CN106827722A - Multifunctional glass film - Google Patents
Multifunctional glass film Download PDFInfo
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- CN106827722A CN106827722A CN201710164420.7A CN201710164420A CN106827722A CN 106827722 A CN106827722 A CN 106827722A CN 201710164420 A CN201710164420 A CN 201710164420A CN 106827722 A CN106827722 A CN 106827722A
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
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- B32B17/064—
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B27/08—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/36—Layered products comprising a layer of synthetic resin comprising polyesters
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B33/00—Layered products characterised by particular properties or particular surface features, e.g. particular surface coatings; Layered products designed for particular purposes not covered by another single class
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
- B32B7/04—Interconnection of layers
- B32B7/06—Interconnection of layers permitting easy separation
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Abstract
The invention provides a kind of multifunctional glass film, the multifunctional glass film is multilayer film composite construction, and the multifunctional glass film includes successively：Mould release membrance, the first glue-line, the first base material layer, the second glue-line, Multifunctional layered and the second substrate layer；Wherein, the multifunctional glass film fits in glass surface by the mould release membrance；The Multifunctional layered includes anti-dazzle regulation film layer, core layer and protective layer；Anti-dazzle regulation film layer and protective layer are distributed in the both sides of the core layer, and the anti-dazzle regulation film layer fits in second substrate layer, and the protective layer fits in second glue-line；The core layer is made up of at least one set of three-layer metal layer；The anti-dazzle regulation film layer is by least one first medium layer D1Constitute, the protective layer is by least one second dielectric layer D '1Constitute.In addition, the present invention uses advanced magnetron sputtering deposition method, the resistance to environmental characteristics of film layer system is enhanced, obtain more abundant cie system of color representation cie.
Description
Technical field
Single plane fluoroscopy technology and heat-insulated field the present invention relates to glass-film, more particularly to a kind of multifunctional glass film.
Background technology
In general, the glass of building or automobile, sun-proof to energy-saving heat-insulating to have inevitable demand.Simultaneously in order to protect
The privacy of people and specific valuables inside shield heavy construction curtain wall, household door glass, automotive window is, it is necessary to reach unidirectional
Perspective is the translucent effect of single direction (from the inside to surface).
In order to reach single plane fluoroscopy and heat-insulated effect simultaneously, in the prior art, a kind of conventional method is directly in glass
Plated film on glass, glass spectral properties in itself are changed by one or more layers film layer structure, but because this film layer is softer, after
Phase generally needs to be fabricated to double glazing and uses, relatively costly.
The conventional method of another kind is that, directly in glass surface fenestrated membrane of the patch with the function, the method cost is relatively low, also
With functions such as uvioresistant, anti-splashing, but existing method can normally only realize single plane fluoroscopy function, single plane fluoroscopy effect
It is poor, and without heat-insulating capability.
The content of the invention
A kind of multifunctional glass film is the embodiment of the invention provides, to protect the privacy of indoor or in-car, thermal insulation is improved
Can, and indoor glare is greatly decreased.
To achieve these goals, a kind of multifunctional glass film, the multifunctional glass film be the embodiment of the invention provides
It is multilayer film composite construction, the multifunctional glass film includes successively：Mould release membrance, the first glue-line, the first base material layer, the second glue
Layer, Multifunctional layered and the second substrate layer；Wherein, the multifunctional glass film fits in glass surface by the mould release membrance；
The Multifunctional layered includes anti-dazzle regulation film layer, core layer and protective layer；Anti-dazzle regulation film layer and protective layer distribution
In the both sides of the core layer, and the anti-dazzle regulation film layer fits in second substrate layer, and the protective layer is fitted in
Second glue-line；The core layer is made up of at least one set of three-layer metal layer；The anti-dazzle regulation film layer is by least one the
One dielectric layer D1Constitute, the protective layer is by least one second dielectric layer D '1Constitute.
In one embodiment, the multifunctional glass film also includes：Wearing layer, is arranged on the second substrate layer outside.
