CN106824007B - A kind of liquid distribution trough with mass transfer function - Google Patents

A kind of liquid distribution trough with mass transfer function Download PDF

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Publication number
CN106824007B
CN106824007B CN201710095186.7A CN201710095186A CN106824007B CN 106824007 B CN106824007 B CN 106824007B CN 201710095186 A CN201710095186 A CN 201710095186A CN 106824007 B CN106824007 B CN 106824007B
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liquid
hole
air rising
ctst
calotte
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CN106824007A (en
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李春利
闫磊
姜挺
马帅明
王洪海
方静
董立会
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Hebei University of Technology
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Hebei University of Technology
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J4/00Feed or outlet devices; Feed or outlet control devices
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D1/00Evaporating
    • B01D1/30Accessories for evaporators ; Constructional details thereof
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D3/00Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping
    • B01D3/14Fractional distillation or use of a fractionation or rectification column
    • B01D3/32Other features of fractionating columns ; Constructional details of fractionating columns not provided for in groups B01D3/16 - B01D3/30
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/14Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
    • B01D53/18Absorbing units; Liquid distributors therefor

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Vaporization, Distillation, Condensation, Sublimation, And Cold Traps (AREA)

Abstract

The present invention is a kind of liquid distribution trough with mass transfer function.The structure of the distributor includes catch tray, CTST calotte, air rising hole, liquid distributing hole, catheter and liquid barrier;Wherein, parallel rectangle air rising hole is provided on the catch tray, the long side of air rising hole is welded with vertical liquid barrier;CTST calotte is provided with above air rising hole;The CTST calotte is rectangular cylindrical structure, and the long edge position of rectangle is two pieces of jet trays, is two end plates at short side, and the lower weld of end plate is welded in the short side edge of air rising hole, top and separating plate;The distance at top of the jet tray top away from end plate is 30-50mm, and distance of the lower part away from catch tray is 5-20mm;The liquid distributing hole distribution on the collection tray, is welded with a catheter immediately below each liquid distributing hole.The present invention eliminates the problems of above-mentioned traditional distributor;Mass transfer effect is had both while playing gas and liquid collecting, distribution, fully utilizes the useful space in tower.

Description

A kind of liquid distribution trough with mass transfer function
Technical field:
The present invention relates to a kind of chemical tower trim apparatus, in particular to a kind of liquid distribution trough with mass transfer function.
Background technique:
As chemical industry mass transfer, the fundamental equipments of separation, packed tower is using the filler in tower as gas-liquid two-phase The mass transfer apparatus of contact member.Gas and liquid two phases are efficient mass transfers along being uniformly distributed for tower section, and component is divided in effective journey From guarantee.For the bad distribution for avoiding liquid, guarantee distributing homogeneity, liquid distribution trough and redistributor is arranged in tower domestic demand. The quality of distributed mass significantly affects the operating flexibility of filler separative efficiency and tower.Therefore, liquid distribution trough and redistributor It is particularly important filler tower internals.
As the liquid re-distributor of undertaking two sections filler, while playing the role of collection, redistribution, corrects in time Concentration difference on tower section caused by wall stream, bias current, channel etc. due to caused by filler self performance.Distributor shape is many It is more, configurations, therefore advantage is different and same.It is divided into pressure-type and gravity-type by motive force;It is divided into hole stream, weir by outflow mode Film Flow etc. on stream, conduit stream and draining plate;It is divided into tubular type, slot type, disc type by structure shape.
Disc type distributor is widely used, and cloth liquid disk is equipped with liquid distributing hole and riser road, and gas rises from riser, gas, Liquid channel is separated;Liquid is evenly distributed with through liquid distributing hole simultaneously.It is divided into hole disc type and slotted disc type two again according to riser is different Kind.
Due to above-mentioned distributor design when, gas-liquid shunt, pursue low pressure drop, the air-liquid channel of distributor be it is separated, Riser and catch tray are seamless welding, and distributor is the effect for collect, be distributed to air-liquid.And because The blocking and liquid flow irregularity in the radial direction itself that riser flows liquid, so that the liquid on catch tray exists Concentration distribution difference, liquid level drop, a large amount of the problems such as occupying effective volume in tower.
