CN104676458B - A kind of LED anti-reflection anti-dazzle glas lampshade and production method thereof - Google Patents

A kind of LED anti-reflection anti-dazzle glas lampshade and production method thereof Download PDF

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CN104676458B
CN104676458B CN201510066374.8A CN201510066374A CN104676458B CN 104676458 B CN104676458 B CN 104676458B CN 201510066374 A CN201510066374 A CN 201510066374A CN 104676458 B CN104676458 B CN 104676458B
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led
dazzle
ethanol
mass ratio
white carbon
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CN104676458A (en
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林和春
高中明
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YANGZHOU MINGSHENG NEW ENERGY TECHNOLOGY Co Ltd
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YANGZHOU MINGSHENG NEW ENERGY TECHNOLOGY Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/34Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
    • C03C17/3411Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions with at least two coatings of inorganic materials
    • C03C17/3429Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions with at least two coatings of inorganic materials at least one of the coatings being a non-oxide coating
    • C03C17/3482Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions with at least two coatings of inorganic materials at least one of the coatings being a non-oxide coating comprising silicon, hydrogenated silicon or a silicide
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D183/00Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
    • C09D183/04Polysiloxanes
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F21LIGHTING
    • F21VFUNCTIONAL FEATURES OR DETAILS OF LIGHTING DEVICES OR SYSTEMS THEREOF; STRUCTURAL COMBINATIONS OF LIGHTING DEVICES WITH OTHER ARTICLES, NOT OTHERWISE PROVIDED FOR
    • F21V3/00Globes; Bowls; Cover glasses
    • F21V3/04Globes; Bowls; Cover glasses characterised by materials, surface treatments or coatings
    • F21V3/06Globes; Bowls; Cover glasses characterised by materials, surface treatments or coatings characterised by the material
    • F21V3/061Globes; Bowls; Cover glasses characterised by materials, surface treatments or coatings characterised by the material the material being glass

Abstract

A kind of LED anti-reflection anti-dazzle glas lampshade and production method thereof, belong to glass anti-dazzle technical field.This LED is anti-reflection anti-dazzle glas lampshade, by successively carrying out plated film, anti-dazzle coating film treatment or successively carrying out anti-dazzle plated film, saturating coating film treatment or carry out the most saturating anti-dazzle coating film treatment and obtain to LED glass lamp shade surface.The method is by LED glass lamp shade pretreatment;By saturating coating liquid plated film in LED glass lamp shade surface, drying at room temperature, obtain LED anti-reflective glass lampshade;By anti-dazzle coating liquid plated film in LED saturating glass lamp shade surface, after carrying out cured cooling in high temperature furnace, obtain LED anti-reflection anti-dazzle glas lampshade.The production method of a kind of LED of the present invention anti-reflection anti-dazzle glas lampshade, production technology is simple, low cost, is suitable for industrial-scale production, the LED anti-reflection anti-dazzle glas lampshade light transmittance produced and anti-dazzle performance significantly improve, and can significantly improve luminous flux and the antiglare effect of light fixture.

Description

A kind of LED anti-reflection anti-dazzle glas lampshade and production method thereof
Technical field
The present invention relates to glass anti-dazzle technical field, particularly to a kind of LED anti-reflection anti-dazzle glas lampshade and producer thereof Method.
Background technology
Owing to LED luminous efficiency improves constantly, and have that life-span length, volume be little, tunable optical, the photochromic advantage such as abundant, Popularity rate in lighting application market improves the most rapidly, and the characteristics of luminescence phase of the characteristics of luminescence of LED light source and conventional light source Difference is very remote, in addition to optical design maneuver is completely different, owing to LED light-emitting area is less than the light-emitting area of conventional light source, causes Glare problem is serious.Particular design through fitting structure can partly reduce the glare problem of LED, such as patent CN2013101371818, CN201310265674X, CN201310589770X, propose special LED lamp respectively Anti-dazzle design, more structurally sound method is then the glare reduction techniques using lampshade, as the micropartical being used for traditional monitor industry mixed Miscellaneous diffuser plate as LED lamp cover or the PMMA lampshade that uses frosted, but diffuser plate lampshade or frosted PMMA lampshade by Relatively low in its light transmission rate, cause the luminous efficiency of LED lamp substantially to reduce, cause the waste of the energy.