In one embodiment, the three-layer metal layer includes：First absorbed layer M1, the second absorbed layer M '1And thermal insulation layer M2, three
The distribution sequence of layer metal level is M1M2M′1, it is described it is anti-dazzle regulation film layer be distributed in the first absorbed layer M1Side, it is described
Protective layer is distributed in the second absorbed layer M '1Side；
The first absorbed layer M1A kind of metal or at least two alloy in for SS, Ni, Cr, Ti, Mo, Al；
The second absorbed layer M '1A kind of metal or at least two alloy in for SS, Ni, Cr, Ti, Mo, Al；
The thermal insulation layer M2A kind of metal or at least two alloy in for Ag, Pd, In, Cu.
In one embodiment, the thermal insulation layer M2Thickness range be 8~30nm；The second absorbed layer M '1Thickness value model
It is 0.8~6nm to enclose；First absorbed layer M1Thickness and the second absorbed layer M '1Thickness ratio be n, and n meet：1.5≤n≤
15。
In one embodiment, n meets：2≤n≤10.
In one embodiment, the first medium layer D1It is the one kind in Al, Zn, Nb, Sn, Ga, Zr, Hf, In, Ti, Ta, Si
Or at least two oxides of alloy, nitride or nitrogen oxides；
The second dielectric layer D '1It is the one kind in Al, Zn, Nb, Sn, Ga, Zr, Hf, In, Ti, Ta, Si or at least two
The oxide of alloy, nitride or nitrogen oxides.
In one embodiment, the thickness of the anti-dazzle regulation film layer is 30~80nm, the thickness of the protective layer for 5~
20nm。
In one embodiment, the first base material layer is pet film, polycarbonate film, poly- first
One kind in base Methylacrylate Film；Second substrate layer is pet film, makrolon is thin
One kind in film, polymethyl methacrylate film, the Multifunctional layered is formed in a surface of second substrate layer；Institute
The thickness range for stating the first base material layer and the second substrate layer is 15~100 μm.
In one embodiment, first glue-line and the second glue-line are esters of acrylic acid adhesive or polyurethane tackifier
With the mixture of ultraviolet absorber, thickness is 1~20 μm.
In one embodiment, the thickness of the mould release membrance is 15~50 μm, and the thickness of the wearing layer is 1~5 μm.
In one embodiment, each layer that the multifunctional glass film is affixed on during glass outer side in the Multifunctional layered is more with described
Each layer that functional glass film is affixed on during glass inner side in the Multifunctional layered is in specular, and manufacturing order is opposite.
In one embodiment, the Multifunctional layered passes through magnetron sputtering deposition plated film.
In one embodiment, the visible light transmissivity of the multifunctional glass film is 5~65%, it is seen that light internal reflection rate ＜
15%, it is seen that light external reflectance rate ＞ 25%；Total rejection rate >=50% of solar energy.
In one embodiment, total rejection rate >=75% of solar energy；The appearance color of the multifunctional glass film is neutrality
Color, or grey, or it is light blue, or light green color.
Multifunctional glass film of the invention, can not only protect the privacy of indoor or in-car, and indoor glare is greatly decreased, and increase
The comfort level of human eye, moreover it is possible to reduce heat through glass to propagation in indoor or window.In addition, the present invention is splashed using advanced magnetic control
Deposition (PVD) method is penetrated, the resistance to environmental characteristics of film layer system is enhanced, more abundant cie system of color representation cie is obtained.
Brief description of the drawings
In order to illustrate more clearly about the embodiment of the present invention or technical scheme of the prior art, below will be to embodiment or existing
The accompanying drawing to be used needed for having technology description is briefly described, it should be apparent that, drawings in the following description are only this
Some embodiments of invention, for those of ordinary skill in the art, on the premise of not paying creative work, can be with
Other accompanying drawings are obtained according to these accompanying drawings.
Fig. 1 is the structural representation one of the multifunctional glass film of the embodiment of the present invention；
Fig. 2 is the structural representation two of the multifunctional glass film of the embodiment of the present invention；
Fig. 3 is the structural representation of the Multifunctional layered of the embodiment of the present invention.
