CN106785922A - A kind of gas discharge tube electrode and preparation method thereof - Google Patents

A kind of gas discharge tube electrode and preparation method thereof Download PDF

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Publication number
CN106785922A
CN106785922A CN201710199786.8A CN201710199786A CN106785922A CN 106785922 A CN106785922 A CN 106785922A CN 201710199786 A CN201710199786 A CN 201710199786A CN 106785922 A CN106785922 A CN 106785922A
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China
Prior art keywords
parts
discharge tube
electrode
gas discharge
radiating fin
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CN201710199786.8A
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Chinese (zh)
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CN106785922B (en
Inventor
谷春宁
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Dongguan City Standard Hardware Co Ltd
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Dongguan City Standard Hardware Co Ltd
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Priority to CN201710199786.8A priority Critical patent/CN106785922B/en
Priority to CN201810188493.4A priority patent/CN108521076B/en
Publication of CN106785922A publication Critical patent/CN106785922A/en
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Publication of CN106785922B publication Critical patent/CN106785922B/en
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01TSPARK GAPS; OVERVOLTAGE ARRESTERS USING SPARK GAPS; SPARKING PLUGS; CORONA DEVICES; GENERATING IONS TO BE INTRODUCED INTO NON-ENCLOSED GASES
    • H01T4/00Overvoltage arresters using spark gaps
    • H01T4/02Details
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01JELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
    • H01J17/00Gas-filled discharge tubes with solid cathode
    • H01J17/02Details
    • H01J17/04Electrodes; Screens
    • H01J17/06Cathodes
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01JELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
    • H01J17/00Gas-filled discharge tubes with solid cathode
    • H01J17/02Details
    • H01J17/28Cooling arrangements
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01JELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
    • H01J9/00Apparatus or processes specially adapted for the manufacture, installation, removal, maintenance of electric discharge tubes, discharge lamps, or parts thereof; Recovery of material from discharge tubes or lamps
    • H01J9/02Manufacture of electrodes or electrode systems
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01TSPARK GAPS; OVERVOLTAGE ARRESTERS USING SPARK GAPS; SPARKING PLUGS; CORONA DEVICES; GENERATING IONS TO BE INTRODUCED INTO NON-ENCLOSED GASES
    • H01T1/00Details of spark gaps
    • H01T1/16Series resistor structurally associated with spark gap
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01TSPARK GAPS; OVERVOLTAGE ARRESTERS USING SPARK GAPS; SPARKING PLUGS; CORONA DEVICES; GENERATING IONS TO BE INTRODUCED INTO NON-ENCLOSED GASES
    • H01T1/00Details of spark gaps
    • H01T1/20Means for starting arc or facilitating ignition of spark gap
    • H01T1/22Means for starting arc or facilitating ignition of spark gap by the shape or the composition of the electrodes
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01TSPARK GAPS; OVERVOLTAGE ARRESTERS USING SPARK GAPS; SPARKING PLUGS; CORONA DEVICES; GENERATING IONS TO BE INTRODUCED INTO NON-ENCLOSED GASES
    • H01T1/00Details of spark gaps
    • H01T1/24Selection of materials for electrodes
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01TSPARK GAPS; OVERVOLTAGE ARRESTERS USING SPARK GAPS; SPARKING PLUGS; CORONA DEVICES; GENERATING IONS TO BE INTRODUCED INTO NON-ENCLOSED GASES
    • H01T21/00Apparatus or processes specially adapted for the manufacture or maintenance of spark gaps or sparking plugs

Landscapes

  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Gas-Filled Discharge Tubes (AREA)
  • Formation Of Various Coating Films On Cathode Ray Tubes And Lamps (AREA)
  • Details Of Resistors (AREA)
  • Oxygen, Ozone, And Oxides In General (AREA)

