CN106823760A - A kind of multitube path length spray gun for thermal power plant's SNCR denitration system - Google Patents

A kind of multitube path length spray gun for thermal power plant's SNCR denitration system Download PDF

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Publication number
CN106823760A
CN106823760A CN201710171126.9A CN201710171126A CN106823760A CN 106823760 A CN106823760 A CN 106823760A CN 201710171126 A CN201710171126 A CN 201710171126A CN 106823760 A CN106823760 A CN 106823760A
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China
Prior art keywords
steel pipe
layer steel
spray gun
multitube
power plant
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CN201710171126.9A
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Chinese (zh)
Inventor
张向宇
高宁
陆续
张波
向小凤
徐宏杰
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China Huaneng Group Co Ltd
Xian Thermal Power Research Institute Co Ltd
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China Huaneng Group Co Ltd
Xian Thermal Power Research Institute Co Ltd
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Application filed by China Huaneng Group Co Ltd, Xian Thermal Power Research Institute Co Ltd filed Critical China Huaneng Group Co Ltd
Priority to CN201710171126.9A priority Critical patent/CN106823760A/en
Publication of CN106823760A publication Critical patent/CN106823760A/en
Pending legal-status Critical Current

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/77Liquid phase processes
    • B01D53/79Injecting reactants
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/46Removing components of defined structure
    • B01D53/54Nitrogen compounds
    • B01D53/56Nitrogen oxides
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2251/00Reactants
    • B01D2251/20Reductants
    • B01D2251/206Ammonium compounds
    • B01D2251/2067Urea
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2258/00Sources of waste gases
    • B01D2258/02Other waste gases
    • B01D2258/0283Flue gases

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Biomedical Technology (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Nozzles (AREA)

Abstract

The present invention provides a kind of multitube path length spray gun for thermal power plant's SNCR denitration system, simple and light, reasonable in design ingenious, it is easy to manufacture, and the weight and degree of disturbing increment that length increase brings are small.It includes three steel pipes of coaxial nested encryptions, and three front ends of steel pipe seal the gap set and between adjacent steel pipe and form accommodation space;The rear end of innermost layer steel pipe is passed through urea liquid and forms urea liquid pipeline, and the rear end of intermediate layer steel pipe is passed through compressed air and forms compressed air line, and the rear end of outermost layer steel pipe is passed through cooling water and forms cooling water pipeline;Outermost layer steel pipe disposed outside has multiple nozzles, and urea liquid pipeline is connected with multiple nozzles respectively with compressed air line;Intermediate layer steel pipe and outermost layer steel pipe are welded using the stainless steel tube of multistage different wall;Wall thickness reduces and keeps the external diameter of each section of tube wall constant paragraph by paragraph from back to front.

