CN106769361A - The device and method that particle is separate in a kind of lubricating oil based on microflow control technique - Google Patents

The device and method that particle is separate in a kind of lubricating oil based on microflow control technique Download PDF

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Publication number
CN106769361A
CN106769361A CN201710028821.XA CN201710028821A CN106769361A CN 106769361 A CN106769361 A CN 106769361A CN 201710028821 A CN201710028821 A CN 201710028821A CN 106769361 A CN106769361 A CN 106769361A
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China
Prior art keywords
channel
particle
fluid
main channel
micro
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Chinese (zh)
Inventor
潘新祥
刘志坚
于可真
苑海超
江佳威
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Dalian Maritime University
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Dalian Maritime University
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Priority to CN201710028821.XA priority Critical patent/CN106769361A/en
Publication of CN106769361A publication Critical patent/CN106769361A/en
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    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N21/00Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
    • G01N21/62Systems in which the material investigated is excited whereby it emits light or causes a change in wavelength of the incident light
    • G01N21/71Systems in which the material investigated is excited whereby it emits light or causes a change in wavelength of the incident light thermally excited
    • G01N21/718Laser microanalysis, i.e. with formation of sample plasma
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N1/00Sampling; Preparing specimens for investigation
    • G01N1/28Preparing specimens for investigation including physical details of (bio-)chemical methods covered elsewhere, e.g. G01N33/50, C12Q
    • G01N1/34Purifying; Cleaning
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N21/00Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
    • G01N21/62Systems in which the material investigated is excited whereby it emits light or causes a change in wavelength of the incident light
    • G01N21/63Systems in which the material investigated is excited whereby it emits light or causes a change in wavelength of the incident light optically excited

Abstract

The present invention provides a kind of device of particle separation in lubricating oil based on microflow control technique, it is characterised in that including:Micro-fluidic chip, micro-fluidic chip includes substrate and micro-fluidic chip body;Micro-fluidic chip body is provided with main channel, focus channel, hybrid channel, and a plurality of split tunnel;Micro-injection pump, has two, and one is connected with the main channel inlet opening of main channel, for pre-set velocity to be measured fluid of the injection with metallic particles;Another is connected with the focus channel inlet opening of focus channel, and the pure fluid without particle is injected to pre-set velocity;LIBS detecting systems, the tail end with each bar split tunnel is connected, and is used to determine that the metal types of each split tunnel judge whether to reach separating effect.The invention also discloses in lubricating oil particle separate method, with simple structure, simple to operation, portability etc. a little.

Description

The device and method that particle is separate in a kind of lubricating oil based on microflow control technique
Technical field
Technology the present invention relates to separate different types of metallic particles from lubricating oil, more particularly to it is a kind of based on miniflow Control the device and method of particle separation in the lubricating oil of chip technology.
Background technology
Lubricating fluid is widely applied in motive power machine equipment as industrial " blood ", is actually included in lubricating fluid A large amount of pollutants, wherein the most serious with the harm of solid pollutant.Metallic particles hardness in solid pollutant is higher, easily The abrasion of plant equipment moving component is caused, triggers mechanical breakdown.In addition by the material to lubricant oil metal and non-metallic particle The research of the characteristics such as material, quantity and size, can effectively evaluate the working condition of plant equipment, while it is also predicted that the machinery The malfunction of equipment.In order to ensure the safe operation of plant equipment, maintenance cost is reduced, examined in real time for running status Survey and detect essential link as mechanical equipment state, it is a wherein very important part that detection is carried out to lubricating oil.
Operation principle according to sensor is different, and lubricating oil detection can be divided into following a few classes:KINETIC METHOD, dielectrophoresis Method, magnetic separation method, acoustic method etc..This several method has respective advantage and disadvantage:
1) KINETIC METHOD:For dynamics separation method, the geometry of fixed obstacle by decision systems point From efficiency.And when needing to change separation parameter for those, this will greatly limit the use of this method.
2) dielectrophoresis method:For dielectrophoresis separation method, system needs the extremely complex chip of construction, and It is difficult to collect the particle of separation.