Specific embodiment
Below in conjunction with the accompanying drawing in the embodiment of the present invention, the technical scheme in the embodiment of the present invention is carried out clear, complete
Site preparation is described, it is clear that described embodiment is only a part of embodiment of the invention, rather than whole embodiments.It is based on
Embodiment in the present invention, it is every other that those of ordinary skill in the art are obtained under the premise of creative work is not made
Embodiment, belongs to the scope of protection of the invention.
Fig. 1 is the structural representation one of the multifunctional glass film of the embodiment of the present invention, and the multifunctional glass film is multilayer film
Composite construction, the multifunctional glass film can fit in inner surface or the outer surface of glass, it is adaptable to household door glass, vapour
Car vehicle window etc..
Multifunctional glass film in Fig. 1 fits in the inner surface of glass.As shown in figure 1, from interior surfaces of glass outwards, many work(
Energy glass-film includes successively：Mould release membrance 1, the first glue-line 2, the first base material layer 3, the second glue-line 4, the base material of Multifunctional layered 5 and second
Layer 6, multifunctional glass film fits in interior surfaces of glass by mould release membrance 1.Wherein, Multifunctional layered 5 is multilayer film composite construction, bag
Include anti-dazzle regulation film layer, core layer and protective layer.Anti-dazzle regulation film layer and protective layer are distributed in the both sides of core layer, and described
Anti-dazzle regulation film layer fits in second substrate layer 6, and the protective layer fits in second glue-line 4；Core layer is by least
One group of three-layer metal layer is constituted；Anti-dazzle regulation film layer (being also called bottom) is by least one first medium layer D1Constitute, the guarantor
Sheath (being also called top layer) is by least one second dielectric layer D '1Constitute.
During specific implementation, in order to increase the wearability of multifunctional glass film, it is provided with the outer surface of the second substrate layer 6 wear-resisting
Layer 7.
Fig. 2 is the structural representation two of the multifunctional glass film of the embodiment of the present invention, many in Fig. 2 and unlike Fig. 1
Functional glass film fits in the outer surface of glass.The mould release membrance 1 that multifunctional glass film is included can be seen that by Fig. 1 and Fig. 2, the
One glue-line 2, the first base material layer 3, the second glue-line 4, the order of Multifunctional layered 5, the second substrate layer 6 and wearing layer 7 is constant, but phase
For glass, the single plane fluoroscopy in each layer (Multifunctional layered 5 is used as an entirety) and Fig. 2 in the multifunctional glass film in Fig. 1
Each layer in windowpane is in specular.
It should be noted that it is different from other each layers in multifunctional glass film, because Multifunctional layered 5 includes multilayer, when such as
When multifunctional glass film shown in Fig. 2 is attached to glass outer side, Multifunctional layered 5 with Fig. 1 in relative to glass be in specular, and
And, and Fig. 1 is opposite with the manufacturing order of the Multifunctional layered 5 in Fig. 2.
As shown in figure 3, one group of three-layer metal layer includes：First absorbed layer M1, the second absorbed layer M '1And thermal insulation layer M2, three layers
The distribution sequence of metal level is M1M2M′1, anti-dazzle regulation film layer D1It is distributed in the first absorbed layer M1Side, protective layer D '1Distribution
In the second absorbed layer M '1Side.
During specific implementation, the first absorbed layer M1For a kind of metal in SS (stainless steel), Ni, Cr, Ti, Mo, Al or extremely
Few two kinds alloy；
Second absorbed layer M '1It can also be a kind of metal or at least two in SS (stainless steel), Ni, Cr, Ti, Mo, Al
The alloy planted；
Thermal insulation layer M2A kind of metal or at least two alloy in for Ag, Pd, In, Cu.
First medium layer D1A kind of oxide in for Al, Zn, Nb, Sn, Ga, Zr, Hf, In, Ti, Ta, Si, nitride
Or the oxide of nitrogen oxides or at least two alloys, nitride or nitrogen oxides；
Second dielectric layer D '1It can also be a kind of oxidation in Al, Zn, Nb, Sn, Ga, Zr, Hf, In, Ti, Ta, Si
The oxide of thing, nitride or nitrogen oxides or at least two alloys, nitride or nitrogen oxides.
