CN106832962A - A kind of anti-aging cable insulation layer formula of high temperature resistant - Google Patents

A kind of anti-aging cable insulation layer formula of high temperature resistant Download PDF

Info

Publication number
CN106832962A
CN106832962A CN201611264836.8A CN201611264836A CN106832962A CN 106832962 A CN106832962 A CN 106832962A CN 201611264836 A CN201611264836 A CN 201611264836A CN 106832962 A CN106832962 A CN 106832962A
Authority
CN
China
Prior art keywords
parts
high temperature
insulation layer
temperature resistant
cable insulation
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201611264836.8A
Other languages
Chinese (zh)
Inventor
李兵
朱峰林
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Anhui Lingyu Cable Technology Co Ltd
Original Assignee
Anhui Lingyu Cable Technology Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Anhui Lingyu Cable Technology Co Ltd filed Critical Anhui Lingyu Cable Technology Co Ltd
Priority to CN201611264836.8A priority Critical patent/CN106832962A/en
Publication of CN106832962A publication Critical patent/CN106832962A/en
Pending legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
    • C08L83/04—Polysiloxanes
    • C08L83/08—Polysiloxanes containing silicon bound to organic groups containing atoms other than carbon, hydrogen and oxygen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
    • C08J9/06—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent
    • C08J9/08—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent developing carbon dioxide
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
    • C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
    • C08J9/14—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
    • C08J9/143—Halogen containing compounds
    • C08J9/147—Halogen containing compounds containing carbon and halogen atoms only
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
    • H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
    • H01B3/28—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances natural or synthetic rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2203/00—Foams characterized by the expanding agent
    • C08J2203/02—CO2-releasing, e.g. NaHCO3 and citric acid
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2203/00—Foams characterized by the expanding agent
    • C08J2203/14—Saturated hydrocarbons, e.g. butane; Unspecified hydrocarbons
    • C08J2203/142—Halogenated saturated hydrocarbons, e.g. H3C-CF3
    • C08J2203/144—Perhalogenated saturated hydrocarbons, e.g. F3C-CF3
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2203/00—Foams characterized by the expanding agent
    • C08J2203/18—Binary blends of expanding agents
    • C08J2203/184—Binary blends of expanding agents of chemical foaming agent and physical blowing agent, e.g. azodicarbonamide and fluorocarbon
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2383/00—Characterised by the use of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen, or carbon only; Derivatives of such polymers
    • C08J2383/04—Polysiloxanes
    • C08J2383/08—Polysiloxanes containing silicon bound to organic groups containing atoms other than carbon, hydrogen, and oxygen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2483/00—Characterised by the use of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen, or carbon only; Derivatives of such polymers
    • C08J2483/04—Polysiloxanes
    • C08J2483/08—Polysiloxanes containing silicon bound to organic groups containing atoms other than carbon, hydrogen, and oxygen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/017—Additives being an antistatic agent
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/02—Flame or fire retardant/resistant
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/08—Stabilised against heat, light or radiation or oxydation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00—Applications
    • C08L2203/14—Applications used for foams
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00—Applications
    • C08L2203/20—Applications use in electrical or conductive gadgets
    • C08L2203/202—Applications use in electrical or conductive gadgets use in electrical wires or wirecoating
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Insulating Materials (AREA)

Abstract

The invention discloses a kind of anti-aging cable insulation layer formula of high temperature resistant, including silicon nitrile rubber, fluorosioloxane rubber, fire retardant, antioxidant, plasticizer, antistatic additive and foaming agent, the silicon nitrile rubber is 50 80 parts, fluorosioloxane rubber is 20 30 parts, the fire retardant is 10 20 parts, the antioxidant is 5 10 parts, the plasticizer is 38 parts, and the antistatic additive is 13 parts, and the foaming agent is 15 parts.The cable product that the present invention is made is fire-retardant, anti-aging, durable, economical and practical.