Abstract

Claimed a kind of gas discharge tube electrode and preparation method thereof, the electrode is mainly made up of metal material, and electronic powder is coated with the inside of the electrode, has electric insulation heat transfer film in the electrode outer application;Further, the gas-discharge tube is mainly used in ceramic gas discharge tube, and thermal resistance is provided with the electric insulation heat transfer film surface, and the thermal resistance is connected with glass gas-discharge pipe, then in parallel with the ceramic gas discharge tube again.The preparation method of electrode is first to pour to be made the metal electrode with radiating fin in the present invention, then in metal electrode radiating fin side spraying electric insulation heat transfer film.Easily overheated present invention mainly solves gas-discharge tube in the prior art, the short technical problem of service life;Also further solve the long technical problem of ceramic gas discharge tube response time in the prior art.

Description

A kind of gas discharge tube electrode and preparation method thereof
Technical field
The invention belongs to gas-discharge tube field, more particularly to a kind of gas discharge tube electrode and preparation method thereof.
Background technology
Ceramic gas discharge tube is that appropriate gas medium is filled with discharging gap, is equipped with the electron emission material of high activity Material and the mechanism, the gas discharge of a kind of special cermet structure being made up of silver-copper brazing alloy intermediate temperature sealing high of igniting of discharging Device.It is mainly used in instantaneous overvoltage protection, also can be used as ignition switch.The through-current capacity of ceramic gas discharge tube is than pressure-sensitive electricity Resistance and TVS pipe are big, and the protection device such as gas-discharge tube and TVS should make most overcurrent pass through gas-discharge tube when sharing Release.The insulaion resistance of gas-discharge tube is very high, can reach the magnitude of begohm.The value of interelectrode capacity is very small, and one As it is very small in below 2pF, interelectrode leakageg stream, be nA grades.Therefore gas-discharge tube is attempted by circuit and circuit substantially will not Any influence constituted.But gas-discharge tube for a long time bear or continually overcurrent when, gas-discharge tube can be heating up, gas Two metal electrodes of discharge tube melt sputtering amount greatly, are easily caused electric discharge tube impedance and decline or even form short-circuit.Therefore how to have Effect prevents gas generating pipe from overheating, and improves the service life of gas-discharge tube, is the technical problem that this area is badly in need of solving.This Outward, existing ceramic gas discharge tube electrode is generally made of oxygen-free copper and 4J42 iron nickel (42%) nickel alloy, in electrode Side is coated with one layer of electronic powder, is used to accelerate the response time of ceramic gas discharge tube.But general ceramic gas discharge tube Response time, so that counting ms, is most slow in protection device, therefore how to improve the sound of ceramic gas discharge tube in hundreds of ns It is also the technical problem of this area urgent need solution between seasonable.
The content of the invention
Present invention seek to address that existing gas-discharge tube is easily overheated, a kind of short technical barrier of service life, there is provided gas Discharge tube electrode and preparation method thereof.On this basis, long carried out present invention is alternatively directed to the ceramic gas discharge tube response time Improve, the gas discharge tube electrode after improvement can significantly shorten the response time of ceramic gas discharge tube.
In order to achieve the above object, present invention employs following technical scheme:
A kind of gas discharge tube electrode, is mainly made up of metal material, and electronic powder is coated with the inside of the electrode, The electrode outer application has one layer of electric insulation heat transfer film.
Used as improved technical scheme of the invention, the electrode outside is provided with multiple radiating fins, the radiating fin and institute Electrode is stated to be integrally formed by metal material.
Further, the radiating fin is sequentially arranged in parallel, and middle radiating fin is long, and the radiating fin of both sides is short.
Used as further improved technical scheme of the present invention, the gas discharge tube electrode is mainly used in ceramic gas and puts Fulgurite, thermal resistance is mounted with the electric insulation heat transfer film surface, and the thermal resistance is connected with a glass gas-discharge pipe It is in parallel with the ceramic gas discharge tube again afterwards.
Further, thermal resistance " Z " type is distributed in the electric insulation heat transfer film surface.
Further, the thermal resistance winds helically tubulose by heating wire bending.
As another object of the present invention, the invention provides a kind of preparation method of gas discharge tube electrode, mainly Comprise the following steps:Step one, is poured using metal material and is made electrode of the one side with radiating fin;Step 2, in radiating fin Be electrically insulated heat transfer film in the electrode surface spraying of side.
