CN106832223A - The black paste produced in vitamin B6 industrial processes is in anticorrosive paint as the application of curing agent - Google Patents
The black paste produced in vitamin B6 industrial processes is in anticorrosive paint as the application of curing agent Download PDFInfo
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- CN106832223A CN106832223A CN201611248444.2A CN201611248444A CN106832223A CN 106832223 A CN106832223 A CN 106832223A CN 201611248444 A CN201611248444 A CN 201611248444A CN 106832223 A CN106832223 A CN 106832223A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
- C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
- C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
- C08G59/62—Alcohols or phenols
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Paints Or Removers (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
- Fuel Cell (AREA)
Abstract
The present invention relates in a kind of vitamin B6 industrial processes produce black paste (hereinafter referred to as black cream) as the curing agent component of anticorrosive paint application, the black paste produced in vitamin B6 industrial processes and epoxy resin reaction product are applied to metal surface, solidification drying and forming-film intercepts chemical reagent to reach corrosion-resistant purpose the beneficial effects of the invention are as follows the resource reutilization for vitamin B6 waste residue and the anti-corrosion effective to metal at a certain temperature, industrial effective income is improve, while solving environmental issue.
Description
Technical field
The present invention relates to trade waste resource technology field, more particularly to a kind of vitamin B6 industrial processes
The black paste (hereinafter referred to as black cream) of middle generation as the curing agent component of anticorrosive paint application.
Background technology
The phenomenon referred to as metal erosion that metal is damaged by the chemistry of surrounding medium or electrochemical action.With society
Can develop and industrial technological advancement, the use scope of metal is more and more extensive, and corrosion of metal problem is throughout national economy
Every field, according to the investigation statisticses of World Developed Countries, produces because the direct losses that corrosion is caused account for national economy every year
The 2.5%~4.2% of total value, and according to estimates, the metal material that 20% is there are about in the world cannot be reclaimed because being corroded, thus
Corrosion of metal and protection question cause the most attention of countries in the world.In order to reduce the loss of corrosion, people take very
Many measures, but most universal, most economical, most practical so far safeguard measure or coating protection, anticorrosion with coat are constructed with it
It is easy, economic and practical, widely should by device area, the constraint of shape and the features such as with certain decorative effect
With.
Chemical industry equipment preserving method：(1) method (3) electrical anticorrosion method of method (2) face coat of environmental treatment.
The present invention mainly considers that the method for face coat carrys out anti-corrosion.
Corrosion mechanism can substantially be divided three classes：Chemical attack, the rotten candle of physics, the rotten candle of electrochemistry
The anticorrosion mechanism of anticorrosive paint mainly has three aspects：Passivation corrosion inhibition to matrix, Isolated Shield effect and
Form electro-chemical protection
Refer to the surface property for changing matrix, such as by the pigment in paint coatings to the passivation corrosion inhibition of matrix
To change, its matrix current potential is set to be moved towards positive direction, thus metal begins to passivation, can thus play the mesh for delaying corrosion
's.
Isolated Shield is acted on, and is the coating by being formed in metal base surface, is just forming one in metal base surface
Individual barrier layer, just can isolate and shield the medium such as contact of oxygen gas and water and acid-alkali salt with metallic matrix, so as to reach to Metal Substrate
The purpose of body protection.
Electro-chemical protection is formed, is by adding current potential metal packing more more negative than parent metal in anticorrosive paint
Such as zinc powder or aluminium powder, when there is coating of the electrolyte through Isolated Shield to penetrate into metal surface, such electronegative metals
Filler just forms battery with metallic matrix, and what sacrifice dissolving occurred first is as the metal packing of anode, such metallic matrix
Just protect, so as to reach to matrix protection effect, this kind of coating thus be sacrificial anticorrosive paint.
The content of the invention
The technical problems to be solved by the invention are directed to above-mentioned prior art and provide a kind of many carboxylic class solid wastes of polyamines and exist
As the application of curing agent in anticorrosive paint, the remaining waste residue of production vitamin B6 in industrial production can be effectively utilized, and it is right
The effective anti-corrosion of hardware.
The technical solution adopted in the present invention is：The black paste produced in vitamin B6 industrial processes is in anti-corrosion
As the application of curing agent in coating.
By such scheme：The black paste that will be produced in vitamin B6 industrial processes reacts generation with epoxy resin
Thing is applied to metal surface, drying and forming-film is solidified at a certain temperature and intercepts chemical reagent to reach corrosion-resistant purpose.
By such scheme：Solidification temperature is 120~150 DEG C.
By such scheme：Hardening time is 30~60min.
By such scheme：The black paste and asphalt mixtures modified by epoxy resin produced in the added vitamin B6 industrial processes of reaction
Fat mass ratio is 3:1~1:3.
By such scheme, it is characterised in that：The black paste and asphalt mixtures modified by epoxy resin produced in vitamin B6 industrial processes
Fat reaction temperature is first to heat 0.5-5h at 50-90 DEG C, improves temperature to 60-200 DEG C of heating 0.5-3h.
One of concrete scheme is：Black cream and 1,2-PD are added in reaction vessel, after black cream is completely dissolved,
According to epoxy resin to the reaction vessel that black cream and the mass ratio of epoxy resin are 1: 1 addition respective quality, in 90 DEG C of oil
2h is stirred in bath, temperature to 180 DEG C of stirring 1h is improved, it is suitable rear stand-by to viscosity.
