CN106812260A - A kind of waterproof material - Google Patents

A kind of waterproof material Download PDF

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Publication number
CN106812260A
CN106812260A CN201510867046.8A CN201510867046A CN106812260A CN 106812260 A CN106812260 A CN 106812260A CN 201510867046 A CN201510867046 A CN 201510867046A CN 106812260 A CN106812260 A CN 106812260A
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CN
China
Prior art keywords
waterproof material
particle
characterised
inorganic
filler
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CN201510867046.8A
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Chinese (zh)
Inventor
熊玉钦
徐恩顺
刘振华
刘宝印
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北京东方雨虹防水技术股份有限公司
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Priority to CN201510867046.8A priority Critical patent/CN106812260A/en
Publication of CN106812260A publication Critical patent/CN106812260A/en

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/18Layered products comprising a layer of synthetic resin characterised by the use of special additives
    • B32B27/20Layered products comprising a layer of synthetic resin characterised by the use of special additives using fillers, pigments, thixotroping agents
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B33/00Layered products characterised by particular properties or particular surface features, e.g. particular surface coatings; Layered products designed for particular purposes not covered by another single class
    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04DROOF COVERINGS; SKY-LIGHTS; GUTTERS; ROOF-WORKING TOOLS
    • E04D5/00Roof covering by making use of flexible material, e.g. supplied in roll form
    • E04D5/12Roof covering by making use of flexible material, e.g. supplied in roll form specially modified, e.g. perforated, with granulated surface, with attached pads

Abstract

The invention discloses a kind of waterproof material; wherein; including the water-proof substrate, formation of pressure-sensitive adhesive layer, the protective layer by impermeabilisation paint solidification that set gradually; the protective layer includes organic matrix with the inorganic filler and inorganic particle that are dispersed in the organic matrix; the particle diameter of the inorganic filler is less than the particle diameter of the inorganic particle, and the part inorganic particle protrudes from the surface away from the pressure sensitive adhesive adhesive layer of the organic matrix.In the waterproof material; protective layer includes the organic matrix being solidify to form by polymer emulsion and dispersion wherein inorganic particle, filler; therefore; the protective layer has preferable ultraviolet-resistant aging performance; so as to improve the overall weatherability of waterproof material, be conducive to the long-term storage of the waterproof material.

Description

A kind of waterproof material

Technical field

The invention belongs to architectural waterproof material technical field, and in particular to a kind of waterproof material.

Background technology

It is in the engineering constructions such as building, traffic, subway, tunnel to use concrete structure more, In these areas, the water-impervious requirement to concrete structure is very high.

In order to realize the infiltration energy of concrete structure, it is often necessary in concrete knot The surface coating antiseepage water paint of structure, can be in concrete knot after the water-impervious paint solidification The surface of structure forms antiseepage antireflective coating layer.

When concrete floor carries out waterproof, it usually needs use splash guard.But splash guard Typically it is made up of macromolecular material, this material weatherability is poor, if when long Between storage then easy ageing failure.If aging splash guard is applied into site operation In, easily cause buildings waterproof unqualified.

Therefore, how to improve the weatherability of splash guard turns into this area technology urgently to be resolved hurrily Problem.

The content of the invention

It is an object of the invention to provide a kind of waterproof material, the waterproof material has good Weatherability.

As one aspect of the present invention, there is provided a kind of waterproof material, wherein, including according to The water-proof substrate of secondary setting, formation of pressure-sensitive adhesive layer, the guarantor by impermeabilisation paint solidification Sheath, the protective layer includes organic matrix and is dispersed in inorganic in the organic matrix Filler and inorganic particle, the particle diameter of the particle diameter less than the inorganic particle of the inorganic filler, The part inorganic particle protrude from the organic matrix away from the pressure sensitive adhesive binding agent The surface of layer, the total mass ratio of each component of the impervious antireflective coating material is 100wt%, institute Each component for stating impervious antireflective coating material has following mass percent:

Preferably, projected area of the inorganic particle on the pressure sensitive adhesive adhesive layer It is the 40%~80% of the pressure sensitive adhesive adhesive layer area.

Preferably, the particle diameter of the inorganic particle is 50~500 μm.