Description

A kind of multitube path length spray gun for thermal power plant's SNCR denitration system
Technical field
The present invention relates to thermal power plant's SNCR denitration technology, specially a kind of multi-pipe-diameter for thermal power plant's SNCR denitration system Spray gun long.
Background technology
Selective non-catalytic reduction (SNCR) be reducing agent (ammoniacal liquor, urea, ammonia) be injected to 880 DEG C- In 1050 DEG C of regions, it is not necessary to catalyst, the NOx in flue gas optionally can be reduced into harmless N by reducing agent2And H2O。 SNCR techniques can realize that the construction period is short, and investment and operating cost are than it with burner hearth as reactor by the transformation to boiler Its gas denitrifying technology is low, is suitable for the transformation to medium small boiler.The controllable NOx emission reduction by 20 of modern SNCR technologies~ 50%, as unit capacity increases, size of burner hearth and unit load excursion expand, and increased reaction temperature window with reduction The mixed uniformly control difficulty of agent, causes denitration efficiency to reduce.
One typical SNCR system by reducing agent storage, conveying and injection apparatus constitute, wherein injection apparatus is The nucleus equipment of SNCR systems, its performance has a significant impact to the denitration efficiency of SNCR systems.At present both at home and abroad for SNCR sprays Injection device has carried out numerous studies, a kind of multiinjector spray with two-stage diffusion ratio as disclosed in Chinese patent CN102896054A Rifle, and a kind of spray gun being applied in SNCR denitration device disclosed in Chinese patent CN204320086U, pipette tips diameter are less than 25mm, between furnace wall cooling being inserted directly into, simple installation.And for example a kind of SNCR disclosed in Chinese patent CN205361046U takes off Nitre system reducing agent injection apparatus, it enters line replacement, realizes injection using process water to the reducing agent remained in injection branch road The isolation maintenance of device.
Inside SNCR spray guns insertion burner hearth, with flue gas directly contact, abrasion and high temperature corrosion greatly constrain making for spray gun With the life-span, on the other hand, with the increase of furnace volume, the reducing agent of SNCR lance ejections is difficult to reach burner hearth middle part, it is impossible to Fully, uniformly mix with flue gas, cause SNCR techniques denitration efficiency to decline, the escaping of ammonia increases.To alleviate SNCR spray guns in cigarette Abrasion in gas, Chinese patent CN205361748U discloses a kind of two-fluid streamline type spray gun for SNCR systems, passes through Using the outer shower nozzle of streamlined structure, can greatly alleviate pipette tips abrasion;And for example one disclosed in Chinese patent CN205413412U The abrasionproof injector for SNCR denitration is planted, by the outer surface brushing fire resistant wear prevention ceramic coating in gas phase pipe front end, can Abrasion of the injector front end in high temperature grey flue gas high is prevented, and reduces injector appearance and size.For the height of SNCR spray guns Warm etching problem, Chinese patent CN204911212U proposes the denitrating flue gas spray gun that a kind of cylinder is promoted, and it sets cold air Cold air in standby is entered into guide rod sheath via refrigerator pipe and reduces the temperature of guide rod sheath and guide rod end, so as to prevent it Burnt out because temperature is too high;A kind of SNCR denitration multiinjector spear injection that and for example Chinese patent CN102160964A is related to Device, realizes cooling water circulating in spray gun, so as to reduce spray gun temperature by increasing cooling water input and output loop Degree.
In order to realize being sufficiently mixed for reducing agent and flue gas, Chinese patent CN201445911U discloses one kind and is applied to The spray gun type bubble atomizing nozzle long of SNCR method denitrating flue gas processes, it is by by gases at high pressure from the cone for spreading all over bubble generator Shape injecting hole enters in the liquid stream of outer flow passage, and forms the spray orifice ejection that blister is flowed through on spray gun outer tube long, can cover whole anti- Area is answered, so as to improve the mixed effect of reducing agent and flue gas.And for example a kind of boiler disclosed in Chinese patent CN104384039A takes off Nitre Multi-nozzle spray gun, spray gun spraying technique after evaporation in rifle using reducing agent, with spraying, uniform, mixing is sufficient A little.And for example a kind of SNCR denitrating flue gas spray gun disclosed in Chinese patent CN205495328U, employs the nozzle of atomization type, So that flow adjusting range is larger, the region-wide interior uniform particle sizes of spray shapes, jet length is remote.
In the prior art, with the expansion of furnace cavity size, the inhomogeneities of NOx distributions is also brighter on section of burner hearth It is aobvious, burner hearth middle part NOx concentration highest, but the reducing agent of conventional lance injection is difficult to arrival burner hearth middle part, so as to constrain reduction Agent and the mixed effect of flue gas, reduce denitration efficiency.In large-sized unit SNCR techniques, it is to solve reducing agent to increase spray gun length The maximally effective means of jet length, but the spray gun weight brought of length increase and degree of disturbing increase, and will jeopardize the safe handling of spray gun.
The content of the invention
For problems of the prior art, the present invention provides a kind of multi-pipe-diameter for thermal power plant's SNCR denitration system Spray gun long, simple and light, reasonable in design ingenious, it is easy to manufacture, the weight and degree of disturbing increment that length increase brings are small.
The present invention is to be achieved through the following technical solutions:
A kind of multitube path length spray gun for thermal power plant's SNCR denitration system, including three steel pipes of coaxial nested encryptions, Three front ends of steel pipe seal the gap set and between adjacent steel pipe and form accommodation space;The rear end of innermost layer steel pipe is passed through Urea liquid forms urea liquid pipeline, and the rear end of intermediate layer steel pipe is passed through compressed air and forms compressed air line, outermost layer The rear end of steel pipe is passed through cooling water and forms cooling water pipeline;Outermost layer steel pipe disposed outside has multiple nozzles, urea liquid pipeline Connected with multiple nozzles respectively with compressed air line;Intermediate layer steel pipe and outermost layer steel pipe use multistage different wall not Rust steel-pipe welding is formed;Wall thickness reduces and keeps the external diameter of each section of tube wall constant paragraph by paragraph from back to front.
