CN106830801A - A kind of preparation method of high intensity split tile and its application in composite thermal-insulating wall - Google Patents

A kind of preparation method of high intensity split tile and its application in composite thermal-insulating wall Download PDF

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Publication number
CN106830801A
CN106830801A CN201710087928.1A CN201710087928A CN106830801A CN 106830801 A CN106830801 A CN 106830801A CN 201710087928 A CN201710087928 A CN 201710087928A CN 106830801 A CN106830801 A CN 106830801A
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pug
split tile
base substrate
split
weight portions
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CN106830801B (en
Inventor
李少杰
赵舰
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Binzhou Shenghua Building Materials Co Ltd
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Binzhou Shenghua Building Materials Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B28WORKING CEMENT, CLAY, OR STONE
    • B28BSHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
    • B28B11/00Apparatus or processes for treating or working the shaped or preshaped articles
    • B28B11/24Apparatus or processes for treating or working the shaped or preshaped articles for curing, setting or hardening
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B28WORKING CEMENT, CLAY, OR STONE
    • B28BSHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
    • B28B3/00Producing shaped articles from the material by using presses; Presses specially adapted therefor
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B40/00Processes, in general, for influencing or modifying the properties of mortars, concrete or artificial stone compositions, e.g. their setting or hardening ability
    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04FFINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
    • E04F13/00Coverings or linings, e.g. for walls or ceilings
    • E04F13/07Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor
    • E04F13/08Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of a plurality of similar covering or lining elements
    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04FFINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
    • E04F15/00Flooring
    • E04F15/02Flooring or floor layers composed of a number of similar elements
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2201/00Mortars, concrete or artificial stone characterised by specific physical values
    • C04B2201/30Mortars, concrete or artificial stone characterised by specific physical values for heat transfer properties such as thermal insulation values, e.g. R-values
    • C04B2201/32Mortars, concrete or artificial stone characterised by specific physical values for heat transfer properties such as thermal insulation values, e.g. R-values for the thermal conductivity, e.g. K-factors
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2201/00Mortars, concrete or artificial stone characterised by specific physical values
    • C04B2201/50Mortars, concrete or artificial stone characterised by specific physical values for the mechanical strength

Abstract

A kind of preparation method the present invention relates to high intensity split tile and its application in composite thermal-insulating wall, belong to building material manufacture field.For the technical deficiency for overcoming the hardness and heat-insulating property of split brick in the prior art not good, a kind of preparation method of high intensity split tile of the present invention and its application in composite thermal-insulating wall, by controlling active component and firing temperature gradient heating in split tile pug so that the heat-insulating property and compression strength of the split tile fired are obviously improved in the preparation technology, it is adapted in building trade popularization and application.

