CN106811297A - A kind of preparation method of thermal response tobacco aromaticss with tobacco fruity note and its application in cigarette - Google Patents
A kind of preparation method of thermal response tobacco aromaticss with tobacco fruity note and its application in cigarette Download PDFInfo
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- CN106811297A CN106811297A CN201611209905.5A CN201611209905A CN106811297A CN 106811297 A CN106811297 A CN 106811297A CN 201611209905 A CN201611209905 A CN 201611209905A CN 106811297 A CN106811297 A CN 106811297A
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11B—PRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
- C11B9/00—Essential oils; Perfumes
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24B—MANUFACTURE OR PREPARATION OF TOBACCO FOR SMOKING OR CHEWING; TOBACCO; SNUFF
- A24B15/00—Chemical features or treatment of tobacco; Tobacco substitutes, e.g. in liquid form
- A24B15/18—Treatment of tobacco products or tobacco substitutes
- A24B15/28—Treatment of tobacco products or tobacco substitutes by chemical substances
- A24B15/30—Treatment of tobacco products or tobacco substitutes by chemical substances by organic substances
- A24B15/305—Treatment of tobacco products or tobacco substitutes by chemical substances by organic substances of undetermined constitution characterised by their preparation
- A24B15/306—Treatment of tobacco products or tobacco substitutes by chemical substances by organic substances of undetermined constitution characterised by their preparation one reactant being an amino acid or a protein, e.g. Maillard's reaction
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11B—PRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
- C11B9/00—Essential oils; Perfumes
- C11B9/0003—Compounds of unspecified constitution defined by the chemical reaction for their preparation
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- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Proteomics, Peptides & Aminoacids (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Toxicology (AREA)
- Fats And Perfumes (AREA)
- Manufacture Of Tobacco Products (AREA)
Abstract
A kind of preparation method the invention discloses thermal response tobacco aromaticss with tobacco fruity note and its application in cigarette, the mixing natural perfume material that the present invention passes through addition 1~10% in the concentrate to offal extract solution, amino acid and saccharide compound, then prepare tobacco aromaticss through Maillard reaction.Prepared spices has the notes such as suitable tobacco perfume, fruity, sour perfume, the fragrance of a flower, is applied in cigarette, can significantly enrich fragrance, coordinates and reduce miscellaneous gas, improves excitant, improves pleasant impression comfort.
Description
Technical field
The invention belongs to tobacco leaf production technical field, in particular it relates to a kind of heat with tobacco fruity note
React the preparation method of tobacco aromaticss and its application in cigarette.
Background technology
The topmost premise material of Maillard reaction is amino acids and recuding sugars compound, and the result of reaction is to make mesh
Mark coloured product is deepened and assigns its certain fragrance, and Maillard reaction has been widely used in and has prepared all kinds of essence perfume
Material, it is general that protein and saccharide compound in plant or animal are hydrolyzed into by assembled unit by acid, alkali and enzyme hydrolysis, then add
Plus a certain amount of amino acids and saccharide compound reaction, the fragrance product required for generation, reacting the fragrance for producing can basis
Different amino acid and the proportioning of carbohydrate, reaction temperature and reaction time and it is different, it can produce the spices of diverse fragrant flavour.
The existing patent report of method on preparing tobacco spice using Maillard reaction, for example, patent
CN101204249A discloses a kind of preparation method of tobacco extract, and it is by enzymolysis, extraction, the Maillard reaction of being added water to offal
Prepare spices；Patent CN1103661A discloses a kind of method for producing tobacco aromaticss, and the method is through acidolysis, enzyme by tobacco powder
Solution, hydrolyzate, then prepare tobacco aromaticss through Maillard reaction；U.S. patent Nos US 4537204 discloses one kind and prepares
The method of tobacco spice, the method is that tobacco digests, separates, Maillard reaction prepares tobacco aromaticss.Patent CN 103045369A
A kind of preparation method of cigarette thermal response class tobacco aromaticss and its application in cigarette are disclosed, the method is by offal
Alkali process are first carried out, acid treatment is carried out again, through Maillard reaction cigarette thermal response class spices is prepared again.
However, the thermal response class spices flue gas concentration of above method preparation is still inadequate and fragrance is single.
The content of the invention
It is contemplated that overcoming the defect of above-mentioned prior art, there is provided a kind of thermal response cigarette with tobacco fruity note is used
The preparation method of spices, so that prepared spices has the notes such as suitable tobacco perfume, fruity, sour perfume, the fragrance of a flower, while described
Spices can enrich fragrance when being applied in cigarette, coordinate and reduce miscellaneous gas, reduce excitant, improve pleasant impression comfort.
The technical problems to be solved by the invention are achieved by the following technical programs：
A kind of preparation method of the thermal response tobacco aromaticss with tobacco fruity note, comprises the following steps：
S1. the concentrate of the offal extract solution that solid content weight content is 35~65% is prepared；
S2. toward add in concentrate the amino acid of concentrate weight 0.5%~7%, 5%~40% saccharide compound and
1~10% mixing natural perfume material, it is well mixed to form mixed liquor；
S3. to 7~9,90~130 DEG C of temperature control reacts 1~5h to the pH value of regulation mixed solution, is prepared through Maillard reaction
Tobacco aromaticss；Wherein described mixing natural perfume material is the mixture of osmanthus concrete, apple extract and dark plum medicinal extract.
