Specific embodiment
Specific embodiment of the invention is described in detail below.It should be appreciated that described herein specific
Implementation method is merely to illustrate and explain the present invention, and is not intended to limit the invention.
The invention provides a kind of insulating coating composition, wherein, the composition includes insulating materials, binding agent and molten
Agent.
Above-mentioned design is mixed to prepare insulating coating by by insulating materials, binding agent and solvent, then will be obtained above
Insulating coating is coated on battery pole piece simultaneously with anode sizing agent and/or cathode size, then again to being coated with this insulating coating
Battery pole piece blank be punched, the burr of battery pole piece that is obtained after being punched in this way and drop off situation and can obtain
Effective control, solves the problems, such as that short circuit easily occurs in obtained lithium ion battery.
The insulating materials, the binding agent and the solvent can be adjusted according to being actually needed, for example, in this hair
It is bright it is a kind of preferred embodiment in, in order to further improve the insulating properties of obtained insulating coating, adhesive property and
Processing characteristics (for example, die-cutting performance etc.) so that obtained insulating coating can preferably be punched out, after further reducing punching
Burr the problems such as, on the basis of the gross weight of the composition, the content of the insulating materials is 30 weight %-50 weights
Amount %, the content of the binding agent is 2 weight %-5 weight %, and the content of the solvent is 48 weight %-68 weight %.
Here insulating materials can be insulating materials commonly used in the art, for example, one kind is preferred embodiment
In, the insulating materials can select to be ceramic material.Certainly, ceramic material here can be pottery commonly used in the art
Porcelain type, for example, can be silicon carbide ceramics, silicon nitride ceramics etc., certainly, in the implementation method being more highly preferred to, in order to more preferable
Prevent from occurring burr in pole piece blanking process and drop off phenomenon, preferably the mould cutter head being punched is protected, improve mould
Tool cutter head service life, the insulating materials can be further selected as aluminum oxide and/or boehmite.By using aluminum oxide
And/or boehmite, so as to improve insulating coating overall compactness, finish, cool-hot fatigue, fracture toughness, creep resistance
Energy and anti-wear performance etc..It is further preferred that the particle diameter of the aluminum oxide and/or the boehmite is not more than 1 μm.
Similarly, binding agent here can be type commonly used in the art, for example, the binding agent can be selected from
Polyvinyl alcohol, polytetrafluoroethylene (PTFE), sodium carboxymethylcellulose, TPO binding agent and Viton etc., certainly, of the invention
In a kind of implementation method being more highly preferred to, occurs burr when preventing pole piece to be die cut to further improve obtained insulating coating
And the effect for dropping off, the binding agent can be further selected as Kynoar.
Certainly, in order to adhesive property is better achieved, and the obtained insulating coating of raising occurs when preventing pole piece to be die cut
Burr and the effect for dropping off, the Kynoar can be further defined to its intrinsic viscosity and be not less than 2.2dl/g.
Here solvent can also select to be type commonly used in the art, for example, can select for ethylene carbonate,
Propene carbonate etc., certainly, in the implementation method being more highly preferred to, the solvent can be further selected as N- crassitudes
Ketone.
Present invention also offers a kind of preparation method of insulating coating, wherein, the insulating coating is by group described above
Compound is obtained.The preparation method can be conventional mixing, for example, being directly stirred mixing etc..
Certainly, in a kind of implementation method being more highly preferred to, lithium is being coated in order to further improve obtained insulating coating
Die-cutting performance after ion battery, the preparation method includes:
1) binding agent and Part I solvent are mixed, glue is obtained;
2) by step 1) in obtained glue and insulating materials mixing, the young material of coating is obtained;
3) by step 2) in the young material of obtained coating and the mixing of Part II solvent, insulating coating is obtained;
Wherein, on the basis of the gross weight of the solvent, the consumption of the Part I solvent is 80 weight %-90 weights
Amount %, the consumption of the Part II solvent is 10 weight %-20 weight %.
Step 1) in glue can directly be used upon configuration, certainly, in a kind of preferred embodiment party of the invention
In formula, in order that obtained insulating coating processing characteristics more preferably, step 1) in can also include obtained glue is placed in temperature
Spend to place 120-300min under conditions of 10-30 DEG C.
In further preferred embodiment, step 3) in can also include the sieving of obtained insulating coating, and sieving
Sieve aperture be 120-150 mesh.
Mixed process can be mode commonly used in the art, for example, in a preferred embodiment, step 1)
In be mixed into stirring mixing, stir speed (S.S.) is 1200-1500r/min, and mixing time is 120-180min;And/or
Step 2) in be mixed into stirring mixing, stir speed (S.S.) is 1500-2000r/min, and mixing time is 240-360min;
And/or
Step 3) in be mixed into stirring mixing, stir speed (S.S.) is 1500-2000r/min, and mixing time is 30-60min.
Present invention also offers a kind of positive plate, wherein, the positive plate is included according to preparation method system described above
The insulating coating for obtaining.
Certainly, the preparation method of positive plate here can be with specific as follows:Insulating coating and anode sizing agent are coated on just
Pole sheet metal surface;And/or insulating coating and cathode size are coated on negative metal piece surface.Will insulating coating and slurry
Sheet metal surface is coated on, as shown in figure 1, the aluminium foil to be coated with insulating coating and anode sizing agent.