When core layer is made up of one group of three-layer metal layer, and anti-dazzle regulation film layer is by a kind of first medium layer D1Constitute, protect
Sheath is by a kind of second dielectric layer D '1During composition, according to production sequencing, structure is D1M1M2M′1D′1。
During specific implementation, the first absorbed layer M1With the second absorbed layer M '1Thickness and material can be with identical, it is also possible to not phase
Together.
The invention is not restricted to above-mentioned one group of M1M2M′1Structure, core layer M1M2M′1Can be superimposed and expand to multigroup
D1M1M2M′1D′1Structure, for example, M1M2M′1 M1M2M′1, M1M2M′1M1M2M′1M1M2M′1Deng.Core layer can be expressed as MN, N
It is M1M2M1' structure group number, such as M3Represent M1M2M′1M1M2M′1M1M2M′1。
Dielectric layer D1With D '1Thickness and material can be with identical, it is also possible to differ.In this foundation structure, dielectric layer
D1、D′1The number of plies can expand to D1D2……Dn1-1Dn1、D′n2D′n2-1……D′2D′1(n1 >=2, n2 >=2).
In one embodiment, thermal insulation layer M2Thickness range be 8~30nm；Second absorbed layer M '1Range of values of thickness be 0.8
~6nm；First absorbed layer M1Thickness and the second absorbed layer M '1Thickness ratio be n, and n meet：1.5≤n≤15, preferably
Ground, 2≤n≤10.
Anti-dazzle regulation film layer D in one embodiment1D2……Dn1-1Dn1(n1>=thickness 1) is 30~80nm, protective layer D 'n2D′n2-1……D′2D′1The thickness of (n2 >=1) is 5~20nm.
During specific implementation, Multifunctional layered D can be coated with using winding high vacuum magnetron sputtering technique1M1M2M′1D′1, vacuum
Degree reaches 1 × 10E-5Pa or higher.It is coated with original position and end position is respectively anti-dazzle regulation film layer and protective layer.
During specific implementation, as shown in figure 3, when multifunctional glass film is installed on interior surfaces of glass as shown in Figure 1, according to life
The sequencing of manufacture is produced, the structure of Multifunctional layered 5 is D1D2……Dn1-1Dn1MND′n2D′n2-1……D′2D′1(sequentially from a left side to
It is right).Based on Fig. 1, the sequencing according to the manufacturing of the Multifunctional layered 5 in Fig. 2, structure is D '1D′2……D′n2-1D′n2MNDn1Dn1-1……D2D1。
First glue-line 2 is the mixture of esters of acrylic acid adhesive or polyurethane tackifier and ultraviolet absorber, thickness
It is 1~20 μm.Second glue-line 4 can also be the mixing of esters of acrylic acid adhesive or polyurethane tackifier and ultraviolet absorber
Thing, thickness is 1~20 μm.
In one embodiment, the 3, second substrate layer 6 of the first base material layer can be the base material of water white transparency, or opaque
Base material, preferably optical grade polyester film (PET), its visible light transmissivity ＞ 88%.Or be with mass colouring such as black,
The optical grade polyester film (PET) of the colors such as green, blueness, its visible light transmissivity ＞ 30%.
Specifically, the first base material layer 3 is pet film, the poly- carbon of water white transparency or mass colouring
One kind in acid esters film, polymethyl methacrylate film.Second substrate layer 6 is the poly- to benzene of water white transparency or mass colouring
One kind in naphthalate film, polycarbonate film, polymethyl methacrylate film, Multifunctional layered 5 is formed in
One surface of the second substrate layer 6.The first base material layer 3 can be with identical or different with the thickness of the second substrate layer 6.The first base material layer
3 and second the thickness range of substrate layer 6 be 15~100 μm.
In one embodiment, the thickness of mould release membrance 1 is 15~50 μm, and the thickness of wearing layer 7 is 1~5 μm.