Summary of the invention:
It is an object of the invention to provide a kind of with mass transfer function for deficiency existing for traditional trough-tray liquid distributor The liquid distribution trough of energy.The distributor passes through the gap being arranged between jet tray lower part and catch tray, enters cover as liquid Channel, while being carried in riser and mixing by the gas of high-speed motion using the channel liquid, make mass transport process sufficiently into Row;One side liquid mixes in riser, on the other hand strengthens the flowing of liquid on catch tray, dense so as to effectively eliminate The problems such as spending distributional difference, liquid level drop.
Technical scheme is as follows:
A kind of liquid distribution trough with mass transfer function, the structure of the distributor include catch tray, CTST calotte, rise gas Hole, liquid distributing hole, catheter and liquid barrier;
Wherein, parallel rectangle air rising hole is provided on the catch tray, the long side of air rising hole is welded with vertical liquid barrier; Wherein, the percent opening of air rising hole on the collection tray is 22%-35%, is spaced 30-70mm, central symmetry distribution;Air rising hole width It is mutually all 20-60mm;The height of liquid barrier is 10-30mm;CTST calotte is provided with above air rising hole;
The CTST calotte is rectangular cylindrical structure, and the long edge position of rectangle is two pieces of jet trays, the same air rising hole of length The length of long side, is two end plates at short side, and width is 5-20mm wider than the short side of air rising hole;The a height of 150-250mm of CTST calotte, Top is provided with separating plate, and the length of separating plate is equal to the length of air rising hole long side, and the two sides of separating plate are growing end plate 15- 90 are turned over downwards at 50mm0, and extend 50-80mm vertically downward, block the gas-liquid mixture ejected;
The lower weld of end plate is welded in the short side edge of air rising hole, top and separating plate;Jet tray top is away from end plate The distance at top is 30-50mm;Distance of the lower part away from catch tray is 5-20mm, and the height in the gap of formation is lower than the height of liquid barrier Spend 5~20mm;
On the collection tray, square is evenly distributed for the liquid distributing hole distribution, 300-1000/m of liquid distributing hole density2;Position In the outside of jet tray;The diameter of liquid distributing hole is 6-10mm;Spacing between adjacent liquid distributing hole is 30-80mm;In catch tray Lower part, each liquid distributing hole underface are welded with a catheter;The length 30-50mm of catheter, internal diameter 16-30mm.
The beneficial effects of the present invention are:
It is separated for existing traditional distributor air-liquid channel, air-liquid does not contact on this tower internals of distributor, only divides Cloth effect, wastes space in tower;Blocking and liquid itself stream radially that liquid on catch tray is flowed due to riser Dynamic inhomogeneities, is designed and has both mass transfer energy the liquid on catch tray the problems such as there are concentration distribution differences, liquid level drop The liquid distributor of power.The distributor by liter gas hood air-liquid hybrid mode eliminate above-mentioned traditional distributor and deposited The problem of;The distributor has both mass transfer effect while playing gas and liquid collecting, distribution, fully utilizes effective sky in tower Between.
The liquid distribution trough (1) is carrying out having both mass transfer function while air-liquid is uniformly distributed, and takes full advantage of empty in tower Between;In structure, traditional distributor gas-liquid two-phase channel be it is independent, distributor only to air-liquid carried out collect, distribution, This device combines the cap of big flux solid mass-transferring CTST in combination with air rising hole and catheter, while above riser road Cover carries out interphase mass transfer so that gas-liquid two-phase comes into full contact in channel;Since delivery hole is incorporated in air rising hole on catch tray Make (2) by the air-liquid hybrid mode in riser together, one side liquid mixes in riser, on the other hand reinforces The flowing of liquid on catch tray, to eliminate concentration distribution difference, liquid level drop present in above-mentioned traditional distributor etc. Problem fully utilizes the useful space in tower.