Further, the step 2 is:Take 2~6 parts of titanium dioxide, 3~7 parts of alundum (Al2O3), 1~5 part of carborundum, 9.5~15 parts of kaolin, 15~25 parts of propyl alcohol, 20~30 parts of polymethyl methacrylate, polyarylene sulfide resin 24~35 Part, 0.5~2 part of trimethoxy silane are well mixed, and the electrode surface of radiating fin side are then sprayed on, by the electrode after spraying It is put into 60~80 DEG C of baking oven into 1~3h is changed, is then transferred to 4~10h of intermediate temperature setting in 300~400 DEG C of baking oven, it is naturally cold But.
Further, the step 2 is:Take 3~5 parts of titanium dioxide, 4~6 parts of alundum (Al2O3), 2~4 parts of carborundum, 10.2~13.5 parts of kaolin, 18~23 parts of propyl alcohol, 23~27 parts of polymethyl methacrylate, polyarylene sulfide resin 27~ 32 parts, 0.8~1.5 part of trimethoxy silane be well mixed, the electrode surface of radiating fin side is then sprayed on, after spraying Electrode is put into 60~80 DEG C of baking oven into 1~3h is changed, and is then transferred to 4~10h of intermediate temperature setting in 300~400 DEG C of baking oven, from So cooling.
Preferably, the step 2 is:Take 4 parts of titanium dioxide, 5 parts of alundum (Al2O3), 3 parts of carborundum, 12 parts of kaolin, 20 parts of propyl alcohol, 25 parts of polymethyl methacrylate, 30 parts of polyarylene sulfide resin, 1 part of trimethoxy silane are well mixed, so The electrode surface of radiating fin side is sprayed on afterwards, the electrode after spraying is put into 70 DEG C of baking oven into 2h is changed, be then transferred to 380 DEG C baking oven in intermediate temperature setting 8h, natural cooling.
Beneficial effect:
The present invention is gone out using the heat Quick diffusing that the heat transfer film that is electrically insulated produces gas-discharge tube, is conducive to preventing Only gas-discharge tube overheat, extends the service life of gas-discharge tube.The present invention is also by electric insulation heat transfer film surface Placement thermal resistance, the thermal resistance is connected with glass gas-discharge pipe, therefore when gas-discharge tube two ends produce high pressure, glass Gas-discharge tube quick response is turned on, and electric current passes through heated by electrodes of the thermal resistance to ceramic gas discharge tube so that ceramic gas Electronic powder in discharge tube is easier to discharge electronics, and gas motion in ceramic gas discharge tube is more violent, be more easy to puncture, from And greatly shorten the response time of ceramic gas.Formula the invention further relates to be applied to electric insulation heat transfer film of the invention And preparation method.The features such as gas discharge tube electrode has good good insulating, heat conductivility, high temperature resistant obtained in the formula.
Brief description of the drawings
Fig. 1 is the present invention for the structural representation in ceramic gas discharge tube;
Fig. 2 is structural representation of the thermal resistance in electric insulation heat transfer film surface " Z " type distribution.
Specific embodiment
In order that those skilled in the art becomes apparent from understanding that the understands the present invention, in conjunction with specific embodiment and attached Figure, the present invention is described in detail.
As shown in figure 1, gas discharge tube electrode of the invention is mainly used in ceramic gas discharge tube.Common ceramic gas Body discharge tube mainly includes metal electrode 5, earthenware 6, electronic powder 7, lead 1, lead 2.The present invention is to common ceramic gas Discharge tube is transformed, and is first to coat one layer of electric insulation heat transfer film (not shown) on the surface of metal electrode 5.It is described thin Film it is main by 2~6 parts of titanium dioxide, 3~7 parts of alundum (Al2O3), 1~5 part of carborundum, 9.5~15 parts of kaolin, propyl alcohol 15~ 25 parts, 20~30 parts of polymethyl methacrylate, 24~35 parts of polyarylene sulfide resin, 0.5~2 part of trimethoxy silane system Into.In order that metal electrode 5 has more preferable radiating effect, outside of the metal electrode 5 just to electronic powder 7 is sequentially put down in the present invention Row is arranged with multiple radiating fins 5 ', and the radiating fin 5 ' is integrally formed with the electrode 5 by metal material, middle radiating fin 5 ' Long, the radiating fin 5 ' of both sides is short.Thus, born for a long time or during continually overcurrent when ceramic gas discharge tube, gas discharge Two metal electrodes 5 of pipe will quickly be derived heat by radiating fin 5 ', so as to prevent gas-discharge tube from overheating.
For the technical problem that the ceramic gas discharge tube response time is long, the present invention it is above-mentioned it is improved on the basis of to ceramics Gas-discharge tube has made further improvement.Be first in electric insulation heat transfer film placement thermal resistance 4, the thermal resistance 4 with One glass gas-discharge pipe 3 is in parallel with the ceramic gas discharge tube again after connecting.4 ' is drawing for two thermal resistances 4 of connection Line.When ceramic gas discharge tube two ends produce high pressure, the conducting of the quick response of glass gas-discharge pipe 3 generally only needs several nanoseconds, Electric current is heated by thermal resistance 4 to the electrode 5 of ceramic gas discharge tube so that the electronic powder 7 in ceramic gas discharge tube more holds Easy release electronics, gas motion in ceramic gas discharge tube is more violent, be more easy to puncture, so as to greatly shorten ceramic gas Response time.Using this scheme, the response time of ceramic gas discharge tube can be made by hundreds of original nanoseconds to several milliseconds It was reduced to for tens nanoseconds.In order to increase the resistance value of thermal resistance 4, can be in by heating wire bending winding by the thermal resistance 4 first Helix, then " Z " type is distributed in the electric insulation heat transfer film surface again, as shown in Figure 2.
