CN106807333A - The production equipment of Ag-carried nanometer titanium dioxide aeroge - Google Patents
The production equipment of Ag-carried nanometer titanium dioxide aeroge Download PDFInfo
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- CN106807333A CN106807333A CN201610346703.9A CN201610346703A CN106807333A CN 106807333 A CN106807333 A CN 106807333A CN 201610346703 A CN201610346703 A CN 201610346703A CN 106807333 A CN106807333 A CN 106807333A
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- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/22—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material
- B01J20/24—Naturally occurring macromolecular compounds, e.g. humic acids or their derivatives
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- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/06—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising oxides or hydroxides of metals not provided for in group B01J20/04
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- B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
- B01J20/12—Naturally occurring clays or bleaching earth
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Abstract
The present invention relates to aeroge production technical field.A kind of production equipment of Ag-carried nanometer titanium dioxide airsetting, including bracket and 2 agitators being arranged on bracket, the agitator includes staving and agitator, the top of the staving is provided with charging aperture and bottom is provided with discharging opening, an agitator in 2 agitators is that high-order agitator, another are low level agitator, low level agitator is provided with Temperature controlled heater and ultrasonic vibrator, the discharging opening of high-order agitator links together with the charging aperture of low level agitator, the bracket is provided with wheel and wheel is lifted away from the hydraulic supporting feet on ground, and bracket is provided with suspension ring.The production equipment of convenient Ag-carried nanometer titanium dioxide aeroge when can easily carry out global transfer, make sol solutionses the invention provides a kind of equipment, inconvenience and equipment shift inconvenience when solving the problems, such as the sol solutionses of existing equipment making Ag-carried nanometer titanium dioxide aeroge.
Description
Technical field
The present invention relates to aeroge production technical field, more particularly to a kind of production equipment of Ag-carried nanometer titanium dioxide aeroge.
Background technology
At present, general the oil in water body is adsorbed using oil absorption material, what is at most used is high oil-absorbing resin.High oil-absorbing resin is the monomer crosslinked polymer of lipophile, intermolecular with three-dimensional crosslinked network shape structure, makes resin that swelling action to occur by the solvation of Intramolecular oil base segment and oil molecule.Because high oil-absorbing resin can only occur swelling without dissolving, therefore oil molecule will be carried in tridimensional network, realized high oil-absorbing resin oil suction and protected the function of oil.
The Chinese patent of Application No. CN201510692238.X discloses a kind of high oil-absorbing resin and preparation method thereof, and the high oil-absorbing resin includes following raw material in parts by weight：Oil phase is 4 ~ 8 parts of divinylbenzene, 20 ~ 30 parts of styrene, 20 ~ 30 parts of lauryl acrylate, 20 ~ 30 parts of butyl acrylate, 20 ~ 30 parts of butadiene rubber, 3 ~ 9 parts of azodiisobutyronitrile, 40 ~ 50 parts of toluene；Water is mutually 5 ~ 9 parts of polyvinyl alcohol, 10 ~ 20 parts of gelatin, NaCl5 ~ 8 part, CaCO35 ~ 10 parts, 500 ~ 600 parts of deionized water.
But high oil-absorbing resin there is also certain weak point, such as due to the porosity of high oil-absorbing resin is not sufficiently high enough, therefore the capacity of the oil suction of the high oil-absorbing resin of unit mass also receives certain limitation, and swelling rate is also not fast enough.Additionally, the density of high oil-absorbing resin is higher, the resin of unit volume is heavier, also not readily transportable, collection etc..The most key, high oil-absorbing resin can only be adsorbed oil product by physical action, but it can not degrade oil product, it is still necessary to wait oil product to be processed after recovery, not only inconvenient, also increase cost.Above-mentioned deficiency can be overcome if using aeroge.
In the production overload of aeroge, most basic processing step is obtained solution A and B, then carries out being mixed to prepare sol solutionses by solution A and B.The existing equipment for making aeroge is that solution A and B are made by the agitator being independently arranged, therefore inconvenience during transfer solution and equipment.
The content of the invention
The production equipment of convenient Ag-carried nanometer titanium dioxide aeroge when can easily carry out global transfer, make sol solutionses the invention provides a kind of equipment, inconvenience and equipment shift inconvenience when solving the problems, such as the sol solutionses of existing equipment making Ag-carried nanometer titanium dioxide aeroge.