The tobacco aromaticss fragrance level that the concentrate of offal extract solution is prepared through Maillard reaction is not enough and fragrance list
One.Inventor is found through experiments that, is concentrated when by osmanthus concrete, the mixture of apple extract and dark plum medicinal extract and offal spices
When preparing tobacco aromaticss through Maillard reaction after liquid, amino acid and saccharide compound are well mixed, exclusive use offal is overcome
Flue gas not enough defect when preparing spices, prepared spices has the notes such as suitable tobacco perfume, fruity, sour perfume, the fragrance of a flower, will
It is applied in cigarette, can significantly enrich fragrance, coordinates and reduce miscellaneous gas, reduces excitant, improves pleasant impression comfort.
Preferably, in the step S2 amino acid be arginine, glycine, threonine two or more.
Preferably, saccharide compound is one or more in glucose, xylose, maltose, fructose in the step S2.
Being added in combination for osmanthus concrete, apple extract and dark plum medicinal extract, not only enriches the fragrance of tobacco aromaticss, gives
Tobacco aromaticss increase the notes such as fruity, sour perfume, the fragrance of a flower, and the fragrance applications being made are when cigarette flavouring, moreover it is possible to significantly rich
Taste when richness is sucked, increases really fragrant and sweet and acid perfume, effectively reduces excitant and improves pleasant impression comfort.Preferably, it is described mixed
The mass ratio of osmanthus concrete, apple extract and dark plum medicinal extract is in conjunction natural perfume material：Osmanthus concrete:Apple extract:Dark plum
Medicinal extract=0.4:4:1.
Fruity in tobacco aromaticss fragrance is mainly derived from the apple extract in mixing natural perfume material, and the fragrance of a flower is from mixed
The osmanthus concrete in natural perfume material is closed, osmanthus concrete, apple extract and dark plum medicinal extract further enrich the perfume (or spice) of tobacco aromaticss
Gas.The notes such as fruity, sour perfume, the fragrance of a flower of varying strength can be obtained by controlling the consumption of mixing natural perfume material.When mixing day
During the large usage quantity of right spices, in the present invention, the consumption of corresponding mixing natural perfume material is concentrate weight 8%~10%
When, fruity, fragrant and the fragrance of a flower the intensity of acid can be significantly improved.
In addition, inventor has found that the consumption of saccharide compound smells fragrant performance and produces influence on mixing natural perfume material.When
When the consumption of saccharide compound is higher, correspondingly, in the present invention saccharide compound consumption for concentrate weight 20%~
When 40%, spices is respectively provided with fragrant and sweet feature.
In addition, when the consumption of amino acid in the step S2 is higher, in the middle of the present invention, accordingly, the step S2
When the consumption of middle amino acid is the 5%~7% of concentrate weight, prepared spices acid perfume (or spice) is changed into fragrant and sweet.Additionally, being commented in suction
When also have just fragrant and sweet and slightly Hui Tian.
The preparation method of the concentrate of offal extract solution refers to prior art described in S1 of the present invention, it is preferable that the S1
Comprise the following steps：Mixing offal and water, it is 9~13 to adjust material liquid pH with alkali after being uniformly dispersed, heating extraction offal, filtering,
It is 4~7 with acid regulation extracting liquid pH value, adds ethanol, 1~10h of refluxing extraction, centrifugation, filtering takes supernatant, concentrates supernatant
Liquid obtains the concentrate of offal extract solution.It is highly preferred that the ratio of offal and water is 1 in the step S1:5~1:20.
It is highly preferred that the size of offal is 10~100 mesh in the step S1.
The offal refers to the accessory substance of tobacco industry, and alternatively, the present invention can be used by cigar mill's throwing
Process makes the powder that broken process is produced, and is screened by unified, and the offal is without conglomeration, free from extraneous odour, without going mouldy, it is highly preferred that institute
Offal moisture content is stated less than 15%.
It is highly preferred that the alkali is potassium hydroxide or NaOH.
It is highly preferred that the acid is citric acid.
The invention discloses the tobacco aromaticss prepared using above-mentioned preparation method.
The invention also discloses application of the tobacco aromaticss in cigarette is prepared.
Specifically, be added to tobacco aromaticss in pipe tobacco by the present invention, and the addition of the tobacco aromaticss is tobacco quality
0.5~30 ‰.As one of which addition manner, the tobacco aromaticss are mixed with solvent, be then sprayed onto pipe tobacco
In, the solvent is preferably water.
Compared with prior art, the present invention has the advantages that：The present invention effectively utilizes pipe tobacco manufacturing process sheet
Body makes broken offal, is concentrated by extracting, and add a certain amount of mixing natural perfume material, the perfume (or spice) prepared by Maillard reaction
Material has the notes such as suitable tobacco perfume, fruity, sour perfume, the fragrance of a flower, is applied in cigarette, can significantly enrich fragrance, assists
Miscellaneous gas is adjusted and reduced, excitant is reduced, pleasant impression comfort is improved, is overcome and flue gas deficiency when offal prepares spices is used alone
Defect；Simultaneously prepared spices solubility is good, can be directly used for perfuming cigarette charging, using convenient, can add in pipe tobacco, swollen
In change stem, expanded cut tobacco or reconstituted tobacoo.
