CN106833337A - A kind of scratch resistance water-borne wood coating and preparation method thereof - Google Patents

A kind of scratch resistance water-borne wood coating and preparation method thereof Download PDF

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Publication number
CN106833337A
CN106833337A CN201710099277.8A CN201710099277A CN106833337A CN 106833337 A CN106833337 A CN 106833337A CN 201710099277 A CN201710099277 A CN 201710099277A CN 106833337 A CN106833337 A CN 106833337A
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Prior art keywords
scratch resistance
parts
agent
coalescents
wood coating
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Pending
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CN201710099277.8A
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Chinese (zh)
Inventor
覃旭豪
岑成全
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Guangzhou Pu Bamboo Water Coating Co Ltd
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Guangzhou Pu Bamboo Water Coating Co Ltd
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Priority to CN201710099277.8A priority Critical patent/CN106833337A/en
Publication of CN106833337A publication Critical patent/CN106833337A/en
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04Polyurethanes
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04Polyurethanes
    • C09D175/14Polyurethanes having carbon-to-carbon unsaturated bonds
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/18Fireproof paints including high temperature resistant paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/43Thickening agents
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/47Levelling agents
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/70Additives characterised by shape, e.g. fibres, flakes or microspheres
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/08Stabilised against heat, light or radiation or oxydation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/14Polymer mixtures characterised by other features containing polymeric additives characterised by shape
    • C08L2205/18Spheres

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention discloses a kind of scratch resistance water-borne wood coating, by weight, including following weight portion component:70~95 parts of organosilicon-modified acrylic polyaminoester emulsion, 2~20 parts of deionized water, 0.1~0.2 part of defoamer, 0.1~0.3 part of wetting agent, 2~5 parts of coalescents, 1~5 part of scratch resistance auxiliary agent, 0.1~0.3 part of levelling agent, 0.1~0.7 part of thickener, 0.05~0.15 part of preservative.The invention also discloses a kind of preparation method of scratch resistance water-borne wood coating.The coating is environmentally friendly, have the advantages that hardness of film is high, richness is good, early stage anti-after-tackiness is good, scratch resistance, and the preparation method is simple, is adapted to industrialized production.