3) magnetic separation point-score:For magnetic separation separation method, particle must be ferromagnetic particle, this particle to separation Scope can cause very big limitation.
4) acoustic method:It is this for the separation method of acoustics, it is contemplated that cube being directly proportional for sound power and particle radii Method is generally not suitable for little particle.
The above method has the deficiencies such as energy supply demand is big, reagent dosage is more, disengaging time is long, separation expense is high Place, with stronger limitation, it is impossible to inexpensive, quick, the easy detection requirement required for fully meeting at present.
The content of the invention
According to technical problem set forth above, and a kind of low cost, simple structure are provided, rapidly can be divided online From the device and method that generalization is strong in field, variety classes particle is separate in lubricating oil based on microfluidic chip technology. The present invention is mainly separated using microfluidic chip technology, centrifugal principle to different types of metallic particles in fluid, and Detected with LIBS (LIBS) technology, the composition of metal is confirmed, so that for the analysis of liquid provides ginseng Examine, realize that liquid on-line is detected.
The technological means that the present invention is used is as follows:
The device that particle is separate in a kind of lubricating oil based on microflow control technique, it is characterised in that including:
Micro-fluidic chip, the micro-fluidic chip includes substrate and setting micro-fluidic chip body on the substrate; The micro-fluidic chip body is provided with a main channel for fluid to be detected flowing, and one is connected with the main channel For focused particle fluid flowing focus channel, the use being connected with the main channel and the focus channel tail end In mixing the hybrid channel of fluid to be measured and focused particle fluid, and it is arranged on a plurality of separation of the hybrid channel tail end and leads to Road;
Micro-injection pump, has two, and one is connected with the main channel inlet opening of the main channel, for pre-set velocity To be measured fluid of the injection with metallic particles;Another is connected with the focus channel inlet opening of the focus channel, is used to preset Pure fluid of the speed injection without particle;
LIBS detecting systems, the tail end with each bar split tunnel is connected, and is used to determine the metal types of each split tunnel, Judge whether to reach separating effect with this.
Two above-mentioned micro-injection pumps, wherein one is connected with the main channel inlet opening of main channel, it is micro by adjusting The program of syringe pump, is allowed to inject fluid to be measured to main channel in preset speed.Another with the focus channel of focus channel Inlet opening is connected, and adjusts the program of micro-injection pump, is allowed to flow to focus channel in preset speed, the fluid of focus channel Effect is exactly the particle in prepare liquid is run close to channel wall, different types of particle is entered in same position Enter bend, it is because different types of metallic particles density is differed and then different types of according to the principle of centrifugation The quality of particle is differed, in order to ensure separate accuracy, this separate mode just for similar particle size particle, According to centrifugal force formula:
On the premise of particle size is approximate, in the case of initial velocity identical, suffered by different types of metallic particles Centrifugal force is different, therefore different types of particle can form different tracks after bend is entered, different so as to enter Split tunnel.LIBS detecting systems are connected with split tunnel tail end, are mainly used for each passage after detection separation terminates Metal species, play a part of a checking, check different types of particle whether enter different split tunnel (LIBS, LIBS technology, the technology focuses on sample surfaces and forms plasma by ultra-short pulse laser, using light Spectrometer plasma emission spectrum is analyzed, and the element constituent in sample is recognized with this, and then can carry out material The identification of material, classification, qualitative and quantitative analysis).
Further, the main channel includes that the master for throwing sample for lubricating oil sample for being arranged at the main channel end is led to Road inlet opening, the main channel is rectangular passage for longitudinal section.
Further, the focus channel includes being arranged at the focusing for injecting pure fluid of the focus channel end Passage inlet opening, the focus channel is rectangular passage for longitudinal section, the focus channel and the main channel into 30 °- 90 ° of angle, angle is preferably 30 ° -60 °, and the width of flow path of the aggregation passage is wider than the width of flow path of the main channel, really The metallic particles of fluid to be measured can be pressed to wall by guarantor, it is moved close to wall.
Generally, the focus channel can reach with the angle of the main channel at 30 ° -90 ° according to required Effect is selected, and angle is bigger, easier focused particle, particle is moved close to wall.