It is many after multifunctional glass film comprising Multifunctional layered 5 is affixed on common float glass (3mm thickness) surface (inner or outer)
The visible light transmissivity of functional glass film is 5~65%, it is seen that light internal reflection rate ＜ 15%, it is seen that light external reflectance rate ＞ 25%.
Total rejection rate >=50% of solar energy, it is preferable that total rejection rate >=75% of solar energy.More than 99% can reach to ultraviolet light isolation.
The appearance color of the multifunctional glass film of the embodiment of the present invention is muted color, or grey, or light blue, or
Light green color.
For isolation solar radiation heat (the total rejection rate of solar energy), numerical value is bigger, shows that less heat is passed through
Glass is inwardly propagated, and energy-saving effect is more notable.
For visible ray external reflectance rate index, numerical value is higher, represents that the mirrored effect of glass outer surface is stronger, outdoor
Observer cannot more see indoor scene clearly, and peep-proof effect is better.
For penetrating rate index in visible ray is outer, numerical value is lower, represents that the mirrored effect of interior surfaces of glass is weaker, anti-dazzle
Light effect is better, and human eye comfort level is better.
For visible light transmissivity index, numerical value is higher, and expression looks out of the window from interior, it can be seen that brighter scape
As.
Above-mentioned multifunctional glass film of the invention, compared to existing single-way perspective membrane, not only passes through bottom in structure design
Layer dielectric layer regulation internal reflection rate reduces the possibility of dazzle, by the thickness difference for controlling the first absorbed layer and the second absorbed layer
Peep-proof effect is have adjusted, and employs more environmentally friendly manufacturing process, enhanced using more advanced magnetron sputtering deposition method
The resistance to environmental characteristics of film layer system, obtains more abundant cie system of color representation cie.
The present invention is not limited to distinguish " interior " and " outdoor ", for example, can be arranged on the country with single plane fluoroscopy function
Hearing room of the settings such as office etc..
It should be noted that under common night environment, outdoor unglazed or dim light and during the strong light of interior, the present invention
The single plane fluoroscopy effect of multifunctional glass film be to reverse, can reasonable employment according to specific needs.
In multifunctional glass film of the invention, in addition to Multifunctional layered 5, remaining raw material and its physicochemical property, technique
Several embodiments of step are as described below：
Embodiment one：Second substrate layer is water white transparency PET, and thickness is 38 μm.Takeup type is used on the second substrate layer
Magnetron sputtering coater, initial depression is 6 × 10E-6Pa, and working gas is Ar, according to the sequencing of substrate transport, according to
Secondary to be coated with ZnAlOx, NiCr, Ag, NiCr, ZnAlOx, thicknesses of layers is followed successively by 40nm, 5nm, 10nm, 1nm, 15nm.
Embodiment two：Second substrate layer is water white transparency PET, and thickness is 50 μm.Takeup type is used on the second substrate layer
Magnetron sputtering coater, initial depression is 6 × 10E-6Pa, and working gas is Ar, according to the sequencing of substrate transport, according to
Secondary to be coated with NbOx, NiCr, Ag, NiCr, NbOx, thicknesses of layers is followed successively by 30nm, 4nm, 10nm, 2nm, 10nm.
Embodiment three：Second substrate layer is mass colouring (blueness) PET of visible light transmissivity 70%, and thickness is 50 μm.
Winding magnetic control sputtering coating machine is used on the second substrate layer, initial depression is 5 × 10E-6Pa, and working gas is Ar, is pressed
According to the sequencing of substrate transport, TiOx, NbOx, NiCr, Ag, NiCr, Ag, NiCr, SiNx are coated with successively, thicknesses of layers is successively
It is 10nm, 25nm, 9nm, 9nm, 6nm, 9nm, 2nm, 10nm.
Example IV：Second substrate layer is mass colouring (black) PET of visible light transmissivity 35%, and thickness is 23 μm.
