Elongation is split, peel strength is moderate, paint film can be peeled off completely in flakes, additionally, paint film Corrosion Protection is good, and with anti-purple Outside line function;
(3) adding silicone release agent can reduce the adhesive force of paint film and base material, improve removability.
Specific embodiment
With reference to embodiment, the invention will be further described.
A kind of preparation method of aqueous Stripable paint, including following operating procedure:
(1) deionized water is added in container, is sequentially added under 200~600r/min of rotating speed stirrings and account for gross weight matter Amount fraction be 0.1%~0.5% wetting agent, 1%~2% dispersant, 0.1%~0.5% thickener, stirring 5~ 10min;
(2) be subsequently adding the mica powder that mass fraction is 5%, under 1500~2500r/min of rotating speed disperse 20~ 40min;
(3) regulation rotating speed is 700~1300r/min, and it is 45%~70% polyaminoester emulsion and 10% to add mass fraction ~30% styrene-acrylic emulsion, stirs 15~20min, and polyaminoester emulsion is 7: 3 with the mass ratio of styrene-acrylic emulsion.
(4) regulation rotating speed is 200~600r/min, sequentially adds levelling agent, coalescents, silicone release agent, aqueous Corrosion inhibiter, and it is 8~9 to adjust pH, wherein mass fraction shared by silicone release agent is 0.8%.
The aqueous Stripable paint paint film tensile strength of the present invention reaches 10.79MPa, and elongation at break reaches 353.5%, 180 ° of peel strength 0.43kN/m, paint film intensity is high, and peeling effect is good, and drying time is short, and water resistance and the solution of resistance to 3%NaCl are super Cross 24h.Additionally, the addition of mica powder makes paint film have anti-ultraviolet function.

Claims (5)

1. a kind of preparation method of aqueous Stripable paint, it is characterised in that:Including following operating procedure:
(1) deionized water is added in container, sequentially adding mass fraction under 200~600r/min of rotating speed stirrings is 0.1%~0.5% wetting agent, 1%~2% dispersant, 0.1%~0.5% thickener, stir 5~10min;
(2) be subsequently adding the inorganic filler of mass fraction 1%~8%, under 1500~2500r/min of rotating speed disperse 20~ 40min;
(3) regulation rotating speed be 700~1300r/min, add mass fraction be 45%~70% polyaminoester emulsion and 10%~ 30% styrene-acrylic emulsion, stirs 15~20min;
(4) regulation rotating speed is 200~600r/min, sequentially adds levelling agent, coalescents, silicone release agent, aqueous inhibition Agent, and it is 8~9 to adjust pH.
2. the preparation method of aqueous Stripable paint according to claim 1, it is characterised in that:The polyaminoester emulsion with The mass ratio of styrene-acrylic emulsion is 7: 3.
3. the preparation method of aqueous Stripable paint according to claim 1, it is characterised in that:The inorganic filler is cloud Female powder.
4. the preparation method of aqueous Stripable paint according to claim 3, it is characterised in that:Matter shared by the mica powder Amount fraction is 5%.
5. the preparation method of aqueous Stripable paint according to claim 1 and 2, it is characterised in that:The organosilicon stripping It is 0.8%~1.0% from mass fraction shared by agent.
CN201710098659.9A 2017-02-23 2017-02-23 A kind of preparation method of aqueous Stripable paint Pending CN106833342A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710098659.9A CN106833342A (en) 2017-02-23 2017-02-23 A kind of preparation method of aqueous Stripable paint

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201710098659.9A CN106833342A (en) 2017-02-23 2017-02-23 A kind of preparation method of aqueous Stripable paint

Publications (1)

Publication Number Publication Date
CN106833342A true CN106833342A (en) 2017-06-13

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Country Status (1)

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108276892A (en) * 2018-03-02 2018-07-13 山东七维新材料有限公司 A kind of aqueous Stripable paint and preparation method thereof
CN110218472A (en) * 2019-07-16 2019-09-10 安徽华路塑料制品有限公司 A kind of strippable water-based paint
CN113861824A (en) * 2021-10-15 2021-12-31 亚士创能科技(上海)股份有限公司 Artistic coating and preparation method and application thereof
CN114163909A (en) * 2021-12-10 2022-03-11 无锡畅宏科技有限公司 Water-based antistatic peelable glue and coating and application thereof
CN115449282A (en) * 2022-09-14 2022-12-09 中昊北方涂料工业研究设计院有限公司 Indoor temporary-protection water-based strippable coating and preparation method thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102827537A (en) * 2012-09-15 2012-12-19 合肥华清金属表面处理有限责任公司 Aqueous normal temperature curing peelable paint and preparation method of paint
CN103360931A (en) * 2013-07-01 2013-10-23 华南理工大学 Waterborne strippable coating for temporarily protecting metal
CN105153910A (en) * 2015-09-27 2015-12-16 常州市奥普泰科光电有限公司 Preparing method for water-based strippable paint with modified silicon sol

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102827537A (en) * 2012-09-15 2012-12-19 合肥华清金属表面处理有限责任公司 Aqueous normal temperature curing peelable paint and preparation method of paint
CN103360931A (en) * 2013-07-01 2013-10-23 华南理工大学 Waterborne strippable coating for temporarily protecting metal
CN105153910A (en) * 2015-09-27 2015-12-16 常州市奥普泰科光电有限公司 Preparing method for water-based strippable paint with modified silicon sol

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108276892A (en) * 2018-03-02 2018-07-13 山东七维新材料有限公司 A kind of aqueous Stripable paint and preparation method thereof
CN110218472A (en) * 2019-07-16 2019-09-10 安徽华路塑料制品有限公司 A kind of strippable water-based paint
CN113861824A (en) * 2021-10-15 2021-12-31 亚士创能科技(上海)股份有限公司 Artistic coating and preparation method and application thereof
CN114163909A (en) * 2021-12-10 2022-03-11 无锡畅宏科技有限公司 Water-based antistatic peelable glue and coating and application thereof
CN115449282A (en) * 2022-09-14 2022-12-09 中昊北方涂料工业研究设计院有限公司 Indoor temporary-protection water-based strippable coating and preparation method thereof

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Application publication date: 20170613