CN106830857B - Can anti-sulfur dioxide corrosion canvas concrete and preparation method thereof - Google Patents

Can anti-sulfur dioxide corrosion canvas concrete and preparation method thereof Download PDF

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Publication number
CN106830857B
CN106830857B CN201710090236.2A CN201710090236A CN106830857B CN 106830857 B CN106830857 B CN 106830857B CN 201710090236 A CN201710090236 A CN 201710090236A CN 106830857 B CN106830857 B CN 106830857B
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China
Prior art keywords
concrete
canvas
screen cloth
preparation
cement
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CN201710090236.2A
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Chinese (zh)
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CN106830857A (en
Inventor
牛建刚
王潇鹏
胡伟勋
刘晓
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Inner Mongolia University of Science and Technology
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Inner Mongolia University of Science and Technology
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/02Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
    • C04B28/06Aluminous cements
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B28WORKING CEMENT, CLAY, OR STONE
    • B28BSHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
    • B28B1/00Producing shaped prefabricated articles from the material
    • B28B1/04Producing shaped prefabricated articles from the material by tamping or ramming
    • B28B1/045Producing shaped prefabricated articles from the material by tamping or ramming combined with vibrating or jolting
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B28WORKING CEMENT, CLAY, OR STONE
    • B28BSHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
    • B28B11/00Apparatus or processes for treating or working the shaped or preshaped articles
    • B28B11/24Apparatus or processes for treating or working the shaped or preshaped articles for curing, setting or hardening
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B28WORKING CEMENT, CLAY, OR STONE
    • B28BSHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
    • B28B13/00Feeding the unshaped material to moulds or apparatus for producing shaped articles; Discharging shaped articles from such moulds or apparatus
    • B28B13/02Feeding the unshaped material to moulds or apparatus for producing shaped articles
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B16/00Use of organic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of organic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B16/04Macromolecular compounds
    • C04B16/06Macromolecular compounds fibrous
    • C04B16/0675Macromolecular compounds fibrous from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C04B16/0683Polyesters, e.g. polylactides
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/20Resistance against chemical, physical or biological attack
    • C04B2111/2015Sulfate resistance
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/20Resistance against chemical, physical or biological attack
    • C04B2111/23Acid resistance, e.g. against acid air or rain

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Structural Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Manufacturing & Machinery (AREA)
  • Inorganic Chemistry (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)

Abstract

The present invention relates to it is a kind of can anti-sulfur dioxide corrosion canvas concrete and preparation method thereof.Above-mentioned canvas concrete includes: 3D screen cloth, and the cement being filled between the gap of the 3D screen cloth.Aluminium sulfate canvas coagulation earth removal provided by the invention has outside good mechanical property, also has good corrosion resistance.Preparation method is to pour into cement powder in 3D screen cloth, and scene is mated formation when in use, hardened forming of then sprinkling water.It eliminates the process of stirring and maintenance compared with normal concrete, can be used in engineering faster.Its advantage is that facilitating storage, transport, easy for construction, the time is saved.