Summary of the invention
The present invention provides a kind of LED anti-reflection anti-dazzle glas lampshade, it is therefore intended that overcome existing LED glass lamp shade anti-dazzle The defect that in technology, lampshade light transmittance is relatively low.It is a further object of the present invention to provide the production of a kind of LED anti-reflection anti-dazzle glas lampshade Method.
The present invention be the technical scheme is that a kind of LED anti-reflection anti-dazzle glas lampshade, its feature for achieving the above object Be: by LED glass lamp shade surface is successively carried out plated film, anti-dazzle coating film treatment or successively carry out anti-dazzle plated film, Thoroughly coating film treatment or carry out the most saturating anti-dazzle coating film treatment and obtain.
The production method of a kind of LED is anti-reflection anti-dazzle glas lampshade, it is characterised in that: comprise the following steps:
(1) LED glass lamp shade pure water is cleaned up, be dried in an oven, cooling;
(2) by saturating coating liquid plated film in LED glass lamp shade surface, drying at room temperature, LED anti-reflective glass lampshade is obtained;
(3) by anti-dazzle coating liquid plated film in LED saturating glass lamp shade surface, high temperature furnace carries out cured, process temperature Degree is 500~720 DEG C, obtains LED anti-reflection anti-dazzle glas lampshade after cooling.
The production method of a kind of LED is anti-reflection anti-dazzle glas lampshade, it is characterised in that: comprise the following steps:
(1) LED glass lamp shade pure water is cleaned up, be dried in an oven, cooling;
(2) anti-dazzle coating liquid being sprayed at LED glass lamp shade surface, carry out cured in high temperature furnace, treatment temperature is 200~250 DEG C, after cooling, obtain LED anti-dazzle glas lampshade;
(3) by saturating coating liquid dip-coating in LED anti-dazzle glas cover surface, high temperature furnace carries out cured, process temperature Degree is 500~720 DEG C, obtains LED saturating anti-dazzle glas lampshade after cooling.
Further, described coating liquid is prepared by following steps:
(1) tetraethoxysilane is disperseed in ethanol, add the aqueous acetic acid that concentration is 0.1~0.3N, ethanol and tetrem The mass ratio of TMOS is 1~2, and ethanol is 1~2 with the mass ratio of acetum, is stirred at room temperature at least 24 hours, By rotary evaporation, concentrating silica is obtained Nano silica sol 1;
(2) tetraethoxysilane is disperseed in ethanol, add the ammonia that concentration is 0.1~0.2N, ethanol and tetraethoxy-silicane The mass ratio of alkane is 5~7, and ethanol is 10~12 with the mass ratio of ammonia spirit, is stirred at room temperature at least 24 hours, passes through Rotary evaporation, obtains Nano silica sol 2 by concentrating silica;
(3) under magnetic stirring, Nano silica sol 1 is joined in the mixed solution of ethanol and isopropanol, ethanol and isopropyl The mass ratio of alcohol is 1, magnetic agitation uniformly after, continue to be slowly added into by Nano silica sol 2 under magnetic stirring above-mentioned In the solution of stirring, after addition, it is stirred at room temperature reaction at least 12 hours, prepares coating liquid.
Further, described anti-dazzle coating liquid is prepared by following steps:
(1) tetraethoxysilane is disperseed in ethanol, add the aqueous hydrochloric acid solution that concentration is 0.1~0.3N, ethanol and tetrem The mass ratio of TMOS is 1~2, and ethanol is 1~2 with the mass ratio of hydrochloric acid solution, is stirred at room temperature at least 24 hours, By rotary evaporation, concentrating silica is obtained Nano silica sol 4;
(2) white carbon is joined in isopropanol, adds silicone active agent, the mass ratio of isopropanol and white carbon be 20~ 50, white carbon is 30~50 with the mass ratio of silicone active agent, is stirred at room temperature and obtains homodisperse white carbon dispersion liquid;
(3) under magnetic stirring, gained white carbon dispersion liquid in step (2) is slowly added in Nano silica sol 4, adds After, it is stirred at room temperature uniformly, prepares anti-dazzle coating liquid.
