CN106833171A - A kind of production method of Lawn lamp cover surface coating - Google Patents

A kind of production method of Lawn lamp cover surface coating Download PDF

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Publication number
CN106833171A
CN106833171A CN201611164147.XA CN201611164147A CN106833171A CN 106833171 A CN106833171 A CN 106833171A CN 201611164147 A CN201611164147 A CN 201611164147A CN 106833171 A CN106833171 A CN 106833171A
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China
Prior art keywords
lamp shade
glass lamp
production method
powder
cover surface
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Pending
Application number
CN201611164147.XA
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Chinese (zh)
Inventor
施成贵
余奥林
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ANHUI AURORA LIGHTING ENGINEERING Co Ltd
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ANHUI AURORA LIGHTING ENGINEERING Co Ltd
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Priority to CN201611164147.XA priority Critical patent/CN106833171A/en
Publication of CN106833171A publication Critical patent/CN106833171A/en
Pending legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D129/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal, or ketal radical; Coating compositions based on hydrolysed polymers of esters of unsaturated alcohols with saturated carboxylic acids; Coating compositions based on derivatives of such polymers
    • C09D129/14—Homopolymers or copolymers of acetals or ketals obtained by polymerisation of unsaturated acetals or ketals or by after-treatment of polymers of unsaturated alcohols
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/32—Phosphorus-containing compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/34—Silicon-containing compounds
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/61—Additives non-macromolecular inorganic
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F21—LIGHTING
    • F21V—FUNCTIONAL FEATURES OR DETAILS OF LIGHTING DEVICES OR SYSTEMS THEREOF; STRUCTURAL COMBINATIONS OF LIGHTING DEVICES WITH OTHER ARTICLES, NOT OTHERWISE PROVIDED FOR
    • F21V3/00—Globes; Bowls; Cover glasses
    • F21V3/04—Globes; Bowls; Cover glasses characterised by materials, surface treatments or coatings
    • F21V3/10—Globes; Bowls; Cover glasses characterised by materials, surface treatments or coatings characterised by coatings
    • F21V3/12—Globes; Bowls; Cover glasses characterised by materials, surface treatments or coatings characterised by coatings the coatings comprising photoluminescent substances
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K2003/2237—Oxides; Hydroxides of metals of titanium
    • C08K2003/2241—Titanium dioxide
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K2003/2296—Oxides; Hydroxides of metals of zinc
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/011—Nanostructured additives
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/08—Stabilised against heat, light or radiation or oxydation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/10—Transparent films; Clear coatings; Transparent materials
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00—Applications
    • C08L2203/20—Applications use in electrical or conductive gadgets

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Medicinal Chemistry (AREA)
  • Materials Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • General Engineering & Computer Science (AREA)
  • Inorganic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Vessels And Coating Films For Discharge Lamps (AREA)

Abstract

The invention discloses a kind of production method of Lawn lamp cover surface coating, including following operating procedure：1) vinyl-formal resin powder is dissolved in acetone solvent, after stirring and dissolving, to addition halogen calcium phosphate fluoressent powder, talcum powder and calcium pyroborophosphate in solution, then again to addition nano zine oxide and nano titanium oxide in solution, then by ball milling in mixed liquor addition ball mill, after stirring, filtering obtains target product；2) by step 1) in the target product spray gun spraying that obtains on the inner surface of cleaning glass lamp shade；3) glass lamp shade after spraying is placed on into ventilation to dry；4) inner surface of glass lamp shade is cleaned with clear water, is then dried；5) glass lamp shade is placed in baking oven and is toasted, the coating obtained using inventive formulation is used to be sprayed on the surface of lampshade, and the characteristics of can not only play good attractive in appearance, translucency and reduces cost, and luminous intensity distribution is uniform, light efficiency is good, greatly reduces injury of the light to human eyesight.