Preferably, intermediate layer steel pipe and outermost layer steel pipe are welded using the stainless steel tube of three sections of different walls;From Afterwards forward, first paragraph stainless steel tube wall thickness is 11mm, and length is 5m;Second segment stainless steel tube wall thickness is 7mm, and length is 3.6m; 3rd section of stainless steel tube wall thickness is 3.5mm, and length is 1.4m-3.4m.
Preferably, multiple nozzles of outermost layer steel pipe disposed outside are enterprising in each section of stainless steel tube of different wall by correspondence Row packet, and the trend that correspondence wall thickness reduces paragraph by paragraph from back to front, the flow of multigroup nozzle also reduce by group.
Preferably, the dividing plate being axially fixed to outside compressed air line is provided with cooling water pipeline, by cooling water Pipeline is divided into two pipeline up and down of only front end connection, and lower pipeline part sets cooling water inlet, and upper pipeline part sets cooling water Outlet.
Preferably, also including the adpting flange of fixed innermost layer steel pipe, the rear end of innermost layer steel pipe sets through adpting flange Put.
Further, the rear end of intermediate layer steel pipe is fixedly connected on flange.
Preferably, the rear end of outermost layer steel pipe is fixed on the steel pipe of intermediate layer by assembly flange, compressed air line Entrance is arranged between adpting flange and assembly flange.
Compared with prior art, the present invention has following beneficial technique effect:
Multitube path length spray gun of the present invention uses compound steel pipe nested encryptions, and innermost layer is urea liquid pipeline, in Between one layer be compressed air line, outermost layer be cooling water circulation pipeline, simple structure, it is easy to fabricate.Urea liquid pipe Road seals with compressed air line front end, is independent of each other between each pipeline.Compressed air line and cooling water pipeline are used The stainless steel tube that wall thickness is gradually reduced is welded, and can significantly reduce spray gun weight, increases spray gun length so as to improve reducing agent Jet length.
Further, three kinds of nozzle sets of flow that multiple nozzles are formed, each nozzle sets stream are disposed with cooling water pipeline Amount distribution is consistent with the concentration distribution of nitrogen oxides in effluent using the change of caliber, can improve reducing agent and be imitated with the mixing of flue gas Really, the escaping of ammonia is reduced.
Further, the cooled water dividing plate of cooling water pipeline is divided into upper and lower two-layer, and cooling water is passed through from lower floor, from upper stream Go out, compared with traditional spray gun long, a cooling water pipeline is reduced, so as to reduce spray gun weight.
Brief description of the drawings
Fig. 1 is the Longitudinal cross section schematic of multitube path length spray gun described in present example.
Fig. 2 is the schematic cross-section in A-A directions in Fig. 1.
In figure:1 is urea liquid pipeline;2 is compressed air line;3 is cooling water inlet;4 is coolant outlet;5 are Cooling water dividing plate;6 is first paragraph stainless steel tube;7 is second segment stainless steel tube;8 is the 3rd section of stainless steel tube;9 is first group of spray Mouth;10 is second group of nozzle;11 is the 3rd group of nozzle;12 is adpting flange, and 13 is assembly flange.
Specific embodiment
With reference to specific embodiment, the present invention is described in further detail, it is described be explanation of the invention and It is not to limit.
The present invention proposes a kind of multitube path length spray gun for thermal power plant's SNCR denitration system, its structure as shown in figure 1, spray Rifle total length is 10-12 meters adjustable, can be inserted into burner hearth middle part.Comprising multiple nozzles on spray gun, to reducing agent is sprayed in flue gas, will Nitrogen oxides in flue gas is reduced into nitrogen and water.The reducing agent is the urea liquid of mass concentration 5-10%, using compression Air atomizing.Cooling agent used by spray gun is water.
Spray gun structure is compound steel sleeve pipe, and nested encryptions, innermost layer is urea liquid pipeline 1, and intermediate layer is compressed air Pipeline 2, outermost layer is cooling water pipeline, and three cannula tips are sealed, and are not influenceed mutually between each pipeline.Steel pipe is preferably used Stainless steel is made, and adpting flange 12 is used for the connection of innermost layer steel pipe and the sealing of intermediate layer steel pipe;After outermost layer steel pipe End is fixed on the steel pipe of intermediate layer by assembly flange 13, and assembly flange 13 is used for the assembling of spray gun and executing agency.
Compressed air line 2 and cooling water pipeline are welded using the stainless steel tube of three sections of different walls, outside steel pipe Footpath is consistent.The wall thickness of first paragraph stainless steel tube 6 is 11mm, and length is 5m;The wall thickness of second segment stainless steel tube 7 is 7mm, and length is 3.6m;The 3rd section of wall thickness of stainless steel tube 8 is 3.5mm, and length is that 1.4-3.4m is adjustable.
One group of nozzle is respectively mounted with three sections of steel pipes of different wall, for spraying urea liquid.Three groups of streams of nozzle Amount distribution is consistent with the concentration distribution of nitrogen oxides in effluent, big in particular close to the 3rd group of anterior flow of nozzle 11 of spray gun, And it is small near first group of flow of nozzle 9 of spray gun afterbody, second group of middle flow of nozzle 10 is therebetween.
As depicted in figs. 1 and 2, a cooling water dividing plate 5 is increased in cooling water pipeline, by being axially fixed to compression Pipeline is divided into upper and lower two-way on air pipe line 2, cooling water is passed through from the cooling water inlet 3 of lower road pipeline, by upper road pipeline Coolant outlet 4 is discharged, and reduces spray gun temperature.