Above technical problem is solved by following technical proposal：A kind of production equipment of Ag-carried nanometer titanium dioxide airsetting, it is characterized in that, including bracket and 2 agitators being arranged on bracket, the agitator includes staving and agitator, the top of the staving is provided with charging aperture and bottom is provided with discharging opening, an agitator in 2 agitators is high-order agitator, another is low level agitator, low level agitator is provided with Temperature controlled heater and ultrasonic vibrator, the discharging opening of high-order agitator links together with the charging aperture of low level agitator, the bracket is provided with wheel and wheel is lifted away from the hydraulic supporting feet on ground, bracket is provided with suspension ring, the inner peripheral surface of the suspension ring is provided with least two anti-slop serrations, the anti-slop serrations are detachably connected with the suspension ring, the anti-slop serrations are distributed along the bearing of trend of suspension ring.Due to two kinds of agitators are arranged on bracket in the way of high-low-position simultaneously, therefore convenient when solution B is transferred in solution A, low level agitator is provided with Temperature controlled heater and ultrasonic vibrator, further improves convenience when example makes sol solutionses.Two brackets are provided with wheel, and easily equipment can be shifted.Bracket is supported by hydraulic supporting feet when not shifting.During the lifting present invention, being hooked in suspension ring by suspension hook is carried out.Anti-slop serrations are set in the inner peripheral surface of suspension ring, anti-skidding effect can be played so that be not easy to slide during lifting.Anti-slop serrations are detachably connected between suspension ring, can be according to using needing selectivity to install anti-slop serrations, so that the present invention disclosure satisfy that and different use needs.
As preferred, the wheel includes spoke, it is connected to the wheel rim of spoke, it is connected to the inflation tyre and anti-tie mechanism for tire of wheel rim, the anti-tie mechanism for tire includes roller, air reservoir, the screw mandrel for wearing and being rotationally connected with roller and the thread bush being threaded on screw mandrel, the roller is coaxially fixed together with the wheel rim, inflation piston of the axis with the diameter parallel of the wheel rim is provided with the air reservoir, the air reservoir is isolated annular seal space by the inflation piston, the annular seal space is connected with the tire, the inflation piston is linked together by push rod with the thread bush, the roller be additionally provided with the prevention thread bush with the screw mandrel be axle relative to the spline structure that the roller is rotated；The wheel can by change the tire pressure of inflation tyre come when tire tyre surface along wheel rim radially beyond or less than the roller side face.Existing wheel has the following disadvantages：When the section with sharp objects of passing through（Hereinafter referred to as prick tire section）Shi Rongyi is produced and is rolled tire phenomenon, and the technical program solves the problem.When pricking tire section when to pass through, rotary screw rod, screw mandrel drives thread bush translation, and thread bush drives piston to be moved towards the direction for increasing annular seal space by push rod so that the gas in tire is flowed into annular seal space and causes the reduction of tire tire pressure.Piston particular location is：Piston is moved to tire pressure and is reduced to when tire is contacted with ground and flat can be supported by then passing through roller to the position being supported to vehicle by roller, so that tire will not be poked by sharp objects.When cross prick tire section after, rotate backward screw mandrel so that thread bush by push rod drive piston towards when the place that reduces of annular seal space it is mobile so that the gas in annular seal space is punched into tire again, and tire pressure is raised so that wheel is supported again through tire.
Preferably, the spline structure is the strip hole axially extending along wheel rim for being arranged at the roller, the push rod is arranged in the strip hole.Simple structure.
The wheel also includes making the box of tricks for producing speed discrepancy between the roller and screw mandrel, the screw mandrel includes input section and deferent segment, the input section and deferent segment are linked together by force-limiting device, the thread bush line is connected to the deferent segment, the box of tricks include being connected to the ring gear of roller, be connected to the input section and the external toothing in ring gear and the clutch gear that can be arranged to plug between ring gear and external toothing.When to drive inflation piston to move by screw mandrel, change-speed gearing is inserted between ring gear and external toothing and interior external toothing is meshed together, change-speed gearing is fixed on vehicle frame and prevents from being rotated with wheel.Now difference mechanism enables to screw mandrel and thread bush to produce the rotating speed of speed discrepancy and screw mandrel higher than the rotating speed of thread bush, so as to realize the translation of thread bush.Tire inflation/deflation can be carried out by the rotation of gear, laborsaving convenience during inflation/deflation.When piston moves to extreme position, the moment of torsion of screw mandrel can increase, and then produced between input section and deferent segment when increasing above the force-limiting device amount to be driven and rotate and cause to continue to obtain piston movement and realization is automatically stopped driving.
As preferred, the force-limiting device includes being connected to the first friction plate of the input section and is connected to the second friction plate of the deferent segment, first friction plate and the second friction plate are pushed against together, and the input section and deferent segment transmit power by the rubbing action between first friction plate and the second friction plate.Structure is individually compact.