Description

A kind of production method of Lawn lamp cover surface coating
Technical field
The invention discloses a kind of production method of coating, more particularly to a kind of producer of Lawn lamp cover surface coating Method.
Background technology
At present, continuing to develop with society, the use of illuminating lamp is ubiquitous, and either unremarkable town is small Lane, or the larger railway station of flow of the people, bus station, trip and carry that the widely using of illuminating lamp has greatly facilitated people The operating efficiency of people high, the coming into operation of illuminating lamp causes that black night is late also can be as day.With LED electricity-saving lamps Popularization, existing LED electricity-saving lamps mostly using plastic products lampshade or traditional handicraft frosted glass lamp shade, this technique The lampshade manufacturing cost of production is higher, and lamp distribution is uneven, and light efficiency is poor, and ring can be polluted when chemical reagent is processed in addition Border, what is had is then the inner surface one layer of coating of coating in glass lamp shade so that LED light line spreads, and becomes soft not dazzling, existing Lampshade inner surface coating is generally prepared using the method for solvent, binding agent, inorganic filler well mixed simultaneously ball milling in technology.But It is that coating storage stability of the prior art is poor, sedimentation will be generally sent within 24 hours, coating light transmittance is low, The present invention on the basis of existing technology, discloses a kind of method of easy making cover surface coating, is manufactured using this method Coating the characteristics of there is light transmittance high, good stability, excellent heat-proof quality.
The content of the invention
It is poor, heat-insulated to solve existing lampshade coatings translucency the invention aims to overcome the deficiencies in the prior art Effect difference and cost of manufacture technical problem high, the scheme that the present invention solves above technical problem are as follows：
The invention discloses a kind of production method of Lawn lamp cover surface coating, including following operating procedure：
1) vinyl-formal resin powder is dissolved in acetone solvent, after stirring and dissolving, is added in solution successively Halogen calcium phosphate fluoressent powder, talcum powder and calcium pyroborophosphate, it is 5~6 to adjust mixed liquor pH value with hydrochloric acid, is then added in solution again Enter nano zine oxide and nano titanium oxide, then by ball milling in mixed liquor addition ball mill, after stirring, filtering is obtained Target product；The regulation of pH value can more preferably improve the solubility of coating.
2) by step 1) in the target product spray gun spraying that obtains on the inner surface of cleaning glass lamp shade；
3) glass lamp shade after spraying is placed on into ventilation to dry 2~3 hours；
4) inner surface of glass lamp shade is cleaned with clear water, is then dried；
5) glass lamp shade is placed in 100~120 DEG C of baking oven and is toasted 30~60 minutes；
Wherein, the component content of raw material is：
Vinyl-formal resin be it is a kind of can form insulating properties and the high film of mechanical strength, its film has soft The features such as soft, tough and tensile, wear-resisting, heat resistance and transparency high, the toughness of its performance collection formal and the film forming of acetal are Integrally.And halogen calcium phosphate fluoressent powder is to use a kind of most wide phosphor material powder at present, made using calcium pyroborophosphate in this programme It is strengthening agent, can be good at clagging in cover surface, and nano titanium oxide, nanometer is added in formulation for coating material Zinc oxide can improve the light transmittance of lampshade, and the two can play heat-insulated effect again with the silver powder for adding, and can prevent Strong sunshine irradiates to the long-time of outdoor lampshade, the service life of lampshade is improve, while nano particle is also carried significantly The decentralization of coating high, prevents coating from settling, and improves the stability of coating.
Further, in order to improve coating dispersiveness and stability, the nano zine oxide and nano titanium oxide Particle diameter be 0.5~5nm.
Further, 0.1~1 part of silver powder, the grain of the silver powder are also included in order to improve the heat resistance of lampshade, in raw material Footpath is 0.2~20nm.Not only cause that lampshade transparency is high, translucency by the silver powder and metal oxide using nano particle It is good, and cause that light forms diffusing reflection in cover surface, so as to improve visual comfort.
Using Lawn lamp lampshade produced by the present invention, with translucency it is good, heat-proof quality is good, emergent light is soft the characteristics of, Cell and square etc. can be extensively put into appear occasion, and compared to other coating, this formula also has good dispersion, energy Enough prolonged dispersions are without sedimentation.