Description

A kind of scratch resistance water-borne wood coating and preparation method thereof
Technical field
The invention belongs to technical field of paint preparation, and in particular to a kind of scratch resistance water-borne wood coating and its preparation side Method.
Background technology
As people are to the high speed development of industry and going from bad to worse for environment, people realize gradually to the low-carbon environment-friendly of environment Enhancing, the especially feature of environmental protection requirement to raw material in coating are higher, and the environmental regulation that current various countries formulate is all to volatility in coating Organic compound (VOC) has strict limitation.
Woodwork coating has water-borne wood coating and solvent wood coatings.Water-borne wood coating and solvent wood coatings phase Than, there is environmental protection, energy-conservation, safe and reliable, easy to use, thus the development of water-borne wood coating is contained very much in recent years OK, but water-borne wood coating (one-component) generally existing that hardness of film is low, richness is poor, early stage anti-after-tackiness is poor, do not resist The problems such as scuffing.
The content of the invention
In view of the defect that above-mentioned prior art is present, the purpose of the present invention is to propose to a kind of scratch resistance water-borne wood coating. The coating is environmentally friendly, have the advantages that hardness of film is high, richness is good, early stage anti-after-tackiness is good, scratch resistance.Another mesh of the invention Be to propose a kind of preparation method of scratch resistance water-borne wood coating.The preparation method is simple, is adapted to industrialized production.
The purpose of the present invention will be achieved by the following technical programs:
A kind of scratch resistance water-borne wood coating, by weight, including following weight portion component:Organic-silicon-modified propylene 70~95 parts of sour polyaminoester emulsion, 2~20 parts of deionized water, 0.1~0.2 part of defoamer, 0.1~0.3 part of wetting agent, film forming is helped 2~5 parts of agent, 1~5 part of scratch resistance auxiliary agent, 0.1~0.3 part of levelling agent, 0.1~0.7 part of thickener, preservative 0.05~0.15 Part.
A kind of above-mentioned scratch resistance water-borne wood coating, by weight, including following weight portion component:Organosilicon changes 75~90 parts of property acroleic acid polyurethane emulsion, 4~18 parts of deionized water, 0.12~0.18 part of defoamer, wetting agent 0.15~ 0.25 part, 3~5 parts of coalescents, 2~4 parts of scratch resistance auxiliary agent, 0.15~0.25 part of levelling agent, 0.2~0.6 part of thickener is prevented 0.08~0.12 part of rotten agent.
Above-mentioned a kind of scratch resistance water-borne wood coating, by weight including the component of following weight portion:Organosilicon changes 78~85 parts of property acroleic acid polyurethane emulsion, 5~15 parts of deionized water, 0.14~0.16 part of defoamer, 0.2 part of wetting agent, into 4~5 parts of film auxiliary agent, 2~4 parts of scratch resistance auxiliary agent, 0.2 part of levelling agent, 0.3~0.5 part of thickener, 0.1 part of preservative.
A kind of preparation method according to above-mentioned scratch resistance water-borne wood coating, by organosilicon-modified acrylic polyaminoester emulsion Input dispersion cylinder, sequentially adds deionized water, defoamer, wetting agent, coalescents and scratch resistance auxiliary agent, 1200r/ while stirring Min disperses at a high speed, without shrinkage cavity phenomenon, levelling agent, thickener, preservative is then put into successively until in fineness plate upper scraping plate, stirs Mix uniform, adjustment viscosity 80-100 seconds (applying 4 glasss of surveys), filtering and discharging is obtained final product.
A kind of preparation method of above-mentioned scratch resistance water-borne wood coating, the defoamer is Airex902W defoamers, institute Wetting agent is stated for BYK341 wetting agents, the coalescents are OXFILM351 coalescents, the scratch resistance auxiliary agent is polyolefin Aqueous dispersion, the levelling agent is EFKA-3772 levelling agents, and the thickener is RM-8W thickeners, and institute's Hu preservative is Kathon CG.
A kind of preparation method of above-mentioned scratch resistance water-borne wood coating, the organosilicon-modified acrylic polyurethane copolymerization Emulsion selects SY8908 emulsions.