Preferably, the inorganic particle is selected from calcite particle, quartz particle, feldspar Any one or any several persons' in particle, silicate granules and chloric acid salt particle is mixed Compound.

Preferably, the thickness of the formation of pressure-sensitive adhesive layer is 50~1500 μm.

Preferably, the formation of pressure-sensitive adhesive layer uses butyl rubber based adhesive, poly- isobutyl Alkenyl adhesive, butyl system adhesive, acrylic based binders, styrene-isoprene - styrenic based adhesives, styrene-ethylene-butylene-styrene based adhesive, styrene- It is butadiene-styrene based adhesive, SBR styrene butadiene rubberses based adhesive, unformed poly- One or more in olefines adhesive, rubber modified asphalt adhesive.

Preferably, the thickness of the water-proof substrate is 50~2500 μm.

Preferably, water-proof substrate is by EVA waterproof materials, TPO waterproof materials, HDPE Any one in waterproof material is made.

Preferably, the polymer emulsion is selected from acrylic copolymer emulsion, polyethylene Any one in vinyl acetate copolymer emulsion and SBR emulsion or any several persons Mixture.

Preferably, the inorganic filler is selected from pearl filler, perlite filler, titanium white Any one or any several persons' in powder filler, kaolin clay filler, wollastonite packing is mixed Compound.

Preferably, the dispersant is dispersant DP270, dispersant DA40, dispersant One or more in 5040;

The wetting agent is wetting agent NP10, wetting agent X405, wetting agent CF10, profit One or more in humectant DM-410;

The defoamer is defoamer 7010, defoamer NXZ, defoamer F-111, disappears One or more in infusion A10;

Described thickener is thickener RM-8W, thickener ASE-60, thickener One or more in 250HBR;

The auxiliary agent be preservative, anti-settling agent, antifreezing agent, coalescents in one kind or It is several.

In the waterproof material, protective layer is included by having that polymer emulsion solidify to form Machine matrix and dispersion wherein inorganic particle, filler, therefore, the protective layer have compared with Good ultraviolet-resistant aging performance, so as to improve the overall weatherability of waterproof material, has Beneficial to the long-term storage of the waterproof material.

Brief description of the drawings

Fig. 1 is the structural representation of waterproof material provided by the present invention;

Fig. 2 is the overall structure diagram that the waterproof material in Fig. 1 is combined with concrete.

Description of reference numerals

100- waterproof materials 110:Water-proof substrate

120:Formation of pressure-sensitive adhesive layer 130:Protective layer

131:Organic matrix 132:Inorganic particle

133:Inorganic filler 200:Concrete

Specific embodiment

To make those skilled in the art more fully understand technical scheme, tie below The drawings and specific embodiments are closed to be described in further detail the present invention.

As one aspect of the present invention, there is provided a kind of waterproof material 100, wherein, such as Shown in Fig. 1, the waterproof material includes the water-proof substrate 110, pressure-sensitive adhesive for setting gradually Oxidant layer 120, the protective layer 130 by impermeabilisation paint solidification.The protective layer 130 is wrapped Organic matrix 131 is included with the inorganic filler 133 and nothing that are dispersed in the organic matrix 131 Machine particle 132, the particle diameter of the particle diameter less than inorganic particle 133 of inorganic filler 133.Part Inorganic particle 132 protrude from organic matrix 131 away from pressure sensitive adhesive adhesive layer 120 Surface, the total mass ratio of each component of the impervious antireflective coating material is 100wt%, described anti- Each component for permeating coating has following mass percent:

It is pointed out that water-proof substrate 110 is flexible macromolecular material being made. Water-proof substrate 110 has preferable water resistance, it may have good flexibility, Ke Yiyu Ground is fitted.

When waterproof material 100 provided by the present invention is prepared, pressure sensitive adhesive is bonded first Oxidant layer 120 is bonded on water-proof substrate 110, is then again coated the impervious antireflective coating material On pressure sensitive adhesive adhesive layer 120, finally the impermeabilisation paint solidification is dried, with Acquisition is bonded in the protective layer 130 on pressure sensitive adhesive adhesive layer 120.Because pressure sensitive adhesive is bonded The surface of oxidant layer 120 is provided with protective layer 130, therefore, in transport waterproof material 100 When, waterproof material 100 can be rolled into coiled material, without causing unnecessary adhesion. Also, protective layer 130 include the organic matrix 131 that is solidify to form by polymer emulsion with And dispersion wherein inorganic particle 132, filler 133, therefore, the protective layer has preferable Ultraviolet-resistant aging performance, so as to improve the overall weatherability of waterproof material 100, Be conducive to the long-term storage of the waterproof material 100.

