CN106811185A - A kind of PS lignin gel-type profile control agent and preparation method thereof - Google Patents
A kind of PS lignin gel-type profile control agent and preparation method thereof Download PDFInfo
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- CN106811185A CN106811185A CN201710020279.3A CN201710020279A CN106811185A CN 106811185 A CN106811185 A CN 106811185A CN 201710020279 A CN201710020279 A CN 201710020279A CN 106811185 A CN106811185 A CN 106811185A
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- agent
- profile control
- gel
- type profile
- lignin
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K8/00—Compositions for drilling of boreholes or wells; Compositions for treating boreholes or wells, e.g. for completion or for remedial operations
- C09K8/50—Compositions for plastering borehole walls, i.e. compositions for temporary consolidation of borehole walls
- C09K8/504—Compositions based on water or polar solvents
- C09K8/506—Compositions based on water or polar solvents containing organic compounds
- C09K8/508—Compositions based on water or polar solvents containing organic compounds macromolecular compounds
- C09K8/512—Compositions based on water or polar solvents containing organic compounds macromolecular compounds containing cross-linking agents
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/24—Crosslinking, e.g. vulcanising, of macromolecules
- C08J3/246—Intercrosslinking of at least two polymers
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L97/00—Compositions of lignin-containing materials
- C08L97/005—Lignin
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2397/00—Characterised by the use of lignin-containing materials
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2433/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers
- C08J2433/24—Homopolymers or copolymers of amides or imides
- C08J2433/26—Homopolymers or copolymers of acrylamide or methacrylamide
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- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Sealing Material Composition (AREA)
Abstract
The present invention relates to a kind of PS lignin gel-type profile control agent.Mainly solve the problems, such as that existing profile control agent initial viscosity is high, the profile control term of validity is short, efficiency is low causes profile control effect poor for closure.It is characterized in that:Its component and proportioning are as follows by weight percentage:High molecular polymer 0.5 1.5%, gel 1 10%, deflocculant 0.2 2.0%, reducing agent 0.2 2.0%, intercalating agent 0.2 0.6%, retarder 0 1.0%, crosslinking agent 0.5 1.5%, remaining be water;The preparation method of the gel-type profile control agent is first to add water in a reservoir, sequentially adds gel, deflocculant, reducing agent, intercalating agent, after circulation stirring half an hour at normal temperatures and pressures, then high molecular polymer is sprinkled into, stirred 2 hours, place 8 hours, A agent is obtained;Crosslinking agent and water are pressed 1 simultaneously:1 ratio is completely dissolved prepared B agent;A agent is added into retarder before injection, then again B agent is added thereto, stirred.The PS lignin gel-type profile control agents, the profile control term of validity is long, it is good to block efficiency high, profile control effect.
Description
Technical field
The present invention relates to a kind of inorganic agent in oil extraction in oil field technical field, especially a kind of PS lignin gel-type profile control agent
And preparation method thereof.
Background technology
Most of current oil field uses waterflooding extraction, due to washing away for injection water, makes the inhomogeneity of oil reservoir over time
Passage and aggravate.The heterogeneity of oil reservoir, make injection water usually be absorbed by high permeability zone, in order in playing, less permeable layer
Effect, improves the intake profile for being related to coefficient, must just adjusting Deplug of injection water, i.e. profile control namely seals profile control agent
Stifled high permeability zone, reduces the water absorbing capacity of high permeability zone, so that hydrologic(al) budget injection profile.The profile control agent of application is due to first at present
Beginning viscosity it is high and cause profile control agent enter non-profile control target zone, and then to non-closure site pollute;Gel strength is low, colloid is unstable
Fixed, the easy syneresis of colloid, so as to cause the term of validity of profile control short, closure efficiency is low, and profile control effect is poor.
The content of the invention
The invention reside in overcoming, existing profile control agent initial viscosity present in background technology is high, the profile control term of validity is short, closure
Efficiency is low to cause the problem of profile control effect difference, and provides a kind of PS lignin gel-type profile control agent.The PS lignin gel-type is adjusted
Agent is cutd open, the profile control term of validity is long, it is good to block efficiency high, profile control effect.Present invention also offers a kind of PS lignin gel-type profile control
The preparation method of agent.
The present invention solves its problem can be reached by following technical solution:The PS lignin gel-type profile control agents, its group
Divide and match as follows by weight percentage:High molecular polymer 0.5-1.5%, gel 1-10%, deflocculant 0.2-2.0%,
Reducing agent 0.2-2.0%, intercalating agent 0.2-0.6%, retarder 0-1.0%, crosslinking agent 0.5-1.5%, remaining be water.Described percentage
Than being counted as 100% with the gross weight of lignin gel-type profile control agent.