Description

Can anti-sulfur dioxide corrosion canvas concrete and preparation method thereof
Technical field
The present invention relates to concrete material technical field, in particular to it is a kind of can anti-sulfur dioxide corrosion canvas concrete And preparation method thereof.
Background technique
Concrete structure, which is chronically in the corrosive environments such as acid, salt, to be destroyed and influence its normal use.At present It is mainly to use encased steel plate for the measure that concrete structure is protected, stickup fibrous composite, external prestressing steels, Enlarged cross section product is reinforced, and damage concrete is repaired in the measures such as displacement concrete strengthening.These measures are substantially from changing Start in terms of becoming concrete structure, at high cost, engineering difficulty is big, and the construction time is long.There is no in the resistance to of concrete for these measures It is played a role in terms of long property, being applied in industrial environment can not play the role of enhancing well concrete to erosion-resisting.
Existing guard technology is mainly in concrete surface brush coating, though coating can effectively improve concrete structure Anti-corrosion ability, but there is no mature building trade standard and detecting appraisal method at present.
Summary of the invention
In view of this, the present invention provide it is a kind of can anti-sulfur dioxide corrosion canvas concrete and preparation method thereof.
Firstly, the present invention provide it is a kind of can anti-sulfur dioxide corrosion canvas concrete comprising: 3D screen cloth, and filling out Fill the cement between the gap in the 3D screen cloth.
Further, the cement uses sulphate aluminium cement.
Correspondingly, the present invention also provides it is a kind of can anti-sulfur dioxide corrosion canvas concrete preparation method comprising:
Step a, cement powder is poured into 3D screen cloth, and is consolidated with concrete vibrator, with to be used;
Step b, it in use, the canvas concrete that step a makes is routed on desired position, then directly sprinkles water Preparation can be completed in hardening.
Further, it sprinkles water in the step b process of hardening specifically: sprinkle water to canvas concrete, until canvas is carried on the back Face is soaked, and until not extra moisture outflow.
Aluminium sulfate canvas coagulation earth removal provided by the invention has outside good mechanical property, also has good corrosion resistant Corrosion.Preparation method is to pour into cement powder in 3D screen cloth, and scene is mated formation when in use, hardened forming of then sprinkling water.Its with Normal concrete is compared, and the process of stirring and maintenance is eliminated, and can be used in engineering faster.Its advantage is that facilitate storage, It transports, is easy for construction, saving the time.
Specific embodiment
The invention discloses it is a kind of can anti-sulfur dioxide corrosion canvas concrete and preparation method thereof.Those skilled in the art Member can use for reference present disclosure, be suitably modified realization of process parameters.In particular, it should be pointed out that all similar substitutions and modifications Apparent to those skilled in the art, they are considered as being included in the present invention.Method and application of the invention Be described by preferred embodiment, related personnel obviously can not depart from the content of present invention, in spirit and scope it is right Method described herein and application are modified or appropriate changes and combinations, carry out implementation and application the technology of the present invention.
The present invention provide it is a kind of can anti-sulfur dioxide corrosion canvas concrete.Concrete canvas (Concrete Canvas it) is used as a kind of new material, belongs to fabric reinforced cement composite.The research in relation to CC both at home and abroad is main at present It concentrates on preparing tent using CC, becomes a kind of provisional building, in military defense project and earthquake relief work.Using CC as one Kind protective materials is used for industry SO2Research in environment is also very rare.The material of concrete canvas is usually (to be washed by polyester fiber Synthetic fibre) it is made, fiber itself has certain acid resistance, therefore concrete canvas is used for industry SO as a kind of outsourcing material2Ring The erosion of sour gas internally structure can be slowed down on concrete structure in border, guarantee that building can reach design requirement Service life.
It is provided by the invention can the canvas concrete of anti-sulfur dioxide corrosion include: 3D screen cloth, and be filled in the 3D Cement between the gap of screen cloth.
The 3D screen cloth is commonly called as special thick sandwich eyelet fabric, also referred to as 3D material or 3D space fabric, it belongs to through needle Fine work inside woven fabric is disposably woven using Polymer Synthesizing fiber by accurate board, has the double-deck mesh design, in Between monofilament with X-90 ° of vertical array, so that it is had breathable moisture permeability, keep its durable.
Preferably, the cement uses sulphate aluminium cement.
It is provided by the invention it is above-mentioned can anti-sulfur dioxide corrosion canvas concrete, in addition to good mechanical property, Also there is good corrosion resistance, be suitable for the application of in concrete structure.
Correspondingly, the present invention also provides it is a kind of can anti-sulfur dioxide corrosion canvas concrete preparation method comprising:
Step a, cement powder is poured into 3D screen cloth, and is consolidated with concrete vibrator, with to be used;
Step b, it in use, the canvas concrete that step a makes is routed on desired position, then directly sprinkles water Preparation can be completed in hardening.
Further, it sprinkles water in the step b process of hardening specifically: sprinkle water to canvas concrete, until canvas is carried on the back Face is soaked, and until not extra moisture outflow.
In above-mentioned preparation method, in the preparation, cement powder is poured into 3D screen cloth, scene is mated formation when in use, is then spilt Water hardening molding.It eliminates the process of stirring and maintenance compared with normal concrete, can be used in engineering faster.Its Advantage is to facilitate storage, transport, easy for construction, saves the time.
Below with reference to embodiment, the present invention is further explained:
Embodiment
3D screen cloth and cement are selected in the preparation of test specimen in test.The wherein selection sulphate aluminium cement of cement, performance is such as Shown in table 1.3D screen cloth is cut into 200mm × 300mm rectangle before test specimen production, then cement powder is circulated into 3D screen cloth, most It sprinkles water afterwards to concrete canvas test specimen, until the canvas back side is soaked, until not extra moisture outflow.To in canvas concrete The abundant aquation of cement powder after, test block is put into natural environment and is conserved.
1 sulphate aluminium cement performance indicator of table
Vulcanization test is referring to " normal concrete chronicity and durability test method standard " (GB/T 50082-2009) In requirement about carbon dioxide to concrete carbonization part carry out vulcanization test.The concentration of SO2 is set as when vulcanization 1000ppm, temperature are 25 DEG C ± 1 DEG C, and humidity is 80% ± 1%.Condition carry out vulcanization test.Vulcanization front and back aluminium sulfate sail Every experimental performance index variation of cloth concrete is as shown in table 2.
Each experimental performance variation in 2 aluminium sulfate canvas concrete of table vulcanization front and back
It can be seen that aluminium sulfate canvas coagulation earth removal provided by the invention with good power by the data in table 2 It learns outside performance, also there is good corrosion resistance.
The above is only a preferred embodiment of the present invention, it is noted that for the ordinary skill people of the art For member, various improvements and modifications may be made without departing from the principle of the present invention, these improvements and modifications are also answered It is considered as protection scope of the present invention.