Description

A kind of anti-aging cable insulation layer formula of high temperature resistant
Technical field
The present invention relates to a kind of anti-aging cable insulation layer formula of high temperature resistant, belong to field of cable technology.
Background technology
Cable is the basis of modern society's electric power, and electric power is the basis for bringing up modern civilization society, with modern society Development, requirement to cable height all the more, it is necessary to cable has high temperature resistant, the advantages of fire-retardant.
The content of the invention
To overcome above-mentioned deficiency, the object of the invention to provide a kind of anti-aging cable insulation layer formula of high temperature resistant.
The solution of the present invention is as follows：A kind of anti-aging cable insulation layer formula of high temperature resistant, including silicon nitrile rubber, fluorine silicon rubber Glue, fire retardant, antioxidant, plasticizer, antistatic additive and foaming agent, the silicon nitrile rubber are 50-80 parts, and fluorosioloxane rubber is 20-30 parts, the fire retardant is 10-20 parts, the antioxidant is 5-10 parts, and the plasticizer is 3-8 parts, described antistatic Agent is 1-3 parts, and the foaming agent is 1-5 parts, and the fire retardant is by 10-15 parts of MAP and 5-10 parts of decabrominated dipheny ethene Composition, the antioxidant be by 3-8 parts of 2,6 di-t-butyl Pyrogentisinic Acids and 1-5 portions of propylgallate, the plasticizer be by 1-5 parts of diisobutyl phthalate and 2-6 parts of ditridecyl phthalate composition, the antistatic additive is by 1-2 parts of ethyoxyl Change alkylamine and the 0.5-1.5 parts of cruel amine composition of ethyoxyl bay, the foaming agent is by 1-3 parts of magnesium carbonate and 2-4 parts of dichloro four Fluoroethane is constituted, and a kind of anti-aging cable insulation layer formula of high temperature resistant is 25 parts of fluorosioloxane rubber by 60 parts of silicon nitrile rubbers, 12 parts of MAPs, 8 parts of decabrominated dipheny ethene, 4 part 2,6 di-t-butyl Pyrogentisinic Acids, 3 portions of propylgallates, 2 parts of O-phthalics Sour diisobutyl ester, 3 parts of ditridecyl phthalates, 1 part of ethoxylated alkylamine, 1 part of cruel amine of ethyoxyl bay, 1 part of magnesium carbonate and 2 Part dichlorotetra-fluoroethane composition.
Beneficial effects of the present invention：The cable product that the present invention is made is fire-retardant, anti-aging, durable, high temperature resistant.
Specific embodiment
A kind of anti-aging cable insulation layer formula of high temperature resistant, including it is silicon nitrile rubber, fluorosioloxane rubber, fire retardant, anti-oxidant Agent, plasticizer, antistatic additive and foaming agent, the silicon nitrile rubber are 50-80 parts, and fluorosioloxane rubber is 20-30 parts, the fire retardant For 10-20 parts, the antioxidant are 5-10 parts, the plasticizer is 3-8 parts, and the antistatic additive is 1-3 parts, the foaming Agent is 1-5 parts, and the fire retardant is made up of 10-15 parts of MAP and 5-10 parts of decabrominated dipheny ethene, the antioxidant It is that, by 3-8 parts of 2,6 di-t-butyl Pyrogentisinic Acids and 1-5 portions of propylgallate, the plasticizer is by 1-5 parts of phthalic acid two Isobutyl ester and 2-6 parts of ditridecyl phthalate composition, the antistatic additive is by 1-2 parts of ethoxylated alkylamine and 0.5-1.5 The cruel amine composition of part ethyoxyl bay, the foaming agent is made up of 1-3 parts of magnesium carbonate and 2-4 parts of dichlorotetra-fluoroethane, and described one It is by 60 parts of silicon nitrile rubbers, 25 parts of fluorosioloxane rubber, 12 parts of MAPs, 8 part ten to plant the anti-aging cable insulation layer formula of high temperature resistant Bromine talan, 4 part 2,6 di-t-butyl Pyrogentisinic Acids, 3 portions of propylgallates, 2 parts of diisobutyl phthalates, 3 parts of adjacent benzene Dicarboxylate, 1 part of ethoxylated alkylamine, 1 part of cruel amine of ethyoxyl bay, 1 part of magnesium carbonate and 2 parts of dichlorotetra-fluoroethane groups Into.
Although detailed description being given to specific embodiment of the invention above and being illustrated, it should be noted that We can carry out various equivalent changes and modification to above-mentioned implementation method according to conception of the invention, and the function produced by it is made With still without departing from specification covered it is spiritual when, all should be within protection scope of the present invention.

Claims (7)

1. a kind of anti-aging cable insulation layer formula of high temperature resistant, including silicon nitrile rubber, fluorosioloxane rubber, fire retardant, antioxidant, Plasticizer, antistatic additive and foaming agent, it is characterised in that：The silicon nitrile rubber is 50-80 parts, and fluorosioloxane rubber is 20-30 parts, institute Fire retardant is stated for 10-20 parts, the antioxidant are 5-10 parts, the plasticizer is 3-8 parts, and the antistatic additive is 1-3 parts, The foaming agent is 1-5 parts.
2. the anti-aging cable insulation layer formula of a kind of high temperature resistant according to claim 1, it is characterised in that：The fire retardant It is made up of 10-15 parts of MAP and 5-10 parts of decabrominated dipheny ethene.
3. the anti-aging cable insulation layer formula of a kind of high temperature resistant according to claim 1, it is characterised in that：It is described anti-oxidant Agent is by 3-8 parts of 2,6 di-t-butyl Pyrogentisinic Acids and 1-5 portions of propylgallate.
4. the anti-aging cable insulation layer formula of a kind of high temperature resistant according to claim 1, it is characterised in that：The plasticizer It is made up of 1-5 parts of diisobutyl phthalate and 2-6 parts of ditridecyl phthalate.
5. the anti-aging cable insulation layer formula of a kind of high temperature resistant according to claim 1, it is characterised in that：It is described antistatic Agent is made up of 1-2 parts of ethoxylated alkylamine and the 0.5-1.5 parts of cruel amine of ethyoxyl bay.
6. the anti-aging cable insulation layer formula of a kind of high temperature resistant according to claim 1, it is characterised in that：The foaming agent It is made up of 1-3 parts of magnesium carbonate and 2-4 parts of dichlorotetra-fluoroethane.
7. the anti-aging cable insulation layer formula of a kind of high temperature resistant according to claim 1, it is characterised in that：Described one kind is resistance to The anti-aging cable insulation layer formula of high temperature is by 60 parts of silicon nitrile rubbers, 25 parts of fluorosioloxane rubber, 12 parts of MAPs, 8 part of ten bromine two Styrene, 4 part 2,6 di-t-butyl Pyrogentisinic Acids, 3 portions of propylgallates, 2 parts of diisobutyl phthalates, 3 parts of O-phthalics Acid diesters, 1 part of ethoxylated alkylamine, 1 part of cruel amine of ethyoxyl bay, 1 part of magnesium carbonate and 2 parts of dichlorotetra-fluoroethane compositions.
CN201611264836.8A 2016-12-30 2016-12-30 A kind of anti-aging cable insulation layer formula of high temperature resistant Pending CN106832962A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201611264836.8A CN106832962A (en) 2016-12-30 2016-12-30 A kind of anti-aging cable insulation layer formula of high temperature resistant