Specific embodiment
Explanation is further expalined to the present invention with reference to specific embodiment, its description is more specific and detailed, but
Therefore the limitation to the scope of the claims of the present invention can not be interpreted as, as long as being obtained in the form of equivalent or equivalent transformation
The technical scheme for obtaining, all should be included within the protection domain of the claims in the present invention.
Osmanthus concrete of the present invention is 10% osmanthus concrete of the buying from Guangzhou Baihua Aromatics Co. Ltd.
Alcoholic solution (mass fraction of osmanthus concrete is 10%, and solvent is ethanol), apple extract and dark plum medicinal extract are purchased from Hua Fangyan
Spices Co., Ltd is used, other reagents and raw material are also conventional purchased in market.Unless stated otherwise, the method for using is led for this technology
The conventional method in domain.
Embodiment 1
S1. offal is crushed to 80 mesh, takes offal 500g and is placed in container, adds 8000mL water, is uniformly dispersed, and adds hydrogen-oxygen
Change potassium, regulation feed liquid makes the pH of system be 13, in 0.5h is extracted at 110 DEG C, heating extraction offal is filtered, and filtrate is extract solution,
It is 4.5 to adjust extracting liquid pH value with citric acid, and it is 80% to add ethanol to system ethanol volumetric concentration, refluxing extraction 3h, suction filtration,
Supernatant is taken, by supernatant concentration to the concentrate that solid content weight content is 50%；
S2. 250g concentrates are taken, 2g arginine, 1g glycine, 5g glucose, 9g maltose is added, stirring and dissolving are uniform,
Add 20g mixing natural perfume material (10% osmanthus concrete alcoholic solution:Apple extract:Dark plum medicinal extract=4:4:1, mass ratio),
It is well mixed；
S3. add the pH value of NaOH regulation mixed solution to 7,2h is reacted under the conditions of 90 DEG C, through Maillard reaction
Prepare tobacco aromaticss.
That investigates prepared spices smells fragrant feature, the results are shown in Table 1.
By with the tobacco aromaticss water dissolves of the ratio of tobacco quality 1.5% into 10% concentration (mass concentration) solution, and add
It is added in pipe tobacco, is fabricated to cigarette, the group of smokeing panel test smokes panel test through specialty, smoking result is shown in Table 2.
Embodiment 2
S1. offal is crushed to 80 mesh, takes offal 500g and is placed in container, adds 8000mL water, is uniformly dispersed, and adds hydrogen-oxygen
Change potassium, regulation feed liquid makes the pH of system be 13, in 0.5h is extracted at 110 DEG C, heating extraction offal is filtered, and filtrate is extract solution,
It is 4.5 to adjust extracting liquid pH value with citric acid, and it is 80% to add ethanol to system ethanol volumetric concentration, refluxing extraction 3h, suction filtration,
Supernatant is taken, by supernatant concentration to the concentrate that solid content weight content is 50%；
S2. 250g concentrates are taken, 0.83g arginine, 0.42g glycine, 5g glucose, 9g maltose is added, is stirred molten
Solution is uniform, adds 20g mixing natural perfume material (10% osmanthus concrete alcoholic solution:Apple extract:Dark plum medicinal extract=4:4:1, matter
Amount ratio), it is well mixed；
S3. add the pH value of NaOH regulation mixed solution to 7,2h is reacted under the conditions of 90 DEG C, through Maillard reaction
Prepare tobacco aromaticss.
That investigates prepared spices smells fragrant feature, the results are shown in Table 1.
By with the tobacco aromaticss water dissolves of the ratio of tobacco quality 1.5% into 10% concentration (mass concentration) solution, and add
It is added in pipe tobacco, is fabricated to cigarette, the group of smokeing panel test smokes panel test through specialty, smoking result is shown in Table 2.
Embodiment 3
S1. offal is crushed to 80 mesh, takes offal 500g and is placed in container, adds 8000mL water, is uniformly dispersed, and adds hydrogen-oxygen
Change potassium, regulation feed liquid makes the pH of system be 13, in 0.5h is extracted at 110 DEG C, heating extraction offal is filtered, and filtrate is extract solution,
It is 4.5 to adjust extracting liquid pH value with citric acid, and it is 80% to add ethanol to system ethanol volumetric concentration, refluxing extraction 3h, suction filtration,
Supernatant is taken, by supernatant concentration to the concentrate that solid content weight content is 50%；
S2. 250g concentrates are taken, 2g arginine, 1g glycine, 4g glucose, 8.5g maltose is added, stirring and dissolving is equal
It is even, add 20g mixing natural perfume material (10% osmanthus concrete alcoholic solution:Apple extract:Dark plum medicinal extract=4:4:1, quality
Than), it is well mixed；
S3. add the pH value of NaOH regulation mixed solution to 7,2h is reacted under the conditions of 90 DEG C, through Maillard reaction
Prepare tobacco aromaticss.
That investigates prepared spices smells fragrant feature, the results are shown in Table 1.
By with the tobacco aromaticss water dissolves of the ratio of tobacco quality 1.5% into 10% concentration (mass concentration) solution, and add
It is added in pipe tobacco, is fabricated to cigarette, the group of smokeing panel test smokes panel test through specialty, smoking result is shown in Table 2.