Winding magnetic control sputtering coating machine is used on the second substrate layer, initial depression is 5 × 10E-6Pa, and working gas is Ar, is pressed
According to the sequencing of substrate transport, be coated with NbOx, Ti, Ag, Ti, NbOx successively, thicknesses of layers be followed successively by 25nm, 15nm, 12nm,
3nm、10nm。
According to the standards of GB/T 2680, learnt through spectrophotometer and infrared spectrometer detection, embodiment multifunctional glass film
After sample is through 3mm float glass pad pastings, single plane fluoroscopy and the effect of heat insulation such as following table for reaching：
| Sample | Visible light transmissivity | Visible ray internal reflection rate | Visible ray external reflectance rate | The total rejection rate of solar energy |
| Embodiment one | 41% | 11% | 27% | 57% |
| Embodiment two | 53% | 8% | 25% | 51% |
| Embodiment three | 14% | 13% | 46% | 77% |
| Example IV | 5% | 7% | 37% | 74% |
Apply specific embodiment in the present invention to be set forth principle of the invention and implementation method, above example
Explanation be only intended to help and understand the method for the present invention and its core concept；Simultaneously for those of ordinary skill in the art,
According to thought of the invention, will change in specific embodiments and applications, in sum, in this specification
Appearance should not be construed as limiting the invention.
Claims (14)
1. a kind of multifunctional glass film, it is characterised in that the multifunctional glass film is multilayer film composite construction, described multi-functional
Glass-film includes successively：Mould release membrance, the first glue-line, the first base material layer, the second glue-line, Multifunctional layered and the second substrate layer；Wherein,
The multifunctional glass film fits in glass surface by the mould release membrance；
The Multifunctional layered includes anti-dazzle regulation film layer, core layer and protective layer；Anti-dazzle regulation film layer and protective layer are distributed in institute
The both sides of core layer are stated, and the anti-dazzle regulation film layer fits in second substrate layer, and the protective layer fits in described
Second glue-line；The core layer is made up of at least one set of three-layer metal layer；The anti-dazzle regulation film layer is situated between by least one first
Matter layer D1Constitute, the protective layer is by least one second dielectric layer D '1Constitute.
2. multifunctional glass film according to claim 1, it is characterised in that also include：Wearing layer, is arranged on described second
Substrate layer outside.
3. multifunctional glass film according to claim 1, it is characterised in that the three-layer metal layer includes：First absorbs
Layer M1, the second absorbed layer M '1And thermal insulation layer M2, the distribution sequence of three-layer metal layer is M1M2M′1, the anti-dazzle regulation film layer distribution
In the first absorbed layer M1Side, the protective layer is distributed in the second absorbed layer M '1Side；
The first absorbed layer M1A kind of metal or at least two alloy in for SS, Ni, Cr, Ti, Mo, Al；
The second absorbed layer M '1A kind of metal or at least two alloy in for SS, Ni, Cr, Ti, Mo, Al；
The thermal insulation layer M2A kind of metal or at least two alloy in for Ag, Pd, In, Cu.
4. multifunctional glass film according to claim 3, it is characterised in that the thermal insulation layer M2Thickness range for 8~
30nm；The second absorbed layer M '1Range of values of thickness be 0.8~6nm；First absorbed layer M1Thickness and the second absorbed layer M '1
Thickness ratio be n, and n meet：1.5≤n≤15.
5. multifunctional glass film according to claim 4, it is characterised in that n meets：2≤n≤10.
6. the multifunctional glass film according to claim 1 or 3, it is characterised in that
The first medium layer D1It is the one kind in Al, Zn, Nb, Sn, Ga, Zr, Hf, In, Ti, Ta, Si or at least two alloys
Oxide, nitride or nitrogen oxides；
The second dielectric layer D '1It is the one kind in Al, Zn, Nb, Sn, Ga, Zr, Hf, In, Ti, Ta, Si or at least two alloys
Oxide, nitride or nitrogen oxides.
7. multifunctional glass film according to claim 6, it is characterised in that the thickness of the anti-dazzle regulation film layer for 30~
80nm, the thickness of the protective layer is 5~20nm.
