CN106811044A - The interior wall coating of decomposing formaldehyde - Google Patents

The interior wall coating of decomposing formaldehyde Download PDF

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Publication number
CN106811044A
CN106811044A CN201510861176.0A CN201510861176A CN106811044A CN 106811044 A CN106811044 A CN 106811044A CN 201510861176 A CN201510861176 A CN 201510861176A CN 106811044 A CN106811044 A CN 106811044A
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CN
China
Prior art keywords
parts
interior wall
chelate
titanium dioxide
wall coating
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201510861176.0A
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Chinese (zh)
Inventor
王颖
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Qingdao Hongtai Litian Amperex Technology Ltd
Original Assignee
Qingdao Hongtai Litian Amperex Technology Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Qingdao Hongtai Litian Amperex Technology Ltd filed Critical Qingdao Hongtai Litian Amperex Technology Ltd
Priority to CN201510861176.0A priority Critical patent/CN106811044A/en
Publication of CN106811044A publication Critical patent/CN106811044A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/02Elements
    • C08K3/08Metals
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/34Silicon-containing compounds
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D125/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Coating compositions based on derivatives of such polymers
    • C09D125/02Homopolymers or copolymers of hydrocarbons
    • C09D125/04Homopolymers or copolymers of styrene
    • C09D125/08Copolymers of styrene
    • C09D125/14Copolymers of styrene with unsaturated esters
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04Polyurethanes
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/32Radiation-absorbing paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2237Oxides; Hydroxides of metals of titanium
    • C08K2003/2241Titanium dioxide
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives

Abstract

The present invention relates to coatings industry technical field, particularly a kind of interior wall coating of decomposing formaldehyde.It is made up of the raw material of following mass parts:Film forming binder 50-60 parts, filler 30-40 parts, diatomite 10-20 parts, photocatalyst 2-5 parts, pigment 20-30 parts, auxiliary agent 0.5-2 parts, the photocatalyst is nano-noble metal-titanium dioxide chelate, and its average grain diameter is 5-20 nanometers.Compared with prior art, the interior wall coating of decomposing formaldehyde of the invention, with nano-noble metal-titanium dioxide chelate as photocatalyst so that formaldehyde can be decomposed under the even infrared light action of natural light, visible ray, substantially increase the effect of decomposing formaldehyde.

Description

The interior wall coating of decomposing formaldehyde
Technical field
The present invention relates to coatings industry technical field, particularly a kind of interior wall coating of decomposing formaldehyde.
Background technology
Interior wall coating has construction simple, there is multiple color tones, preferably intersperses various ornaments thereon, decorative effect simplicity generosity, It is current most widely used decorative material for internal wall.China's development and production since the eighties, so far existing tens kind types Number, its key property is identical, is substantially made up of water, pigment, emulsion, filler and various auxiliary agents.But it is this by emulsion, The interior wall coating that auxiliary agent etc. is made, has the shortcomings that VOC emission, contains heavy metal.With the continuous progress of society, people couple Interior wall coating has requirement higher, and except dicoration, people more focus on the feature of environmental protection and high-performance.In the prior art, typically will Photocatalyst is added in coating to decompose indoor formaldehyde, and in all of photocatalyst material, nano TiO 2 not only has light very high Catalysis activity, and there is acid-alkali-corrosive-resisting, resistant to chemical etching, nontoxic, price is also moderate, thus in the market makes mostly With nano titanium oxide as main raw material(s).But pure nano titanium dioxide powder, can only absorb the purple of below 400nm Outer light, under natural environment, ultraviolet light occupies that ratio is relatively low, and the 10% of not enough natural light, thus pure nano titanium oxide Effect of photocatalyst is very low.
The content of the invention
It is an object of the invention to the drawbacks described above for overcoming prior art to exist, there is provided a kind of,
The present invention is realized using following technical scheme:
A kind of interior wall coating of decomposing formaldehyde, is made up of the raw material of following mass parts:Film forming binder 50-60 parts, filler 30-40 Part, diatomite 10-20 part, photocatalyst 2-5 parts, pigment 20-30 parts, auxiliary agent 0.5-2 parts, the photocatalyst for nanometer it is expensive Metal-titanium dioxide chelate, its average grain diameter is 5-20 nanometers.
The nano-noble metal-titanium dioxide chelate be Platinum Nanoparticles-titanium dioxide chelate, Technique of Nano Pd-titanium dioxide chelate or Person's nanometer rhodium-titanium dioxide chelate.
The film forming binder is water-soluble for polyurethane resin, acrylic resin, vinylacetate or Styrene-acrylic copolymer Liquid.
The auxiliary agent is self-dispersing agent, levelling agent, wetting agent, defoamer, bactericide, pH adjusting agent, delustering agent and thickener In one or more.
Nano-noble metal is after such as platinum, rhodium, palladium and photocatalyst material carry out coordination chelating, can be greatly improved photo-generated carrier point From efficiency and suppress electron-hole and be combined again, so as to further widen the light wave absorption region of titanium dioxide.
The beneficial effects of the invention are as follows:Compared with prior art, the interior wall coating of decomposing formaldehyde of the invention, with nano-noble metal- Titanium dioxide chelate is photocatalyst so that formaldehyde can be decomposed under the even infrared light action of natural light, visible ray, greatly The big effect that improve decomposing formaldehyde.
Specific embodiment
With reference to embodiment, the present invention will be further described.
Embodiment 1
A kind of interior wall coating of decomposing formaldehyde, is made up of the raw material of following mass parts:50 parts of the polyurethane resin aqueous solution, filler 30 parts, 10 parts of diatomite, Platinum Nanoparticles -2 parts of titanium dioxide chelate that average grain diameter is 5 nanometers, 20 parts of pigment, dispersion Totally 0.5 part of agent, levelling agent, wetting agent, defoamer, bactericide, pH adjusting agent, delustering agent and thickener.
Embodiment 2
A kind of interior wall coating of decomposing formaldehyde, is made up of the raw material of following mass parts:60 parts of acrylic resin aqueous solution, filler 40 parts, 20 parts of diatomite, Technique of Nano Pd -5 parts of titanium dioxide chelate that average grain diameter is 20 nanometers, 30 parts of pigment, dispersion Agent, levelling agent, wetting agent, defoamer, bactericide, totally 2 parts.
Embodiment 3
A kind of interior wall coating of decomposing formaldehyde, is made up of the raw material of following mass parts:The Styrene-acrylic copolymer aqueous solution 55 Part, 35 parts of filler, 15 parts of diatomite, Technique of Nano Pd -4 parts of titanium dioxide chelate, the pigment 25 that average grain diameter is 15 nanometers Part, dispersant, levelling agent, bactericide, totally 1 part.