Claims (7)

1. a kind of multitube path length spray gun for thermal power plant's SNCR denitration system, it is characterised in that including three it is coaxial it is nested even The steel pipe for connecing, three front ends of steel pipe seal the gap set and between adjacent steel pipe and form accommodation space;Innermost layer steel pipe Rear end be passed through urea liquid and form urea liquid pipeline (1), the rear end of intermediate layer steel pipe is passed through compressed air, and to form compression empty Air pipe (2), the rear end of outermost layer steel pipe is passed through cooling water and forms cooling water pipeline;
Outermost layer steel pipe disposed outside has multiple nozzles, and urea liquid pipeline (1) sprays with multiple respectively with compressed air line (2) Mouth is connected;
Intermediate layer steel pipe and outermost layer steel pipe are welded using the stainless steel tube of multistage different wall;Wall thickness from back to front by Section reduces and keeps the external diameter of each section of tube wall constant.
2. a kind of multitube path length spray gun for thermal power plant's SNCR denitration system according to claim 1, it is characterised in that Intermediate layer steel pipe and outermost layer steel pipe are welded using the stainless steel tube of three sections of different walls;From back to front, first paragraph is not Rust steel pipe (6) wall thickness is 11mm, and length is 5m;Second segment stainless steel tube (7) wall thickness is 7mm, and length is 3.6m;3rd section stainless Steel pipe (8) wall thickness is 3.5mm, and length is 1.4m-3.4m.
3. a kind of multitube path length spray gun for thermal power plant's SNCR denitration system according to claim 1, it is characterised in that Multiple nozzles of outermost layer steel pipe disposed outside are grouped by correspondence on each section of stainless steel tube of different wall, and correspondence wall The thick trend for reducing paragraph by paragraph from back to front, the flow of multigroup nozzle also reduces by group.
4. a kind of multitube path length spray gun for thermal power plant's SNCR denitration system according to claim 1, it is characterised in that It is provided with cooling water pipeline and is axially fixed to the outside dividing plate (5) of compressed air line (2), cooling water pipeline is divided into only Two pipeline up and down of front end connection, lower pipeline part sets cooling water inlet (3), and upper pipeline part sets coolant outlet (4).
5. a kind of multitube path length spray gun for thermal power plant's SNCR denitration system according to claim 1, it is characterised in that Also include the adpting flange (12) of fixed innermost layer steel pipe, the rear end of innermost layer steel pipe is set through adpting flange (12).
6. a kind of multitube path length spray gun for thermal power plant's SNCR denitration system according to claim 5, it is characterised in that The rear end of intermediate layer steel pipe is fixedly connected on flange (12).
7. a kind of multitube path length spray gun for thermal power plant's SNCR denitration system according to claim 1, it is characterised in that The rear end of outermost layer steel pipe is fixed on the steel pipe of intermediate layer by assembly flange (13), and the entrance of compressed air line is arranged on company Between acting flange (12) and assembly flange (13).
CN201710171126.9A 2017-03-21 2017-03-21 A kind of multitube path length spray gun for thermal power plant's SNCR denitration system Pending CN106823760A (en)

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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS54149007A (en) * 1978-05-15 1979-11-21 Babcock Hitachi Kk Reducing-agent injecting header
CN104056542A (en) * 2014-06-09 2014-09-24 广西壮族自治区建筑材料科学研究设计院 SNCR (selective non-catalytic reduction) denitration method and SNCR denitration device
CN204220334U (en) * 2014-10-13 2015-03-25 北京洛卡环保技术有限公司 A kind of denitrating flue gas directly sprays spraying urea liquid emitter
CN205627564U (en) * 2016-05-30 2016-10-12 沈阳隆达环保节能集团有限公司 High -efficient denitration spray gun
CN206676221U (en) * 2017-03-21 2017-11-28 中国华能集团公司 Multitube path length spray gun for thermal power plant's SNCR denitration system

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS54149007A (en) * 1978-05-15 1979-11-21 Babcock Hitachi Kk Reducing-agent injecting header
CN104056542A (en) * 2014-06-09 2014-09-24 广西壮族自治区建筑材料科学研究设计院 SNCR (selective non-catalytic reduction) denitration method and SNCR denitration device
CN204220334U (en) * 2014-10-13 2015-03-25 北京洛卡环保技术有限公司 A kind of denitrating flue gas directly sprays spraying urea liquid emitter
CN205627564U (en) * 2016-05-30 2016-10-12 沈阳隆达环保节能集团有限公司 High -efficient denitration spray gun
CN206676221U (en) * 2017-03-21 2017-11-28 中国华能集团公司 Multitube path length spray gun for thermal power plant's SNCR denitration system

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Application publication date: 20170613