In having benefited from cementation and the impervious dope layer of pressure sensitive adhesive adhesive layer 120 The solidification of polymer emulsion, the protective layer 130 that impervious antireflective coating material is formed can be firm Be bonded on water-proof substrate 110.Therefore, during the waterproof material is transported It is not easy the phenomenon that inorganic particle 132 comes off occur.

In protective layer 130, organic matrix 131 is the company of polymer emulsion solidification Continuous phase, inorganic particle 132 and filler 133 are dispersed in the dispersion in the organic matrix Phase.Therefore, inorganic particle 133 can be securely fixed in protection by organic matrix 131 In layer 130, thereby further ensure that inorganic particle 133 will not be from the waterproof material On come off.

When the waterproof material to be applied to the waterproof of building lot, by the waterproof material Material be laid on the foundation surface of building, the surface of water-proof substrate 110 towards building lot, Then to casting concrete on protective layer 130.Bonded by pressure sensitive adhesive adhesive layer 120 Protective layer 130 on water-proof substrate 110 can be protected to water-proof substrate, so that The useful life of waterproof material provided by the present invention 100 can effectively be extended.Also, As shown in Fig. 2 due in protective layer 130 larger-size inorganic particle 133 protrude from The surface of protective layer 130, such that it is able to the concrete 200 for being cast in protective layer Preferable mechanical snap structure is formed, so as to improve concrete 200 with the waterproof material Bond strength between material.

In addition, waterproof material provided by the present invention 100 is advance before construction It is made, protective layer 130 has cured, and is readily transported.Also, due to waterproof material 100 is to be made in advance, therefore, it can batch production.When using waterproof material 100, Directly waterproof material 100 is laid on ground, without scene to waterproof material 100 Upper armor coated 130, so that the time needed for having saved site operation.

In the impervious antireflective coating material, can add wetting agent, dispersant, defoamer, Thickener and auxiliary agent.The effect for adding wetting agent is that can cause impervious antireflective coating material more Spread over well on pressure sensitive adhesive adhesive layer, improve pressure sensitive adhesive adhesive layer and protective layer it Between bond strength.The effect of dispersant is to improve dividing for impervious antireflective coating material inorganic particle Uniformity is dissipated, so that inorganic particle is evenly distributed in the protective layer that solidification is obtained In organic matrix.

Preferably, projected area of the inorganic particle on the pressure sensitive adhesive adhesive layer It is the 40%~80% of the pressure sensitive adhesive adhesive layer area.In this case, inorganic particulate Shared ratio has been enough to protect water-proof substrate in grain protective layer, also, Inorganic particle will not be caused to come off because the quantity of inorganic particle is excessive.

In order to reach good mechanical snap effect, it is preferable that the grain of the inorganic particle Footpath is 50~500 μm.

In the present invention, the material to inorganic particle does not do special restriction, for example, The inorganic particle can be selected from calcite particle, quartz particle, feldspar particle, silicon The mixture of any one or any several persons in hydrochlorate particle and chloric acid salt particle.

Preferably, the thickness of the formation of pressure-sensitive adhesive layer is 50~1500 μm.By the pressure The thickness of quick glue is set within this range, it can be ensured that bond the protective layer securely On the water-proof substrate.

In the present invention, the concrete structure of pressure sensing adhesive adhesive layer 120 is not also special Limitation, it is preferable that formation of pressure-sensitive adhesive layer 120 is using butyl rubber based adhesive, poly- Isobutenyl adhesive, butyl system adhesive, acrylic based binders, styrene-isoamyl Styrene based adhesive, styrene-ethylene-butylene-styrene based adhesive, benzene second Alkene-butadiene-styrene based adhesive, SBR styrene butadiene rubberses based adhesive, nothing are fixed One or more in type TPO adhesive, rubber modified asphalt adhesive.

In order to provide preferable waterproof effect, it is preferable that the thickness of water-proof substrate 110 is 50~2500 μm.