The beneficial effects of the invention are as follows the resource reutilization for vitamin B6 waste residue and the anti-corrosion effective to metal, improve
Industrial effective income, while solving environmental issue.
Specific embodiment
With reference to specific embodiment, the present invention will be described in detail.Following examples will be helpful to the skill of this area
Art personnel further understand the present invention, but the invention is not limited in any way.It should be pointed out that to the common skill of this area
For art personnel, without departing from the inventive concept of the premise, various modifications and improvements can be made.These belong to this hair
Bright protection domain.
Embodiment 1
Black cream (the black paste produced in vitamin B6 industrial processes of certain mass is added in four-hole boiling flask
The many carboxylic class solid wastes of thing, mainly polyamines) and 1,2-PD, after black cream is completely dissolved, according to black cream and the matter of epoxy resin
Amount compares in 1: 1 epoxy resin to the four-hole boiling flask for adding respective quality, and 2h is stirred in 90 DEG C of oil bath pan, improves temperature extremely
180 DEG C of stirring 1h, until stand-by after viscosity is suitable.The mixture of preparation is placed in by polishing, washing, dry tinplate sheet
On, quickly and evenly to be brushed along direction in length and breadth in tinplate sheet using spreader, the thickness of film is 125 μm, then by iron
Piece is placed in the baking oven that temperature is 130 DEG C and dries 30min, after dried coating film, 10% HCl, 30% is soaked in by the 2/3 of film
NaOH and 30% NaCl solution in see film change.In HCl, NaOH and NaCl the anti-corrosion time be respectively 7d, 8d and
9d。
Embodiment 2
The black cream and 1,2-PD of certain mass are added in four-hole boiling flask, after black cream is completely dissolved, according to black cream
In epoxy resin to the four-hole boiling flask that the mass ratio 1: 2 of epoxy resin adds respective quality, stirred in 90 DEG C of oil bath pan
2h is mixed, temperature to 180 DEG C of stirring 1h is improved, until stand-by after viscosity is suitable.The mixture of preparation is placed in by polishing, washing
Wash, in dry tinplate sheet, quickly and evenly brushed along direction in length and breadth in tinplate sheet using spreader, the thickness of film
It is 125 μm, then iron plate is placed in the baking oven that temperature is 130 DEG C and dries 30min, after dried coating film, by 2/3 immersion of film
The change of film is seen in HCl, 30% NaOH and 30% NaCl solution in 10%.In HCl, NaOH and NaCl during anti-corrosion
Between be respectively 9d, 9d and 9d.
Embodiment 3
The black cream and 1,2-PD of certain mass are added in four-hole boiling flask, after black cream is completely dissolved, according to black cream
In epoxy resin to the four-hole boiling flask that the mass ratio 1: 3 of epoxy resin adds respective quality, stirred in 90 DEG C of oil bath pan
2h is mixed, temperature to 180 DEG C of stirring 1h is improved, until stand-by after viscosity is suitable.The mixture of preparation is placed in by polishing, washing
Wash, in dry tinplate sheet, quickly and evenly brushed along direction in length and breadth in tinplate sheet using spreader, the thickness of film
It is 125 μm, then iron plate is placed in the baking oven that temperature is 130 DEG C and dries 30min, after dried coating film, by 2/3 immersion of film
The change of film is seen in HCl, 30% NaOH and 30% NaCl solution in 10%.In HCl, NaOH and NaCl during anti-corrosion
Between be respectively 8d, 9d and 9d.
Embodiment 4
The black cream and 1,2-PD of certain mass are added in four-hole boiling flask, after black cream is completely dissolved, according to black cream
In epoxy resin to the four-hole boiling flask that the mass ratio 1: 1 of epoxy resin adds respective quality, stirred in 90 DEG C of oil bath pan
2h is mixed, temperature to 180 DEG C of stirring 1h is improved, until stand-by after viscosity is suitable.The mixture of preparation is placed in by polishing, washing
Wash, in dry tinplate sheet, quickly and evenly brushed along direction in length and breadth in tinplate sheet using spreader, the thickness of film
It is 125 μm, then iron plate is placed in the baking oven that temperature is 130 DEG C and dries 40min, after dried coating film, by 2/3 immersion of film
The change of film is seen in HCl, 30% NaOH and 30% NaCl solution in 10%.In HCl, NaOH and NaCl during anti-corrosion
Between be respectively 7d, 9d and 9d.
Embodiment 5
The black cream and 1,2-PD of certain mass are added in four-hole boiling flask, after black cream is completely dissolved, according to black cream
In epoxy resin to the four-hole boiling flask that the mass ratio 1: 2 of epoxy resin adds respective quality, stirred in 90 DEG C of oil bath pan
2h is mixed, temperature to 180 DEG C of stirring 1h is improved, until stand-by after viscosity is suitable.The mixture of preparation is placed in by polishing, washing
Wash, in dry tinplate sheet, quickly and evenly brushed along direction in length and breadth in tinplate sheet using spreader, the thickness of film
It is 125 μm, then iron plate is placed in the baking oven that temperature is 130 DEG C and dries 40min, after dried coating film, by 2/3 immersion of film
The change of film is seen in HCl, 30% NaOH and 30% NaCl solution in 10%.In HCl, NaOH and NaCl during anti-corrosion
Between be respectively 9d, 10d and 10d.