Liquid distribution trough of the invention is by test, and most of distributed point flow rate relative deviation is within 4%, distributor It can be excellent.In atmospheric distillation or compression rectification etc. in the insensitive component separation process of pressure drop, the liquid distributor because Distinctive mass transfer function is able to achieve maximally utilizing for space in tower.
Detailed description of the invention:
Fig. 1 has the trough-tray liquid distributor bottom view of mass transfer function;
Fig. 2 has the trough-tray liquid distributor cross-sectional view of mass transfer function;
Wherein: 1-catch tray;2-CTST calottes;3-air rising holes;4-liquid distributing holes;5-catheters;6-liquid barriers; 7-separating plates;8-two sides jet trays;9-end plates;
Fig. 3 CTST calotte schematic diagram;
Fig. 4 empty tower gas velocity F0Each cloth liquid point flow rate figure when=1.5;
Fig. 5 empty tower gas velocity F0Each cloth liquid point relative deviation figure when=1.5;
Influence diagram of Fig. 6 sprinkle density to distributor pressure drop;
Fig. 7 empty tower gas velocity F0Liquid level when=1.5 under each sprinkle density.
Specific embodiment:
Present invention will be described in further detail below with reference to the accompanying drawings and specific embodiments.
Trough-tray liquid distributor with mass transfer function of the invention, as shown in figure 1-3, mainly by catch tray (1), CTST calotte (2), air rising hole (3), liquid distributing hole (4), catheter (5), liquid barrier (6) are constituted;Specific structure is for example following;
Parallel rectangle air rising hole (3) is provided on the catch tray (1), the long side of air rising hole (3) is welded with vertical gear Liquid plate (6);Wherein, percent opening of the air rising hole (3) on catch tray (1) is 22%-35%, is spaced 30-70mm, central symmetry point Cloth;Air rising hole (3) of same size is 20-60mm, and the height of liquid barrier (6) is 10-30mm;Air rising hole (3) is provided with above CTST calotte (2);
The main body of the CTST calotte (2) is to project the tubular structure that shape is rectangle, and the long edge position of rectangle is two pieces of sprays It penetrates plate (8), the length of the same air rising hole of length (3) long side, is at short side two end plates (9), width is wider than the short side of air rising hole (3) 5-20mm, (two sides, which are grown, to be equidistant);CTST calotte (2) a height of 150-250mm, top are provided with separating plate (7), separating plate (7) length of the same air rising hole of length (3) long side, the two sides of separating plate (7) are turned over downwards 90 at end plate 15-50mm growing0, And extend 50-80mm vertically downward, block the gas-liquid mixture ejected;
The lower weld of end plate (9) is welded in the short side edge of air rising hole (3), top and separating plate (7);Jet tray (8) Height be different from the height of end plate (9), the distance at top of the top away from end plate (9) is 30-50mm, is going out for gas-liquid mixture Mouthful;Distance of the lower part away from catch tray (1) is 5-20mm, and the height in the gap of formation is lower than the 5~20mm of height of liquid barrier (6); The gap of formation is the channel that liquid enters CTST calotte (2) cover;
The liquid distributing hole (4) is distributed on catch tray (1), and square is evenly distributed, and liquid distributing hole density 300-1000/ m2;Positioned at the outside of jet tray (8);
The diameter of liquid distributing hole (4) is 6-10mm;Spacing between adjacent liquid distributing hole (4) is 30-80mm;In catch tray (1) Lower part, be welded with a catheter (5) immediately below each liquid distributing hole (4);The length 30-50mm of catheter (5), internal diameter are 16-30mm。
Embodiment 1
As shown in Figure 1, the trough-tray liquid distributor with mass transfer function of the invention, mainly by catch tray (1), CTST Calotte (2), air rising hole (3), liquid distributing hole (4), catheter (5), liquid barrier (6) are constituted;Catch tray is provided with air rising hole on (1) (3);Rectangle air rising hole (3) two sides are provided with height 30mm liquid barrier (6);CTST calotte (2) are provided with above air rising hole (3), CTST calotte (2) height 200mm is made of separating plate (7), two sides jet tray (8), end plate (9), rectangle calotte two sides jet tray (8) it is provided with the bottom 10mm gap between lower part and catch tray, the channel of cover is entered for liquid;Catch tray is provided with liquid distributing hole on (1) (4), liquid distributing hole (4) diameter 6mm, 300/m of liquid distributing hole density2;Catheter (5), catheter are provided with below liquid distributing hole (4) (5) length 50mm.