8. multifunctional glass film according to claim 1, it is characterised in that the first base material layer for water white transparency or this
One kind in pet film, polycarbonate film, the polymethyl methacrylate film of body coloring；Institute
It is water white transparency or pet film, polycarbonate film, the poly- first of mass colouring to state the second substrate layer
One kind in base Methylacrylate Film, the Multifunctional layered is formed in a surface of second substrate layer；Described first
The thickness range of substrate layer and the second substrate layer is 15~100 μm.
9. multifunctional glass film according to claim 1, it is characterised in that first glue-line and the second glue-line are third
The mixture of olefin(e) acid ester adhesive or polyurethane tackifier and ultraviolet absorber, thickness is 1~20 μm.
10. multifunctional glass film according to claim 2, it is characterised in that the thickness of the mould release membrance is 15~50 μm,
The thickness of the wearing layer is 1~5 μm.
The 11. multifunctional glass film according to claim 1 or 3, it is characterised in that the multifunctional glass film is affixed on glass
It is each in the Multifunctional layered when each layer during outside in the Multifunctional layered is affixed on glass inner side with the multifunctional glass film
Layer is in specular, and manufacturing order is opposite.
12. multifunctional glass films according to claim 1, it is characterised in that the Multifunctional layered is heavy by magnetron sputtering
Product plated film.
13. multifunctional glass films according to claim 1, it is characterised in that the visible ray of the multifunctional glass film is saturating
It is 5~65% to cross rate, it is seen that light internal reflection rate ＜ 15%, it is seen that light external reflectance rate ＞ 25%；Total rejection rate >=50% of solar energy.
14. multifunctional glass films according to claim 13, it is characterised in that total rejection rate >=75% of solar energy；
The appearance color of the multifunctional glass film is muted color, or grey, or light blue, or light green color.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710164420.7A CN106827722B (en) | 2017-03-20 | 2017-03-20 | Multifunctional glass film |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710164420.7A CN106827722B (en) | 2017-03-20 | 2017-03-20 | Multifunctional glass film |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN106827722A true CN106827722A (en) | 2017-06-13 |
| CN106827722B CN106827722B (en) | 2019-06-07 |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108276924A (en) * | 2018-01-15 | 2018-07-13 | 东莞市纳利光学材料有限公司 | A kind of high xanthochromia of resistance to UV cured film and preparation method thereof |
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| CN101474901A (en) * | 2009-01-16 | 2009-07-08 | 中山市万丰胶粘电子有限公司 | Heat-insulating pad pasting |
| CN102757185A (en) * | 2012-07-26 | 2012-10-31 | 福耀玻璃工业集团股份有限公司 | Low-radiation heat-treatable coated glass and interlayer glass product thereof |
| CN104354413A (en) * | 2014-11-03 | 2015-02-18 | 大连爱瑞德纳米科技有限公司 | Method for preventing metal layer in fenestrated film from being oxidated and fenestrated film |
| CN206623483U (en) * | 2017-03-20 | 2017-11-10 | 大连爱瑞德纳米科技有限公司 | Multifunctional glass film |
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| CN101474901A (en) * | 2009-01-16 | 2009-07-08 | 中山市万丰胶粘电子有限公司 | Heat-insulating pad pasting |
| CN102757185A (en) * | 2012-07-26 | 2012-10-31 | 福耀玻璃工业集团股份有限公司 | Low-radiation heat-treatable coated glass and interlayer glass product thereof |
| CN104354413A (en) * | 2014-11-03 | 2015-02-18 | 大连爱瑞德纳米科技有限公司 | Method for preventing metal layer in fenestrated film from being oxidated and fenestrated film |
| CN206623483U (en) * | 2017-03-20 | 2017-11-10 | 大连爱瑞德纳米科技有限公司 | Multifunctional glass film |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN108276924A (en) * | 2018-01-15 | 2018-07-13 | 东莞市纳利光学材料有限公司 | A kind of high xanthochromia of resistance to UV cured film and preparation method thereof |
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| CN106827722B (en) | 2019-06-07 |
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