In the present invention, it is excellent to the material of water-proof substrate 110 also without special requirement Selection of land, water-proof substrate is by EVA waterproof materials, TPO waterproof materials, HDPE waterproof materials Any one in material is made.

In the present invention, the particular type to polymer emulsion does not do special restriction yet, As long as can play the inorganic particle is bonded together.For example, the polymerization Thing emulsion is selected from acrylic copolymer emulsion, polyethylene vinylacetate copolymers emulsion With any one in SBR emulsion or the mixture of any several persons.

Preferably, what the protective layer also included being dispersed in the organic matrix inorganic fills out Material, in the impervious antireflective coating material, the mass ratio shared by the inorganic filler is 5%~10%.

Inorganic filler can increase the viscosity of impervious antireflective coating material, so that impervious Antireflective coating material can be uniformly coated on pressure sensitive adhesive adhesive layer 120.Also, it is inorganic to fill out Material can also increase the intensity of protective layer 130, such that it is able to be carried out more preferably to water-proof substrate Protection.In addition, inorganic filler being increased in protective layer can also improve the protection The ability of the anti-ultraviolet aging of layer.

Preferably, the inorganic filler is selected from pearl filler, perlite filler, titanium white Any one or any several persons' in powder filler, kaolin clay filler, wollastonite packing is mixed Compound.

Preferably, the dispersant is dispersant DP270, dispersant DA40, dispersant One or more in 5040.

Preferably, the wetting agent is wetting agent NP10, wetting agent X405, wetting agent One or more in CF10, wetting agent DM-410.

Preferably, the defoamer is defoamer 7010, defoamer NXZ, defoamer One or more in F-111, defoamer A10.

Preferably, described thickener be thickener RM-8W, thickener ASE-60, One or more in thickener 250HBR.

Preferably, the auxiliary agent is in preservative, anti-settling agent, antifreezing agent, coalescents One or more.

Following is a brief introduction of the preparation method of waterproof material provided by the present invention, the system Preparation Method is comprised the following steps:

Prepare impervious antireflective coating material;

Pressure sensitive adhesive adhesive layer is set on water-proof substrate;

Impervious antireflective coating material is coated on pressure sensitive adhesive adhesive layer, to form impervious antireflective coating material Layer;

Solidification is dried to the impermeabilisation dope layer, to cause the impervious antireflective coating material The protective layer is formed after layer solidification.

In the present invention, impervious antireflective coating material can be sprayed on by institute by automatic spraying equipment State on pressure sensitive adhesive adhesive layer, it shall be guaranteed that the thickness of coating layer that impervious antireflective coating material is formed is equal It is even it is consistent, not loose colour, do not grow dim, do not trickle.

When solidification is dried to impermeabilisation dope layer, can will include water-proof substrate, The semi-finished product of pressure sensitive adhesive adhesive layer and impermeabilisation dope layer integrally are put into drying equipment Row drying, drying temperature is 80~100 DEG C, and drying time is 3~5 minutes.

After the completion of drying, the waterproof material to obtaining is cooled down and packed.

Embodiment

Embodiment 1

The present embodiment provides a kind of waterproof material, is prepared as follows the waterproof material Material:

1st, impervious antireflective coating material is prepared, the impervious antireflective coating material includes following component:

The polymer emulsion is a kind of vinegar-acrylic emulsion BLJ-358 (acrylic copolymers Emulsion), the inorganic particle is the calcite particle of 100 mesh, and the dispersant is to divide Powder DP270, the defoamer is defoamer F-111, and the auxiliary agent is anti-settling agent;

2nd, HDPE self-adhesives film water-proofing material is launched, and removes release layer, wherein, HDPE self-adhesives film water-proofing material is the HDPE self-adhesions of Dong Fangyuhong companies production and sales Glued membrane waterproof roll, the waterproof roll is anti-water base including what is be made up of HDPE waterproof materials Material and the butyl rubber based adhesive being arranged in waterproof substrate;

3rd, using automatic spraying equipment, drive spray equipment back and forth equal with mechanical reciprocating mechanism Even motion band logical spray equipment is back and forth uniformly moved, and impervious antireflective coating material is uniformly coated on On the pressure sensitive adhesive adhesive layer of HDPE self-adhesive film water-proofing materials, to form impermeabilisation painting The bed of material;

4th, will be coated with impermeabilisation dope layer HDPE self-adhesive film water-proofing materials be put into it is dry Dried in dry stove, temperature is 80 DEG C, drying time is 5 minutes.