Compared with prior art, a kind of scratch resistance water-borne wood coating that the present invention is provided and preparation method thereof, reaches Have the technical effect that:Preparation method of the present invention is simple, is adapted to industrialized production, the water-borne wood coating environmental protection of preparation, with film Hardness is high, richness is good, good early stage anti-after-tackiness, scratch resistance the advantages of;The present invention uses organosilicon-modified acrylic polyurethane Emulsion has hardness high, and damage resistant is heat-resisting, water-tolerant, and rate of drying is fast, the features such as environmental pollution is small;Adopted in the present invention OXFILM351 coalescents are a kind of low smell, the almost coalescents of Diamond Search, traditional coalescents such as alcohol ester, It is water-soluble that glycol ethers have some, is partially interposed between the watery phase with high polymer, and OXFILM351 is insoluble in water, And completely into polymer particle, this causes that OXFILM351 is more in hgher efficiency than traditional coalescents;Used in the present invention Polyolefin aqueous dispersion is the organic particle aqueous dispersion based on alkene, in spherical, narrow particle distribution, particle warp 0.01-9.5 μm, 110-148 DEG C of softening point so that with good adhesion strength and early stage anti-after tack performance.
Below just in conjunction with the embodiments, specific embodiment of the invention is described in further detail, so that technical scheme is more Should be readily appreciated that, grasp.
Specific embodiment
Below by specific embodiment, the present invention will be described, but the invention is not limited in this.In following embodiments The experimental technique, unless otherwise specified, is conventional method;The reagent and material, unless otherwise specified, can be from business Approach is obtained, and example below simultaneously is not used to limit the scope of the claims of the invention, all equivalence enforcements without departing from carried out by the present invention Or change, it is intended to be limited solely by this patent protection domain.
Embodiment 1
A kind of scratch resistance water-borne wood coating, by weight, including following weight portion component:Organic-silicon-modified propylene 78 parts of sour polyaminoester emulsion, 14.85 parts of deionized water, 0.15 part of defoamer, 0.2 part of wetting agent, 4 parts of coalescents, scratch resistance 2 parts of auxiliary agent, 0.2 part of levelling agent, 0.5 part of thickener, 0.1 part of preservative.
A kind of scratch resistance water-borne wood coating, is prepared from by following mass parts by following preparation methods:By organosilicon 78 parts of input dispersion cylinders of modified acrylic polyurethane emulsion, sequentially add 14.85 parts of deionized water, defoamer 0.15 while stirring 2 parts of part, 0.2 part of wetting agent, 4 parts of coalescents and scratch resistance auxiliary agent, dispersion (1200rpm/min) is until on fineness plate at a high speed Then scraper plate puts into 0.2 part of levelling agent, 0.5 part of thickener, 0.1 part of preservative successively without shrinkage cavity phenomenon, stirs, and adjusts Viscosity 80-100 seconds (applying 4 glasss of surveys), filtering and discharging is obtained final product.
Defoamer is Foamex810 in this example, and wetting agent is Wet KL245, and coalescents are OXFILM351, anti-zoned Hinder auxiliary agent for polyolefin aqueous dispersion, levelling agent is EFKA-3772, and thickener is RM-2020, and preservative is Kathon CG, is had Machine fluorine-silicon modified acrylic polyurethane copolymerization emulsion is from the SY8908 emulsions for having row shark (Shanghai) Science and Technology Co., Ltd..
Embodiment 2
A kind of scratch resistance water-borne wood coating, by weight, including following weight portion component:Organic-silicon-modified propylene 82 parts of sour polyaminoester emulsion, 10.05 parts of deionized water, 0.15 part of defoamer, 0.2 part of wetting agent, 4 parts of coalescents, scratch resistance 3 parts of auxiliary agent, 0.2 part of levelling agent, 0.3 part of thickener, 0.1 part of preservative.
A kind of scratch resistance water-borne wood coating, is prepared from by following mass parts by following preparation methods:
By 82 parts of input dispersion cylinders of organosilicon-modified acrylic polyaminoester emulsion, deionization is sequentially added under stirring 3 parts of 10.05 parts of water, 0.15 part of defoamer, 0.2 part of wetting agent, 4 parts of coalescents and scratch resistance auxiliary agent, disperse at a high speed (1200rpm/min) until in fineness plate upper scraping plate without shrinkage cavity phenomenon.Then 0.2 part of levelling agent, thickener 0.3 are put into successively Part, 0.1 part of preservative, are stirred, adjustment viscosity 80-100 seconds (applying 4 glasss of surveys), and filtering and discharging is obtained final product.