Description

A kind of preparation method of high intensity split tile and its application in composite thermal-insulating wall
Technical field
A kind of preparation method the present invention relates to high intensity split tile and its application in composite thermal-insulating wall, belong to and build Build material manufacture field.
Background technology
Split tile also known as Splitting Tile or split brick, are a kind of for inner-outer wall or the building decorating glazed tile of ground decoration, are Back-to-back two-layer is made in shaping, it is split from centre after burning till is left into two pieces and is used.It is with feldspar, quartz, kaolinite The ceramic raw materials such as soil are made the wet blank with preferable plasticity after being pulverized and mixed through dry or wet, use vacuum screw extruder The two-sided hollow adobe being connected with flat thin rib is squeezed into, then it is cleaved, dry and then burnt till under 1100 DEG C of high temperature above, It is split into 2 along the weak connecting portion of rib in either manually or mechanically method again.Split tile have it is red, reddish brown, orange red, yellow, The multiple color of deep yellow, coffee, greyish white, black, golden, rice, ash etc. ten.Color does not take off constant, surface not glazing, without reflection string light, And wearability is good.
Split tile is divided into two kinds of lugless brick and rustic brick by the degree of roughness on surface, and the particle in the former blank is thinner, produces Product surface is more smooth and exquisiteness, and the latter's blank particle is thicker, and product surface has prominent particle and pit.Dividing by purposes can It is divided into two kinds of walltile and floor tile.Dividing by surface configuration can be divided into plane brick and special form brick etc..At present, American-European countries split from Brick production capacity is very strong, and the place using split tile is also a lot, and majority is used for residential housing, garden, square, racecourse, trip The stadiums facility such as swimming pool, and airport, harbour etc. are architectural.The current split tile production capacity of China is also relatively low, Shang Yuan The big industry as polished bricks, color glazed brick is not formed.
Split tile at present main deficiency be brick hardness it is poor, simply the life-span of its product in actual use and The rugged performance built a wall is unsatisfactory, and the heat-insulating property of its product can not make one satisfied in addition, how solve its resistance to compression Hardness and heat-insulating property turn into the key factor of influence split tile application.
The content of the invention
For the technical deficiency for overcoming the hardness and heat-insulating property of split brick in the prior art not good, the present invention is a kind of high-strength Spend the preparation method of split tile and its application in composite thermal-insulating wall, in the preparation technology by controlling split tile pug in Active component and firing temperature gradient heating cause fire split tile heat-insulating property and compression strength be obviously improved, It is adapted in building trade popularization and application.
The present invention is achieved through the following technical solutions above-mentioned technique effect:
A kind of preparation method of high intensity split tile, it comprises the steps:
1)Weigh the slag of 25-35 weight portions, the stone of 25-35 weight portions, the flyash of 15-25 weight portions, 10-20 weight portions Cement and 4-6 weight portions the good abundant mixing of ground granulated blast furnace slag plasticity as split tile base substrate manufacture material, The running water for being added thereto to split tile base substrate manufacture material 0.5-2 times of quality of quality is carried out and mud, to adding soil in pug The silica of quality 0.2%-0.4%, the alumina silicate of soil quality 0.05%-0.1%, the magnesium nitride of soil quality 0.8%-1.2%, 2- { 5- [3- (4 '-methyl) phenyl -4- amino-(1,2,4) triazole] } thio-N- (2 '-furans of soil quality 0.4%-0.6% Mutter) methine acethydrazide, stir, obtain split tile pug;
2)Split tile pug is placed in carries out old 24h-36h in room temperature environment, old period is once turned over mud every 3h;It is old Mechanical pugging 2-3 times is carried out after the completion of corruption, the bubble in pug is driven out of;Pug after pugging is carried out 5 DEG C -10 DEG C of environment In carry out it is secondary old, every 2h detect pug water content, be delivered to when water content in pug is down to 15%-18% and be extruded into Type machine;
3)Control the ejection speed of extrusion shaping machine for 20-24 blocks/point prepared split tile base substrate, base substrate is placed in 20 DEG C -24 DEG C Load after standing 18h in environment and suppressed in pressboard, to the pressure for applying 1200t-1400t on split tile base substrate, compacting Time is 15-25 seconds, the split tile base substrate suppressed in completing is placed in steam-cured stove and is conserved, and controls steam-cured in-furnace temperature to exist Normal temperature is naturally cooled between 180-220 DEG C, after continuous maintenance 7-11h can obtain high intensity split tile.
The present invention is also claimed the high intensity split tile for preparing according to the method described above.
The present invention is also claimed application of the above-mentioned high intensity split tile in composite thermal-insulating wall.
The preparation method of high intensity split tile of the present invention is compared with prior art:
1)Several functions component is added in base substrate in described preparation method so that preparation-obtained high intensity split tile Heat-insulating property and the more existing split tile of compression strength have the lifting of conspicuousness.