Impervious antireflective coating material needed for preparation process 1 in accordance with the following methods:

(1) running water is weighed by formula is accurate, is added in dispersion cylinder, speed of agitator is 100 Rev/min, stir;

(2) dispersant, wetting agent, defoamer, thickener, auxiliary agent are accurately weighed, plus Enter in dispersion cylinder, speed of agitator is 100 revs/min, and stirring at low speed 3 minutes, stirring is equal It is even;

(3) mixing speed is improved to 200 revs/min, is slowly uniformly added into and is accurately weighed Inorganic particle, addition in 10 minutes finishes, stirs;

(4) it is accurate to weigh emulsion and then be slowly uniformly added into paint mixing cylinder, feed within 5 minutes Finish, speed of agitator is 200 revs/min, and low speed disperses 5 minutes, stirs, and stands 5 Minute, obtain impervious antireflective coating material.

Embodiment 2

The present embodiment provides a kind of waterproof material, can be according to provided in embodiment 1 Method prepares the waterproof material, and the difference with embodiment 1 is:

The impervious antireflective coating material contains following component according to weight meter:

The main body emulsion is styryl acrylic emulsion bc-991, and the inorganic filler is 1000 mesh Perlite filler, the dispersant be dispersant 5040, the wetting agent be wetting agent NP10, the defoamer is defoamer A10, and the auxiliary agent is antifreezing agent, described inorganic Particle is the quartz particle of 200 mesh;

Water-proof substrate is TPO splash guards, and thickness is 1000 μm, pressure sensitive adhesive adhesive layer It is made up of polyisobutene based adhesive, thickness is 100 μm.

Embodiment 3

The present embodiment provides a kind of waterproof material, can be according to provided in embodiment 1 Method prepares the waterproof material, and the difference with embodiment 1 is:

The main body emulsion is silicon-acralyte latex SD-528, and the inorganic filler is 60g1000 The mixture of mesh coarse whiting and 50g Du Ponts R902 titanium dioxides, the dispersant is dispersant DA40, the wetting agent is wetting agent CF10, and the defoamer is defoamer 7010, The auxiliary agent is preservative.

The waterproof material, difference are prepared according to the method disclosed in embodiment 1 It is that drying temperature is 100 DEG C, drying time is 3 minutes.

Embodiment 4

The present embodiment provides a kind of waterproof material, can be according to provided in embodiment 1 Method prepares the waterproof material, and the difference with embodiment 1 is:

The main body emulsion is polyethylene vinylacetate copolymers emulsion GW-707, institute Filler is stated for pearl filler, the dispersant is dispersant DP270, the wetting agent It is wetting agent NP10, the defoamer is defoamer NXZ and defoamer F-111 (weight Than being 3:2), for antifreezing agent and coalescents, (weight ratio is 1 to the auxiliary agent:3);

Water-proof substrate is EVA waterproof materials, and thickness is 2500 μm, and adhesive thickness is 300μm。

The waterproof material is prepared according to the method disclosed in embodiment 1.

Experimental example

By the waterproof material in embodiment 3, the commercially available waterproof material (HDPE of comparative sample 1 Splash guard), the commercially available waterproof material (TPO splash guards) of comparative sample 2, press respectively Detected according to test basis listed in table 1, inspection project and experimental condition.From Table 1 can be seen that and be respectively relative to comparative sample 1, comparative sample 2, in embodiment 3 Waterproof material in not water drenching, waterproof material through artificial weathering aging process after poured with after Concrete peel strength is higher than comparative sample 1, comparative sample 2;Waterproof in embodiment 3 Material in water drenching, shell by waterproof material pouring concrete with after after artificial weathering aging treatment It is higher than comparative sample 1, comparative sample 2 from intensity.

Table 1

The protective layer set on waterproof material in the present embodiment so that nothing on waterproof material Removable anti-sticking peel ply need to be set, waterproof material can directly uncoiling, upper people's walking, And waterproof material also has the adhesive strength more excellent with concrete, anti-channeling aqueous, Special good weatherability, the adhesive strength conservation rate of the formation of pressure-sensitive adhesive layer of waterproof material is high.