Specific embodiment
Embodiments of the invention are elaborated below, the present embodiment is carried out under premised on technical solution of the present invention Implement, give detailed implementation method and specific operating process, but protection scope of the present invention is not limited to following implementations Example.
Haze detection：Using PMS-80 types visible ray thoroughly/reflectivity, mist degree tester test lampshade sample mist degree；Thoroughly Light rate is detected：Using PMS-80 types visible ray thoroughly/reflectivity, mist degree tester test lampshade sample light transmittance；Stability is examined Survey：Each position constituent content of coating is detected by elementary analysis detector to test sedimentation degree.
Embodiment 1
Embodiment 1 discloses a kind of production method of Lawn lamp cover surface coating, including following operating procedure：
1) vinyl-formal resin powder is dissolved in acetone solvent, after stirring and dissolving, is added in solution successively Halogen calcium phosphate fluoressent powder, talcum powder and calcium pyroborophosphate, it is 5 to adjust mixed liquor pH value with hydrochloric acid, is then added in solution again Nano zine oxide and nano titanium oxide, then by ball milling in mixed liquor addition ball mill, after stirring, filtering obtains mesh Mark product；
2) by step 1) in the target product spray gun spraying that obtains on the inner surface of cleaning glass lamp shade；
3) glass lamp shade after spraying is placed on into ventilation to dry 2~3 hours；
4) inner surface of glass lamp shade is cleaned with clear water, is then dried；
5) glass lamp shade is placed in 120 DEG C of baking oven and is toasted 30 minutes；
Wherein, the component content of the raw material is：
Wherein, the particle diameter of nano zine oxide and nano titanium oxide is 0.5nm, and 1 part of silver powder, institute are also included in raw material The particle diameter for stating silver powder is 20nm.Formulation for coating material mist degree in the present embodiment reaches 96%, and light transmittance reaches 91%, and coating storage is steady Do not settle within qualitative 45 days.
Embodiment 2
A kind of production method of Lawn lamp cover surface coating, including following operating procedure are disclosed in the present embodiment：
1) vinyl-formal resin powder is dissolved in acetone solvent, after stirring and dissolving, is added in solution successively Halogen calcium phosphate fluoressent powder, talcum powder and calcium pyroborophosphate, it is 6 to adjust mixed liquor pH value with hydrochloric acid, is then added in solution again Nano zine oxide and nano titanium oxide, then by ball milling in mixed liquor addition ball mill, after stirring, filtering obtains mesh Mark product；
2) by step 1) in the target product spray gun spraying that obtains on the inner surface of cleaning glass lamp shade；
3) glass lamp shade after spraying is placed on into ventilation to dry 2~3 hours；
4) inner surface of glass lamp shade is cleaned with clear water, is then dried；
5) glass lamp shade is placed in 100 DEG C of baking oven and is toasted 60 minutes；
Wherein, the component content of raw material is：
The particle diameter of wherein nano zine oxide and nano titanium oxide is 5nm, and 0.1~1 part of silver powder is also included in raw material, The particle diameter of the silver powder is 0.2~20nm, and the formulation for coating material mist degree in the present embodiment reaches 92%, and light transmittance reaches 89%, applies Material storage stability is not settled for 50 days.
Embodiment 3
Embodiment 3 discloses a kind of production method of Lawn lamp cover surface coating, including following operating procedure：
1) vinyl-formal resin powder is dissolved in acetone solvent, after stirring and dissolving, is added in solution successively Halogen calcium phosphate fluoressent powder, talcum powder and calcium pyroborophosphate, it is 5 to adjust mixed liquor pH value with hydrochloric acid, is then added in solution again Nano zine oxide and nano titanium oxide, then by ball milling in mixed liquor addition ball mill, after stirring, filtering obtains mesh Mark product；
2) by step 1) in the target product spray gun spraying that obtains on the inner surface of cleaning glass lamp shade；
3) glass lamp shade after spraying is placed on into ventilation to dry 2~3 hours；
4) inner surface of glass lamp shade is cleaned with clear water, is then dried；
5) glass lamp shade is placed in 110 DEG C of baking oven and is toasted 30 minutes；
Wherein, the component content of the raw material is：
The particle diameter of wherein nano zine oxide and nano titanium oxide is 0.5~5nm, the formulation for coating material mist in the present embodiment Degree reaches 97%, and light transmittance reaches 93%, and coating storage stability is not settled for 60 days.