Embodiment 6
The black cream and 1,2-PD of certain mass are added in four-hole boiling flask, after black cream is completely dissolved, according to black cream
In epoxy resin to the four-hole boiling flask that the mass ratio 1: 3 of epoxy resin adds respective quality, stirred in 90 DEG C of oil bath pan
2h is mixed, temperature to 180 DEG C of stirring 1h is improved, until stand-by after viscosity is suitable.The mixture of preparation is placed in by polishing, washing
Wash, in dry tinplate sheet, quickly and evenly brushed along direction in length and breadth in tinplate sheet using spreader, the thickness of film
It is 125 μm, then iron plate is placed in the baking oven that temperature is 130 DEG C and dries 40min, after dried coating film, by 2/3 immersion of film
The change of film is seen in HCl, 30% NaOH and 30% NaCl solution in 10%.In HCl, NaOH and NaCl during anti-corrosion
Between be respectively 9d, 9d and 9d.
Embodiment 7
The black cream and 1,2-PD of certain mass are added in four-hole boiling flask, after black cream is completely dissolved, according to black cream
In epoxy resin to the four-hole boiling flask that the mass ratio 1: 1 of epoxy resin adds respective quality, stirred in 90 DEG C of oil bath pan
2h is mixed, temperature to 180 DEG C of stirring 1h is improved, until stand-by after viscosity is suitable.The mixture of preparation is placed in by polishing, washing
Wash, in dry tinplate sheet, quickly and evenly brushed along direction in length and breadth in tinplate sheet using spreader, the thickness of film
It is 125 μm, then iron plate is placed in the baking oven that temperature is 130 DEG C and dries 50min, after dried coating film, by 2/3 immersion of film
The change of film is seen in HCl, 30% NaOH and 30% NaCl solution in 10%.In HCl, NaOH and NaCl during anti-corrosion
Between be respectively 9d, 8d and 8d.
Embodiment 8
The black cream and 1,2-PD of certain mass are added in four-hole boiling flask, after black cream is completely dissolved, according to black cream
In epoxy resin to the four-hole boiling flask that the mass ratio 1: 2 of epoxy resin adds respective quality, stirred in 90 DEG C of oil bath pan
2h is mixed, temperature to 180 DEG C of stirring 1h is improved, until stand-by after viscosity is suitable.The mixture of preparation is placed in by polishing, washing
Wash, in dry tinplate sheet, quickly and evenly brushed along direction in length and breadth in tinplate sheet using spreader, the thickness of film
It is 125 μm, then iron plate is placed in the baking oven that temperature is 130 DEG C and dries 50min, after dried coating film, by 2/3 immersion of film
The change of film is seen in HCl, 30% NaOH and 30% NaCl solution in 10%.In HCl, NaOH and NaCl during anti-corrosion
Between be respectively 9d, 10d and 9d.
Embodiment 9
The black cream and 1,2-PD of certain mass are added in four-hole boiling flask, after black cream is completely dissolved, according to black cream
In epoxy resin to the four-hole boiling flask that the mass ratio 1: 3 of epoxy resin adds respective quality, stirred in 90 DEG C of oil bath pan
2h is mixed, temperature to 180 DEG C of stirring 1h is improved, until stand-by after viscosity is suitable.The mixture of preparation is placed in by polishing, washing
Wash, in dry tinplate sheet, quickly and evenly brushed along direction in length and breadth in tinplate sheet using spreader, the thickness of film
It is 125 μm, then iron plate is placed in the baking oven that temperature is 130 DEG C and dries 50min, after dried coating film, by 2/3 immersion of film
The change of film is seen in HCl, 30% NaOH and 30% NaCl solution in 10%.In HCl, NaOH and NaCl during anti-corrosion
Between be respectively 9d, 9d and 9d.
Embodiment 10
The black cream and 1,2-PD of certain mass are added in four-hole boiling flask, after black cream is completely dissolved, according to black cream
In epoxy resin to the four-hole boiling flask that the mass ratio 1: 1 of epoxy resin adds respective quality, stirred in 90 DEG C of oil bath pan
2h is mixed, temperature to 180 DEG C of stirring 1h is improved, until stand-by after viscosity is suitable.The mixture of preparation is placed in by polishing, washing
Wash, in dry tinplate sheet, quickly and evenly brushed along direction in length and breadth in tinplate sheet using spreader, the thickness of film
It is 125 μm, then iron plate is placed in the baking oven that temperature is 130 DEG C and dries 60min, after dried coating film, by 2/3 immersion of film
The change of film is seen in HCl, 30% NaOH and 30% NaCl solution in 10%.In HCl, NaOH and NaCl during anti-corrosion
Between be respectively 9d, 9d and 9d.
Embodiment 11
The black cream and 1,2-PD of certain mass are added in four-hole boiling flask, after black cream is completely dissolved, according to black cream
In epoxy resin to the four-hole boiling flask that the mass ratio 1: 2 of epoxy resin adds respective quality, stirred in 90 DEG C of oil bath pan
2h is mixed, temperature to 180 DEG C of stirring 1h is improved, until stand-by after viscosity is suitable.The mixture of preparation is placed in by polishing, washing
Wash, in dry tinplate sheet, quickly and evenly brushed along direction in length and breadth in tinplate sheet using spreader, the thickness of film
It is 125 μm, then iron plate is placed in the baking oven that temperature is 130 DEG C and dries 60min, after dried coating film, by 2/3 immersion of film
The change of film is seen in HCl, 30% NaOH and 30% NaCl solution in 10%.In HCl, NaOH and NaCl during anti-corrosion
Between be respectively 9d, 9d and 10d.