As shown in Fig. 2, the distributor is on the basis of catch tray (1);It opens up liquid distributing hole (4), comprehensive liquid load, liquid level are high Degree, discharge coefficient correlation formula, liquid distributing hole diameter 6mm, spacing 50mm, square are evenly distributed;Rectangle air rising hole (3) are opened up, Calculating percent opening is 27%, and rectangle hole width is 30mm;
As shown in figure 3, rectangle air rising hole (3) two sides welding liquid barrier (6), height 30mm;It is above rectangle air rising hole (3) For CTST calotte (2) part;
As shown in Figure 1, wherein CTST cap height 200mm, length and rectangle air rising hole (3) are isometric, and width is than rectangle liter Stomata (3) width 20mm, each 10mm in both sides, end plate (9) bottom and catch tray (1) weld;Two sides jet tray (8) lower end is away from catch tray (1) the bottom gap is arranged in 10mm, and the channel of cover is entered for liquid, and away from separating plate (7) 50mm, the gap is mixed as gas-liquid for upper end Close the outlet of object;Separating plate (7) is 50mm wider than cover, and each 25mm in both sides extends downwards 70mm, blocks and eject gas-liquid mixed Object prevents from carrying secretly.
Its principle are as follows: gas passes through the air rising hole (3) on plate and rises, because rising gas passages shrink, speed is got higher, and gas becomes For the jet stream of high-speed motion.The gas that passes through of high speed forms low pressure in CTST calotte, is kept on file in advance gap drop by jet tray lower end The sucking of the liquid on plate will be collected, and be sufficiently mixed contact therewith, carry out interphase mass transfer.
Liquid from upper layer packing section is enriched on catch tray (1), forms certain altitude liquid layer;Pass through jet tray lower end Keep on file gap in advance, liquid is drawn into mixing in CTST calotte (2) riser by the gas of high-speed motion, and further promotion, membrane, Broken, gas and liquid two phases come into full contact with, and enhance mass transport process.
Liquid is by entering next packing section by catheter (5) after liquid distributing hole (4) even cloth.
Traditional distributor because of blocking that riser flows liquid and liquid flow irregularity in the radial direction itself, So that the liquid on catch tray the problems such as there are concentration distribution differences, liquid level drop.CTST calotte passes through setting bottom gap, benefit The three-dimensional process intensification drawn liquid into gas, promoted, mix, sprayed liquid flowing, to solve above-mentioned tradition Distributor there are the problem of.
Gas passes through the air rising hole (3) on plate and rises, and the gas passed through at a high speed contacts in CTST calotte with liquid.It comes from The liquid of upper layer packing section is enriched on catch tray (1), forms certain altitude liquid layer;By gap of keeping on file in advance, pass through the channel liquid Body is carried to mixing in CTST calotte (2) riser by the gas of high-speed motion, and further promotion, membrane, broken, air-liquid Two-phase comes into full contact with, and enhances mass transport process.
Liquid is by entering next packing section by catheter (5) after liquid distributing hole (4) even cloth.
Having built a set of diameter is 580mm organic glass tower test macro, is carried out with air-water system to the distributor Distribution performance test.
Distributor Performance Test System mainly includes several parts such as water system, ventilating system, metering section, distributor. Blower is opened, the differential manometer of regulating butterfly valve aperture, observation connection Pitot tube is sized depending on counting to;It opens after a period of stabilisation Centrifugal pump will be promoted to diameter 580mm freezing mask column overhead in cyclic water tank;First it is distributed in advance through comb distributor;Then through dividing After the dispersion of cloth device, water tank is returned;Water size is by valve and flowmeter control, display;Guarantee the level of distributor installation.Experiment Arrange empty tower gas velocity F0Hydrodynamic calculations research under=1.5.Before experiment starts, blower is first opened, regulating butterfly valve aperture arrives Required gas velocity;After a period of stabilisation, water circulating pump is opened, control valve is successively observed under each fluid flow from small to large Kinetic energy factor, pressure drop, after stablizing, timing connects liquid metering, and records above-mentioned each measured value.