Embodiment 4
S1. offal is crushed to 80 mesh, takes offal 500g and is placed in container, adds 8000mL water, is uniformly dispersed, and adds hydrogen-oxygen
Change potassium, regulation feed liquid makes the pH of system be 13, in 0.5h is extracted at 110 DEG C, heating extraction offal is filtered, and filtrate is extract solution,
It is 4.5 to adjust extracting liquid pH value with citric acid, and it is 80% to add ethanol to system ethanol volumetric concentration, refluxing extraction 3h, suction filtration,
Supernatant is taken, by supernatant concentration to the concentrate that solid content weight content is 50%；
S2. 250g concentrates are taken, 2g arginine, 1g glycine, 5g glucose, 9g maltose is added, stirring and dissolving are uniform,
Add 2.5g mixing natural perfume material (10% osmanthus concrete alcoholic solution:Apple extract:Dark plum medicinal extract=4:4:1, mass ratio),
It is well mixed；
S3. add the pH value of NaOH regulation mixed solution to 7,2h is reacted under the conditions of 90 DEG C, through Maillard reaction
Prepare tobacco aromaticss.
That investigates prepared spices smells fragrant feature, the results are shown in Table 1.
By with the tobacco aromaticss water dissolves of the ratio of tobacco quality 1.5% into 10% concentration (mass concentration) solution, and add
It is added in pipe tobacco, is fabricated to cigarette, the group of smokeing panel test smokes panel test through specialty, smoking result is shown in Table 2.
Embodiment 5
S1. offal is crushed to 80 mesh, takes offal 500g and is placed in container, adds 8000mL water, is uniformly dispersed, and adds hydrogen-oxygen
Change potassium, regulation feed liquid makes the pH of system be 13, in 0.5h is extracted at 110 DEG C, heating extraction offal is filtered, and filtrate is extract solution,
It is 4.5 to adjust extracting liquid pH value with citric acid, and it is 80% to add ethanol to system ethanol volumetric concentration, refluxing extraction 3h, suction filtration,
Supernatant is taken, by supernatant concentration to the concentrate that solid content weight content is 50%；
S2. 250g concentrates are taken, 2g arginine, 1g glycine, 5g glucose, 9g maltose is added, stirring and dissolving are uniform,
Add 20g mixing natural perfume material (10% osmanthus concrete alcoholic solution:Apple extract:Dark plum medicinal extract=4:4:1, mass ratio),
It is well mixed；
S3. add the pH value of NaOH regulation mixed solution to 7,1h is reacted under the conditions of 90 DEG C, through Maillard reaction
Prepare tobacco aromaticss.
That investigates prepared spices smells fragrant feature, the results are shown in Table 1.
By with the tobacco aromaticss water dissolves of the ratio of tobacco quality 1.5% into 10% concentration (mass concentration) solution, and add
It is added in pipe tobacco, is fabricated to cigarette, the group of smokeing panel test smokes panel test through specialty, smoking result is shown in Table 2.
Embodiment 6
S1. offal is crushed to 80 mesh, takes offal 500g and is placed in container, adds 8000mL water, is uniformly dispersed, and adds hydrogen-oxygen
Change potassium, regulation feed liquid makes the pH of system be 13, in 0.5h is extracted at 110 DEG C, heating extraction offal is filtered, and filtrate is extract solution,
It is 4.5 to adjust extracting liquid pH value with citric acid, and it is 80% to add ethanol to system ethanol volumetric concentration, refluxing extraction 3h, suction filtration,
Supernatant is taken, by supernatant concentration to the concentrate that solid content weight content is 50%；
S2. 250g concentrates are taken, 11.7g arginine, 5.8g glycine, 5g glucose, 9g maltose, stirring and dissolving is added
Uniformly, 20g mixing natural perfume material (10% osmanthus concrete alcoholic solution is added:Apple extract:Dark plum medicinal extract=4:4:1, quality
Than), it is well mixed；
S3. add the pH value of NaOH regulation mixed solution to 7,2h is reacted under the conditions of 90 DEG C, through Maillard reaction
Prepare tobacco aromaticss.
That investigates prepared spices smells fragrant feature, the results are shown in Table 1.
By with the tobacco aromaticss water dissolves of the ratio of tobacco quality 1.5% into 10% concentration (mass concentration) solution, and add
It is added in pipe tobacco, is fabricated to cigarette, the group of smokeing panel test smokes panel test through specialty, smoking result is shown in Table 2.
Embodiment 7
S1. offal is crushed to 80 mesh, takes offal 500g and is placed in container, adds 8000mL water, is uniformly dispersed, and adds hydrogen-oxygen
Change potassium, regulation feed liquid makes the pH of system be 13, in 0.5h is extracted at 110 DEG C, heating extraction offal is filtered, and filtrate is extract solution,
It is 4.5 to adjust extracting liquid pH value with citric acid, and it is 80% to add ethanol to system ethanol volumetric concentration, refluxing extraction 3h, suction filtration,
Supernatant is taken, by supernatant concentration to the concentrate that solid content weight content is 50%；
S2. 250g concentrates are taken, 2g arginine, 1g glycine, 36g glucose, 64g maltose is added, stirring and dissolving is equal
It is even, add 20g mixing natural perfume material (10% osmanthus concrete alcoholic solution:Apple extract:Dark plum medicinal extract=4:4:1, quality
Than), it is well mixed；
S3. add the pH value of NaOH regulation mixed solution to 7,2h is reacted under the conditions of 90 DEG C, through Maillard reaction
Prepare tobacco aromaticss.