Embodiment 12
The black cream and 1,2-PD of certain mass are added in four-hole boiling flask, after black cream is completely dissolved, according to black cream
In epoxy resin to the four-hole boiling flask that the mass ratio 1: 3 of epoxy resin adds respective quality, stirred in 90 DEG C of oil bath pan
2h is mixed, temperature to 180 DEG C of stirring 1h is improved, until stand-by after viscosity is suitable.The mixture of preparation is placed in by polishing, washing
Wash, in dry tinplate sheet, quickly and evenly brushed along direction in length and breadth in tinplate sheet using spreader, the thickness of film
It is 125 μm, then iron plate is placed in the baking oven that temperature is 130 DEG C and dries 60min, after dried coating film, by 2/3 immersion of film
The change of film is seen in HCl, 30% NaOH and 30% NaCl solution in 10%.In HCl, NaOH and NaCl during anti-corrosion
Between be respectively 9d, 9d and 9d.
Embodiment 13
The black cream and 1,2-PD of certain mass are added in four-hole boiling flask, after black cream is completely dissolved, according to black cream
In epoxy resin to the four-hole boiling flask that the mass ratio 1: 1 of epoxy resin adds respective quality, stirred in 90 DEG C of oil bath pan
2h is mixed, temperature to 180 DEG C of stirring 1h is improved, until stand-by after viscosity is suitable.The mixture of preparation is placed in by polishing, washing
Wash, in dry tinplate sheet, quickly and evenly brushed along direction in length and breadth in tinplate sheet using spreader, the thickness of film
It is 125 μm, then iron plate is placed in the baking oven that temperature is 140 DEG C and dries 30min, after dried coating film, by 2/3 immersion of film
The change of film is seen in HCl, 30% NaOH and 30% NaCl solution in 10%.In HCl, NaOH and NaCl during anti-corrosion
Between be respectively 9d, 9d and 10d.
Embodiment 14
The black cream and 1,2-PD of certain mass are added in four-hole boiling flask, after black cream is completely dissolved, according to black cream
In epoxy resin to the four-hole boiling flask that the mass ratio 1: 2 of epoxy resin adds respective quality, stirred in 90 DEG C of oil bath pan
2h is mixed, temperature to 180 DEG C of stirring 1h is improved, until stand-by after viscosity is suitable.The mixture of preparation is placed in by polishing, washing
Wash, in dry tinplate sheet, quickly and evenly brushed along direction in length and breadth in tinplate sheet using spreader, the thickness of film
It is 125 μm, then iron plate is placed in the baking oven that temperature is 140 DEG C and dries 30min, after dried coating film, by 2/3 immersion of film
The change of film is seen in HCl, 30% NaOH and 30% NaCl solution in 10%.In HCl, NaOH and NaCl during anti-corrosion
Between be respectively>10d, 10d and 10d.
Embodiment 15
The black cream and 1,2-PD of certain mass are added in four-hole boiling flask, after black cream is completely dissolved, according to black cream
In epoxy resin to the four-hole boiling flask that the mass ratio 1: 3 of epoxy resin adds respective quality, stirred in 90 DEG C of oil bath pan
2h is mixed, temperature to 180 DEG C of stirring 1h is improved, until stand-by after viscosity is suitable.The mixture of preparation is placed in by polishing, washing
Wash, in dry tinplate sheet, quickly and evenly brushed along direction in length and breadth in tinplate sheet using spreader, the thickness of film
It is 125 μm, then iron plate is placed in the baking oven that temperature is 140 DEG C and dries 30min, after dried coating film, by 2/3 immersion of film
The change of film is seen in HCl, 30% NaOH and 30% NaCl solution in 10%.In HCl, NaOH and NaCl during anti-corrosion
Between be respectively 10d, 10d and 10d.
Embodiment 16
The black cream and 1,2-PD of certain mass are added in four-hole boiling flask, after black cream is completely dissolved, according to black cream
In epoxy resin to the four-hole boiling flask that the mass ratio 1: 1 of epoxy resin adds respective quality, stirred in 90 DEG C of oil bath pan
2h is mixed, temperature to 180 DEG C of stirring 1h is improved, until stand-by after viscosity is suitable.The mixture of preparation is placed in by polishing, washing
Wash, in dry tinplate sheet, quickly and evenly brushed along direction in length and breadth in tinplate sheet using spreader, the thickness of film
It is 125 μm, then iron plate is placed in the baking oven that temperature is 140 DEG C and dries 40min, after dried coating film, by 2/3 immersion of film
The change of film is seen in HCl, 30% NaOH and 30% NaCl solution in 10%.In HCl, NaOH and NaCl during anti-corrosion
Between be respectively 9d, 9d and 10d.