2)Temperature, the secondary technique such as old so that preparation-obtained are controlled using segmented in described preparation technology Split tile is smooth, and outward appearance preferably, is highly suitable for preparing composite thermal-insulating wall.
Specific embodiment
The present invention further describes the present invention by following embodiments, but the embodiment is limited specially never in any form The scope of profit protection.
Embodiment 1
A kind of preparation method of high intensity split tile, it comprises the steps:
1)Weigh the slag of 25 weight portions, the stone of 25 weight portions, the flyash of 15 weight portions, the cement of 10 weight portions and 4 The good abundant mixing of the ground granulated blast furnace slag plasticity of weight portion as split tile base substrate manufacture material, be added thereto to split from Adobe body manufacture material 0.5 times of running water of quality of quality is carried out and mud, to the titanium dioxide that soil quality 0.2% is added in pug Silicon, the alumina silicate of soil quality 0.05%, the magnesium nitride of soil quality 0.8%, the 2- { 5- [3- (4 '-methyl) of soil quality 0.4% Phenyl -4- amino-(1,2,4) triazole] } thio-N- (2 '-furans) methine acethydrazide, stir, obtain splitting from Brick pug;
2)Split tile pug is placed in carries out old 24h in room temperature environment, old period is once turned over mud every 3h;It is old complete Mechanical pugging 2 times is carried out after, the bubble in pug is driven out of;Carried out in the environment that pug after pugging is carried out 5 DEG C secondary It is old, every the water content that 2h detects pug, extrusion shaping machine is delivered to when water content in pug is down to 15%;
3)Control the ejection speed of extrusion shaping machine for the prepared split tile base substrate of 20 pieces/point, base substrate is placed in 20 DEG C of DEG C of environment Load after standing 18h and suppressed in pressboard, to the pressure for applying 1200t on split tile base substrate, the press time is 15 seconds, will Split tile base substrate in compacting completion is placed in steam-cured stove and is conserved, and controls steam-cured in-furnace temperature between 180 DEG C, continuously supports Normal temperature is naturally cooled to after shield 7h can obtain high intensity split tile.
Embodiment 2
A kind of preparation method of high intensity split tile, it comprises the steps:
1)Weigh the slag of 35 weight portions, the stone of 35 weight portions, the flyash of 25 weight portions, the cement of 20 weight portions and The good abundant mixing of the ground granulated blast furnace slag plasticity of 6 weight portions is added thereto to split as split tile base substrate manufacture material Carried out and mud from adobe body manufacture material 2 times of running water of quality of quality, to the titanium dioxide that soil quality 0.4% is added in pug Silicon, the alumina silicate of soil quality 0.1%, the magnesium nitride of soil quality 1.2%, the 2- { 5- [3- (4 '-methyl) of soil quality 0.6% Phenyl -4- amino-(1,2,4) triazole] } thio-N- (2 '-furans) methine acethydrazide, stir, obtain splitting from Brick pug;
2)Split tile pug is placed in carries out old 36h in room temperature environment, old period is once turned over mud every 3h;It is old complete Mechanical pugging 3 times is carried out after, the bubble in pug is driven out of;Carried out in the environment that pug after pugging is carried out 10 DEG C secondary It is old, every the water content that 2h detects pug, extrusion shaping machine is delivered to when water content in pug is down to 18%;
3)Control the ejection speed of extrusion shaping machine for the prepared split tile base substrate of 24 pieces/point, base substrate is placed in quiet in 24 DEG C of environment Put to load after 18h and suppressed in pressboard, to the pressure for applying 1400t on split tile base substrate, the press time is 25 seconds, will be pressed Split tile base substrate in system completion is placed in steam-cured stove and is conserved, and controls steam-cured in-furnace temperature between 220 DEG C, continuously conserves Normal temperature is naturally cooled to after 11h and can obtain high intensity split tile.
Embodiment 3
A kind of preparation method of high intensity split tile, it comprises the steps:
1)Weigh the slag of 30 weight portions, the stone of 30 weight portions, the flyash of 20 weight portions, the cement of 15 weight portions and 5 The good abundant mixing of the ground granulated blast furnace slag plasticity of weight portion as split tile base substrate manufacture material, be added thereto to split from Adobe body manufacture material 1.25 times of running water of quality of quality are carried out and mud, to the titanium dioxide that soil matter 0.3% is added in pug Silicon, the alumina silicate of soil quality 0.075%, the magnesium nitride of soil quality 1%, the 2- { 5- [3- (4 '-methyl) of soil quality 0.5% Phenyl -4- amino-(1,2,4) triazole] } thio-N- (2 '-furans) methine acethydrazide, stir, obtain splitting from Brick pug;
2)Split tile pug is placed in carries out old 30h in room temperature environment, old period is once turned over mud every 3h;It is old complete Mechanical pugging 3 times is carried out after, the bubble in pug is driven out of;Carried out in the environment that pug after pugging is carried out 8 DEG C secondary It is old, every the water content that 2h detects pug, extrusion shaping machine is delivered to when water content in pug is down to 17%;
3)Control the ejection speed of extrusion shaping machine for the prepared split tile base substrate of 22 pieces/point, base substrate is placed in quiet in 22 DEG C of environment Put to load after 18h and suppressed in pressboard, to the pressure for applying 1300t on split tile base substrate, the press time is 20 seconds, will be pressed Split tile base substrate in system completion is placed in steam-cured stove and is conserved, and controls steam-cured in-furnace temperature between 200 DEG C, continuously conserves Normal temperature is naturally cooled to after 9h and can obtain high intensity split tile.