As preferred, the agitator includes rotating shaft, the motor of drive shaft and is connected to some stirring vanes of rotating shaft, the rotating shaft vertically extends, the each stirring vane is respectively provided with a sliding sleeve being set in the rotating shaft, and the sliding sleeve is fixed together by lock-screw with the rotating shaft.Can be according to the height of material in staving, it is connected in the screwed hole of different height position come the change of the height and position for realizing stirring vane by by threaded connector, so that stirring vane can be located at material inside and is substantially homogeneously distributed along material depth direction, so as to not only avoid producing the exposed idle phenomenon of stirring vane but also can efficiently stirring material.
Present invention additionally comprises removable bindiny mechanism, the anti-slop serrations are detachably connected by the removable bindiny mechanism with the suspension ring, and the removable bindiny mechanism includes the driving spring for being arranged at the jack of the suspension ring, being movably connected on the inserted block of the anti-slop serrations and drive inserted block to be inserted into the jack.Convenience during installing/dismounting anti-slop serrations is good.
Preferably, the inserted block is spherical, the inserted block is mating spherical surfaces between the coupler body.Convenience during installing/dismounting anti-slop serrations can further be improved.
Preferably, the removable bindiny mechanism also includes support bowl, the driving spring is abutted together by the support bowl with the inserted block, is mating spherical surfaces between the support bowl and the inserted block.Patency when reliability and inserted block when can improve Spring driving inserted block are rotated.
Preferably, the face of the support inserted block of the support bowl is provided with specular layer.Patency when inserted block is rotated is good.
Preferably, the anti-slop serrations are provided with power-assisted hole.During the lower protection tooth of dismounting, by by the body of rod（Such as inner hexagon spanner）Cat-in resisting force hole China and foreign countries draw anti-slop serrations to be exerted oneself, and convenience during dismounting anti-slop serrations is good.
Preferably, the power-assisted hole position is on the end face in anti-slop serrations facewidth direction.Convenience when the insertion body of rod is in resistance hole is good.
Present invention tool has the advantage that：It is convenient when transfer and making sol solutionses；Lifting is convenient.
Brief description of the drawings
Fig. 1 is the schematic diagram of making apparatus of the invention.
Fig. 2 is the section view enlarged diagram of the wheel in Fig. 1, the state that can only be supported by roller for tyre pressure is inadequate in the figure.
Fig. 3 is the close-up schematic view at the A of Fig. 2.
Fig. 4 is the section view enlarged diagram of wheel, and the state that tire is supported is passed through for tyre pressure is enough in the figure
Fig. 5 is agitator schematic diagram.
Fig. 6 is the schematic cross-sectional view of the junction of suspension ring and anti-slop serrations.
Fig. 7 is the close-up schematic view at the B of Fig. 6.
In figure：,Wheel 2,Wheel rim 21,Spoke 22,Inflation tyre 23,Anti-tie mechanism for tire 29,Roller 291,Spline structure 2911,Air reservoir 292,Inflation piston 2921,Annular seal space 2922,Push rod 2923,Air flue 2924,Thread bush 293,Screw mandrel 294,Input section 2941,Force-limiting device 2942,First friction plate 29421,Second friction plate 29422,Coupling mechanism force regulating bolt 29423,Deferent segment 2943,Box of tricks 295,Ring gear 2951,External toothing 2952,Clutch gear 2953,Connecting shaft 2954,Staving 31,Charging aperture 12,Suspension ring 4,Anti-slop serrations 41,Power-assisted hole 411,The end face 412 in anti-slop serrations facewidth direction,Removable bindiny mechanism 42,Jack 421,Inserted block 422,Driving spring 423,Support bowl 424,Specular layer 425,Agitator 5,Rotating shaft 51,Stirring vane 52,Motor 53,Driving gear 54,Driven gear 55,Sliding sleeve 56,Lock-screw 57.
Specific embodiment
The present invention is further illustrated with embodiment below in conjunction with the accompanying drawings.
Referring to Fig. 1, a kind of production equipment of Ag-carried nanometer titanium dioxide airsetting, including bracket 1 and 2 agitators 3 being arranged on bracket.
Bracket 1 is provided with wheel 2 and wheel is lifted away from the hydraulic supporting feet 11 on ground.Wheel 2 includes spoke 22, is connected to the wheel rim 21 of spoke and is connected to the inflation tyre 23 of wheel rim.
The two ends of the horizontal direction of bracket 1 are provided with suspension ring 4.The inner peripheral surface of suspension ring 4 is provided with least two anti-slop serrations 41.Anti-slop serrations 41 are distributed along the bearing of trend of suspension ring 4.Anti-slop serrations 41 are detachably connected with suspension ring 4.