Due to the electric insulation heat transfer film on the surface of metal electrode 5 need to meet electrical insulating property is good, heat conduction efficiency is high and Resistant to elevated temperatures feature, therefore formula of the present invention also to the heat transfer film that is electrically insulated is studied, specific embodiment is as follows.
Embodiment 1
A kind of preparation method of gas discharge tube electrode, mainly includes the following steps that:Step one, is poured using metal material Build and be made electrode of the one side with radiating fin;Step 2, takes 2 parts of titanium dioxide, 7 parts of alundum (Al2O3), 5 parts of carborundum, kaolinite 15 parts of soil, 15 parts of propyl alcohol, 30 parts of polymethyl methacrylate, 24 parts of polyarylene sulfide resin, 2 parts of mixing of trimethoxy silane Uniformly, the electrode surface of radiating fin side is then sprayed on, into 1h is changed, then the electrode after spraying is put into 60 DEG C of baking oven It is transferred to intermediate temperature setting 10h, natural cooling in 300 DEG C of baking oven.
Embodiment 2
A kind of preparation method of gas discharge tube electrode, mainly includes the following steps that:Step one, is poured using metal material Build and be made electrode of the one side with radiating fin;Step 2, takes 3 parts of titanium dioxide, 6 parts of alundum (Al2O3), 4 parts of carborundum, kaolinite 13.5 parts of soil, 18 parts of propyl alcohol, 27 parts of polymethyl methacrylate, 27 parts of polyarylene sulfide resin, 1.5 parts of trimethoxy silane It is well mixed, the electrode surface of radiating fin side is then sprayed on, the electrode after spraying is put into 70 DEG C of baking oven into changing 2h, Then intermediate temperature setting 8h, natural cooling in 350 DEG C of baking oven are transferred to.
Embodiment 3
A kind of preparation method of gas discharge tube electrode, mainly includes the following steps that:Step one, is poured using metal material Build and be made electrode of the one side with radiating fin;Step 2, takes 4 parts of titanium dioxide, 5 parts of alundum (Al2O3), 3 parts of carborundum, kaolinite 12 parts of soil, 20 parts of propyl alcohol, 25 parts of polymethyl methacrylate, 30 parts of polyarylene sulfide resin, 1 part of mixing of trimethoxy silane Uniformly, the electrode surface of radiating fin side is then sprayed on, into 3h is changed, then the electrode after spraying is put into 70 DEG C of baking oven It is transferred to intermediate temperature setting 8h, natural cooling in 380 DEG C of baking oven.
Embodiment 4
A kind of preparation method of gas discharge tube electrode, mainly includes the following steps that:Step one, is poured using metal material Build and be made electrode of the one side with radiating fin;Step 2, takes 5 parts of titanium dioxide, 4 parts of alundum (Al2O3), 2 parts of carborundum, kaolinite 10.2 parts of soil, 23 parts of propyl alcohol, 23 parts of polymethyl methacrylate, 32 parts of polyarylene sulfide resin, 0.8 part of trimethoxy silane It is well mixed, the electrode surface of radiating fin side is then sprayed on, the electrode after spraying is put into 80 DEG C of baking oven into changing 1h, Then intermediate temperature setting 4h, natural cooling in 400 DEG C of baking oven are transferred to.
Embodiment 5
A kind of preparation method of gas discharge tube electrode, mainly includes the following steps that:Step one, is poured using metal material Build and be made electrode of the one side with radiating fin;Step 2, takes 6 parts of titanium dioxide, 3 parts of alundum (Al2O3), 1 part of carborundum, kaolinite 9.5 parts of soil, 25 parts of propyl alcohol, 20 parts of polymethyl methacrylate, 35 parts of polyarylene sulfide resin, 0.5 part of trimethoxy silane It is well mixed, the electrode surface of radiating fin side is then sprayed on, the electrode after spraying is put into 70 DEG C of baking oven into changing 2h, Then intermediate temperature setting 4h, natural cooling in 380 DEG C of baking oven are transferred to.
Gas discharge tube electrode obtained in above method disclosure satisfy that electrical insulating property is good, thermal conductivity is good, resistant to elevated temperatures It is required that.
Obviously, above-described embodiment is used for the purpose of clearly demonstrating example, rather than the limitation to implementation method.It is right For those of ordinary skill in the art, can also make on the basis of the above description other multi-forms change or Change.There is no need and unable to be exhaustive to all of implementation method.As long as made on the basis of the embodiment of the present invention The change scheme of common-sense, among protection scope of the present invention.