Defoamer is Foamex810 in this example, and wetting agent is Wet KL245, and coalescents are OXFILM351, anti-zoned Hinder auxiliary agent for polyolefin aqueous dispersion, levelling agent is EFKA-3772, and thickener is RM-2020, and preservative is Kathon CG, is had Machine fluorine-silicon modified acrylic polyurethane copolymerization emulsion is from the SY8908 emulsions for having row shark (Shanghai) Science and Technology Co., Ltd..
Embodiment 3
A kind of scratch resistance water-borne wood coating, by weight, including following weight portion component:Organic-silicon-modified propylene 85 parts of sour polyaminoester emulsion, 5.55 parts of deionized water, 0.15 part of defoamer, 0.2 part of wetting agent, 4.5 parts of coalescents, scratch resistance 4 parts of auxiliary agent, 0.2 part of levelling agent, 0.3 part of thickener, 0.1 part of preservative.
A kind of scratch resistance aqueous woodware paint, is prepared from by following mass parts by following preparation methods:Organosilicon is changed Property 85 parts of input dispersion cylinders of acroleic acid polyurethane emulsion, 5.55 parts of deionized water is sequentially added under stirring, defoamer 0.15 part, 0.2 part of wetting agent, 4 parts of 4.5 parts of coalescents and scratch resistance auxiliary agent, dispersion (1200rpm/min) is until thin at a high speed Degree plate upper scraping plate is without shrinkage cavity phenomenon.Then 0.2 part of levelling agent, 0.3 part of thickener, 0.1 part of preservative are put into successively, and stirring is equal It is even, adjustment viscosity 80-100 seconds (applying 4 glasss of surveys), filtering and discharging is obtained final product.
Defoamer is Foamex810 in this example, and wetting agent is Wet KL245, and coalescents are OXFILM351, anti-zoned Hinder auxiliary agent for polyolefin aqueous dispersion, levelling agent is EFKA-3772, and thickener is RM-2020, and preservative is Kathon CG, is had Machine fluorine-silicon modified acrylic polyurethane copolymerization emulsion is from the SY8908 emulsions for having row shark (Shanghai) Science and Technology Co., Ltd..
Comparative example 1
Difference from Example 1 is that organosilicon-modified acrylic polyaminoester emulsion replaces with commercially available conventional propylene yogurt Liquid.
Comparative example 2
Difference from Example 1 is that polyolefin aqueous dispersion replaces with micronizing wax class scratch resistance auxiliary agent.
Comparative example 3
Difference from Example 1 is that OXFILM351 coalescents replace with the Texanol of alcohol ester 12.
Through inspection, both film-formation results show that the consumption of OXFILM35 coalescents need to only reach organic in embodiment 1 The 5% of fluorine-silicon modified acrylic polyaminoester emulsion can reach preferable low temperature (less than 10 DEG C) film-formation result, and work as OXFILM35 Coalescents equivalent does not reach effect during using OXFILM351 then when changing 12 Texanol of alcohol ester into, it is impossible to complete film forming. Furthermore, proved through substantial amounts of experiment, the amount of the Texanol of alcohol ester 12 to be added to more than the 7% of emulsion content reach it is good low Warm film-formation result, but paint film can be caused to feel like jelly when Texanol dosages are excessive, hardness does not reach requirement.
Scratch resistance water-borne wood coating prepared by embodiment 1-3, comparative example 1-2 is carried out by the method that GB/T9279 specifies Test, test result is as follows:
The scratch resistance water-borne wood coating performance testing index result of table 1
As shown in Table 1, have hardness high using organosilicon-modified acrylic polyaminoester emulsion, damage resistant is heat-resisting, water-fast Property, rate of drying is fast, the features such as environmental pollution is small;Add the good adhesion strength of polyolefin aqueous dispersion physical efficiency and morning Phase anti-after tack performance;
Described above has shown and described some preferred embodiments of the invention, but as previously described, it should be understood that the present invention Be not limited to form disclosed herein, be not to be taken as the exclusion to other embodiment, and can be used for various other combinations, Modification and environment, and can be in invention contemplated scope described herein, by above-mentioned teaching or the technology or knowledge of association area It is modified.And the change and change that those skilled in the art are carried out do not depart from the spirit and scope of the present invention, then all should be in this hair In the protection domain of bright appended claims.

