CN106785922B - A kind of gas discharge tube electrode and preparation method thereof - Google Patents

A kind of gas discharge tube electrode and preparation method thereof Download PDF

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Publication number
CN106785922B
CN106785922B CN201710199786.8A CN201710199786A CN106785922B CN 106785922 B CN106785922 B CN 106785922B CN 201710199786 A CN201710199786 A CN 201710199786A CN 106785922 B CN106785922 B CN 106785922B
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Prior art keywords
discharge tube
electrode
gas discharge
parts
gas
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CN201710199786.8A
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CN106785922A (en
Inventor
谷春宁
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Dongguan City Standard Hardware Co Ltd
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Dongguan City Standard Hardware Co Ltd
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Priority to CN201810188493.4A priority patent/CN108521076B/en
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01TSPARK GAPS; OVERVOLTAGE ARRESTERS USING SPARK GAPS; SPARKING PLUGS; CORONA DEVICES; GENERATING IONS TO BE INTRODUCED INTO NON-ENCLOSED GASES
    • H01T4/00Overvoltage arresters using spark gaps
    • H01T4/02Details
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01JELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
    • H01J17/00Gas-filled discharge tubes with solid cathode
    • H01J17/02Details
    • H01J17/04Electrodes; Screens
    • H01J17/06Cathodes
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01JELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
    • H01J17/00Gas-filled discharge tubes with solid cathode
    • H01J17/02Details
    • H01J17/28Cooling arrangements
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01JELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
    • H01J9/00Apparatus or processes specially adapted for the manufacture, installation, removal, maintenance of electric discharge tubes, discharge lamps, or parts thereof; Recovery of material from discharge tubes or lamps
    • H01J9/02Manufacture of electrodes or electrode systems
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01TSPARK GAPS; OVERVOLTAGE ARRESTERS USING SPARK GAPS; SPARKING PLUGS; CORONA DEVICES; GENERATING IONS TO BE INTRODUCED INTO NON-ENCLOSED GASES
    • H01T1/00Details of spark gaps
    • H01T1/16Series resistor structurally associated with spark gap
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01TSPARK GAPS; OVERVOLTAGE ARRESTERS USING SPARK GAPS; SPARKING PLUGS; CORONA DEVICES; GENERATING IONS TO BE INTRODUCED INTO NON-ENCLOSED GASES
    • H01T1/00Details of spark gaps
    • H01T1/20Means for starting arc or facilitating ignition of spark gap
    • H01T1/22Means for starting arc or facilitating ignition of spark gap by the shape or the composition of the electrodes
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01TSPARK GAPS; OVERVOLTAGE ARRESTERS USING SPARK GAPS; SPARKING PLUGS; CORONA DEVICES; GENERATING IONS TO BE INTRODUCED INTO NON-ENCLOSED GASES
    • H01T1/00Details of spark gaps
    • H01T1/24Selection of materials for electrodes
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01TSPARK GAPS; OVERVOLTAGE ARRESTERS USING SPARK GAPS; SPARKING PLUGS; CORONA DEVICES; GENERATING IONS TO BE INTRODUCED INTO NON-ENCLOSED GASES
    • H01T21/00Apparatus or processes specially adapted for the manufacture or maintenance of spark gaps or sparking plugs

Abstract

A kind of claimed gas discharge tube electrode, the electrode are mainly made up of metal material, and electronic powder is coated with the inside of the electrode, have electric insulation heat transfer film in the electrode outer application;Further, the gas-discharge tube is mainly used in ceramic gas discharge tube, is provided with thermal resistance in the electric insulation heat transfer film surface, the thermal resistance is connected with glass gas-discharge pipe, then in parallel with the ceramic gas discharge tube again.Present invention mainly solves gas-discharge tube in the prior art easily to overheat, the short technical problem of service life;Also further solves the long technical problem of ceramic gas discharge tube response time in the prior art.