Agitator 3 includes staving 31.The top of staving 31 is provided with charging aperture 311 and bottom is provided with discharging opening 312.An agitator in 2 agitators 3 is that high-order agitator 3-1, another are low level agitator 3-2.Low level agitator 3-2 is provided with Temperature controlled heater and ultrasonic vibrator, and the discharging opening of high-order agitator 3-1 links together with the charging aperture of low level agitator 3-2..
Referring to Fig. 2, wheel 2 also includes anti-tie mechanism for tire 29.Anti-tie mechanism for tire 29 includes roller 291, air reservoir 292, thread bush 293, screw mandrel 294 and box of tricks 295.Wheel rim 21 is provided with inflation tyre 23.Roller 291 is coaxially fixed together with wheel rim 21.Roller 291 and wheel rim 21 are distributed along the axial direction of wheel rim 21.Roller 291 is provided with spline structure 2911.Spline structure 2911 is the strip hole axially extending along wheel rim for being arranged at roller 291.Air reservoir 292 is arranged in the barrel of roller 291.Air reservoir 292 is the annular cylinder coaxial with roller 291.Inflation piston 2921 is provided with air reservoir 292.The axis of piston 2921 is inflated with the diameter parallel of wheel rim 21.Air reservoir 292 is isolated annular seal space 2922 by inflation piston 2921.Annular seal space 2922 is connected by air flue 2924 with inflation tyre 23.Inflation piston 2921 is linked together by least two push rods 2923 with thread bush 293.Push rod 2923 is circumferentially distributed along roller 291.Push rod 2923 is correspondingly through the strip hole for constituting spline structure 2911.Screw mandrel 294 is arranged in roller 291.Screw mandrel 294 includes input section 2941, force-limiting device 2942 and deferent segment 2943.One end of deferent segment 2943 is rotatably connected with roller 291, the end also be also axially connected together i.e. screw mandrel 294 along roller 291 between roller 291 can not be along the axial movement of roller 291.The other end of deferent segment 2943 is linked together by force-limiting device 2942 with deferent segment 2943.The screw thread of thread bush 94 is set on deferent segment 2943.Box of tricks 295 includes ring gear 2951, external toothing 2952 and clutch gear 2953.Ring gear 2951 is connected on the inner peripheral surface of roller 291.External toothing 2952 is connected to input section 2941.It is that the two is located at approximately the same plane that external toothing 2952 is located in ring gear 2951.Clutch gear 2953 is provided with connecting shaft 2954.
Referring to Fig. 3, force-limiting device 2942 includes the first friction plate 29421 and the second friction plate 29422 and coupling mechanism force regulating bolt 29423.First friction plate 29421 is connected to input section 2941.Second friction plate 29422 is connected to deferent segment 2943.First friction plate 29421 and the second friction plate 29422 coupling mechanism force regulating bolt 29423 hold out against effect under push against together with and power is transmitted by rubbing action.Can also be adjusted by rotation lock clamp force regulating bolt 29423 between first friction plate 29421 and the second friction plate 29422 friction come come make it possible to transmission power size.
Referring to Fig. 4, when using, spoke 22 links together with bracket 1.Inflation tyre 23 causes tire pressure not enough due to gas flow in annular seal space 2922 when inflation piston 2921 is in the position, is now bracket to be supported by roller 291 and realizes walking, so as to avoid passing through bundle tire section when inflation tyre 23 punctured.
When to recover normal tire pressure and walked by inflation tyre support, clutch gear 2953 is inserted between ring gear 2951 and external toothing 2952 and so that ring gear 2951 is meshed together with external toothing 2952 by clutch gear 2953.Clutch gear 2953 is also fixed together by connecting shaft 2954 with power buggy 3.Then rotate forward wheel, the rotating speed of screw mandrel 294 produces translation to the right higher than the rotating speed of thread bush 293, thread bush 293 also relative to screw mandrel 294 in the presence of box of tricks 295, the structure of translation is to drive inflation piston 2921 to move to right to cause the gas compression in annular seal space 2922 in inflation tyre 23 so that wheel is supported by inflation tyre 23 and walked.When inflating piston 2921 and being shifted to the right to same roller 291 and abut together, the moment of torsion of screw mandrel 294 can increase, so that force-limiting device 2942 skids, so as to be automatically obtained rotation.Similarly, deflated to pneumatic tire 99 and when realizing being supported by roller 291 when having, make wheel reversing, the result of reversion is that screw mandrel drives inflation piston 2921 to move to left, so that the gas in inflation tyre 23 is flowed into annular seal space 2922 so that inflation tyre 23 flat can pass through roller 291 and be supported down.
When not needing inflation/deflation, clutch gear 2953 is extracted between the first friction plate 29421 and the second friction plate 29422.