Embodiment 17
The black cream and 1,2-PD of certain mass are added in four-hole boiling flask, after black cream is completely dissolved, according to black cream
In epoxy resin to the four-hole boiling flask that the mass ratio 1: 2 of epoxy resin adds respective quality, stirred in 90 DEG C of oil bath pan
2h is mixed, temperature to 180 DEG C of stirring 1h is improved, until stand-by after viscosity is suitable.The mixture of preparation is placed in by polishing, washing
Wash, in dry tinplate sheet, quickly and evenly brushed along direction in length and breadth in tinplate sheet using spreader, the thickness of film
It is 125 μm, then iron plate is placed in the baking oven that temperature is 140 DEG C and dries 40min, after dried coating film, by 2/3 immersion of film
The change of film is seen in HCl, 30% NaOH and 30% NaCl solution in 10%.In HCl, NaOH and NaCl during anti-corrosion
Between be respectively>10d, 10d and 10d.
Embodiment 18
The black cream and 1,2-PD of certain mass are added in four-hole boiling flask, after black cream is completely dissolved, according to black cream
In epoxy resin to the four-hole boiling flask that the mass ratio 1: 3 of epoxy resin adds respective quality, stirred in 90 DEG C of oil bath pan
2h is mixed, temperature to 180 DEG C of stirring 1h is improved, until stand-by after viscosity is suitable.The mixture of preparation is placed in by polishing, washing
Wash, in dry tinplate sheet, quickly and evenly brushed along direction in length and breadth in tinplate sheet using spreader, the thickness of film
It is 125 μm, then iron plate is placed in the baking oven that temperature is 140 DEG C and dries 40min, after dried coating film, by 2/3 immersion of film
The change of film is seen in HCl, 30% NaOH and 30% NaCl solution in 10%.In HCl, NaOH and NaCl during anti-corrosion
Between be respectively>10d、>10d and>10d.
Embodiment 19
The black cream and 1,2-PD of certain mass are added in four-hole boiling flask, after black cream is completely dissolved, according to black cream
In epoxy resin to the four-hole boiling flask that the mass ratio 1: 1 of epoxy resin adds respective quality, stirred in 90 DEG C of oil bath pan
2h is mixed, temperature to 180 DEG C of stirring 1h is improved, until stand-by after viscosity is suitable.The mixture of preparation is placed in by polishing, washing
Wash, in dry tinplate sheet, quickly and evenly brushed along direction in length and breadth in tinplate sheet using spreader, the thickness of film
It is 125 μm, then iron plate is placed in the baking oven that temperature is 140 DEG C and dries 50min, after dried coating film, by 2/3 immersion of film
The change of film is seen in HCl, 30% NaOH and 30% NaCl solution in 10%.In HCl, NaOH and NaCl during anti-corrosion
Between be respectively>10d、>10d and>10d.
Embodiment 20
The black cream and 1,2-PD of certain mass are added in four-hole boiling flask, after black cream is completely dissolved, according to black cream
In epoxy resin to the four-hole boiling flask that the mass ratio 1: 2 of epoxy resin adds respective quality, stirred in 90 DEG C of oil bath pan
2h is mixed, temperature to 180 DEG C of stirring 1h is improved, until stand-by after viscosity is suitable.The mixture of preparation is placed in by polishing, washing
Wash, in dry tinplate sheet, quickly and evenly brushed along direction in length and breadth in tinplate sheet using spreader, the thickness of film
It is 125 μm, then iron plate is placed in the baking oven that temperature is 140 DEG C and dries 50min, after dried coating film, by 2/3 immersion of film
The change of film is seen in HCl, 30% NaOH and 30% NaCl solution in 10%.In HCl, NaOH and NaCl during anti-corrosion
Between be respectively>10d、>10d and>10d.
Embodiment 21
The black cream and 1,2-PD of certain mass are added in four-hole boiling flask, after black cream is completely dissolved, according to black cream
In epoxy resin to the four-hole boiling flask that the mass ratio 1: 3 of epoxy resin adds respective quality, stirred in 90 DEG C of oil bath pan
2h is mixed, temperature to 180 DEG C of stirring 1h is improved, until stand-by after viscosity is suitable.The mixture of preparation is placed in by polishing, washing
Wash, in dry tinplate sheet, quickly and evenly brushed along direction in length and breadth in tinplate sheet using spreader, the thickness of film
It is 125 μm, then iron plate is placed in the baking oven that temperature is 140 DEG C and dries 50min, after dried coating film, by 2/3 immersion of film
The change of film is seen in HCl, 30% NaOH and 30% NaCl solution in 10%.In HCl, NaOH and NaCl during anti-corrosion
Between be respectively>10d、>10d and>10d.
Embodiment 22
The black cream and 1,2-PD of certain mass are added in four-hole boiling flask, after black cream is completely dissolved, according to black cream
In epoxy resin to the four-hole boiling flask that the mass ratio 1: 1 of epoxy resin adds respective quality, stirred in 90 DEG C of oil bath pan
2h is mixed, temperature to 180 DEG C of stirring 1h is improved, until stand-by after viscosity is suitable.The mixture of preparation is placed in by polishing, washing
Wash, in dry tinplate sheet, quickly and evenly brushed along direction in length and breadth in tinplate sheet using spreader, the thickness of film
It is 125 μm, then iron plate is placed in the baking oven that temperature is 140 DEG C and dries 60min, after dried coating film, by 2/3 immersion of film
The change of film is seen in HCl, 30% NaOH and 30% NaCl solution in 10%.In HCl, NaOH and NaCl during anti-corrosion
Between be respectively>10d、>10d and>10d.
