CN106831440A - The preparation method of the ferrisodium of ethylenediamine two - Google Patents
The preparation method of the ferrisodium of ethylenediamine two Download PDFInfo
- Publication number
- CN106831440A CN106831440A CN201710041663.1A CN201710041663A CN106831440A CN 106831440 A CN106831440 A CN 106831440A CN 201710041663 A CN201710041663 A CN 201710041663A CN 106831440 A CN106831440 A CN 106831440A
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- China
- Prior art keywords
- ethylenediamine
- ferrisodium
- preparation
- naoh
- metacresol
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05C—NITROGENOUS FERTILISERS
- C05C11/00—Other nitrogenous fertilisers
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C211/00—Compounds containing amino groups bound to a carbon skeleton
- C07C211/01—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to acyclic carbon atoms
- C07C211/02—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to acyclic carbon atoms of an acyclic saturated carbon skeleton
- C07C211/09—Diamines
- C07C211/10—Diaminoethanes
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
The invention discloses a kind of preparation method of the ferrisodium of ethylenediamine two, comprise the following steps：（1）To 5 ~ 6 times of water of weight are added in NaOH, stirring dissolves NaOH, obtains solution I；（2）To metacresol, glyoxalic acid, ethylenediamine and ferric nitrate is sequentially added in solution I, 2 ~ 3h is reacted under conditions of 60 ~ 65 DEG C, dry to obtain the ferrisodium of ethylenediamine two.
Description
Technical field
The invention belongs to chemical industry synthesis field, and in particular to a kind of preparation method of the ferrisodium of ethylenediamine two.
Background technology
Ferro element plays the role of important in growing process, and during iron deficiency, plant tender tip blade is thinning, leaf is small, mesophyll
Jaundice, when serious, leaf abscission influences crop yield.In nature, the ferro element for largely existing, but deposited with oxide
Water insoluble, it is impossible to be absorbed by plants, not only yield is low for the existing technique for preparing the ferrisodium of ethylenediamine two, and purity is low, is produced into
This height, while being also unfavorable for plant absorption.
The content of the invention
For above-mentioned deficiency of the prior art, the present invention provides a kind of preparation method of the ferrisodium of ethylenediamine two, using this
The method of invention, can obtain high-purity and the ferrisodium of ethylenediamine in high yield two.
To solve above-mentioned technical problem, the technical solution adopted by the present invention is
A kind of preparation method of the ferrisodium of ethylenediamine two, comprises the following steps：
（1）To 5 ~ 6 times of water of weight are added in NaOH, stirring dissolves NaOH, obtains solution I；
（2）To metacresol, glyoxalic acid, ethylenediamine and ferric nitrate is sequentially added in solution I, 2 are reacted under conditions of 60 ~ 65 DEG C
~ 3h, dries to obtain the ferrisodium of ethylenediamine two.
Further, the weight ratio of water, metacresol, NaOH, glyoxalic acid, ethylenediamine and ferric nitrate is 5 ~ 6:1~2.5:
1~2:1~2.5:1~1.5:1~2。
Further, the weight ratio of water, metacresol, NaOH, glyoxalic acid, ethylenediamine and ferric nitrate is 6:1.95:
1.07:2:1.05:0.33。
The ferrisodium of ethylenediamine two that above-mentioned preparation method is prepared.
Beneficial effects of the present invention are：
This product belongs to chelating amino acids agent, and its applicable pH value range is wide, and in pH value is for 3 ~ 10 soil, absorptivity is high, in state
It is interior mainly to apply to prevent and treat the yellows that plant iron deficiency is caused；Can also be used for normal plants and mend iron, plant growth can be made more vigorous,
Increase yield and improve fruit quality.
The present invention, as solvent, can be prevented effectively from and produce pollution to environment using water, be reclaimed without to solvent, be dropped
Low production cost.