In order to further make obtained positive plate blank and negative plate the blank burr and to drop off situation less after punching, such as
Shown in Fig. 2, the thickness of the insulating coating can be further selected as 3-8mm;And the insulating coating and the anode sizing agent
The thickness of intersection is 1-2mm (i.e. the part of reference 3 in Fig. 1 and Fig. 2), and/or the insulating coating and described negative
The thickness of pole slurry intersection is 1-2mm (i.e. the part of reference 3 in Fig. 1 and Fig. 2).
Present invention also offers a kind of lithium ion battery, wherein, the lithium ion battery include according to it is described above just
Pole piece.
Below will the present invention will be described in detail by embodiment.In following examples, the aluminum oxide is commercially available grain
Footpath is not more than 1 μm of commercially available product, and the boehmite is conventional commercial product, the Kynoar for the trade mark be 5130 it is commercially available
Product, the 1-METHYLPYRROLIDONE is conventional commercial product.
Preparation example 1
1) 1-METHYLPYRROLIDONE of the Kynoar of 2 weight %, 60 weight % is placed in conjunction pulp grinder and is stirred
180min is obtained glue;
2) obtained glue is placed in temperature to place 300min curings under conditions of 25 DEG C;
3) to after the aluminum oxide that 30 weight % are added in the glue after above-mentioned curing, stirring 300min is obtained the young material of coating;
4) to step 3) in the 1-METHYLPYRROLIDONE of 8 weight % is added in the young material of obtained coating after stir, make
Obtain mixture M 1;
5) by step 4) in after obtained mixture M 1 crosses 150 mesh sieves, insulating coating A1 is obtained.
Preparation example 2
Preparation method according to preparation example 1 is prepared, unlike, the aluminum oxide is substituted with boehmite, gather inclined fluorine
The consumption of ethene is 3 weight %, and the consumption of boehmite is 40 weight %, step 1) in the consumption of 1-METHYLPYRROLIDONE be 50 weights
Amount %, step 4) in the consumption of 1-METHYLPYRROLIDONE be 7 weight %, insulating coating A2 is obtained.
Preparation example 3
Preparation method according to preparation example 1 is prepared, unlike, step 3) in be additionally added boehmite, polyvinylidene fluoride
The consumption of alkene is 5 weight %, and the consumption of boehmite is 25 weight %, and the consumption of aluminum oxide is 25 weight %, step 1) in N- first
The consumption of base pyrrolidones be 40 weight %, step 4) in 1-METHYLPYRROLIDONE consumption be 5 weight %, be obtained insulating coating
A3。
Preparation example 4
The aluminum oxide of the Kynoar of 2 weight %, the 1-METHYLPYRROLIDONE of 68 weight % and 30 weight % is placed in
After crossing 150 mesh sieves after stirring 180min in conjunction pulp grinder, insulating coating A4 is obtained.
Application examples 1
Obtained insulating coating A1 in preparation example 1 and anode sizing agent are coated in anode collection simultaneously by extrusion coating machine
Simultaneously, insulating coating A1's body aluminium foil goes forward side by side along anode sizing agent edge-coating about 5-6mm (i.e. the thickness of insulating coating is 5-6mm)
Row drying, it is to be dried after, continue coat plus plate current-collecting body aluminium foil another side.Simultaneously, it is ensured that anode sizing agent and insulating coating A1
The degree of registration of side is 0.5-1mm, and positive plate blank is obtained.Positive plate blank obtained above is punched out, positive pole is obtained
Piece B1.
Application examples 2
Preparation method according to application examples 1 is prepared, unlike, the insulating coating for using is insulating coating A2, system
Obtain positive plate B2.
Application examples 3
Preparation method according to application examples 1 is prepared, unlike, the insulating coating for using is insulating coating A2, system
Obtain positive plate B3.
Application examples 4
Preparation method according to application examples 1 is prepared, unlike, the insulating coating for using is insulating coating A4, system
Obtain positive plate B4.
Comparative example 1
Preparation method according to application examples 1 is prepared, unlike, insulating coating A1 is not used, positive plate D1 is obtained.
Test case
Detect respectively and the burr of B1-B3 obtained above and D1 and drop off situation, while by B1-B3 obtained above and D1
Lithium ion battery is assembled into by this area usual manner, its cycle life is detected, the result for obtaining is as shown in table 1.
Table 1
The preferred embodiment of the present invention described in detail above, but, the present invention is not limited in above-mentioned implementation method
Detail, in range of the technology design of the invention, various simple variants can be carried out to technical scheme, this
A little simple variants belong to protection scope of the present invention.
It is further to note that each particular technique feature described in above-mentioned specific embodiment, in not lance
In the case of shield, can be combined by any suitable means, in order to avoid unnecessary repetition, the present invention to it is various can
The combination of energy is no longer separately illustrated.
Additionally, can also be combined between a variety of implementation methods of the invention, as long as it is without prejudice to originally
The thought of invention, it should equally be considered as content disclosed in this invention.