The production method of a kind of LED is anti-reflection anti-dazzle glas lampshade, it is characterised in that: comprise the following steps:
(1) LED glass lamp shade pure water is cleaned up, be dried in an oven, cooling;
(2) by saturating anti-dazzle coating liquid plated film in LED glass lamp shade surface, high temperature furnace carries out cured, process temperature Degree is 500~720 DEG C, obtains LED saturating anti-dazzle glas lampshade after cooling.
Further, described anti-dazzle coating liquid is prepared by following steps:
(1) white carbon is joined in isopropanol, adds silicone active agent, the mass ratio of isopropanol and white carbon be 10~ 20, white carbon is 40~60 with the mass ratio of silicone active agent, is stirred at room temperature and obtains homodisperse white carbon dispersion liquid;
(2) under magnetic stirring, gained white carbon dispersion liquid in step (1) is slowly added in coating liquid, has added Bi Hou, is stirred at room temperature uniformly, prepares anti-dazzle coating liquid.
The production method of a kind of LED of the present invention anti-reflection anti-dazzle glas lampshade, production technology is simple, and low cost is suitable Closing industrial-scale production, the LED anti-reflection anti-dazzle glas lampshade light transmittance produced and anti-dazzle performance significantly improve, Ke Yiming The aobvious luminous flux improving light fixture and antiglare effect.
Accompanying drawing explanation
Fig. 1 is light design sketch when passing through common LED glass lamp shade.
Fig. 2 is that light is by utilizing design sketch during LED of the present invention anti-reflection anti-dazzle glas lampshade.
Detailed description of the invention
Embodiment 1
First, coating liquid is prepared by following steps:
(1) being dispersed in 450g ethanol by 313g tetraethoxysilane, adding 233g concentration is the aqueous acetic acid of 0.2N, It is stirred at room temperature 24 hours, by rotary evaporation, concentrating silica is obtained 460g Nano silica sol 1;
(2) being dispersed in 1080g ethanol by 178g tetraethoxysilane, adding 98g concentration is the ammonia of 0.16N, in room The lower stirring of temperature 24 hours, by rotary evaporation, obtains 630g Nano silica sol 2 by concentrating silica;
(3) mixing that under magnetic stirring, 460g Nano silica sol 1 joins 1210g ethanol and 1210g isopropanol is molten In liquid, magnetic agitation uniformly after, continue to be slowly added into by 630g Nano silica sol 2 under magnetic stirring and above-mentioned stirring In solution, after addition, it is stirred at room temperature reaction 12 hours, prepares coating liquid.
Secondly, anti-dazzle coating liquid is prepared by following steps:
(1) being dispersed in 400g ethanol by 270g tetraethoxysilane, adding 233g concentration is the aqueous hydrochloric acid solution of 0.2N, It is stirred at room temperature 24 hours, by rotary evaporation, concentrating silica is obtained 360g Nano silica sol 4;
(2) 3.9g white carbon is joined in 120g isopropanol, add 0.1g silicone active agent, be stirred at room temperature Obtain homodisperse white carbon dispersion liquid;
(3) under magnetic stirring, gained white carbon dispersion liquid in step (2) is slowly added in 360g Nano silica sol 4, After addition, it is stirred at room temperature uniformly, prepares anti-dazzle coating liquid.
A kind of LED anti-reflection anti-dazzle glas lampshade, by successively carrying out plated film, anti-dazzle plating to LED glass lamp shade surface Film processes and obtains, and specifically includes following steps:
(1) LED glass lamp shade pure water is cleaned up, be dried in an oven, cooling;
(2) by saturating coating liquid plated film in LED glass lamp shade surface, drying at room temperature, LED anti-reflective glass lampshade is obtained;
(3) by anti-dazzle coating liquid plated film in LED saturating glass lamp shade surface, high temperature furnace carries out cured, process temperature Degree is 720 DEG C, obtains LED anti-reflection anti-dazzle glas lampshade after cooling.