Further, the head end and tail end of the hybrid channel respectively with the main channel, the focus channel and described Split tunnel is connected, and the hybrid channel is the curved passage with gentle transition.
Further, the split tunnel include be arranged at the split tunnel tail end for collect separate after metal The sorting hole of particle, the split tunnel is provided with N bars, a kind of every split tunnel metallic particles of correspondence, and the split tunnel is Longitudinal section is rectangular passage.
The invention also discloses a kind of separation side of particle sorting apparatus in above-mentioned lubricating oil based on microflow control technique Method, it is characterised in that comprise the following steps,
S1, two injecting programs of micro-injection pump of debugging, keep it logical to the master respectively with constant speed Fluid to be measured and pure fluid are injected in road inlet opening and the focus channel inlet opening;
S2, the injection with fluid to be measured and pure fluid, fluid to be measured is by the main channel and pure fluid by described Focus channel mixes in the hybrid channel, and pure fluid enables the particle in fluid to be measured close to the wall of the hybrid channel Move in face;
S3, by coutroi velocity, when metallic particles enters the curved passage of the hybrid channel, different type metal Grain is subject to centrifugal forces to produce different motion track, eventually flow to different split tunnels, converge in sorting hole, lead to Cross LIBS systems to be detected, confirm metal ingredient, check whether different metallic particles are stayed in the middle of different split tunnels, Ensure separate accuracy.
Compared with prior art, this has advantages below:
1st, due to the platform as different metal particle in oil and water separation separate using micro-fluidic chip, related detection sets Standby small volume, relative to large-scale valuable testing equipment, with simple structure, operation easily and the features such as portability.
2nd, the technology used in the present invention and principle are simple, overcome equipment complexity, the low shortcoming of efficiency, while microfluid Passage design is easy, with very strong actual operation.
3rd, the technology used in the present invention is simple to operate without being marked to sample.
For the foregoing reasons, the present invention is capable of achieving low cost, simply and rapidly carries out ON-LINE SEPARATION, can be in lubricating oil The fields such as detection are widely popularized.
Brief description of the drawings
In order to illustrate more clearly about the embodiment of the present invention or technical scheme of the prior art, below will be to embodiment or existing The accompanying drawing to be used needed for having technology description does simply to introduce, it should be apparent that, drawings in the following description are this hairs Some bright embodiments, for those of ordinary skill in the art, without having to pay creative labor, can be with Other accompanying drawings are obtained according to these accompanying drawings.
Fig. 1 is the structural representation of particle sorting apparatus in lubricating oil of the present invention based on microflow control technique.
Fig. 2 is the structural representation of micro-fluidic detection chip of the present invention.
Fig. 3 is the design sketch for using device and method of the invention reached needed for particle is separated.
Fig. 4 is separating resulting figure of the present invention based on the simulation of ansys softwares.
In figure:1st, main channel inlet opening;2nd, focus channel inlet opening;3rd, the first sorting hole;4th, the second sorting hole;5th, it is main logical Road;6th, focus channel;7th, hybrid channel;8th, the first split tunnel;9th, the second split tunnel;10th, No. 1 micro-injection pump;11、2 Number micro-injection pump;12nd, LIBS detecting systems;13rd, micro-fluidic chip body;14th, substrate.
Specific embodiment
To make the purpose, technical scheme and advantage of the embodiment of the present invention clearer, below in conjunction with the embodiment of the present invention In accompanying drawing, the technical scheme in the embodiment of the present invention is clearly and completely described, it is clear that described embodiment is A part of embodiment of the present invention, rather than whole embodiments.Based on the embodiment in the present invention, those of ordinary skill in the art The every other embodiment obtained under the premise of creative work is not made, belongs to the scope of protection of the invention.
As shown in Figure 1 and Figure 2, the device that particle is separate in a kind of lubricating oil based on microflow control technique, including:
Micro-fluidic chip, the micro-fluidic chip includes substrate 14 and the micro-fluidic chip master being arranged on the substrate 14 Body 13;The micro-fluidic chip body 13 is provided with a main channel 5 for fluid to be detected flowing, and the main channel 5 is wrapped The main channel inlet opening 1 that sample is thrown for lubricating oil sample for being arranged at the end of the main channel 5 is included, the main channel 5 is cut for vertical Face is rectangular passage.