The high molecular polymer molecular weight is 1200-1600 ten thousand, the polyacrylamide of degree of hydrolysis 20-30%;The gel
Agent is calcium lignosulfonate, and deflocculant is thiocarbamide;Crosslinking agent is sodium dichromate;Reducing agent is anhydrous sodium sulfite;Intercalating agent
It is tetrasodium ethylenediamine tetraacetate;Retarder is sodium citrate.
The present invention also provides a kind of preparation method of PS lignin gel-type profile control agent, adds water, again in a reservoir first
Sequentially add under the normal temperature and pressure of gel, deflocculant, reducing agent, intercalating agent after circulation stirring half an hour, then slowly spread
Enter high molecular polymer, circulation stirring 2 hours is placed 8 hours, is lignin gel-type profile control agent A agent;Simultaneously by crosslinking agent with
Water presses 1:1 ratio is dissolved completely in another container, is lignin gel-type profile control agent B agent;A agent is added into slow setting before injection
, be added thereto for B agent again then by agent, stirs.Product Applicable temperature is 30-65 DEG C.
PS lignin gel-type profile control agents are certain by polyacrylamide (PAM) and calcium lignosulfonate (Ca-LS)
Under the conditions of by the modified new chemical agent formed with grafting as gel-forming substance.In the presence of heat and crosslinking agent, polypropylene
There is condensation reaction in acid amides and calcium lignosulfonate, generate a kind of new gel-forming substance PAM-Ca-LS (being abbreviated as PS).
It is of the invention to be had the advantages that compared with above-mentioned background technology:The PS lignin gel-type profile control agents,
Ground viscosity is small, and gel time is adjustable, and gel strength is big, product plastic stabilization, is difficult syneresis, the water plugging and profile controlling term of validity
It is long, block efficiency high.Behind product injection stratum, using three big mechanism such as physics person blocking, power trapping and absorption, preferably seal
Stifled injectivity index interval high, realizes adjustment intake profile, the purpose of Efficient Development.Product cost is low, and construction technology is easy, can
Pump is strong.
Specific embodiment:
Below in conjunction with specific embodiment, the invention will be further described:
Embodiment 1:
Add 471.0g water in a reservoir first, sequentially add 10g gels calcium lignosulfonate, 2.0g deflocculant sulphur
Urea, 2.5g reducing agents anhydrous sodium sulfite, 2.0g intercalating agent tetrasodium ethylenediamine tetraacetates, circulation stirring half an hour under normal temperature and pressure
Afterwards, then slowly 4.0g macromolecule copolymer polyacrylamides are sprinkled into, circulation stirring 2 hours is placed 8 hours, is lignin gel
Type profile control agent A agent;4.0g crosslinking agents sodium dichromate is dissolved completely in another container with 4.0g water simultaneously, is lignin gel-type
Profile control agent B agent;A agent is added into 0.5g retarder sodium citrates before injection, then again B agent is added thereto, stirred
500g products.It is 150.0mPas to test base fluid apparent viscosity with rotation viscometer.Then product is put into 50 DEG C of baking oven
Reaction, test gelation time 5 hours;It is 43800 mPas into adhesiveness.
Embodiment 2:
Add 452.5g water in a reservoir first, sequentially add 20g gels calcium lignosulfonate, 2.5g deflocculant sulphur
Urea, 2.5g reducing agents anhydrous sodium sulfite, 2.0g intercalating agent tetrasodium ethylenediamine tetraacetates, circulation stirring half an hour under normal temperature and pressure
Afterwards, then slowly 6.0g macromolecule copolymer polyacrylamides are sprinkled into, circulation stirring 2 hours is placed 8 hours, is lignin gel
Type profile control agent A agent;6.0g crosslinking agents sodium dichromate is dissolved completely in another container with 6.0g water simultaneously, is lignin gel-type
Profile control agent B agent;A agent is added into 2.5g retarder sodium citrates before injection, then again B agent is added thereto, stirred
500g products.It is 230.0mPas to test base fluid apparent viscosity with rotation viscometer.Then product is put into 50 DEG C of baking oven
Reaction, test gelation time 24 hours.It is 38200 mPas into adhesiveness.
PS lignin gel-type profile control agents prepared by above-described embodiment 1-2, Applicable temperature is 30-65 DEG C, product injection ground
After layer, injectivity index interval high is preferably blocked, realize adjustment intake profile, the purpose of Efficient Development.