Description

A kind of gas discharge tube electrode and preparation method thereof
Technical field
The invention belongs to gas-discharge tube field, more particularly to a kind of gas discharge tube electrode and preparation method thereof.
Background technology
Ceramic gas discharge tube is that appropriate gas medium is filled with discharging gap, is equipped with the electron emission material of high activity Material and mechanism of igniting of discharging, by the high intermediate temperature sealing of silver-copper brazing alloy and a kind of manufactured gas discharge of special cermet structure Device.It is mainly used in instantaneous overvoltage protection, can also be used as ignition switch.The through-current capacity of ceramic gas discharge tube is than pressure-sensitive electricity Resistance and TVS pipe are big, and the protection device such as gas-discharge tube and TVS should make most overcurrent pass through gas-discharge tube when sharing Release.The insulaion resistance of gas-discharge tube is very high, can reach the magnitude of begohm.The value of interelectrode capacity is very small, and one As in below 2pF, interelectrode leakageg stream is very small, is nA levels.Therefore gas-discharge tube is attempted by circuit substantially will not to circuit What, which is formed, influences.But gas-discharge tube for a long time bear or continually overcurrent when, gas-discharge tube can be heating up, gas Two metal electrodes thawing sputtering amount of discharge tube is big, and easy guiding discharge tube impedance, which declines, even forms short circuit.Therefore how to have Effect prevents gas generating pipe from overheating, and improves the service life of gas-discharge tube, is the technical problem that this area is badly in need of solving.This Outside, existing ceramic gas discharge tube electrode generally use oxygen-free copper and 4J42 iron nickel (42%) nickel alloy is made, in electrode Side is coated with one layer of electronic powder, to accelerate the response time of ceramic gas discharge tube.But in general ceramic gas discharge tube Response time, so that counting ms, is sound that is most slow, therefore how improving ceramic gas discharge tube in protection device in hundreds of ns Between seasonable, and the technical problem of solution is badly in need of in this area.
The content of the invention
Present invention seek to address that existing gas-discharge tube easily overheats, a kind of short technical barrier of service life, there is provided gas Discharge tube electrode and preparation method thereof.On this basis, present invention is alternatively directed to ceramic gas discharge tube response time length to be carried out Improve, the gas discharge tube electrode after improvement can significantly shorten the response time of ceramic gas discharge tube.
In order to achieve the above object, present invention employs following technical scheme:
A kind of gas discharge tube electrode, is mainly made up of metal material, and electronic powder is coated with the inside of the electrode, The electrode outer application has one layer of electric insulation heat transfer film.
As the improved technical scheme of the present invention, multiple radiating fins, the radiating fin and institute are provided with the outside of the electrode Electrode is stated to be integrally formed by metal material.
Further, the radiating fin is sequentially arranged in parallel, middle radiating fin length, and the radiating fin of both sides is short.
As further improved technical scheme of the present invention, the gas discharge tube electrode is mainly used in ceramic gas and put Fulgurite, thermal resistance is mounted with the electric insulation heat transfer film surface, the thermal resistance is connected with a glass gas-discharge pipe It is in parallel with the ceramic gas discharge tube again afterwards.
Further, thermal resistance " Z " type is distributed in the electric insulation heat transfer film surface.
Further, the thermal resistance winds helically tubulose by heating wire bending.
As another object of the present invention, the invention provides a kind of preparation method of gas discharge tube electrode, mainly Comprise the following steps:Step 1, poured using metal material and electrode of the one side with radiating fin is made;Step 2, in radiating fin Be electrically insulated heat transfer film in the electrode surface spraying of side.
Further, the step 2 is:Take 2~6 parts of titanium dioxide, 3~7 parts of alundum (Al2O3), 1~5 part of carborundum, 9.5~15 parts of kaolin, 15~25 parts of propyl alcohol, 20~30 parts of polymethyl methacrylate, polyarylene sulfide resin 24~35 Part, 0.5~2 part of trimethoxy silane are well mixed, the electrode surface of radiating fin side are then sprayed on, by the electrode after spraying It is put into 60~80 DEG C of baking oven into 1~3h is changed, is then transferred to 4~10h of intermediate temperature setting in 300~400 DEG C of baking oven, it is naturally cold But.