Specific embodiment
Specific embodiment of the invention is described below, this hair is understood in order to those skilled in the art
It is bright, it should be apparent that the invention is not restricted to the scope of specific embodiment, for those skilled in the art,
As long as in appended claim restriction and the spirit and scope of the present invention for determining, these changes are aobvious and easy to various change
See, all are using the innovation and creation of present inventive concept in the row of protection.
Embodiment 1
A kind of preparation method of the ferrisodium of ethylenediamine two, comprises the following steps：
（1）To 6 times of water of weight are added in NaOH, stirring dissolves NaOH, obtains solution I；
（2）To metacresol, glyoxalic acid, ethylenediamine and ferric nitrate is sequentially added in solution I, 2h is reacted under conditions of 60 DEG C,
Dry to obtain the ferrisodium of ethylenediamine two；Wherein, the weight ratio of water, metacresol, NaOH, glyoxalic acid, ethylenediamine and ferric nitrate is 6:
2.5:2:2.5:1.5:2。
Embodiment 2
A kind of preparation method of the ferrisodium of ethylenediamine two, comprises the following steps：
（1）To 6 times of water of weight are added in NaOH, stirring dissolves NaOH, obtains solution I；
（2）To metacresol, glyoxalic acid, ethylenediamine and ferric nitrate is sequentially added in solution I, reacted under conditions of 65 DEG C
2.5h, dries to obtain the ferrisodium of ethylenediamine two；Wherein, the weight ratio of water, metacresol, NaOH, glyoxalic acid, ethylenediamine and ferric nitrate
It is 6:1.95:1.07:2:1.05:0.33.
Embodiment 3
A kind of preparation method of the ferrisodium of ethylenediamine two, comprises the following steps：
（1）To 5 times of water of weight are added in NaOH, stirring dissolves NaOH, obtains solution I；
（2）To metacresol, glyoxalic acid, ethylenediamine and ferric nitrate is sequentially added in solution I, 3h is reacted under conditions of 62 DEG C,
Dry to obtain the ferrisodium of ethylenediamine two；Wherein, the weight ratio of water, metacresol, NaOH, glyoxalic acid, ethylenediamine and ferric nitrate is 5:
1:1:1:1:1。
Claims (4)
1. the preparation method of the ferrisodium of a kind of ethylenediamine two, it is characterised in that comprise the following steps：
（1）To 5 ~ 6 times of water of weight are added in NaOH, stirring dissolves NaOH, obtains solution I；
（2）To metacresol, glyoxalic acid, ethylenediamine and ferric nitrate is sequentially added in solution I, 2 are reacted under conditions of 60 ~ 65 DEG C
~ 3h, dries to obtain the ferrisodium of ethylenediamine two.
2. the preparation method of the ferrisodium of ethylenediamine according to claim 1 two, it is characterised in that the water, metacresol, hydrogen-oxygen
The weight ratio for changing sodium, glyoxalic acid, ethylenediamine and ferric nitrate is 5 ~ 6:1~2.5:1~2:1~2.5:1~1.5:1~2.
3. the preparation method of the ferrisodium of ethylenediamine according to claim 2 two, it is characterised in that the water, metacresol, hydrogen-oxygen
The weight ratio for changing sodium, glyoxalic acid, ethylenediamine and ferric nitrate is 6:1.95:1.07:2:1.05:0.33.