Using the concept of statistics large deviations, each distributed point outflow uniformity is assessed, relative deviation indicates each The relative size of distributed point flow rate and average flow rate departure, works as relative deviation > 10%, in distributing homogeneity performance;Relatively partially Poor 4%-6%, distributing homogeneity performance are good;Relative deviation < 4%, distributing homogeneity performance are excellent;Evaluation result shows: except individual Except distributed point flow rate deviation is larger, for most of distributed point flow rate relative deviation within 4%, distributor performance is excellent.
The distributor few for cloth liquid point quantity can judge distributor by each cloth liquid o'clock as a distributed point with this The quality of performance.It is as shown below to calculate each distributed point flow rate, relative deviation;
Each liquid distributing hole flow rate under same operating difference sprinkle density as shown in figure 4, it can be found that:
As sprinkle density increases, each liquid distributing hole flow rate difference reduces, and distribution tends to be uniform.This is because close with spraying Degree increases, and height of liquid layer increases, and air-liquid mixes aggravation in calotte space, and liquid distributing hole is influenced gradually by dripping drops impact Become smaller, each point flow rate tends to be uniform.
Fig. 5 is each cloth liquid point relative deviation, by evaluation of result, it is seen that when empty tower gas velocity is 7.5m3/(h.m2) When, having 9 distributed point flow rate deviations is more than 4%;When empty tower gas velocity is 19.7m3/(h.m2) when, only 1 distributed point flow rate is inclined Difference illustrates that the liquid distributor distributed mass is excellent, operating flexibility 1:2.6 more than 4%.
It means that in atmospheric distillation or compression rectification etc. in the insensitive component separation process of pressure drop, the New Body distributor is able to achieve maximally utilizing for space in tower because of distinctive mass transfer function.
Distributor pressure drop is as shown in Figure 6:
The main reason for pressure drop generates is the castering action to partially liq, to cause pressure drop compared to traditional distributor It is higher.By bottom gap, liquid is mixed in gas lift to calotte space, is broken, and gas and liquid two phases come into full contact with, and realize vertical Mass transport process in body space, this is the main feature of CTST column plate.Fig. 6 shows through the air-liquid hybrid mode in riser, One side liquid mixes in riser, on the other hand strengthens the flowing of liquid on catch tray, to eliminate above-mentioned tradition point The problems such as concentration distribution difference present in cloth device, liquid level drop.
Each liquid distributing hole flow rate under same operating difference sprinkle density as shown in fig. 7, it can be found that;
Liquid level is about the same, this is because height of liquid layer increases as sprinkle density increases, air-liquid is in calotte sky Interior mixing aggravation strengthens the flowing of liquid on catch tray, and influence of the dripping drops impact to liquid fluctuating gradually becomes smaller, liquid Layer height difference becomes smaller.
Trough-tray liquid distributor proposed by the present invention with mass transfer function, is retouched by preferred embodiment State, related technical personnel obviously can not depart from the content of present invention, in spirit and scope to structure as described herein and equipment into Row change or appropriate changes and combinations, the invention of Lai Shixian this technology.In particular, it should be pointed out that all similar replacements and change Apparent to those skilled in the art, they are considered as being included in spirit of that invention, range and content.
Embodiment 2
The parameter of bottom gap between CTST calotte two sides jet tray and catch tray in distributor is modified, setting height of base slot of the downcomer is 5mm, Other parameters remain unchanged.Distribution performance test has been carried out to the distributor by above-mentioned steps.The result shows that: compared to implementation Distributor in example 1, the distributor pressure drop under the conditions of same operation reduce that 50-70Pa, height of liquid layer increases 3- on catch tray The cloth liquid point quantity of 5mm, cloth liquid point flow rate relative deviation greater than 4% is reduced to 1-3, and distributor quality gets a promotion, still Operating flexibility falls to 1:2.2.