Further, the step 2 is:Take 3~5 parts of titanium dioxide, 4~6 parts of alundum (Al2O3), 2~4 parts of carborundum, 10.2~13.5 parts of kaolin, 18~23 parts of propyl alcohol, 23~27 parts of polymethyl methacrylate, polyarylene sulfide resin 27~ 32 parts, 0.8~1.5 part of trimethoxy silane it is well mixed, the electrode surface of radiating fin side is then sprayed on, after spraying Electrode is put into 60~80 DEG C of baking oven into 1~3h is changed, and is then transferred to 4~10h of intermediate temperature setting in 300~400 DEG C of baking oven, from So cooling.
Preferably, the step 2 is:Take 4 parts of titanium dioxide, 5 parts of alundum (Al2O3), 3 parts of carborundum, 12 parts of kaolin, 20 parts of propyl alcohol, 25 parts of polymethyl methacrylate, 30 parts of polyarylene sulfide resin, 1 part of trimethoxy silane are well mixed, so The electrode surface of radiating fin side is sprayed on afterwards, and the electrode after spraying is put into 70 DEG C of baking oven into 2h is changed, is then transferred to 380 DEG C baking oven in intermediate temperature setting 8h, natural cooling.
Beneficial effect:
The present invention is gone out heat Quick diffusing caused by gas-discharge tube using the heat transfer film that is electrically insulated, and is advantageous to prevent Only gas-discharge tube overheats, and extends the service life of gas-discharge tube.The present invention is also by electric insulation heat transfer film surface Thermal resistance is disposed, the thermal resistance is connected with glass gas-discharge pipe, therefore when gas-discharge tube both ends produce high pressure, glass Gas-discharge tube quick response turns on, heated by electrodes of the electric current by thermal resistance to ceramic gas discharge tube so that ceramic gas Electronic powder in discharge tube is easier to discharge electronics, and the gas motion in ceramic gas discharge tube is more violent, is more easy to puncture, from And greatly shorten the response time of ceramic gas.The invention further relates to the formula of the electric insulation heat transfer film suitable for the present invention And preparation method.Gas discharge tube electrode made from the formula has the characteristics that good insulating, heat conductivility be good, high temperature resistant.
Brief description of the drawings
Fig. 1 is the structural representation that the present invention is used in ceramic gas discharge tube;
Fig. 2 is structural representation of the thermal resistance in electric insulation heat transfer film surface " Z " type distribution.
Embodiment
In order that those skilled in the art becomes apparent from understanding that the understands the present invention, in conjunction with embodiment and attached Figure, the present invention is described in detail.
As shown in figure 1, the gas discharge tube electrode of the present invention is mainly used in ceramic gas discharge tube.Common ceramic gas Body discharge tube mainly includes metal electrode 5, earthenware 6, electronic powder 7, lead 1, lead 2.The present invention is to common ceramic gas Discharge tube is transformed, and is that one layer of electric insulation heat transfer film (not shown) is coated on the surface of metal electrode 5 first.It is described thin Film mainly by 2~6 parts of titanium dioxide, 3~7 parts of alundum (Al2O3), 1~5 part of carborundum, 9.5~15 parts of kaolin, propyl alcohol 15~ 25 parts, 20~30 parts of polymethyl methacrylate, 24~35 parts of polyarylene sulfide resin, 0.5~2 part of trimethoxy silane system Into.In order that metal electrode 5 has a more preferable radiating effect, the outside of the face electronic powder 7 of metal electrode 5 is sequentially put down in the present invention Row is arranged with multiple radiating fins 5 ', and the radiating fin 5 ' is integrally formed with the electrode 5 by metal material, middle radiating fin 5 ' Long, the radiating fin 5 ' of both sides is short.Thus, when ceramic gas discharge tube is born or during continually overcurrent for a long time, gas discharge Two metal electrodes 5 of pipe will quickly be exported heat by radiating fin 5 ', so as to prevent gas-discharge tube from overheating.
For the ceramic gas discharge tube response time length technical problem, the present invention it is above-mentioned it is improved on the basis of to ceramics Gas-discharge tube has made further improvement.Be first electric insulation heat transfer film placement thermal resistance 4, the thermal resistance 4 with It is in parallel with the ceramic gas discharge tube again after the series connection of one glass gas-discharge pipe 3.4 ' be drawing for two thermal resistances 4 of connection Line.When ceramic gas discharge tube both ends produce high pressure, the conducting of the quick response of glass gas-discharge pipe 3, several nanoseconds are generally only needed, Electric current is heated by thermal resistance 4 to the electrode 5 of ceramic gas discharge tube so that the electronic powder 7 in ceramic gas discharge tube more holds Easily release electronics, gas motion in ceramic gas discharge tube is more violent, is more easy to puncture, so as to greatly shorten ceramic gas Response time.Using this scheme, response time of ceramic gas discharge tube can be made by hundreds of original nanoseconds to several milliseconds It was reduced to for tens nanoseconds.In order to increase the resistance value of thermal resistance 4, can be in by heating wire bending winding by the thermal resistance 4 first Helix, then " Z " type is distributed in the electric insulation heat transfer film surface again, as shown in Figure 2.