Embodiment 23
The black cream and 1,2-PD of certain mass are added in four-hole boiling flask, after black cream is completely dissolved, according to black cream
In epoxy resin to the four-hole boiling flask that the mass ratio 1: 2 of epoxy resin adds respective quality, stirred in 90 DEG C of oil bath pan
2h is mixed, temperature to 180 DEG C of stirring 1h is improved, until stand-by after viscosity is suitable.The mixture of preparation is placed in by polishing, washing
Wash, in dry tinplate sheet, quickly and evenly brushed along direction in length and breadth in tinplate sheet using spreader, the thickness of film
It is 125 μm, then iron plate is placed in the baking oven that temperature is 140 DEG C and dries 60min, after dried coating film, by 2/3 immersion of film
The change of film is seen in HCl, 30% NaOH and 30% NaCl solution in 10%.In HCl, NaOH and NaCl during anti-corrosion
Between be respectively>10d、>10d and>10d.
Embodiment 24
The black cream and 1,2-PD of certain mass are added in four-hole boiling flask, after black cream is completely dissolved, according to black cream
In epoxy resin to the four-hole boiling flask that the mass ratio 1: 3 of epoxy resin adds respective quality, stirred in 90 DEG C of oil bath pan
2h is mixed, temperature to 180 DEG C of stirring 1h is improved, until stand-by after viscosity is suitable.The mixture of preparation is placed in by polishing, washing
Wash, in dry tinplate sheet, quickly and evenly brushed along direction in length and breadth in tinplate sheet using spreader, the thickness of film
It is 125 μm, then iron plate is placed in the baking oven that temperature is 140 DEG C and dries 60min, after dried coating film, by 2/3 immersion of film
The change of film is seen in HCl, 30% NaOH and 30% NaCl solution in 10%.In HCl, NaOH and NaCl during anti-corrosion
Between be respectively>10d、>10d and>10d.
Embodiment 25
The black cream and 1,2-PD of certain mass are added in four-hole boiling flask, after black cream is completely dissolved, according to black cream
In epoxy resin to the four-hole boiling flask that the mass ratio 1: 1 of epoxy resin adds respective quality, stirred in 90 DEG C of oil bath pan
2h is mixed, temperature to 180 DEG C of stirring 1h is improved, until stand-by after viscosity is suitable.The mixture of preparation is placed in by polishing, washing
Wash, in dry tinplate sheet, quickly and evenly brushed along direction in length and breadth in tinplate sheet using spreader, the thickness of film
It is 125 μm, then iron plate is placed in the baking oven that temperature is 150 DEG C and dries 30min, after dried coating film, by 2/3 immersion of film
The change of film is seen in HCl, 30% NaOH and 30% NaCl solution in 10%.In HCl, NaOH and NaCl during anti-corrosion
Between be respectively>10d、>10d and>10d.
Embodiment 26
The black cream and 1,2-PD of certain mass are added in four-hole boiling flask, after black cream is completely dissolved, according to black cream
In epoxy resin to the four-hole boiling flask that the mass ratio 1: 2 of epoxy resin adds respective quality, stirred in 90 DEG C of oil bath pan
2h is mixed, temperature to 180 DEG C of stirring 1h is improved, until stand-by after viscosity is suitable.The mixture of preparation is placed in by polishing, washing
Wash, in dry tinplate sheet, quickly and evenly brushed along direction in length and breadth in tinplate sheet using spreader, the thickness of film
It is 125 μm, then iron plate is placed in the baking oven that temperature is 150 DEG C and dries 30min, after dried coating film, by 2/3 immersion of film
The change of film is seen in HCl, 30% NaOH and 30% NaCl solution in 10%.In HCl, NaOH and NaCl during anti-corrosion
Between be respectively>10d、>10d and>10d.
Embodiment 27
The black cream and 1,2-PD of certain mass are added in four-hole boiling flask, after black cream is completely dissolved, according to black cream
With the mass ratio 1 of epoxy resin；In 3 epoxy resin to the four-hole boiling flasks for adding respective quality, stirred in 90 DEG C of oil bath pan
2h is mixed, temperature to 180 DEG C of stirring 1h is improved, until stand-by after viscosity is suitable.The mixture of preparation is placed in by polishing, washing
Wash, in dry tinplate sheet, quickly and evenly brushed along direction in length and breadth in tinplate sheet using spreader, the thickness of film
It is 125 μm, then iron plate is placed in the baking oven that temperature is 150 DEG C and dries 30min, after dried coating film, by 2/3 immersion of film
The change of film is seen in HCl, 30% NaOH and 30% NaCl solution in 10%.In HCl, NaOH and NaCl during anti-corrosion
Between be respectively>10d、>10d and>10d.
Embodiment 28
The black cream and 1,2-PD of certain mass are added in four-hole boiling flask, after black cream is completely dissolved, according to black cream
In epoxy resin to the four-hole boiling flask that the mass ratio 1: 1 of epoxy resin adds respective quality, stirred in 90 DEG C of oil bath pan
2h is mixed, temperature to 180 DEG C of stirring 1h is improved, until stand-by after viscosity is suitable.The mixture of preparation is placed in by polishing, washing
Wash, in dry tinplate sheet, quickly and evenly brushed along direction in length and breadth in tinplate sheet using spreader, the thickness of film
It is 125 μm, then iron plate is placed in the baking oven that temperature is 150 DEG C and dries 40min, after dried coating film, by 2/3 immersion of film
The change of film is seen in HCl, 30% NaOH and 30% NaCl solution in 10%.In HCl, NaOH and NaCl during anti-corrosion
Between be respectively>10d、>10d and>10d.