Claims (10)

1. a kind of gas discharge tube electrode, is mainly made up of metal material, it is characterised in that:It is coated with the inside of the electrode Electronic powder, has one layer of electric insulation heat transfer film in the electrode outer application.
2. gas discharge tube electrode according to claim 1, it is characterised in that:The electrode outside is provided with multiple dissipating Hot wing, the radiating fin is integrally formed with the electrode by metal material.
3. gas discharge tube electrode according to claim 2, it is characterised in that:The radiating fin is sequentially arranged in parallel, Middle radiating fin is long, and the radiating fin of both sides is short.
4. gas discharge tube electrode according to claim 1, it is characterised in that:The gas discharge tube electrode is main For ceramic gas discharge tube, thermal resistance, the thermal resistance and a glass are mounted with the electric insulation heat transfer film surface It is in parallel with the ceramic gas discharge tube again after gas-discharge tube series connection.
5. gas discharge tube electrode according to claim 4, it is characterised in that:Thermal resistance " Z " type is distributed in institute State electric insulation heat transfer film surface.
6. gas discharge tube electrode according to claim 4, it is characterised in that:The thermal resistance is twined by heating wire bending Around helically tubulose.
7. a kind of preparation method of gas discharge tube electrode, mainly includes the following steps that:Step one, is poured using metal material It is made electrode of the one side with radiating fin;Step 2, be electrically insulated heat transfer film in the electrode surface spraying of radiating fin side.
8. the preparation method of gas discharge tube electrode according to claim 7, it is characterised in that:The step 2 is to take It is 2~6 parts of titanium dioxide, 3~7 parts of alundum (Al2O3), 1~5 part of carborundum, 9.5~15 parts of kaolin, 15~25 parts of propyl alcohol, poly- 20~30 parts of methyl methacrylate, 24~35 parts of polyarylene sulfide resin, 0.5~2 part of trimethoxy silane are well mixed, Then the electrode surface of radiating fin side is sprayed on, the electrode after spraying is put into 60~80 DEG C of baking oven into 1~3h is changed, so 4~10h of intermediate temperature setting, natural cooling in 300~400 DEG C of baking oven are transferred to afterwards.
9. the preparation method of gas discharge tube electrode according to claim 8, it is characterised in that:The step 2 is to take 3~5 parts of titanium dioxide, 4~6 parts of alundum (Al2O3), 2~4 parts of carborundum, 10.2~13.5 parts of kaolin, 18~23 parts of propyl alcohol, 23~27 parts of polymethyl methacrylate, 27~32 parts of polyarylene sulfide resin, 0.8~1.5 part of mixing of trimethoxy silane Uniformly, the electrode surface of radiating fin side is then sprayed on, the electrode after spraying is put into 60~80 DEG C of baking oven into changing 1~ 3h, is then transferred to 4~10h of intermediate temperature setting, natural cooling in 300~400 DEG C of baking oven.
10. the preparation method of gas discharge tube electrode according to claim 9, it is characterised in that:The step 2 takes 4 parts of titanium dioxide, 5 parts of alundum (Al2O3), 3 parts of carborundum, 12 parts of kaolin, 20 parts of propyl alcohol, 25 parts of polymethyl methacrylate, 30 parts of polyarylene sulfide resin, 1 part of trimethoxy silane are well mixed, and are then sprayed on the electrode surface of radiating fin side, Electrode after spraying is put into 70 DEG C of baking oven into 2h is changed, intermediate temperature setting 8h in 380 DEG C of baking oven is then transferred to, it is naturally cold But.
CN201710199786.8A 2017-03-30 2017-03-30 A kind of gas discharge tube electrode and preparation method thereof Active CN106785922B (en)