Due to the electric insulation heat transfer film on the surface of metal electrode 5 need to meet electrical insulating property is good, heat conduction efficiency is high and Resistant to elevated temperatures feature, therefore the present invention is also studied the formula for the heat transfer film that is electrically insulated, specific embodiment is as follows.
Embodiment 1
A kind of preparation method of gas discharge tube electrode, is mainly included the following steps that:Step 1, poured using metal material Build and electrode of the one side with radiating fin is made;Step 2, take 2 parts of titanium dioxide, 7 parts of alundum (Al2O3), 5 parts of carborundum, kaolinite 2 parts of 15 parts of soil, 15 parts of propyl alcohol, 30 parts of polymethyl methacrylate, 24 parts of polyarylene sulfide resin, trimethoxy silane mixing Uniformly, the electrode surface of radiating fin side is then sprayed on, into 1h is changed, then the electrode after spraying is put into 60 DEG C of baking oven It is transferred to intermediate temperature setting 10h, natural cooling in 300 DEG C of baking oven.
Embodiment 2
A kind of preparation method of gas discharge tube electrode, is mainly included the following steps that:Step 1, poured using metal material Build and electrode of the one side with radiating fin is made;Step 2, take 3 parts of titanium dioxide, 6 parts of alundum (Al2O3), 4 parts of carborundum, kaolinite 13.5 parts of soil, 18 parts of propyl alcohol, 27 parts of polymethyl methacrylate, 27 parts of polyarylene sulfide resin, 1.5 parts of trimethoxy silane It is well mixed, the electrode surface of radiating fin side is then sprayed on, the electrode after spraying is put into 70 DEG C of baking oven into change 2h, Then intermediate temperature setting 8h, natural cooling in 350 DEG C of baking oven are transferred to.
Embodiment 3
A kind of preparation method of gas discharge tube electrode, is mainly included the following steps that:Step 1, poured using metal material Build and electrode of the one side with radiating fin is made;Step 2, take 4 parts of titanium dioxide, 5 parts of alundum (Al2O3), 3 parts of carborundum, kaolinite 1 part of 12 parts of soil, 20 parts of propyl alcohol, 25 parts of polymethyl methacrylate, 30 parts of polyarylene sulfide resin, trimethoxy silane mixing Uniformly, the electrode surface of radiating fin side is then sprayed on, into 3h is changed, then the electrode after spraying is put into 70 DEG C of baking oven It is transferred to intermediate temperature setting 8h, natural cooling in 380 DEG C of baking oven.
Embodiment 4
A kind of preparation method of gas discharge tube electrode, is mainly included the following steps that:Step 1, poured using metal material Build and electrode of the one side with radiating fin is made;Step 2, take 5 parts of titanium dioxide, 4 parts of alundum (Al2O3), 2 parts of carborundum, kaolinite 10.2 parts of soil, 23 parts of propyl alcohol, 23 parts of polymethyl methacrylate, 32 parts of polyarylene sulfide resin, 0.8 part of trimethoxy silane It is well mixed, the electrode surface of radiating fin side is then sprayed on, the electrode after spraying is put into 80 DEG C of baking oven into change 1h, Then intermediate temperature setting 4h, natural cooling in 400 DEG C of baking oven are transferred to.
Embodiment 5
A kind of preparation method of gas discharge tube electrode, is mainly included the following steps that:Step 1, poured using metal material Build and electrode of the one side with radiating fin is made;Step 2, take 6 parts of titanium dioxide, 3 parts of alundum (Al2O3), 1 part of carborundum, kaolinite 9.5 parts of soil, 25 parts of propyl alcohol, 20 parts of polymethyl methacrylate, 35 parts of polyarylene sulfide resin, 0.5 part of trimethoxy silane It is well mixed, the electrode surface of radiating fin side is then sprayed on, the electrode after spraying is put into 70 DEG C of baking oven into change 2h, Then intermediate temperature setting 4h, natural cooling in 380 DEG C of baking oven are transferred to.
Gas discharge tube electrode made from above method disclosure satisfy that electrical insulating property is good, thermal conductivity is good, resistant to elevated temperatures It is required that.
Obviously, above-described embodiment is used for the purpose of clearly demonstrating example, rather than the limitation to embodiment.It is right For those of ordinary skill in the art, can also make on the basis of the above description it is other it is various forms of change or Change.There is no necessity and possibility to exhaust all the enbodiments.As long as made on the basis of the embodiment of the present invention The change scheme of common-sense, among protection scope of the present invention.