Embodiment 29
The black cream and 1,2-PD of certain mass are added in four-hole boiling flask, after black cream is completely dissolved, according to black cream
In epoxy resin to the four-hole boiling flask that the mass ratio 1: 2 of epoxy resin adds respective quality, stirred in 90 DEG C of oil bath pan
2h is mixed, temperature to 180 DEG C of stirring 1h is improved, until stand-by after viscosity is suitable.The mixture of preparation is placed in by polishing, washing
Wash, in dry tinplate sheet, quickly and evenly brushed along direction in length and breadth in tinplate sheet using spreader, the thickness of film
It is 125 μm, then iron plate is placed in the baking oven that temperature is 150 DEG C and dries 40min, after dried coating film, by 2/3 immersion of film
The change of film is seen in HCl, 30% NaOH and 30% NaCl solution in 10%.In HCl, NaOH and NaCl during anti-corrosion
Between be respectively>10d、>10d and>10d.
Embodiment 30
The black cream and 1,2-PD of certain mass are added in four-hole boiling flask, after black cream is completely dissolved, according to black cream
In epoxy resin to the four-hole boiling flask that the mass ratio 1: 3 of epoxy resin adds respective quality, stirred in 50 DEG C of oil bath pan
2h is mixed, temperature to 60 DEG C of stirring 1h is improved, until stand-by after viscosity is suitable.By the mixture of preparation be placed in by polishing, washing,
In dry tinplate sheet, quickly and evenly brushed along direction in length and breadth in tinplate sheet using spreader, the thickness of film is
125 μm, then iron plate is placed in the baking oven that temperature is 150 DEG C and dries 40min, after dried coating film, the 2/3 of film is soaked in
The change of film is seen in 10% HCl, the NaCl solution of 30% NaOH and 30%.The anti-corrosion time in HCl, NaOH and NaCl
Respectively>10d、>10d and>10d.
Embodiment 31
The black cream and 1,2-PD of certain mass are added in four-hole boiling flask, after black cream is completely dissolved, according to black cream
In epoxy resin to the four-hole boiling flask that the mass ratio 1: 1 of epoxy resin adds respective quality, stirred in 90 DEG C of oil bath pan
2h is mixed, temperature to 180 DEG C of stirring 1h is improved, until stand-by after viscosity is suitable.The mixture of preparation is placed in by polishing, washing
Wash, in dry tinplate sheet, quickly and evenly brushed along direction in length and breadth in tinplate sheet using spreader, the thickness of film
It is 125 μm, then iron plate is placed in the baking oven that temperature is 150 DEG C and dries 50min, after dried coating film, by 2/3 immersion of film
The change of film is seen in HCl, 30% NaOH and 30% NaCl solution in 10%.In HCl, NaOH and NaCl during anti-corrosion
Between be respectively>10d、>10d and>10d.
Embodiment 32
The black cream and 1,2-PD of certain mass are added in four-hole boiling flask, after black cream is completely dissolved, according to black cream
In epoxy resin to the four-hole boiling flask that the mass ratio 1: 2 of epoxy resin adds respective quality, stirred in 90 DEG C of oil bath pan
2h is mixed, temperature to 180 DEG C of stirring 1h is improved, until stand-by after viscosity is suitable.The mixture of preparation is placed in by polishing, washing
Wash, in dry tinplate sheet, quickly and evenly brushed along direction in length and breadth in tinplate sheet using spreader, the thickness of film
It is 125 μm, then iron plate is placed in the baking oven that temperature is 150 DEG C and dries 50min, after dried coating film, by 2/3 immersion of film
The change of film is seen in HCl, 30% NaOH and 30% NaCl solution in 10%.In HCl, NaOH and NaCl during anti-corrosion
Between be respectively>10d、>10d and>10d.
Embodiment 33
The black cream and 1,2-PD of certain mass are added in four-hole boiling flask, after black cream is completely dissolved, according to black cream
In epoxy resin to the four-hole boiling flask that the mass ratio 1: 3 of epoxy resin adds respective quality, stirred in 90 DEG C of oil bath pan
2h is mixed, temperature to 180 DEG C of stirring 1h is improved, until stand-by after viscosity is suitable.The mixture of preparation is placed in by polishing, washing
Wash, in dry tinplate sheet, quickly and evenly brushed along direction in length and breadth in tinplate sheet using spreader, the thickness of film
It is 125 μm, then iron plate is placed in the baking oven that temperature is 150 DEG C and dries 50min, after dried coating film, by 2/3 immersion of film
The change of film is seen in HCl, 30% NaOH and 30% NaCl solution in 10%.In HCl, NaOH and NaCl during anti-corrosion
Between be respectively>10d、>10d and>10d.