Referring to Fig. 5, agitator 3 also includes agitator 5.Agitator 5 includes rotating shaft 51, stirring vane 52, motor 53, driving gear 54 and driven gear 55.Rotating shaft 51 is input in staving 31.Rotating shaft 51 is rotationally connected with staving 31.Rotating shaft 51 is vertically extending.Stirring vane 52 is connected to rotating shaft 51 on the part in staving.Stirring vane 52 is blade construction.Driven gear 55 is fixed on the upper end of rotating shaft 51, and driven gear 55 and rotating shaft 51 are coaxial.Driving gear 54 is arranged at the power output shaft of motor 53.Driving gear 54 meshes together with driven gear 55.Each stirring vane 52 is respectively provided with a sliding sleeve 56 being set in rotating shaft 51.Sliding sleeve 56 is fixed together by lock-screw 57 with rotating shaft 51.
Referring to Fig. 6, suspension ring 4 are additionally provided with can formula bindiny mechanism 42.Anti-slop serrations 41 are provided with power-assisted hole 411.Power-assisted hole 411 is located on the end face 412 in anti-slop serrations facewidth direction.Anti-slop serrations 41 are detachably connected by removable bindiny mechanism 82 with suspension ring 4.Removable bindiny mechanism 82 includes jack 421, inserted block 422, driving spring 423 and support bowl 424.Jack 421 is arranged at suspension ring 4.Inserted block 422 is spherical.Inserted block 422 is located in anti-slop serrations 41.Driving spring 423 is located in anti-slop serrations 41.Support bowl 424 is located in anti-slop serrations 41.Driving spring 423 is abutted together by supporting bowl 424 with inserted block 422.It is mating spherical surfaces between support bowl 424 and inserted block 422.
Referring to Fig. 7, inserted block 422 is mating spherical surfaces between suspension ring 4.The face of the support inserted block of bowl 424 is supported to be provided with specular layer 425.
Referring to Fig. 6 to Fig. 7, realize removing anti-slop serrations 41 from suspension ring 4 by the way that the body of rod is inserted in into the China and foreign countries of power-assisted hole 411 drawing anti-slop serrations 41 when using, be directly inserted into during installation.
Embodiment one, a kind of its preparation method of Ag-carried nanometer titanium dioxide aerogel material：
A, from particle diameter be 800 ~ 1000nm, galapectite powder of the purity more than 98%, by galapectite powder infusion in 150 times of 10wt% hydrochloric acid solutions of quality, and carried out at a temperature of 55 DEG C water-bath vibration 1.5h；After galapectite powder is taken out and cleaned, 3.5h is calcined in 450 DEG C of Muffle furnace, modified galapectite powder is finally obtained.
By butyl titanate, modified galapectite powder, hydrophobic porous carboxymethylcellulose calcium, absolute ethyl alcohol, toluene in mass ratio 1:0.2:0.1:20:Mixed in 0.02 low level bucket 3-2 in Fig. 1, obtained solution A；By absolute ethyl alcohol, the glacial acetic acid of 1mol/L and water in mass ratio 15:5:1 is mixed, obtained solution B in high-order bucket 3-1 in Fig. 1；Adjusting ultrasonic vibrator of the temperature by carrying at 55 DEG C by the temperature heater carried in low level bucket to solution A carries out supersonic oscillations treatment, and solution B is added drop-wise in 2 times of solution As of quality, controls the rate of addition 1mL/s of solution B.Simultaneously to the sodium bicarbonate powder that quality is for 0.015 times of solution A is added in solution A, after continuing to stir 1.5h, sol solutionses are obtained.
B, in sol solutionses add quality for 0.2 times of butyl titanate silver nitrate and stir, then to dropwise addition salpeter solution in sol solutionses until the pH of sol solutionses is 5, sol solutionses are heated to 50 DEG C under the conditions of lucifuge and 1.5h is incubated, after unreacting substance being washed with water to sol solutionses, it is under agitation the sodium borohydride of 0.01 times of butyl titanate to quality is added in sol solutionses, while dropwise addition sodium hydroxide solution control sol solutionses pH is between 7 ~ 8；It is obtained after finally washing with water and carries silver sol liquid.
C, silver sol liquid aging 36h at room temperature will be carried, then solvent displacement 48h is carried out to addition n-hexane in carrying silver sol liquid, it is separated off n-hexane, obtain carrying silver gel, hydrophobically modified 36h is carried out at 50 DEG C to carrying silver gel with the mixed solution of organo-silicon compound and n-hexane, in the mixed solution of the organo-silicon compound and n-hexane, organo-silicon compound are 1.5 with the volume ratio of n-hexane:5, organo-silicon compound are 100 with the mixed solution and the mass ratio for carrying silver gel of n-hexane:15.The organo-silicon compound are HMDO.It is last that aerogel material is obtained after vacuum drying at 90 DEG C.