4. the ferrisodium of ethylenediamine two that the preparation method described in any one of claim 1 ~ 3 is prepared.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710041663.1A CN106831440A (en) | 2017-01-20 | 2017-01-20 | The preparation method of the ferrisodium of ethylenediamine two |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710041663.1A CN106831440A (en) | 2017-01-20 | 2017-01-20 | The preparation method of the ferrisodium of ethylenediamine two |
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| CN106831440A true CN106831440A (en) | 2017-06-13 |
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| CN201710041663.1A Pending CN106831440A (en) | 2017-01-20 | 2017-01-20 | The preparation method of the ferrisodium of ethylenediamine two |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109651180A (en) * | 2019-01-22 | 2019-04-19 | 北京海德恒生科技发展有限公司 | A kind of production method of sodium iron ethylene diamine tetra acetate |
Citations (9)
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| US4130582A (en) * | 1977-04-19 | 1978-12-19 | Ciba-Geigy Corporation | Preparation of phenolic ethylenediaminepolycarboxylic acids |
| US4647447A (en) * | 1981-07-24 | 1987-03-03 | Schering Aktiengesellschaft | Diagnostic media |
| RO91667A2 (en) * | 1985-02-21 | 1987-05-15 | Centrul De Chimie,Ro | PROCESS FOR OBTAINING SODIUM SALT AND IRON ETHYLENDIAMINOTETRAACETIC ACID |
| US5177105A (en) * | 1989-05-22 | 1993-01-05 | Alcon Laboratories, Inc. | Methods for controlling intraocular pressure with transition metal complexes |
| CN1426998A (en) * | 2001-12-19 | 2003-07-02 | 钟林 | Production method of EDTA complex metal salt |
| CN1431193A (en) * | 2002-01-10 | 2003-07-23 | 钟林 | Method for producing complexation metal salt of ethylenediamine tetra acetic acid |
| CN102746050A (en) * | 2012-07-30 | 2012-10-24 | 河南农业大学 | Special fertilizer for float seedling raising of tobacco |
| CN103554028A (en) * | 2013-09-23 | 2014-02-05 | 北京石油化工学院 | Alkylimidazole ethylenediaminetetraacetic acid iron (III) water-soluble ionic liquid and synthetic method thereof |
| CN103880692A (en) * | 2014-02-24 | 2014-06-25 | 南通励成生物工程有限公司 | Production method of irony food nutritive fortifier sodium iron ethylenediamine tetraacetate |
-
2017
- 2017-01-20 CN CN201710041663.1A patent/CN106831440A/en active Pending
Patent Citations (9)
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|---|---|---|---|---|
| US4130582A (en) * | 1977-04-19 | 1978-12-19 | Ciba-Geigy Corporation | Preparation of phenolic ethylenediaminepolycarboxylic acids |
| US4647447A (en) * | 1981-07-24 | 1987-03-03 | Schering Aktiengesellschaft | Diagnostic media |
| RO91667A2 (en) * | 1985-02-21 | 1987-05-15 | Centrul De Chimie,Ro | PROCESS FOR OBTAINING SODIUM SALT AND IRON ETHYLENDIAMINOTETRAACETIC ACID |
| US5177105A (en) * | 1989-05-22 | 1993-01-05 | Alcon Laboratories, Inc. | Methods for controlling intraocular pressure with transition metal complexes |
| CN1426998A (en) * | 2001-12-19 | 2003-07-02 | 钟林 | Production method of EDTA complex metal salt |
| CN1431193A (en) * | 2002-01-10 | 2003-07-23 | 钟林 | Method for producing complexation metal salt of ethylenediamine tetra acetic acid |
| CN102746050A (en) * | 2012-07-30 | 2012-10-24 | 河南农业大学 | Special fertilizer for float seedling raising of tobacco |
| CN103554028A (en) * | 2013-09-23 | 2014-02-05 | 北京石油化工学院 | Alkylimidazole ethylenediaminetetraacetic acid iron (III) water-soluble ionic liquid and synthetic method thereof |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109651180A (en) * | 2019-01-22 | 2019-04-19 | 北京海德恒生科技发展有限公司 | A kind of production method of sodium iron ethylene diamine tetra acetate |
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Effective date of registration: 20181019 Address after: 642150 Sichuan Neijiang Industrial Park, Longchang slope Industrial Zone. Applicant after: Longchang one Bio Technology Co., Ltd. Address before: 642153 Gao Hua Bridge, Guihua Jing Town, Longchang, Neijiang, Sichuan Applicant before: Sichuan Long Qiao Chemical Group Co., Ltd |
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