It is understood that the principle that embodiment of above is intended to be merely illustrative of the present And the illustrative embodiments for using, but the invention is not limited in this.For ability For those of ordinary skill in domain, the situation of spirit and substance of the present invention is not being departed from Under, various changes and modifications can be made therein, and these variations and modifications are also considered as of the invention Protection domain.

Claims (11)

1. a kind of waterproof material, it is characterised in that including set gradually water-proof substrate, Formation of pressure-sensitive adhesive layer, the protective layer by impermeabilisation paint solidification, the protective layer bag Organic matrix is included with the inorganic filler and inorganic particle that are dispersed in the organic matrix, institute State the particle diameter of the particle diameter less than the inorganic particle of inorganic filler, the part inorganic particle The surface away from the pressure sensitive adhesive adhesive layer of the organic matrix is protruded from, it is described anti- Permeate coating each component total mass ratio be 100wt%, the impervious antireflective coating material it is each Individual component has following mass percent:
2. waterproof material according to claim 1, it is characterised in that described inorganic Projected area of the particle on the pressure sensitive adhesive adhesive layer is the pressure sensitive adhesive adhesive layer The 40%~80% of area.
3. waterproof material according to claim 1 and 2, it is characterised in that described The particle diameter of inorganic particle is 50~500 μm.
4. waterproof material according to claim 3, it is characterised in that described inorganic Particle is selected from calcite particle, quartz particle, feldspar particle, silicate granules and chlorine The mixture of any one or any several persons in hydrochlorate particle.
5. waterproof material according to claim 1 and 2, it is characterised in that described The thickness of formation of pressure-sensitive adhesive layer is 50~1500 μm.
6. waterproof material according to claim 5, it is characterised in that described pressure-sensitive Gluing oxidant layer is glued using butyl rubber based adhesive, polyisobutene based adhesive, butyl system Mixture, acrylic based binders, styrene-isoprene-phenylethene based adhesive, benzene second Alkene-ethylene-butylene, Styrene based adhesive, s-B-S based adhesive, SBR styrene butadiene rubberses based adhesive, unformed TPO adhesive, modified rubber One or more in bituminous cement.
7. waterproof material according to claim 1 and 2, it is characterised in that described The thickness of water-proof substrate is 50~2500 μm.
8. waterproof material according to claim 7, it is characterised in that water-proof substrate By any one in EVA waterproof materials, TPO waterproof materials, HDPE waterproof materials It is made.
9. waterproof material according to claim 1 and 2, it is characterised in that described Polymer emulsion is selected from acrylic copolymer emulsion, polyethylene vinylacetate copolymers The mixture of any one or any several persons in emulsion and SBR emulsion.
10. waterproof material according to claim 1 and 2, it is characterised in that institute State inorganic filler and be selected from pearl filler, perlite filler, titanium dioxide filler, kaolin The mixture of any one or any several persons in filler, wollastonite packing.
11. waterproof material according to 1 or 2 is required in right, it is characterised in that The dispersant is in dispersant DP270, dispersant DA40, dispersant 5040 Plant or several;
The wetting agent is wetting agent NP10, wetting agent X405, wetting agent CF10, profit One or more in humectant DM-410;
The defoamer is defoamer 7010, defoamer NXZ, defoamer F-111, disappears One or more in infusion A10;
Described thickener is thickener RM-8W, thickener ASE-60, thickener One or more in 250HBR;
The auxiliary agent be preservative, anti-settling agent, antifreezing agent, coalescents in one kind or It is several.
CN201510867046.8A 2015-12-01 2015-12-01 A kind of waterproof material CN106812260A (en)

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CN201510867046.8A CN106812260A (en) 2015-12-01 2015-12-01 A kind of waterproof material
PCT/CN2016/106242 WO2017092570A1 (en) 2015-12-01 2016-11-17 Waterproof material

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CN202925769U (en) * 2012-12-06 2013-05-08 浙江工商大学 Heat-insulation waterproof roof board
CN103232208A (en) * 2013-04-17 2013-08-07 徐州卧牛山新型防水材料有限公司 Flame-retardant waterproof material and preparation method thereof

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