The porosity of aeroge obtained in the present embodiment is 95%, and specific surface area is 563m2/ g, density is 3.68kg/m3, oil suction multiplying power is 14, and tensile strength is 25.2Gpa.
A kind of embodiment 2, Ag-carried nanometer titanium dioxide aerogel material, its preparation method is as follows：
A, from particle diameter be 800 ~ 1000nm, galapectite powder of the purity more than 98%, by galapectite powder infusion in 100 times of 10wt% hydrochloric acid solutions of quality, and carried out at a temperature of 50 DEG C water-bath vibration 2h；After galapectite powder is taken out and cleaned, 5h is calcined in 400 DEG C of Muffle furnace, modified galapectite powder is finally obtained.
By butyl titanate, modified galapectite powder, hydrophobic porous carboxymethylcellulose calcium, absolute ethyl alcohol, toluene in mass ratio 1:0.1:0.05:10:0.01 is mixed, obtained solution A；By absolute ethyl alcohol, the glacial acetic acid of 0.5mol/L and water in mass ratio 10:4:1 is mixed, obtained solution B；Supersonic oscillations treatment is carried out at 50 DEG C to solution A, solution B is added drop-wise in 2 times of solution As of quality, control the rate of addition 0.5mL/s of solution B.Simultaneously to the sodium bicarbonate powder that quality is for 0.01 times of solution A is added in solution A, after continuing to stir 1h, sol solutionses are obtained.
B, in sol solutionses add quality for 0.1 times of butyl titanate silver nitrate and stir, then to dropwise addition salpeter solution in sol solutionses until the pH of sol solutionses is 5, sol solutionses are heated to 45 DEG C under the conditions of lucifuge and 2h is incubated, after unreacting substance being washed with water to sol solutionses, it is under agitation the sodium borohydride of 0.005 times of butyl titanate to quality is added in sol solutionses, while dropwise addition sodium hydroxide solution control sol solutionses pH is between 7 ~ 8；It is obtained after finally washing with water and carries silver sol liquid.
C, silver sol liquid aging 24h at room temperature will be carried, then solvent displacement 36h is carried out to addition n-hexane in carrying silver sol liquid, it is separated off n-hexane, obtain carrying silver gel, hydrophobically modified 48h is carried out at 40 DEG C to carrying silver gel with the mixed solution of organo-silicon compound and n-hexane, in the mixed solution of the organo-silicon compound and n-hexane, organo-silicon compound are 1 with the volume ratio of n-hexane:5, organo-silicon compound are 100 with the mixed solution and the mass ratio for carrying silver gel of n-hexane:10.The organo-silicon compound are HMDS.It is last that aerogel material is obtained after vacuum drying at 60 DEG C.
The porosity of aeroge obtained in the present embodiment is 91%, and specific surface area is 537m2/ g, density is 4.04kg/m3, oil suction multiplying power is 12, and tensile strength is 20.3GPa.
A kind of embodiment 3, Ag-carried nanometer titanium dioxide aerogel material for absorption degradation petroleum hydrocarbon, its preparation method is as follows：A, from particle diameter be 800 ~ 1000nm, galapectite powder of the purity more than 98%, by galapectite powder infusion in 200 times of 10wt% hydrochloric acid solutions of quality, and carried out at a temperature of 60 DEG C water-bath vibration 1h；After galapectite powder is taken out and cleaned, 2h is calcined in 500 DEG C of Muffle furnace, modified galapectite powder is finally obtained.
By butyl titanate, modified galapectite powder, hydrophobic porous carboxymethylcellulose calcium, absolute ethyl alcohol, toluene in mass ratio 1: 0.3: 0.15: 30:0.03 is mixed, obtained solution A；By absolute ethyl alcohol, the glacial acetic acid of 1.5mol/L and water in mass ratio 20: 6:1 is mixed, obtained solution B；Supersonic oscillations treatment is carried out at 60 DEG C to solution A, solution B is added drop-wise in 2 times of solution As of quality, control the rate of addition 1.5mL/s of solution B.Simultaneously to the sodium bicarbonate powder that quality is for 0.02 times of solution A is added in solution A, after continuing to stir 2h, sol solutionses are obtained.