Claims (3)

1. a kind of production method of Lawn lamp cover surface coating, it is characterised in that including following operating procedure：
1) vinyl-formal resin powder is dissolved in acetone solvent, after stirring and dissolving, successively to addition halogen phosphorus in solution Sour calcium fluorescent material, talcum powder and calcium pyroborophosphate, it is 5~6 to adjust mixed liquor pH value with hydrochloric acid, is then received to addition in solution again Rice zinc oxide and nano titanium oxide, then by ball milling in mixed liquor addition ball mill, after stirring, filtering obtains target Product；
2) by step 1) in the target product spray gun spraying that obtains on the inner surface of cleaning glass lamp shade；
3) glass lamp shade after spraying is placed on into ventilation to dry 2~3 hours；
4) inner surface of glass lamp shade is cleaned with clear water, is then dried；
5) glass lamp shade is placed in 100~120 DEG C of baking oven and is toasted 30~60 minutes；
Wherein, the component content of the raw material is：
2. the production method of Lawn lamp cover surface coating as claimed in claim 1, it is characterised in that the nano zine oxide Particle diameter with nano titanium oxide is 0.5~5nm.
3. the production method of Lawn lamp cover surface coating as claimed in claim 1, it is characterised in that also wrapped in the raw material 0.1~1 part of silver powder is included, the particle diameter of the silver powder is 0.2~20nm.
CN201611164147.XA 2016-12-16 2016-12-16 A kind of production method of Lawn lamp cover surface coating Pending CN106833171A (en)

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Application Number Priority Date Filing Date Title
CN201611164147.XA CN106833171A (en) 2016-12-16 2016-12-16 A kind of production method of Lawn lamp cover surface coating

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CN106833171A true CN106833171A (en) 2017-06-13

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108458319A (en) * 2018-02-07 2018-08-28 合肥安力电力工程有限公司 A kind of anti-dazzle noctilucence bedroom lamp shade of ceiling lamp

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Publication number Priority date Publication date Assignee Title
JP2005336351A (en) * 2004-05-27 2005-12-08 Pentel Corp Marking ink composition for writing board
CN1850686A (en) * 2006-04-28 2006-10-25 周新荣 Method for producing glass lamp-shade surface coating
CN101982437A (en) * 2010-11-05 2011-03-02 安徽世林照明股份有限公司 Process for producing frosted glass lampshades of LED energy-saving lamps
CN102070962A (en) * 2010-12-29 2011-05-25 云南光电辅料有限公司 Optical element protective coating and preparation method and using method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2005336351A (en) * 2004-05-27 2005-12-08 Pentel Corp Marking ink composition for writing board
CN1850686A (en) * 2006-04-28 2006-10-25 周新荣 Method for producing glass lamp-shade surface coating
CN101982437A (en) * 2010-11-05 2011-03-02 安徽世林照明股份有限公司 Process for producing frosted glass lampshades of LED energy-saving lamps
CN102070962A (en) * 2010-12-29 2011-05-25 云南光电辅料有限公司 Optical element protective coating and preparation method and using method thereof

Non-Patent Citations (3)

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Title
《电子工业生产技术手册》编委会: "《电子工业生产技术手册（5）电真空器件卷》", 31 July 1991, 国防工业出版社 *
方道腴等: "《电光源工艺 上册》", 30 September 1988, 复旦大学出版社 *
石森森等: "《耐磨耐蚀涂膜材料与技术》", 31 January 2003, 化学工业出版社 *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108458319A (en) * 2018-02-07 2018-08-28 合肥安力电力工程有限公司 A kind of anti-dazzle noctilucence bedroom lamp shade of ceiling lamp

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Application publication date: 20170613