That investigates prepared spices smells fragrant feature, the results are shown in Table 1.
By with the tobacco aromaticss water dissolves of the ratio of tobacco quality 1.5% into 10% concentration (mass concentration) solution, and add
It is added in pipe tobacco, is fabricated to cigarette, the group of smokeing panel test smokes panel test through specialty, smoking result is shown in Table 2.
Embodiment 8
S1. offal is crushed to 80 mesh, takes offal 500g and is placed in container, adds 8000mL water, is uniformly dispersed, and adds hydrogen-oxygen
Change potassium, regulation feed liquid makes the pH of system be 13, in 0.5h is extracted at 110 DEG C, heating extraction offal is filtered, and filtrate is extract solution,
It is 4.5 to adjust extracting liquid pH value with citric acid, and it is 80% to add ethanol to system ethanol volumetric concentration, refluxing extraction 3h, suction filtration,
Supernatant is taken, by supernatant concentration to the concentrate that solid content weight content is 50%；
S2. 250g concentrates are taken, 2g arginine, 1g glycine, 5g glucose, 9g maltose is added, stirring and dissolving are uniform,
Add 25g mixing natural perfume material (10% osmanthus concrete alcoholic solution:Apple extract:Dark plum medicinal extract=4:4:1, mass ratio),
It is well mixed；
S3. add the pH value of NaOH regulation mixed solution to 7,2h is reacted under the conditions of 90 DEG C, through Maillard reaction
Prepare tobacco aromaticss.
That investigates prepared spices smells fragrant feature, the results are shown in Table 1.
By with the tobacco aromaticss water dissolves of the ratio of tobacco quality 1.5% into 10% concentration (mass concentration) solution, and add
It is added in pipe tobacco, is fabricated to cigarette, the group of smokeing panel test smokes panel test through specialty, smoking result is shown in Table 2.
Embodiment 9
S1. offal is crushed to 80 mesh, takes offal 500g and is placed in container, adds 8000mL water, is uniformly dispersed, and adds hydrogen-oxygen
Change potassium, regulation feed liquid makes the pH of system be 13, in 0.5h is extracted at 110 DEG C, heating extraction offal is filtered, and filtrate is extract solution,
It is 4.5 to adjust extracting liquid pH value with citric acid, and it is 80% to add ethanol to system ethanol volumetric concentration, refluxing extraction 3h, suction filtration,
Supernatant is taken, by supernatant concentration to the concentrate that solid content weight content is 50%；
S2. 250g concentrates are taken, 2g arginine, 1g glycine, 5g glucose, 9g maltose is added, stirring and dissolving are uniform,
Add 20g mixing natural perfume material (10% osmanthus concrete alcoholic solution:Apple extract:Dark plum medicinal extract=4:4:1, mass ratio),
It is well mixed；
S3. add the pH value of NaOH regulation mixed solution to 7,2h is reacted under the conditions of 130 DEG C, through Maillard reaction
Prepare tobacco aromaticss.
That investigates prepared spices smells fragrant feature, the results are shown in Table 1.
By with the tobacco aromaticss water dissolves of the ratio of tobacco quality 1.5% into 10% concentration (mass concentration) solution, and add
It is added in pipe tobacco, is fabricated to cigarette, the group of smokeing panel test smokes panel test through specialty, smoking result is shown in Table 2.
Embodiment 10
S1. offal is crushed to 80 mesh, takes offal 500g and is placed in container, adds 8000mL water, is uniformly dispersed, and adds hydrogen-oxygen
Change potassium, regulation feed liquid makes the pH of system be 13, in 0.5h is extracted at 110 DEG C, heating extraction offal is filtered, and filtrate is extract solution,
It is 4.5 to adjust extracting liquid pH value with citric acid, and it is 80% to add ethanol to system ethanol volumetric concentration, refluxing extraction 3h, suction filtration,
Supernatant is taken, by supernatant concentration to the concentrate that solid content weight content is 50%；
S2. 250g concentrates are taken, add 2g arginine, 1g glycine, 5g glucose, 9g maltose stirring and dissolving uniform,
Add 20g mixing natural perfume material (10% osmanthus concrete:Apple extract:Dark plum medicinal extract=4:4:1, mass ratio), mixing is equal
It is even；
S3. add the pH value of NaOH regulation mixed solution to 7,5h is reacted under the conditions of 90 DEG C, through Maillard reaction
Prepare tobacco aromaticss.
That investigates prepared spices smells fragrant feature, the results are shown in Table 1.
By with the tobacco aromaticss water dissolves of the ratio of tobacco quality 1.5% into 10% concentration (mass concentration) solution, and add
It is added in pipe tobacco, is fabricated to cigarette, the group of smokeing panel test smokes panel test through specialty, smoking result is shown in Table 2.