Claims (4)

1. a kind of interior wall coating of decomposing formaldehyde, is made up of the raw material of following mass parts:Film forming binder 50-60 parts, filler 30-40 Part, diatomite 10-20 parts, photocatalyst 2-5 parts, pigment 20-30 parts, auxiliary agent 0.5-2 parts, it is characterised in that the light Catalyst is nano-noble metal-titanium dioxide chelate, and its average grain diameter is 5-20 nanometers.
2. the interior wall coating of decomposing formaldehyde according to claim 1, it is characterised in that the nano-noble metal-titanium dioxide Chelate is Platinum Nanoparticles-titanium dioxide chelate, Technique of Nano Pd-titanium dioxide chelate or nanometer rhodium-titanium dioxide chelate.
3. the interior wall coating of decomposing formaldehyde according to claim 1, it is characterised in that the film forming binder is polyurethane tree The aqueous solution of fat, acrylic resin, vinylacetate or Styrene-acrylic copolymer.
4. the interior wall coating of decomposing formaldehyde according to claim 1, it is characterised in that the auxiliary agent is self-dispersing agent, stream One or more in flat agent, wetting agent, defoamer, bactericide, pH adjusting agent, delustering agent and thickener.
CN201510861176.0A 2015-11-30 2015-11-30 The interior wall coating of decomposing formaldehyde Pending CN106811044A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201510861176.0A CN106811044A (en) 2015-11-30 2015-11-30 The interior wall coating of decomposing formaldehyde

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201510861176.0A CN106811044A (en) 2015-11-30 2015-11-30 The interior wall coating of decomposing formaldehyde

Publications (1)

Publication Number Publication Date
CN106811044A true CN106811044A (en) 2017-06-09

Family

ID=59107427

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201510861176.0A Pending CN106811044A (en) 2015-11-30 2015-11-30 The interior wall coating of decomposing formaldehyde

Country Status (1)

Country Link
CN (1) CN106811044A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107163820A (en) * 2017-07-05 2017-09-15 合肥市片叶装饰工程有限公司 One kind removes formaldehyde indoor decorative paint and preparation method
CN113355568A (en) * 2021-06-09 2021-09-07 湖北美科精毅科技有限公司 Preparation process of aluminum alloy extruded section

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107163820A (en) * 2017-07-05 2017-09-15 合肥市片叶装饰工程有限公司 One kind removes formaldehyde indoor decorative paint and preparation method
CN113355568A (en) * 2021-06-09 2021-09-07 湖北美科精毅科技有限公司 Preparation process of aluminum alloy extruded section

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WD01 Invention patent application deemed withdrawn after publication

Application publication date: 20170609

WD01 Invention patent application deemed withdrawn after publication