Claims (6)

1. a kind of scratch resistance water-borne wood coating, it is characterised in that by weight, including following weight portion component:It is organic 70~95 parts of fluorine-silicon modified acrylic polyaminoester emulsion, 2~20 parts of deionized water, 0.1~0.2 part of defoamer, wetting agent 0.1~ 0.3 part, 2~5 parts of coalescents, 1~5 part of scratch resistance auxiliary agent, 0.1~0.3 part of levelling agent, 0.1~0.7 part of thickener, anti-corrosion 0.05~0.15 part of agent.
2. a kind of scratch resistance water-borne wood coating according to claim 1, it is characterised in that by weight, including such as The component of lower weight portion:75~90 parts of organosilicon-modified acrylic polyaminoester emulsion, 4~18 parts of deionized water, defoamer 0.12 ~0.18 part, 0.15~0.25 part of wetting agent, 3~5 parts of coalescents, 2~4 parts of scratch resistance auxiliary agent, levelling agent 0.15~0.25 Part, 0.2~0.6 part of thickener, 0.08~0.12 part of preservative.
3. a kind of scratch resistance water-borne wood coating according to claim 2, it is characterised in that by weight, including such as The component of lower weight portion:78~85 parts of organosilicon-modified acrylic polyaminoester emulsion, 5~15 parts of deionized water, defoamer 0.14 ~0.16 part, 0.2 part of wetting agent, 4~5 parts of coalescents, 2~4 parts of scratch resistance auxiliary agent, 0.2 part of levelling agent, thickener 0.3~ 0.5 part, 0.1 part of preservative.
4. a kind of preparation method of the scratch resistance water-borne wood coating according to claim any one of 1-3, it is characterised in that will Organosilicon-modified acrylic polyaminoester emulsion puts into dispersion cylinder, sequentially adds deionized water while stirring, defoamer, wetting agent, Coalescents and scratch resistance auxiliary agent, 1200r/min disperse at a high speed, until in fineness plate upper scraping plate without shrinkage cavity phenomenon, then successively Input levelling agent, thickener, preservative, are stirred, adjustment viscosity 80-100 seconds (applying 4 glasss of surveys), and filtering and discharging is obtained final product.
5. a kind of preparation method of scratch resistance water-borne wood coating according to claim 4, it is characterised in that the froth breaking Agent is Airex902W defoamers, and the wetting agent is BYK341 wetting agents, and the coalescents are OXFILM351 coalescents, The scratch resistance auxiliary agent is polyolefin aqueous dispersion, and the levelling agent is EFKA-3772 levelling agents, and the thickener is RM-8W thickeners, the preservative is Kathon CG.
6. the preparation method of a kind of scratch resistance water-borne wood coating according to claim 5, it is characterised in that described organic Fluorine-silicon modified acrylic polyurethane copolymerization emulsion selects SY8908 emulsions.
CN201710099277.8A 2017-02-23 2017-02-23 A kind of scratch resistance water-borne wood coating and preparation method thereof Pending CN106833337A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109651944A (en) * 2018-11-07 2019-04-19 成都普瑞斯特新材料有限公司 A kind of high-performance scratch resistance aqueous woodware paint
CN112680041A (en) * 2020-12-14 2021-04-20 成都展辰涂料有限公司 Water-based skin-feel wood coating and preparation method thereof
CN113913101A (en) * 2021-11-12 2022-01-11 浙江太宜新材料科技有限公司 Water-based scratch-resistant wear-resistant wood paint and preparation method thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1528800A (en) * 2003-09-27 2004-09-15 华南理工大学 Silicone modified acrylic-polyurethane heterocomplexing water dispersion and preparing method thereof
CN102220061A (en) * 2011-05-13 2011-10-19 黄宏亭 Core-shell polyurethane and acrylic acid copolymer aqueous wood lacquer and preparation method thereof
CN102816512A (en) * 2012-03-12 2012-12-12 浙江博星化工涂料有限公司 Scratch resistance water-borne wood coating

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1528800A (en) * 2003-09-27 2004-09-15 华南理工大学 Silicone modified acrylic-polyurethane heterocomplexing water dispersion and preparing method thereof
CN102220061A (en) * 2011-05-13 2011-10-19 黄宏亭 Core-shell polyurethane and acrylic acid copolymer aqueous wood lacquer and preparation method thereof
CN102816512A (en) * 2012-03-12 2012-12-12 浙江博星化工涂料有限公司 Scratch resistance water-borne wood coating

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109651944A (en) * 2018-11-07 2019-04-19 成都普瑞斯特新材料有限公司 A kind of high-performance scratch resistance aqueous woodware paint
CN112680041A (en) * 2020-12-14 2021-04-20 成都展辰涂料有限公司 Water-based skin-feel wood coating and preparation method thereof
CN113913101A (en) * 2021-11-12 2022-01-11 浙江太宜新材料科技有限公司 Water-based scratch-resistant wear-resistant wood paint and preparation method thereof

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Address after: Room 201, 2nd floor, No. 1 Banpu Road, Torch Development Zone, Zhongshan City, Guangdong Province

Applicant after: Guangdong Fanzhu Waterborne Coatings Co., Ltd.

Address before: Room 820, 96 Wanhui Road, Nancun Town, Panyu District, Guangzhou City, Guangdong Province

Applicant before: Guangzhou Pu bamboo water coating Co., Ltd.

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Application publication date: 20170613