Embodiment 11
S1. offal is crushed to 80 mesh, takes offal 500g and is placed in container, adds 8000mL water, is uniformly dispersed, and adds hydrogen-oxygen
Change potassium, regulation feed liquid makes the pH of system be 13, in 0.5h is extracted at 110 DEG C, heating extraction offal is filtered, and filtrate is extract solution,
It is 4.5 to adjust extracting liquid pH value with citric acid, and it is 80% to add ethanol to system ethanol volumetric concentration, refluxing extraction 3h, suction filtration,
Supernatant is taken, by supernatant concentration to the concentrate that solid content weight content is 50%；
S2. 250g concentrates are taken, 2g arginine, 1g glycine, 1g threonines, 5g glucose, 9g maltose, 5g is added really
Sugar, 5g xyloses, stirring and dissolving are uniform, add 20g mixing natural perfume material (10% osmanthus concrete alcoholic solution:Apple extract:Crow
Plum medicinal extract=4:4:1, mass ratio), it is well mixed；
S3. add the pH value of NaOH regulation mixed solution to 7,2h is reacted under the conditions of 90 DEG C, through Maillard reaction
Prepare tobacco aromaticss.
That investigates prepared spices smells fragrant feature, the results are shown in Table 1.
By with the tobacco aromaticss water dissolves of the ratio of tobacco quality 20% into 10% concentration (mass concentration) solution, and add
In pipe tobacco, cigarette is fabricated to, the group of smokeing panel test smokes panel test through specialty, smoking result is shown in Table 2.
Embodiment 12
S1. offal is crushed to 100 mesh, takes offal 500g and is placed in container, adds 2500mL water, is uniformly dispersed, and adds hydrogen
Potassium oxide, regulation feed liquid makes the pH of system be 9, and in 6h is extracted at 110 DEG C, heating extraction offal is filtered, and filtrate is extract solution,
It is 7 to adjust extracting liquid pH value with citric acid, and it is 40% to add ethanol to system ethanol volumetric concentration, and refluxing extraction 1h, suction filtration takes
Supernatant, by supernatant concentration to the concentrate that solid content weight content is 35%；
S2. 250g concentrates are taken, 2g arginine, 1g glycine, 5g glucose, 9g maltose is added, stirring and dissolving are uniform,
Add 20g mixing natural perfume material (10% osmanthus concrete alcoholic solution:Apple extract:Dark plum medicinal extract=4:4:1, mass ratio),
It is well mixed；
S3. add the pH value of NaOH regulation mixed solution to 9,2h is reacted under the conditions of 90 DEG C, through Maillard reaction
Prepare tobacco aromaticss.
That investigates prepared spices smells fragrant feature, the results are shown in Table 1.
By with the tobacco aromaticss water dissolves of the ratio of tobacco quality 1.5% into 10% concentration (mass concentration) solution, and add
It is added in pipe tobacco, is fabricated to cigarette, the group of smokeing panel test smokes panel test through specialty, smoking result is shown in Table 2.
Embodiment 13
S1. offal is crushed to 80 mesh, takes offal 500g and is placed in container, adds 8000mL water, is uniformly dispersed, and adds hydrogen-oxygen
Change potassium, regulation feed liquid makes the pH of system be 13, in 0.5h is extracted at 110 DEG C, heating extraction offal is filtered, and filtrate is extract solution,
It is 4.5 to adjust extracting liquid pH value with citric acid, and it is 80% to add ethanol to system ethanol volumetric concentration, refluxing extraction 3h, suction filtration,
Supernatant is taken, by supernatant concentration to the concentrate that solid content weight content is 50%；
S2. 250g concentrates are taken, 8.3g arginine, 4.2g glycine, 5g glucose, 9g maltose, stirring and dissolving is added
Uniformly, 20g mixing natural perfume material (10% osmanthus concrete alcoholic solution is added:Apple extract:Dark plum medicinal extract=4:4:1, quality
Than), it is well mixed；
S3. add the pH value of NaOH regulation mixed solution to 7,2h is reacted under the conditions of 90 DEG C, through Maillard reaction
Prepare tobacco aromaticss.
That investigates prepared spices smells fragrant feature, the results are shown in Table 1.
By with the tobacco aromaticss water dissolves of the ratio of tobacco quality 1.5% into 10% concentration (mass concentration) solution, and add
It is added in pipe tobacco, is fabricated to cigarette, the group of smokeing panel test smokes panel test through specialty, smoking result is shown in Table 2.
Embodiment 14
S1. offal is crushed to 80 mesh, takes offal 500g and is placed in container, adds 8000mL water, is uniformly dispersed, and adds hydrogen-oxygen
Change potassium, regulation feed liquid makes the pH of system be 13, in 0.5h is extracted at 110 DEG C, heating extraction offal is filtered, and filtrate is extract solution,
It is 4.5 to adjust extracting liquid pH value with citric acid, and it is 80% to add ethanol to system ethanol volumetric concentration, refluxing extraction 3h, suction filtration,
Supernatant is taken, by supernatant concentration to the concentrate that solid content weight content is 50%；
S2. 250g concentrates are taken, 2g arginine, 1g glycine, 18g glucose, 32g maltose is added, stirring and dissolving is equal
It is even, add 20g mixing natural perfume material (10% osmanthus concrete alcoholic solution:Apple extract:Dark plum medicinal extract=4:4:1, quality
Than), it is well mixed；
S3. add the pH value of NaOH regulation mixed solution to 7,2h is reacted under the conditions of 90 DEG C, through Maillard reaction
Prepare tobacco aromaticss.