B, in sol solutionses add quality for 0.3 times of butyl titanate silver nitrate and stir, then to dropwise addition salpeter solution in sol solutionses until the pH of sol solutionses is 5, sol solutionses are heated to 55 DEG C under the conditions of lucifuge and 1h is incubated, after unreacting substance being washed with water to sol solutionses, it is under agitation the sodium borohydride of 0.015 times of butyl titanate to quality is added in sol solutionses, while dropwise addition sodium hydroxide solution control sol solutionses pH is between 7 ~ 8；It is obtained after finally washing with water and carries silver sol liquid.
C, silver sol liquid aging 48h at room temperature will be carried, then solvent displacement 60h is carried out to addition n-hexane in carrying silver sol liquid, it is separated off n-hexane, obtain carrying silver gel, hydrophobically modified 24h is carried out at 60 DEG C to carrying silver gel with the mixed solution of organo-silicon compound and n-hexane, in the mixed solution of the organo-silicon compound and n-hexane, organo-silicon compound are 2 with the volume ratio of n-hexane:5, organo-silicon compound are 100 with the mixed solution and the mass ratio for carrying silver gel of n-hexane: 20.The organo-silicon compound are MTMS.It is last that aerogel material is obtained after vacuum drying at 120 DEG C.
The porosity of aeroge obtained in the present embodiment is 92%, and specific surface area is 519m2/ g, density is 4.28kg/m3, oil suction multiplying power is 11, and tensile strength is 22.7GPa.
A kind of embodiment 4, Ag-carried nanometer titanium dioxide aerogel material for absorption degradation petroleum hydrocarbon, its preparation method is as follows：
A, from particle diameter be 800 ~ 1000nm, galapectite powder of the purity more than 98%, by butyl titanate, galapectite powder, hydrophobic porous carboxymethylcellulose calcium, absolute ethyl alcohol, toluene in mass ratio 1:0.2:0.1:20:0.02 is mixed, obtained solution A；By absolute ethyl alcohol, the glacial acetic acid of 1mol/L and water in mass ratio 15:5:1 is mixed, obtained solution B；Supersonic oscillations treatment is carried out at 55 DEG C to solution A, solution B is added drop-wise in 2 times of solution As of quality, control the rate of addition 1mL/s of solution B.Simultaneously to the sodium bicarbonate powder that quality is for 0.015 times of solution A is added in solution A, after continuing to stir 1.5h, sol solutionses are obtained.
B, in sol solutionses add quality for 0.2 times of butyl titanate silver nitrate and stir, then to dropwise addition salpeter solution in sol solutionses until the pH of sol solutionses is 5, sol solutionses are heated to 50 DEG C under the conditions of lucifuge and 1.5h is incubated, after unreacting substance being washed with water to sol solutionses, it is under agitation the sodium borohydride of 0.01 times of butyl titanate to quality is added in sol solutionses, while dropwise addition sodium hydroxide solution control sol solutionses pH is between 7 ~ 8；It is obtained after finally washing with water and carries silver sol liquid.
C, silver sol liquid aging 36h at room temperature will be carried, then solvent displacement 48h is carried out to addition n-hexane in carrying silver sol liquid, it is separated off n-hexane, obtain carrying silver gel, hydrophobically modified 36h is carried out at 50 DEG C to carrying silver gel with the mixed solution of organo-silicon compound and n-hexane, in the mixed solution of the organo-silicon compound and n-hexane, organo-silicon compound are 1.5 with the volume ratio of n-hexane:5, organo-silicon compound are 100 with the mixed solution and the mass ratio for carrying silver gel of n-hexane:15.The organo-silicon compound are isometric HMDS and trim,ethylchlorosilane.It is last that aerogel material is obtained after vacuum drying at 100 DEG C.
The porosity of aeroge obtained in the present embodiment is 90%, and specific surface area is 445m2/ g, density is 4.51kg/m3, oil suction multiplying power is 10, and tensile strength is 21.2Gpa.
Claims (8)
1. a kind of production equipment of Ag-carried nanometer titanium dioxide airsetting, it is characterized in that, including bracket and 2 agitators being arranged on bracket, the agitator includes staving and agitator, the top of the staving is provided with charging aperture and bottom is provided with discharging opening, an agitator in 2 agitators is high-order agitator, another is low level agitator, low level agitator is provided with Temperature controlled heater and ultrasonic vibrator, the discharging opening of high-order agitator links together with the charging aperture of low level agitator, the bracket is provided with wheel and wheel is lifted away from the hydraulic supporting feet on ground, bracket is provided with suspension ring, the inner peripheral surface of the suspension ring is provided with least two anti-slop serrations, the anti-slop serrations are detachably connected with the suspension ring, the anti-slop serrations are distributed along the bearing of trend of suspension ring.