Embodiment 4
A kind of preparation method of high intensity split tile, it comprises the steps:
1)Weigh the slag of 25 weight portions, the stone of 35 weight portions, the flyash of 15 weight portions, the cement of 20 weight portions and The good abundant mixing of the ground granulated blast furnace slag plasticity of 4 weight portions is added thereto to split as split tile base substrate manufacture material Carried out and mud from adobe body manufacture material 2 times of running water of quality of quality, to the titanium dioxide that soil quality 0.2% is added in pug Silicon, the alumina silicate of soil quality 0.05%, the magnesium nitride of soil quality 1.2%, the 2- { 5- [3- (4 '-methyl) of soil quality 0.4% Phenyl -4- amino-(1,2,4) triazole] } thio-N- (2 '-furans) methine acethydrazide, stir, obtain splitting from Brick pug;
2)Split tile pug is placed in carries out old 36h in room temperature environment, old period is once turned over mud every 3h;It is old complete Mechanical pugging 2 times is carried out after, the bubble in pug is driven out of;Carried out in the environment that pug after pugging is carried out 10 DEG C secondary It is old, every the water content that 2h detects pug, extrusion shaping machine is delivered to when water content in pug is down to 18%;
3)Control the ejection speed of extrusion shaping machine for the prepared split tile base substrate of 20 pieces/point, base substrate is placed in quiet in 24 DEG C of environment Put to load after 18h and suppressed in pressboard, to the pressure for applying 1200t on split tile base substrate, the press time is 25 seconds, will be pressed Split tile base substrate in system completion is placed in steam-cured stove and is conserved, and controls steam-cured in-furnace temperature between 180 DEG C, continuously conserves Normal temperature is naturally cooled to after 11h and can obtain high intensity split tile.
Embodiment 5
A kind of preparation method of high intensity split tile, it comprises the steps:
1)Weigh the slag of 35 weight portions, the stone of 25 weight portions, the flyash of 25 weight portions, the cement of 10 weight portions and 6 The good abundant mixing of the ground granulated blast furnace slag plasticity of weight portion as split tile base substrate manufacture material, be added thereto to split from Adobe body manufacture material 0.5 times of running water of quality of quality is carried out and mud, to the titanium dioxide that soil quality 0.2% is added in pug Silicon, the alumina silicate of soil quality 0.1%, the magnesium nitride of soil quality 0.8%, the 2- { 5- [3- (4 '-methyl) of soil quality 0.6% Phenyl -4- amino-(1,2,4) triazole] } thio-N- (2 '-furans) methine acethydrazide, stir, obtain splitting from Brick pug;
2)Split tile pug is placed in carries out old 24h in room temperature environment, old period is once turned over mud every 3h;It is old complete Mechanical pugging 3 times is carried out after, the bubble in pug is driven out of;Carried out in the environment that pug after pugging is carried out 5 DEG C secondary It is old, every the water content that 2h detects pug, extrusion shaping machine is delivered to when water content in pug is down to 18%;
3)Control the ejection speed of extrusion shaping machine for the prepared split tile base substrate of 20 pieces/point, base substrate is placed in quiet in 20 DEG C of environment Put to load after 18h and suppressed in pressboard, to the pressure for applying 1400t on split tile base substrate, the press time is 15 seconds, will be pressed Split tile base substrate in system completion is placed in steam-cured stove and is conserved, and controls steam-cured in-furnace temperature between 220 DEG C, continuously conserves Normal temperature is naturally cooled to after 7h and can obtain high intensity split tile.
The heat-insulating property and pressure resistance of the high intensity split tile prepared according to above-mentioned preparation technology is determined by experiment Degree, wherein above-mentioned heat-insulating property is represented with its thermal conductivity factor, the measure technique of thermal conductivity factor and compression strength is according to prior art Described in determination of experimental method.The thermal conductivity factor and compressive strength determination result of described high intensity split tile are as shown in table 1.
The thermal conductivity factor and compressive strength determination result of the high intensity split tile of the present invention of table 1
Thermal conductivity factor W/ (㎡ .k) Compression strength Mpa
Embodiment 1 0.58 45
Embodiment 2 0.52 38
Embodiment 3 0.46 65
Embodiment 4 0.61 54
Embodiment 5 0.63 36
Embodiment 6 0.58 47
As can be seen from Table 1, under 0.61, compression strength exists the thermal conductivity factor of high intensity split tile of the present invention 35Mpa, complies fully with《Decorative buiding block of concrete》The standard of JC/T 641-2008, this shows that high intensity of the present invention is split Heat-insulating property and compression strength from brick is excellent.
It is more than the description to the embodiment of the present invention, by the foregoing description of the disclosed embodiments, makes this area special Industry technical staff can realize or use the present invention.Various modifications to these embodiments come to those skilled in the art Say and will be apparent, generic principles defined herein can not depart from the situation of the spirit or scope of the present invention Under, realize in other embodiments.Therefore, the present invention is not intended to be limited to the embodiments shown herein, but to accord with Close the most wide scope consistent with principles disclosed herein and features of novelty.