Embodiment 2
A kind of LED anti-reflection anti-dazzle glas lampshade, by successively carrying out anti-dazzle plated film to LED glass lamp shade surface, thoroughly plate Film processes and obtains, and specifically includes following steps:
(1) LED glass lamp shade pure water is cleaned up, be dried in an oven, cooling;
(2) anti-dazzle coating liquid being sprayed at LED glass lamp shade surface, carry out cured in high temperature furnace, treatment temperature is 200 DEG C, after cooling, obtain LED anti-dazzle glas lampshade;
(3) by saturating coating liquid dip-coating in LED anti-dazzle glas cover surface, high temperature furnace carries out cured, process temperature Degree is 500 DEG C, obtains LED saturating anti-dazzle glas lampshade after cooling.
Embodiment 3
First, anti-dazzle coating liquid is prepared by following steps:
(1) 5.6g white carbon is joined in 100g isopropanol, add 0.1g silicone active agent, be stirred at room temperature Obtain homodisperse white carbon dispersion liquid;
(2) under magnetic stirring, gained white carbon dispersion liquid in step (1) is slowly added in coating liquid, has added Bi Hou, is stirred at room temperature uniformly, prepares anti-dazzle coating liquid.
A kind of LED anti-reflection anti-dazzle glas lampshade, by carrying out the most saturating anti-dazzle coating film treatment to LED glass lamp shade surface Obtain, specifically include following steps:
(1) LED glass lamp shade pure water is cleaned up, be dried in an oven, cooling;
(2) by saturating anti-dazzle coating liquid plated film in LED glass lamp shade surface, high temperature furnace carries out cured, process temperature Degree is 600 DEG C, obtains LED saturating anti-dazzle glas lampshade after cooling.

Claims (4)

1. a LED anti-reflection anti-dazzle glas lampshade, it is characterised in that: by LED glass lamp shade surface first After carry out plated film, anti-dazzle coating film treatment or successively carry out anti-dazzle plated film, saturating coating film treatment or carry out one Secondary anti-dazzle coating film treatment obtains;
Solution used by described coating film treatment is prepared by following steps:
(1) tetraethoxysilane is disperseed in ethanol, add the aqueous acetic acid that concentration is 0.1~0.3N, second Alcohol is 1~2 with the mass ratio of tetraethoxysilane, and ethanol is 1~2 with the mass ratio of acetum, in room temperature Lower stirring at least 24 hours, by rotary evaporation, obtains Nano silica sol 1 by concentrating silica;
(2) tetraethoxysilane is disperseed in ethanol, add the ammonia that concentration is 0.1~0.2N, ethanol and four The mass ratio of Ethoxysilane is 5~7, and ethanol is 10~12 with the mass ratio of ammonia spirit, at room temperature stirs Mix at least 24 hours, by rotary evaporation, concentrating silica is obtained Nano silica sol 2;
(3) under magnetic stirring, Nano silica sol 1 is joined in the mixed solution of ethanol and isopropanol, ethanol It is 1 with the mass ratio of isopropanol, after magnetic agitation is uniform, continues to be delayed by Nano silica sol 2 under magnetic stirring Slowly join in the above-mentioned solution stirred, after addition, be stirred at room temperature reaction at least 12 hours, Prepare coating liquid;
Solution used by described anti-dazzle coating film treatment is prepared by following steps:
(1) tetraethoxysilane is disperseed in ethanol, add the aqueous hydrochloric acid solution that concentration is 0.1~0.3N, second Alcohol is 1~2 with the mass ratio of tetraethoxysilane, and ethanol is 1~2 with the mass ratio of hydrochloric acid solution, in room temperature Lower stirring at least 24 hours, by rotary evaporation, obtains Nano silica sol 4 by concentrating silica;
(2) white carbon is joined in isopropanol, add the quality of silicone active agent, isopropanol and white carbon Ratio is 20~50, and white carbon is 30~50 with the mass ratio of silicone active agent, is stirred at room temperature and obtains all Even scattered white carbon dispersion liquid;
(3) under magnetic stirring, gained white carbon dispersion liquid in step (2) is slowly added into Nano silica sol 4 In, after addition, it is stirred at room temperature uniformly, prepares anti-dazzle coating liquid;
Solution used by the most saturating described anti-dazzle coating film treatment is prepared by following steps:
(1) white carbon is joined in isopropanol, add the quality of silicone active agent, isopropanol and white carbon Ratio is 10~20, and white carbon is 40~60 with the mass ratio of silicone active agent, is stirred at room temperature and obtains all Even scattered white carbon dispersion liquid;
(2) under magnetic stirring, gained white carbon dispersion liquid in step (1) is slowly added in coating liquid, After addition, it is stirred at room temperature uniformly, prepares anti-dazzle coating liquid.