2. the production equipment of Ag-carried nanometer titanium dioxide airsetting according to claim 1, it is characterized in that, the wheel includes spoke, it is connected to the wheel rim of spoke, it is connected to the inflation tyre and anti-tie mechanism for tire of wheel rim, the anti-tie mechanism for tire includes roller, air reservoir, the screw mandrel for wearing and being rotationally connected with roller and the thread bush being threaded on screw mandrel, the roller is coaxially fixed together with the wheel rim, inflation piston of the axis with the diameter parallel of the wheel rim is provided with the air reservoir, the air reservoir is isolated annular seal space by the inflation piston, the annular seal space is connected with the tire, the inflation piston is linked together by push rod with the thread bush, the roller be additionally provided with the prevention thread bush with the screw mandrel be axle relative to the spline structure that the roller is rotated；The wheel can by change the tire pressure of inflation tyre come when tire tyre surface along wheel rim radially beyond or less than the roller side face.
3. the production equipment of Ag-carried nanometer titanium dioxide aeroge according to claim 2, it is characterised in that the spline structure is the strip hole axially extending along wheel rim for being arranged at the roller, and the push rod is arranged in the strip hole.
4. the production equipment of the Ag-carried nanometer titanium dioxide aeroge according to Claims 2 or 3, it is characterized in that, the wheel also includes making the box of tricks for producing speed discrepancy between the roller and screw mandrel, the screw mandrel includes input section and deferent segment, the input section and deferent segment are linked together by force-limiting device, the thread bush line is connected to the deferent segment, the box of tricks include being connected to the ring gear of roller, be connected to the input section and the external toothing in ring gear and the clutch gear that can be arranged to plug between ring gear and external toothing.
5. the production equipment of Ag-carried nanometer titanium dioxide aeroge according to claim 4, it is characterized in that, the force-limiting device includes being connected to the first friction plate of the input section and is connected to the second friction plate of the deferent segment, first friction plate and the second friction plate are pushed against together, and the input section and deferent segment transmit power by the rubbing action between first friction plate and the second friction plate.
6. the production equipment of Ag-carried nanometer titanium dioxide aeroge according to claim 1 and 2, it is characterized in that, the agitator includes rotating shaft, the motor of drive shaft and is connected to some stirring vanes of rotating shaft, the rotating shaft vertically extends, the each stirring vane is respectively provided with a sliding sleeve being set in the rotating shaft, and the sliding sleeve is fixed together by lock-screw with the rotating shaft.
7. the production equipment of Ag-carried nanometer titanium dioxide aeroge according to claim 1 and 2, it is characterized in that, also include removable bindiny mechanism, the anti-slop serrations are detachably connected by the removable bindiny mechanism with the suspension ring, and the removable bindiny mechanism includes the driving spring for being arranged at the jack of the suspension ring, being movably connected on the inserted block of the anti-slop serrations and drive inserted block to be inserted into the jack.
8. the production equipment of Ag-carried nanometer titanium dioxide aeroge according to claim 7, it is characterised in that the inserted block is spherical, and the inserted block is with being mating spherical surfaces between the coupler body.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610346703.9A CN106807333A (en) | 2016-05-24 | 2016-05-24 | The production equipment of Ag-carried nanometer titanium dioxide aeroge |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610346703.9A CN106807333A (en) | 2016-05-24 | 2016-05-24 | The production equipment of Ag-carried nanometer titanium dioxide aeroge |
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| CN106807333A true CN106807333A (en) | 2017-06-09 |
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| CN201610346703.9A Pending CN106807333A (en) | 2016-05-24 | 2016-05-24 | The production equipment of Ag-carried nanometer titanium dioxide aeroge |
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Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1360598A (en) * | 1999-07-14 | 2002-07-24 | 约翰逊聚合物公司 | Process for continuous production of epoxy addition polymers and powder and liquid coating applications contg. same |
| CN102335574A (en) * | 2010-07-14 | 2012-02-01 | 精工爱普生株式会社 | Apparatus for manufacturing gel particle and method for manufacturing gel particle |
| CN203063551U (en) * | 2013-01-23 | 2013-07-17 | 福建合众机械有限公司 | Wheel with anti-explosion mechanism |
-
2016
- 2016-05-24 CN CN201610346703.9A patent/CN106807333A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1360598A (en) * | 1999-07-14 | 2002-07-24 | 约翰逊聚合物公司 | Process for continuous production of epoxy addition polymers and powder and liquid coating applications contg. same |
| CN102335574A (en) * | 2010-07-14 | 2012-02-01 | 精工爱普生株式会社 | Apparatus for manufacturing gel particle and method for manufacturing gel particle |
| CN203063551U (en) * | 2013-01-23 | 2013-07-17 | 福建合众机械有限公司 | Wheel with anti-explosion mechanism |
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Application publication date: 20170609 |