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201611264836.8A CN106832962A (en) 2016-12-30 2016-12-30 A kind of anti-aging cable insulation layer formula of high temperature resistant

Publications (1)

Publication Number Publication Date
CN106832962A true CN106832962A (en) 2017-06-13

Family

ID=59116883

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201611264836.8A Pending CN106832962A (en) 2016-12-30 2016-12-30 A kind of anti-aging cable insulation layer formula of high temperature resistant

Country Status (1)

Country Link
CN (1) CN106832962A (en)

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104017369A (en) * 2014-06-18 2014-09-03 中国科学院宁波材料技术与工程研究所 Preparation method of silicon rubber foam material with high tensile strength
CN104059242A (en) * 2014-06-18 2014-09-24 中国科学院宁波材料技术与工程研究所 Preparation method of self-adhesion silicon rubber foam material

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104017369A (en) * 2014-06-18 2014-09-03 中国科学院宁波材料技术与工程研究所 Preparation method of silicon rubber foam material with high tensile strength
CN104059242A (en) * 2014-06-18 2014-09-24 中国科学院宁波材料技术与工程研究所 Preparation method of self-adhesion silicon rubber foam material

Similar Documents

Publication Publication Date Title
CN106832945A (en) A kind of anti-aging cable cover(ing) formula of high temperature resistant
CN101698731B (en) Non-toxic whether resistant thermoplastic elastomer material
TW201504305A (en) Alternative approach to toughening and flexibilizing thermoplastic and thermoset polymers
CA2798296A1 (en) Flexible pvc compositions made with plasticizers derived from renewable sources
CN104893152A (en) Environment-friendly cold-resistant polyvinyl chloride elastomer composition and preparation method thereof
KR20180092889A (en) Plasticizer composition and resin composition comprising the same
WO2013004265A1 (en) Surface covering comprising a citrate-based plasticizer
CN104072914A (en) Cold-resistant flame-retardant PVC cable material
CN102757588A (en) Polyvinyl chloride flame-retardant fireproof power cable material and preparation method thereof
ES2945695T3 (en) Plasticizing composition, resin composition and preparation processes thereof
CN106604963A (en) Stabilizer composition for vinyl chloride resin, vinyl chloride resin composition using said stabilizer composition, and molded article obtained from said resin composition
KR20160134652A (en) Vinyl chloride resin composition, vinyl chloride resin molded body, and laminate
CN102504444A (en) Plasticizer and polyvinyl chloride (PVC) environmental-friendly electric wire and cable sheath material containing plasticizer
CN106832962A (en) A kind of anti-aging cable insulation layer formula of high temperature resistant
CN106832936A (en) A kind of aging-resistant flame-proof cable cover(ing) formula
CN107531937A (en) Plasticizer composition, resin combination and preparation method thereof
CN106751284A (en) A kind of durable combustion-preventing cable insulation layer formula
CN104327350A (en) Modified high temperature resistant polyethylene plastic particle
CN102863664A (en) Anti-aging antistatic sole material
CN105885461A (en) Formula of waterproof layer of environment-friendly waterproof cable
CN115490975A (en) Modified polyvinyl chloride automobile cable material resistant to high and low temperatures of-40 ℃ and 125 ℃ and preparation method thereof
JP5691147B2 (en) Ethylene-vinyl acetate copolymer resin composition, adhesive comprising the same, adhesive film, and laminate comprising the same
CN103740000A (en) Polyvinyl chloride and polyethylene composite modified plastic
CN106832694A (en) A kind of durable flame-proof cable sheath formula
CN104356529A (en) Formula of heat-resistant antistatic plastic

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication
RJ01 Rejection of invention patent application after publication

Application publication date: 20170613