That investigates prepared spices smells fragrant feature, the results are shown in Table 1.
By with the tobacco aromaticss water dissolves of the ratio of tobacco quality 1.5% into 10% concentration (mass concentration) solution, and add
It is added in pipe tobacco, is fabricated to cigarette, the group of smokeing panel test smokes panel test through specialty, smoking result is shown in Table 2.
Comparative example 1
S1. offal is crushed to 80 mesh, takes offal 500g and is placed in container, adds 8000mL water, is uniformly dispersed, and adds hydrogen-oxygen
Change potassium, regulation feed liquid makes the pH of system be 13, in 0.5h is extracted at 110 DEG C, heating extraction offal is filtered, and filtrate is extract solution,
It is 4.5 to adjust extracting liquid pH value with citric acid, and it is 80% to add ethanol to system ethanol volumetric concentration, refluxing extraction 3h, suction filtration,
Supernatant is taken, by supernatant concentration to the concentrate that solid content weight content is 50%；
S2. 250g concentrates are taken, 2g arginine, 1g glycine, 5g glucose, 9g maltose, stirring and dissolving mixing is added
Uniformly；S3. add the pH value of NaOH regulation mixed solution to 7,2h is reacted under the conditions of 90 DEG C, prepared through Maillard reaction
Tobacco aromaticss.
That investigates prepared spices smells fragrant feature, the results are shown in Table 1.
By with the tobacco aromaticss water dissolves of the ratio of tobacco quality 1.5% into 10% concentration (mass concentration) solution, and add
It is added in pipe tobacco, is fabricated to cigarette, the group of smokeing panel test smokes panel test through specialty, smoking result is shown in Table 2.
Comparative example 2
S1. offal is crushed to 80 mesh, takes offal 500g and is placed in container, adds 8000mL water, is uniformly dispersed, and adds hydrogen-oxygen
Change potassium, regulation feed liquid makes the pH of system be 13, in 0.5h is extracted at 110 DEG C, heating extraction offal is filtered, and filtrate is extract solution,
It is 4.5 to adjust extracting liquid pH value with citric acid, and it is 80% to add ethanol to system ethanol volumetric concentration, refluxing extraction 3h, suction filtration,
Supernatant is taken, by supernatant concentration to the concentrate that solid content weight content is 50%；
S2. 250g concentrates are taken, 2g arginine, 1g glycine, 5g glucose, 9g maltose is added, stirring and dissolving are uniform,
Add 20g mixing natural perfume material (10% osmanthus concrete alcoholic solution:Dark plum medicinal extract=4:1, mass ratio), it is well mixed；
S3. add the pH value of NaOH regulation mixed solution to 7,2h is reacted under the conditions of 90 DEG C, through Maillard reaction
Prepare tobacco aromaticss.
That investigates prepared spices smells fragrant feature, the results are shown in Table 1.
By with the tobacco aromaticss water dissolves of the ratio of tobacco quality 1.5% into 10% concentration (mass concentration) solution, and add
It is added in pipe tobacco, is fabricated to cigarette, the group of smokeing panel test smokes panel test through specialty, smoking result is shown in Table 2.
It is preparation-obtained to above-described embodiment and comparative example using the cigarette without any tobacco aromaticss as blank example
Cigarette carries out suction and comments, and smell fragrant feature and the cigarette of spices are inhaled and comment its result as follows：
The spices of table 1 smells fragrant feature
The cigarette of table 2 is inhaled and comments result
Be can be seen that from the contrast of above-described embodiment and comparative example 1 increases mixed by during tobacco aromaticss are prepared
Natural perfume material is closed, can make the fragrance of tobacco aromaticss increases the notes such as fruity, sour perfume, the fragrance of a flower, while cigarette cigarette perfume can also be enriched,
Excitant is reduced, and obtains suitable fruity, sour perfume (or spice) etc..And understood according to embodiment and the contrast of comparative example 2, if mixing natural perfume
Osmanthus concrete and dark plum medicinal extract are only added in material, it is jointly anti-with apple extract due to having lacked during Maillard reaction
Should so that in addition to sour fragrant note feature, in smoking cigarette, it is sweet that its flue gas lacks fruit to preparation-obtained tobacco aromaticss
Fragrant and acid is fragrant, and flue gas is slightly loose to be dissipated and there are no improvement at the aspect such as excitant and pleasant impression comfort.
Embodiment 1,4,8 for it is different mixing natural perfume material consumptions situations, from these embodiments smell fragrant characteristic results can
Know, the fruity in tobacco aromaticss fragrance is mainly derived from the apple extract in mixing natural perfume material, and the fragrance of a flower is from mixing day
Osmanthus concrete in right spices, dark plum medicinal extract further enriches the fragrance of tobacco aromaticss.By controlling mixing natural perfume material
Consumption can obtain the notes such as fruity, sour perfume, the fragrance of a flower of varying strength.When the large usage quantity of natural perfume material is mixed, i.e., when mixed
When the consumption for closing natural perfume material is 8%~10% (embodiment 1 and embodiment 8), fruity, fragrant and the fragrance of a flower the intensity of acid can be obtained
It is obvious to improve.