Claims (4)
1. a kind of PS lignin gel-type profile control agent, it is characterised in that:Its component and proportioning are as follows by weight percentage:Macromolecule
Polymer 0.5-1.5%, gel 1-10%, deflocculant 0.2-2.0%, reducing agent 0.2-2.0%, intercalating agent 0.2-0.6%,
Retarder 0-1.0%, crosslinking agent 0.5-1.5%, remaining be water.
2. a kind of PS lignin gel-type profile control agent according to claim 1, it is characterised in that:The high molecular polymer
Molecular weight is 1200-1600 ten thousand, the polyacrylamide of degree of hydrolysis 20-30%.
3. a kind of PS lignin gel-type profile control agent according to claim 1, it is characterised in that:The gel is wooden
Plain sulfoacid calcium, deflocculant is thiocarbamide;Crosslinking agent is sodium dichromate;Reducing agent is anhydrous sodium sulfite;Intercalating agent is ethylenediamine
The sodium of tetraacethyl four;Retarder is sodium citrate.
4. a kind of a kind of preparation method of PS lignin gel-type profile control agent according to claim 1, it is characterised in that:First
Water is added in a reservoir, sequentially adds gel, deflocculant, reducing agent, intercalating agent, at normal temperatures and pressures circulation stirring
After half an hour, then high molecular polymer is sprinkled into, circulation stirring 2 hours is placed 8 hours, is lignin gel-type profile control agent A agent;
Crosslinking agent and water are pressed 1 simultaneously:1 ratio is dissolved completely in another container, is lignin gel-type profile control agent B agent;Before injection
A agent is added into retarder, then again B agent is added thereto, stirred.
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Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN114437688A (en) * | 2020-11-02 | 2022-05-06 | 中国石油化工股份有限公司 | Plugging agent raw material composition, polymer gel plugging agent, preparation method and application of polymer gel plugging agent and oil reservoir exploitation method |
CN114672292A (en) * | 2020-12-24 | 2022-06-28 | 中国石油化工股份有限公司 | High-temperature-resistant composite plugging and blending agent as well as preparation method and application thereof |
WO2022134839A1 (en) * | 2020-12-24 | 2022-06-30 | 中国石油化工股份有限公司 | Plugging agent for oil extraction in oilfield and a preparation method therefor and application thereof |
CN115725283A (en) * | 2021-08-31 | 2023-03-03 | 中国石油化工股份有限公司 | Lignin-based composite channeling sealing agent and preparation method and application thereof |
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RU2155861C1 (en) * | 1999-11-30 | 2000-09-10 | Глобал Ойлрековери Лимитед | Aerated viscoelastic composition |
CN102002351A (en) * | 2010-09-16 | 2011-04-06 | 中国海洋石油总公司 | Selective chemical water shutoff agent for gravel-packed well |
CN103498643A (en) * | 2013-10-23 | 2014-01-08 | 天津亿利科能源科技发展股份有限公司 | Composite slug deep water plugging method for oil pool with high water content |
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Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN114437688A (en) * | 2020-11-02 | 2022-05-06 | 中国石油化工股份有限公司 | Plugging agent raw material composition, polymer gel plugging agent, preparation method and application of polymer gel plugging agent and oil reservoir exploitation method |
CN114437688B (en) * | 2020-11-02 | 2023-04-11 | 中国石油化工股份有限公司 | Plugging agent raw material composition, polymer gel plugging agent, preparation method and application of polymer gel plugging agent and oil reservoir exploitation method |
CN114672292A (en) * | 2020-12-24 | 2022-06-28 | 中国石油化工股份有限公司 | High-temperature-resistant composite plugging and blending agent as well as preparation method and application thereof |
WO2022134839A1 (en) * | 2020-12-24 | 2022-06-30 | 中国石油化工股份有限公司 | Plugging agent for oil extraction in oilfield and a preparation method therefor and application thereof |
CN114672292B (en) * | 2020-12-24 | 2023-05-30 | 中国石油化工股份有限公司 | High-temperature-resistant composite plugging agent and preparation method and application thereof |
EP4261265A4 (en) * | 2020-12-24 | 2024-06-12 | China Petroleum & Chem Corp | Plugging agent for oil extraction in oilfield and a preparation method therefor and application thereof |
CN115725283A (en) * | 2021-08-31 | 2023-03-03 | 中国石油化工股份有限公司 | Lignin-based composite channeling sealing agent and preparation method and application thereof |
CN115725283B (en) * | 2021-08-31 | 2024-02-13 | 中国石油化工股份有限公司 | Lignin-based composite channeling sealing agent and preparation method and application thereof |
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