The production method of a kind of LED the most according to claim 1 anti-reflection anti-dazzle glas lampshade, its feature exists In: comprise the following steps:
(1) tetraethoxysilane is disperseed in ethanol, add the aqueous acetic acid that concentration is 0.1~0.3N, second Alcohol is 1~2 with the mass ratio of tetraethoxysilane, and ethanol is 1~2 with the mass ratio of acetum, in room temperature Lower stirring at least 24 hours, by rotary evaporation, obtains Nano silica sol 1 by concentrating silica;
(2) tetraethoxysilane is disperseed in ethanol, add the ammonia that concentration is 0.1~0.2N, ethanol and four The mass ratio of Ethoxysilane is 5~7, and ethanol is 10~12 with the mass ratio of ammonia spirit, at room temperature stirs Mix at least 24 hours, by rotary evaporation, concentrating silica is obtained Nano silica sol 2;
(3) under magnetic stirring, Nano silica sol 1 is joined in the mixed solution of ethanol and isopropanol, ethanol It is 1 with the mass ratio of isopropanol, after magnetic agitation is uniform, continues to be delayed by Nano silica sol 2 under magnetic stirring Slowly join in the above-mentioned solution stirred, after addition, be stirred at room temperature reaction at least 12 hours, Prepare coating liquid;
(4) tetraethoxysilane is disperseed in ethanol, add the aqueous hydrochloric acid solution that concentration is 0.1~0.3N, second Alcohol is 1~2 with the mass ratio of tetraethoxysilane, and ethanol is 1~2 with the mass ratio of hydrochloric acid solution, in room temperature Lower stirring at least 24 hours, by rotary evaporation, obtains Nano silica sol 4 by concentrating silica;
(5) white carbon is joined in isopropanol, add the quality of silicone active agent, isopropanol and white carbon Ratio is 20~50, and white carbon is 30~50 with the mass ratio of silicone active agent, is stirred at room temperature and obtains all Even scattered white carbon dispersion liquid;
(6) under magnetic stirring, gained white carbon dispersion liquid in step (2) is slowly added into Nano silica sol 4 In, after addition, it is stirred at room temperature uniformly, prepares anti-dazzle coating liquid;
(7) LED glass lamp shade pure water is cleaned up, be dried in an oven, cooling;
(8) by saturating coating liquid plated film in LED glass lamp shade surface, drying at room temperature, LED anti-reflective glass is obtained Lampshade;
(9) by anti-dazzle coating liquid plated film in LED saturating glass lamp shade surface, high temperature furnace carries out cured, Treatment temperature is 500~720 DEG C, obtains LED anti-reflection anti-dazzle glas lampshade after cooling.