Claims (1)

1. one kind can anti-sulfur dioxide corrosion canvas concrete characterized by comprising 3D screen cloth, and being filled in described Cement between the gap of 3D screen cloth;Wherein, the 3D screen cloth is disposably woven using Polymer Synthesizing fiber by accurate board It forms, there is the double-deck mesh design, intermediate monofilament is with X-90 ° of vertical array;The cement uses sulphate aluminium cement;
It is described can the preparation method of canvas concrete of anti-sulfur dioxide corrosion include:
Step a, cement powder is poured into 3D screen cloth, and is consolidated with concrete vibrator, with to be used;
Step b, in use, the canvas concrete that step a makes is routed on desired position, then directly watering hardening Preparation can be completed;
It wherein sprinkles water in the step b process of hardening specifically: it sprinkles water to canvas concrete, until the canvas back side is soaked, and Until there is no extra moisture outflow.
CN201710090236.2A 2017-02-20 2017-02-20 Can anti-sulfur dioxide corrosion canvas concrete and preparation method thereof Active CN106830857B (en)

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Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108569883B (en) * 2018-05-28 2021-05-18 东南大学 Cement matrix for concrete canvas system
CN111943610B (en) * 2020-07-29 2022-01-11 黑龙江琪正高新材料科技有限公司 Flexible cuttable fast-curing cement blanket cloth and preparation method thereof

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JPS61232255A (en) * 1985-04-08 1986-10-16 株式会社 オカニシ Concrete for cloth mold frame
GB2455008A (en) * 2006-06-12 2009-06-03 Concrete Canvas Ltd Impregnated fabric
BRPI0804420A2 (en) * 2008-10-15 2010-07-13 Dos Santos Valdeci Alves D cement-based liquid acrylic blanket
WO2010086618A8 (en) * 2009-01-29 2011-08-11 Concrete Canvas Technology Ltd. Impregnated cloth
CN202359681U (en) * 2011-09-15 2012-08-01 江苏尼高科技有限公司 Three-dimensional fiberglass mesh and foam cement composite board, and external thermal insulation system
CN102926502A (en) * 2012-11-01 2013-02-13 中国人民解放军总后勤部建筑工程研究所 Three-dimensional spacer fabric reinforced cement based composite material and preparation method and construction method thereof
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CN106013591A (en) * 2016-05-20 2016-10-12 东南大学 FRP (Fiber Reinforced Plastic)-three-dimensional space fabric reinforced cement-based composite material cloth and making method thereof

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JPS61232255A (en) * 1985-04-08 1986-10-16 株式会社 オカニシ Concrete for cloth mold frame
GB2455008A (en) * 2006-06-12 2009-06-03 Concrete Canvas Ltd Impregnated fabric
BRPI0804420A2 (en) * 2008-10-15 2010-07-13 Dos Santos Valdeci Alves D cement-based liquid acrylic blanket
WO2010086618A8 (en) * 2009-01-29 2011-08-11 Concrete Canvas Technology Ltd. Impregnated cloth
CN202359681U (en) * 2011-09-15 2012-08-01 江苏尼高科技有限公司 Three-dimensional fiberglass mesh and foam cement composite board, and external thermal insulation system
CN102926502A (en) * 2012-11-01 2013-02-13 中国人民解放军总后勤部建筑工程研究所 Three-dimensional spacer fabric reinforced cement based composite material and preparation method and construction method thereof
CN103360027A (en) * 2013-07-24 2013-10-23 东南大学 Quick-setting and rapid-hardening cement matrix for concrete canvas system and use method there of
CN106013591A (en) * 2016-05-20 2016-10-12 东南大学 FRP (Fiber Reinforced Plastic)-three-dimensional space fabric reinforced cement-based composite material cloth and making method thereof

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