It is the situation of different carbohydrate compound amounts from embodiment 1,3,7, knowable to these embodiments, saccharide compound
Consumption smells fragrant performance and produces influence on mixing natural perfume material.When the consumption of saccharide compound is higher, i.e., when saccharide compound is used
Measure for the 20%~40% of concentrate weight when, spices is respectively provided with fragrant and sweet feature.
Embodiment 1,2,6 is the situation of different aminoacids consumption, knowable to these embodiments, when the consumption of amino acid is higher
When, i.e., when the consumption of amino acid is the 5%~7% of concentrate weight, prepared spices acid perfume (or spice) is changed into fragrant and sweet.Additionally,
Also there is just fragrant and sweet and slightly Hui Tian when suction is commented.
Obviously, the above embodiment of the present invention is only intended to clearly illustrate example of the present invention, and is not right
The restriction of embodiments of the present invention.For those of ordinary skill in the field, may be used also on the basis of the above description
To make other changes in different forms.There is no need and unable to be exhaustive to all of implementation method.It is all this
Any modification, equivalent and improvement made within the spirit and principle of invention etc., should be included in the claims in the present invention
Protection domain within.
Claims (10)
1. a kind of preparation method of the thermal response tobacco aromaticss with tobacco fruity note, it is characterised in that comprise the following steps：
S1. the concentrate of the offal extract solution that solid content weight content is 35~65% is prepared；
S2. toward add in concentrate the amino acid of concentrate weight 0.5%~7%, 5%~40% saccharide compound and 1~
10% mixing natural perfume material, it is well mixed to form mixed liquor；
S3. to 7~9,90~130 DEG C of temperature control reacts 1~5h to the pH value of regulation mixed solution, and preparing cigarette through Maillard reaction uses
Spices；
Wherein described mixing natural perfume material is the mixture of osmanthus concrete, apple extract and dark plum medicinal extract.
2. preparation method according to claim 1, it is characterised in that amino acid is arginine, sweet ammonia in the step S2
Acid, threonine two or more.
3. preparation method according to claim 1, it is characterised in that in the step S2 saccharide compound be glucose,
One or more in xylose, maltose, fructose.
4. preparation method according to claim 1, it is characterised in that osmanthus concrete, apple in the mixing natural perfume material
The mass ratio of extract and dark plum medicinal extract is：Osmanthus concrete:Apple extract:Dark plum medicinal extract=0.4:4:1.
5. preparation method according to claim 1, it is characterised in that the consumption of amino acid is concentrate in the step S2
The 5%~7% of weight.
6. preparation method according to claim 1, it is characterised in that the consumption of saccharide compound is dense in the step S2
The 20%~40% of contracting liquid weight.
7. preparation method according to claim 1, it is characterised in that the consumption for mixing natural perfume material in the step S2 is
The 8%~10% of concentrate weight.
8. the tobacco aromaticss that prepared by the preparation method described in claim 1 to 7 any one.
9. application of the tobacco aromaticss described in claim 8 in cigarette is prepared.
10. application according to claim 9, it is characterised in that tobacco aromaticss are added in pipe tobacco, the tobacco aromaticss
Addition for tobacco quality 0.5~30 ‰.
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| CN108013499A (en) * | 2017-12-29 | 2018-05-11 | 深圳睿思奇科技开发有限公司 | One grow tobacco taste tobacco tar preparation method and with this method prepare tobacco tar |
| CN108998246A (en) * | 2018-09-02 | 2018-12-14 | 王婧婧 | A kind of preparation method of fragrance of a flower fragrance |
| CN111887469A (en) * | 2019-05-05 | 2020-11-06 | 贵州中烟工业有限责任公司 | Preparation method of burley tobacco additive |
| CN112469284A (en) * | 2018-07-25 | 2021-03-09 | 奇华顿股份有限公司 | Citrus flavor composition, use thereof and method for improving organoleptic properties |
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| CN103045369A (en) * | 2012-11-08 | 2013-04-17 | 广东中烟工业有限责任公司 | Preparation method for reaction type spice for cigarette and application of reaction type spice to cigarette |
| CN103564646A (en) * | 2012-07-18 | 2014-02-12 | 朱大恒 | Production method of tobacco extractum and use thereof |
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| CN103564646A (en) * | 2012-07-18 | 2014-02-12 | 朱大恒 | Production method of tobacco extractum and use thereof |
| CN103045369A (en) * | 2012-11-08 | 2013-04-17 | 广东中烟工业有限责任公司 | Preparation method for reaction type spice for cigarette and application of reaction type spice to cigarette |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN108013499A (en) * | 2017-12-29 | 2018-05-11 | 深圳睿思奇科技开发有限公司 | One grow tobacco taste tobacco tar preparation method and with this method prepare tobacco tar |
| CN112469284A (en) * | 2018-07-25 | 2021-03-09 | 奇华顿股份有限公司 | Citrus flavor composition, use thereof and method for improving organoleptic properties |
| CN108998246A (en) * | 2018-09-02 | 2018-12-14 | 王婧婧 | A kind of preparation method of fragrance of a flower fragrance |
| CN111887469A (en) * | 2019-05-05 | 2020-11-06 | 贵州中烟工业有限责任公司 | Preparation method of burley tobacco additive |
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Application publication date: 20170609 |