The production method of a kind of LED the most according to claim 1 anti-reflection anti-dazzle glas lampshade, its feature exists In: comprise the following steps:
(1) tetraethoxysilane is disperseed in ethanol, add the aqueous acetic acid that concentration is 0.1~0.3N, second Alcohol is 1~2 with the mass ratio of tetraethoxysilane, and ethanol is 1~2 with the mass ratio of acetum, in room temperature Lower stirring at least 24 hours, by rotary evaporation, obtains Nano silica sol 1 by concentrating silica;
(2) tetraethoxysilane is disperseed in ethanol, add the ammonia that concentration is 0.1~0.2N, ethanol and four The mass ratio of Ethoxysilane is 5~7, and ethanol is 10~12 with the mass ratio of ammonia spirit, at room temperature stirs Mix at least 24 hours, by rotary evaporation, concentrating silica is obtained Nano silica sol 2;
(3) under magnetic stirring, Nano silica sol 1 is joined in the mixed solution of ethanol and isopropanol, ethanol It is 1 with the mass ratio of isopropanol, after magnetic agitation is uniform, continues to be delayed by Nano silica sol 2 under magnetic stirring Slowly join in the above-mentioned solution stirred, after addition, be stirred at room temperature reaction at least 12 hours, Prepare coating liquid;
(4) tetraethoxysilane is disperseed in ethanol, add the aqueous hydrochloric acid solution that concentration is 0.1~0.3N, second Alcohol is 1~2 with the mass ratio of tetraethoxysilane, and ethanol is 1~2 with the mass ratio of hydrochloric acid solution, in room temperature Lower stirring at least 24 hours, by rotary evaporation, obtains Nano silica sol 4 by concentrating silica;
(5) white carbon is joined in isopropanol, add the quality of silicone active agent, isopropanol and white carbon Ratio is 20~50, and white carbon is 30~50 with the mass ratio of silicone active agent, is stirred at room temperature and obtains all Even scattered white carbon dispersion liquid;
(6) under magnetic stirring, gained white carbon dispersion liquid in step (2) is slowly added into Nano silica sol 4 In, after addition, it is stirred at room temperature uniformly, prepares anti-dazzle coating liquid;
(7) LED glass lamp shade pure water is cleaned up, be dried in an oven, cooling;
(8) anti-dazzle coating liquid is sprayed at LED glass lamp shade surface, high temperature furnace carries out cured, place Reason temperature is 200~250 DEG C, obtains LED anti-dazzle glas lampshade after cooling;
(9) by saturating coating liquid dip-coating in LED anti-dazzle glas cover surface, high temperature furnace carries out cured, Treatment temperature is 500~720 DEG C, obtains LED saturating anti-dazzle glas lampshade after cooling.
The production method of a kind of LED the most according to claim 1 anti-reflection anti-dazzle glas lampshade, its feature exists In: comprise the following steps:
(1) white carbon is joined in isopropanol, add the quality of silicone active agent, isopropanol and white carbon Ratio is 10~20, and white carbon is 40~60 with the mass ratio of silicone active agent, is stirred at room temperature and obtains all Even scattered white carbon dispersion liquid;
(2) under magnetic stirring, gained white carbon dispersion liquid in step (1) is slowly added in coating liquid, After addition, it is stirred at room temperature uniformly, prepares anti-dazzle coating liquid;
(3) LED glass lamp shade pure water is cleaned up, be dried in an oven, cooling;
(4) by saturating anti-dazzle coating liquid plated film in LED glass lamp shade surface, high temperature furnace carries out cured, Treatment temperature is 500~720 DEG C, obtains LED saturating anti-dazzle glas lampshade after cooling.
CN201510066374.8A 2015-02-09 2015-02-09 A kind of LED anti-reflection anti-dazzle glas lampshade and production method thereof Active CN104676458B (en)

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CN106242273B (en) * 2016-08-05 2019-04-12 郭迎庆 A kind of preparation method of automatically cleaning tube glass
CN106568067A (en) * 2016-11-04 2017-04-19 东莞市广领光电科技有限公司 Production technology of glass products with light transmitting three-dimensional patterns and light fixtures
CN108458319A (en) * 2018-02-07 2018-08-28 合肥安力电力工程有限公司 A kind of anti-dazzle noctilucence bedroom lamp shade of ceiling lamp
CN110451815A (en) * 2019-08-07 2019-11-15 杭州杭科光电集团股份有限公司 A kind of preparation method of allusion curved shape LED filament lamp anti-reflection film

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