Claims (4)

1. a kind of preparation method of high intensity split tile, it comprises the steps:
1)Weigh the slag of 25-35 weight portions, the stone of 25-35 weight portions, the flyash of 15-25 weight portions, 10-20 weight portions Cement and 4-6 weight portions the good abundant mixing of ground granulated blast furnace slag plasticity as split tile base substrate manufacture material, The running water for being added thereto to split tile base substrate manufacture material 0.5-2 times of quality of quality is carried out and mud, to adding soil in pug The silica of quality 0.2%-0.4%, the alumina silicate of soil quality 0.05%-0.1%, the magnesium nitride of soil quality 0.8%-1.2%, 2- { 5- [3- (4 '-methyl) phenyl -4- amino-(1,2,4) triazole] } thio-N- (2 '-furans of soil quality 0.4%-0.6% Mutter) methine acethydrazide, stir, obtain split tile pug;
2)Split tile pug is placed in carries out old 24h-36h in room temperature environment, old period is once turned over mud every 3h;It is old Mechanical pugging 2-3 times is carried out after the completion of corruption, the bubble in pug is driven out of;Pug after pugging is carried out 5 DEG C -10 DEG C of environment In carry out it is secondary old, every 2h detect pug water content, be delivered to when water content in pug is down to 15%-18% and be extruded into Type machine;
3)Control the ejection speed of extrusion shaping machine for 20-24 blocks/point prepared split tile base substrate, base substrate is placed in 20 DEG C -24 DEG C Load after standing 18h in environment and suppressed in pressboard, to the pressure for applying 1200t-1400t on split tile base substrate, compacting Time is 15-25 seconds, the split tile base substrate suppressed in completing is placed in steam-cured stove and is conserved, and controls steam-cured in-furnace temperature to exist Between 180-220 DEG C, normal temperature is naturally cooled to after continuous maintenance 7-11h, you can obtain high intensity split tile.
2. the preparation method of high intensity split tile according to claim 1, it is characterised in that it comprises the steps:
1)Weigh the slag of 30 weight portions, the stone of 30 weight portions, the flyash of 20 weight portions, the cement of 15 weight portions and 5 The good abundant mixing of the ground granulated blast furnace slag plasticity of weight portion as split tile base substrate manufacture material, be added thereto to split from Adobe body manufacture material 1.25 times of running water of quality of quality are carried out and mud, to the titanium dioxide that soil matter 0.3% is added in pug Silicon, the alumina silicate of soil quality 0.075%, the magnesium nitride of soil quality 1%, the 2- { 5- [3- (4 '-methyl) of soil quality 0.5% Phenyl -4- amino-(1,2,4) triazole] } thio-N- (2 '-furans) methine acethydrazide, stir, obtain splitting from Brick pug;
2)Split tile pug is placed in carries out old 30h in room temperature environment, old period is once turned over mud every 3h;It is old complete Mechanical pugging 3 times is carried out after, the bubble in pug is driven out of;Carried out in the environment that pug after pugging is carried out 8 DEG C secondary It is old, every the water content that 2h detects pug, extrusion shaping machine is delivered to when water content in pug is down to 17%;
3)Control the ejection speed of extrusion shaping machine for the prepared split tile base substrate of 22 pieces/point, base substrate is placed in quiet in 22 DEG C of environment Put to load after 18h and suppressed in pressboard, to the pressure for applying 1300t on split tile base substrate, the press time is 20 seconds, will be pressed Split tile base substrate in system completion is placed in steam-cured stove and is conserved, and controls steam-cured in-furnace temperature between 200 DEG C, continuously conserves Normal temperature is naturally cooled to after 9h and can obtain high intensity split tile.
3. the high intensity split tile that preparation method described in a kind of utilization claim 1 or 2 is prepared.
4. application of the high intensity split tile described in claim 3 in composite thermal-insulating wall.
CN201710087928.1A 2017-02-18 2017-02-18 It is a kind of high intensity split tile preparation method and its application in composite thermal-insulating wall Active CN106830801B (en)

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CN104692720A (en) * 2015-02-02 2015-06-10 武汉市天沭科技发展有限公司 Copper tailing baking-free brick and preparation method thereof

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Publication number Priority date Publication date Assignee Title
CN103233231A (en) * 2013-04-25 2013-08-07 中国科学院海洋研究所 Application of furan-containing triazole compound used as effective corrosion inhibitor
CN104692720A (en) * 2015-02-02 2015-06-10 武汉市天沭科技发展有限公司 Copper tailing baking-free brick and preparation method thereof

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
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