This is because height of base slot of the downcomer is reduced to 5mm, the channel that liquid enters CTST calotte becomes smaller, and resistance increases, identical item The lifting capacity of liquid becomes smaller under part, and distributor pressure drop reduces, and the height of liquid layer also resulted on catch tray in comparison will It increases, so each cloth liquid point flow rate just more tends towards stability.But liquid layer increases the drop for resulting in operating flexibility under the same terms It is low.
Embodiment 3
Air rising hole perforated area parameter in distributor is modified, setting percent opening is 21%, and the width of rectangular opening is reduced to 22mm. Other parameters remain unchanged.Distribution performance test has been carried out to the distributor by above-mentioned steps.The result shows that: compared to implementation Distributor in example 1, the pressure drop under the conditions of same operation increase that 80-100Pa, height of liquid layer reduces 2-3mm, cloth liquid on catch tray Cloth liquid point quantity of the point flow rate relative deviation greater than 4% reduces 1-2, not increased significantly.Distributor quality gets a promotion, Operating flexibility rises to 1:3.2.
This is because the gas velocity after gas passes through becomes higher, corresponding CTST cap after reducing air rising hole perforated area Pressure in cover will be lower, has more liquid to be inhaled into, and distributor pressure drop just has an apparent increase, but same liquid The lifting capacity of body increases.Compared to the distributor in embodiment 1, height of liquid layer is declined, but the liquid on catch tray is not Disconnected is inhaled into, sprays, this process strengthens the mobility of liquid, eliminates liquid level drop problem, concentration difference problem, together When operating flexibility increase.
Unaccomplished matter of the present invention is well-known technique.

Claims (1)

1. a kind of liquid distribution trough with mass transfer function, it is characterized in that the structure of the distributor include catch tray, CTST calotte, Air rising hole, liquid distributing hole, catheter and liquid barrier;
Wherein, parallel rectangle air rising hole is provided on the catch tray, the long side of air rising hole is welded with vertical liquid barrier;Its In, the percent opening of air rising hole on the collection tray is 22%-35%, is spaced 30-70mm, central symmetry distribution;Air rising hole width phase It is all 20-60mm;The height of liquid barrier is 10-30mm;CTST calotte is provided with above air rising hole;
The CTST calotte is rectangular cylindrical structure, and the long edge position of rectangle is two pieces of jet trays, and length is the same as air rising hole long side Length, be two end plates at short side, width is 5-20mm wider than the short side of air rising hole;The a height of 150-250mm of CTST calotte, top Be provided with separating plate, the length of separating plate with air rising hole long side length, the two sides of separating plate grow at end plate 15-50mm to Lower 90 degree of fold, and extend 50-80mm vertically downward;
The lower weld of end plate is welded in the short side edge of air rising hole, top and separating plate;Top of the jet tray top away from end plate Distance be 30-50mm, distance of the lower part away from catch tray is 5-20mm, and the height in the gap of formation is lower than the height 5- of liquid barrier 20mm;
On the collection tray, square is evenly distributed for the liquid distributing hole distribution, 300-1000/m of liquid distributing hole density2, and it is located at spray Penetrate the outside of plate;A catheter is welded with immediately below the lower part of catch tray, each liquid distributing hole;
The diameter of the liquid distributing hole is 6-10mm;Spacing between adjacent liquid distributing hole is 30-80mm;The length 30- of catheter 50mm, internal diameter 16-30mm.
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CN203355335U (en) * 2013-05-21 2013-12-25 武汉宏朗石化设备制造有限公司 Novel slot type liquid distributor
CN103464085A (en) * 2013-09-21 2013-12-25 南京福昌环保有限公司 Bubble-cap tower plate
CN204107514U (en) * 2014-10-27 2015-01-21 天津科林泰克科技有限公司 A kind of Box-type Gas-liquid Distributor

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