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CN201810188493.4A CN108521076B (en) 2017-03-30 2017-03-30 Electrode for gas discharge tube and preparation method thereof

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108091531A (en) * 2018-01-22 2018-05-29 东莞市阿甘半导体有限公司 Gas-discharge tube and overvoltage protection

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CN2788314Y (en) * 2005-03-31 2006-06-14 聚鼎科技股份有限公司 Overcurrent protective element
CN101308759A (en) * 2007-05-16 2008-11-19 台达电子工业股份有限公司 Cold cathode fluorescent lamp and cold cathode fluorescent lamp module
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CN101735563A (en) * 2009-12-04 2010-06-16 郎玉龙 Composite heat-conducting insulated film and method for manufacturing same
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CN2788314Y (en) * 2005-03-31 2006-06-14 聚鼎科技股份有限公司 Overcurrent protective element
CN101308759A (en) * 2007-05-16 2008-11-19 台达电子工业股份有限公司 Cold cathode fluorescent lamp and cold cathode fluorescent lamp module
CN205723432U (en) * 2016-05-04 2016-11-23 深圳市良胜电子有限公司 A kind of highly sensitive ceramic discharge tube

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Publication number Priority date Publication date Assignee Title
CN108091531A (en) * 2018-01-22 2018-05-29 东莞市阿甘半导体有限公司 Gas-discharge tube and overvoltage protection

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CN108521076B (en) 2020-03-27
CN106785922B (en) 2018-04-06
CN108521076A (en) 2018-09-11

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Address after: 448000 a group of Bai Guo village, Li Xi Town, Dongbao District, Jingmen City, Hubei

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