Embodiment 34
The black cream and 1,2-PD of certain mass are added in four-hole boiling flask, after black cream is completely dissolved, according to black cream
In epoxy resin to the four-hole boiling flask that the mass ratio 1: 1 of epoxy resin adds respective quality, stirred in 90 DEG C of oil bath pan
2h is mixed, temperature to 180 DEG C of stirring 1h is improved, until stand-by after viscosity is suitable.The mixture of preparation is placed in by polishing, washing
Wash, in dry tinplate sheet, quickly and evenly brushed along direction in length and breadth in tinplate sheet using spreader, the thickness of film
It is 125 μm, then iron plate is placed in the baking oven that temperature is 150 DEG C and dries 60min, after dried coating film, by 2/3 immersion of film
The change of film is seen in HCl, 30% NaOH and 30% NaCl solution in 10%.In HCl, NaOH and NaCl during anti-corrosion
Between be respectively>10d、>10d and>10d.
Embodiment 35
The black cream and 1,2-PD of certain mass are added in four-hole boiling flask, after black cream is completely dissolved, according to black cream
In epoxy resin to the four-hole boiling flask that the mass ratio 1: 2 of epoxy resin adds respective quality, stirred in 90 DEG C of oil bath pan
2h is mixed, temperature to 180 DEG C of stirring 1h is improved, until stand-by after viscosity is suitable.The mixture of preparation is placed in by polishing, washing
Wash, in dry tinplate sheet, quickly and evenly brushed along direction in length and breadth in tinplate sheet using spreader, the thickness of film
It is 125 μm, then iron plate is placed in the baking oven that temperature is 150 DEG C and dries 60min, after dried coating film, by 2/3 immersion of film
The change of film is seen in HCl, 30% NaOH and 30% NaCl solution in 10%.In HCl, NaOH and NaCl during anti-corrosion
Between be respectively>10d、>10d and>10d.
Embodiment 36
The black cream and 1,2-PD of certain mass are added in four-hole boiling flask, after black cream is completely dissolved, according to black cream
In epoxy resin to the four-hole boiling flask that the mass ratio 1: 3 of epoxy resin adds respective quality, stirred in 90 DEG C of oil bath pan
2h is mixed, temperature to 180 DEG C of stirring 1h is improved, until stand-by after viscosity is suitable.The mixture of preparation is placed in by polishing, washing
Wash, in dry tinplate sheet, quickly and evenly brushed along direction in length and breadth in tinplate sheet using spreader, the thickness of film
It is 125 μm, then iron plate is placed in the baking oven that temperature is 150 DEG C and dries 60min, after dried coating film, by 2/3 immersion of film
The change of film is seen in HCl, 30% NaOH and 30% NaCl solution in 10%.In HCl, NaOH and NaCl during anti-corrosion
Between be respectively>10d、>10d and>10d.
Claims (6)
1. the black paste for being produced in vitamin B6 industrial processes is in anticorrosive paint as the application of curing agent.
2. application according to claim 1, it is characterised in that：The black cream that will be produced in vitamin B6 industrial processes
Shape thing is applied to metal surface with epoxy resin reaction product, drying and forming-film is solidified at a certain temperature and intercepts chemical reagent
To reach corrosion-resistant purpose.
3. application according to claim 2, it is characterised in that：Solidification temperature is 120~150 DEG C.
4. application according to claim 3, it is characterised in that：Hardening time is 30~60min.
5. application according to claim 2, it is characterised in that：Produced in the added vitamin B6 industrial processes of reaction
Raw black paste is 3 with epoxy resin mass ratio:1~1:3.
6. application according to claim 5, it is characterised in that：The black paste produced in vitamin B6 industrial processes
Thing is first to heat 0.5-5h at 50-90 DEG C with epoxy resin reaction temperature, improves temperature to 60-200 DEG C of heating 0.5-3h.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611248444.2A CN106832223B (en) | 2016-12-29 | 2016-12-29 | The black paste generated in vitamin B6 industrial processes is in anticorrosive paint as the application of curing agent |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611248444.2A CN106832223B (en) | 2016-12-29 | 2016-12-29 | The black paste generated in vitamin B6 industrial processes is in anticorrosive paint as the application of curing agent |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN106832223A true CN106832223A (en) | 2017-06-13 |
| CN106832223B CN106832223B (en) | 2018-11-06 |
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| CN201611248444.2A Expired - Fee Related CN106832223B (en) | 2016-12-29 | 2016-12-29 | The black paste generated in vitamin B6 industrial processes is in anticorrosive paint as the application of curing agent |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108795229A (en) * | 2018-05-15 | 2018-11-13 | 武汉工程大学 | Vitamin B6 industrial production solid waste resource utilization method |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103833180A (en) * | 2013-11-19 | 2014-06-04 | 华中药业股份有限公司 | Method for treating waste water obtained during synthesis of vitamin B6 through oxazole method |
| CN106220844A (en) * | 2016-07-26 | 2016-12-14 | 湖北绿色家园精细化工股份有限公司 | A kind of low cost, the polyamide-based epoxy curing agent of environment-friendly type |
-
2016
- 2016-12-29 CN CN201611248444.2A patent/CN106832223B/en not_active Expired - Fee Related
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103833180A (en) * | 2013-11-19 | 2014-06-04 | 华中药业股份有限公司 | Method for treating waste water obtained during synthesis of vitamin B6 through oxazole method |
| CN106220844A (en) * | 2016-07-26 | 2016-12-14 | 湖北绿色家园精细化工股份有限公司 | A kind of low cost, the polyamide-based epoxy curing agent of environment-friendly type |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108795229A (en) * | 2018-05-15 | 2018-11-13 | 武汉工程大学 | Vitamin B6 industrial production solid waste resource utilization method |
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| CN106832223B (en) | 2018-11-06 |
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