Claims (5)

1. a kind of gas discharge tube electrode, is mainly made up of metal material, it is characterised in that:It is coated with the inside of the electrode Electronic powder, there is one layer of electric insulation heat transfer film in the electrode outer application, the gas discharge tube electrode is mainly used in Ceramic gas discharge tube, thermal resistance, the thermal resistance and a glass gas are mounted with the electric insulation heat transfer film surface It is in parallel with the ceramic gas discharge tube again after discharge tube series connection.
2. gas discharge tube electrode according to claim 1, it is characterised in that:Multiple dissipate is provided with the outside of the electrode Hot wing, the radiating fin are integrally formed with the electrode by metal material.
3. gas discharge tube electrode according to claim 2, it is characterised in that:The radiating fin is sequentially arranged in parallel, Middle radiating fin length, the radiating fin of both sides are short.
4. gas discharge tube electrode according to claim 1, it is characterised in that:Thermal resistance " Z " type is distributed in institute State electric insulation heat transfer film surface.
5. gas discharge tube electrode according to claim 1, it is characterised in that:The thermal resistance is twined by heating wire bending Around helically tubulose.
CN201710199786.8A 2017-03-30 2017-03-30 A kind of gas discharge tube electrode and preparation method thereof Active CN106785922B (en)

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CN201810188493.4A CN108521076B (en) 2017-03-30 2017-03-30 Electrode for gas discharge tube and preparation method thereof

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Publication number Priority date Publication date Assignee Title
CN108091531A (en) * 2018-01-22 2018-05-29 东莞市阿甘半导体有限公司 Gas-discharge tube and overvoltage protection

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CN2788314Y (en) * 2005-03-31 2006-06-14 聚鼎科技股份有限公司 Overcurrent protective element
CN101308759A (en) * 2007-05-16 2008-11-19 台达电子工业股份有限公司 Cold cathode fluorescent lamp and cold cathode fluorescent lamp module
CN205723432U (en) * 2016-05-04 2016-11-23 深圳市良胜电子有限公司 A kind of highly sensitive ceramic discharge tube

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DE202005014660U1 (en) * 2005-09-16 2005-12-08 Patent-Treuhand-Gesellschaft für elektrische Glühlampen mbH High pressure electrical gas discharge lamp has electrode fitted with a heating filament for use in a dimmer circuit
CN101735563A (en) * 2009-12-04 2010-06-16 郎玉龙 Composite heat-conducting insulated film and method for manufacturing same
CN104710912B (en) * 2015-03-31 2017-09-22 东莞市闻誉实业有限公司 Fin
CN105860754A (en) * 2016-05-09 2016-08-17 安徽爱莱特照明灯具有限公司 Wear-resistant high-thermal-conductivity insulation varnish for LED lamp holder and preparation method of wear-resistant high-thermal-conductivity insulation varnish for LED lamp holder

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Publication number Priority date Publication date Assignee Title
CN2788314Y (en) * 2005-03-31 2006-06-14 聚鼎科技股份有限公司 Overcurrent protective element
CN101308759A (en) * 2007-05-16 2008-11-19 台达电子工业股份有限公司 Cold cathode fluorescent lamp and cold cathode fluorescent lamp module
CN205723432U (en) * 2016-05-04 2016-11-23 深圳市良胜电子有限公司 A kind of highly sensitive ceramic discharge tube

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CN108521076B (en) 2020-03-27
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Address after: 448000 a group of Bai Guo village, Li Xi Town, Dongbao District, Jingmen City, Hubei

Co-patentee after: Dongguan city standard hardware Co. Ltd.

Patentee after: Gu Chunning

Address before: 448000 a group of Bai Guo village, Li Xi Town, Dongbao District, Jingmen City, Jingzhou, Hubei

Co-patentee before: Dongguan city standard hardware Co. Ltd.

Patentee before: Gu Chunning