The micro-fluidic chip body 13 be provided with one be connected with the main channel 5 for focused particle fluid stream Dynamic focus channel 6, the focus channel 6 includes being arranged at the focusing for injecting pure fluid of the end of the focus channel 6 Passage inlet opening 2, the focus channel 6 is rectangular passage, the focus channel 6 and 5 one-tenth of the main channel for longitudinal section 45 degree of angle, the width of flow path of the aggregation passage 6 is wider than the width of flow path of the main channel 5.
The micro-fluidic chip body 13 is provided with one and is connected with the main channel 5 and the tail end of the focus channel 6 The hybrid channel 7 for mixing fluid to be measured and focused particle fluid, the head end and tail end of the hybrid channel 7 respectively with institute State main channel 5, the focus channel 6 to be connected with the split tunnel, the hybrid channel 7 is curved logical with gentle transition Road.
The a plurality of split tunnel of the tail end of the hybrid channel 7, the split tunnel includes being arranged at the split tunnel tail The sorting hole for collecting the metallic particles after separating at end, for two split tunnels are respectively that the first separation is led to shown in Fig. 2 The split tunnel 9 of road 8 and second, the tail end of corresponding first split tunnel 8 is the first sorting hole 3, the tail end of the second split tunnel 9 It is the second sorting hole 4;A kind of every split tunnel metallic particles of correspondence, the split tunnel is rectangular logical for longitudinal section Road.
Micro-injection pump, has two, is No. 1 micro-injection pump 10 and No. 2 micro-injection pumps 11 in the present embodiment;No. 1 Micro-injection pump 10 is connected with the main channel inlet opening 1 of the main channel 5, for carrying metallic particles with pre-set velocity injection Fluid to be measured;No. 2 micro-injection pumps 11 are connected with the focus channel inlet opening 2 of the focus channel 6, are injected to pre-set velocity Without the pure fluid of particle.
LIBS detecting systems 12, the tail end with each bar split tunnel is connected, and is used to determine the metal class of each split tunnel Type, judges whether to reach separating effect with this.
The invention also discloses the separation method of particle sorting apparatus in the above-mentioned lubricating oil based on microflow control technique, bag Include following steps,
S1, two injecting programs of micro-injection pump of debugging, keep it logical to the master respectively with constant speed Fluid to be measured and pure fluid are injected in road inlet opening 1 and the focus channel inlet opening 2;
S2, the injection with fluid to be measured and pure fluid, fluid to be measured is by the main channel 5 and pure fluid by described Focus channel 6 mixes in the hybrid channel 7, and pure fluid enables the particle in fluid to be measured close to the hybrid channel 7 Wall motion;
S3, by coutroi velocity, when metallic particles enters the curved passage of the hybrid channel 7, different type metal Particle is subject to centrifugal forces to produce different motion track, eventually flow to different split tunnels, in converging in sorting hole, Detected by LIBS systems, confirmed metal ingredient, checked different metallic particles whether to stay in different split tunnels and work as In, it is ensured that the accuracy of separation.
Embodiment 1
The device that particle is separate in lubricating oil based on microflow control technique has said structure, wherein micro-fluidic chip body 13 are made up of PDMS (dimethyl silicone polymer) material, and substrate 14 is made up of PMMA (polymethyl methacrylate), i.e., organic glass Glass.There is good adhesiveness between PDMS (dimethyl silicone polymer) materials and PMMA materials, and with good chemical lazy Property.
Main channel 5 is the passage for fluid to be detected flowing in the micro-fluidic chip body 13;Focus channel 6 is profit The passage of the particle flow of fluid to be measured is focused on pure fluid, mainly, it is close to wall and is moved;Hybrid channel 7, makes difference The different movement locus of generation of type of metal particle;First split tunnel 8 and the second split tunnel 9, in oil and water separation Different metal particle.
Dissimilar metals particle in the lubricating oil based on microflow control technique with reference to described in Fig. 1-Fig. 4 illustrates the present embodiment The operation principle of separator:
First, No. 1 program of micro-injection pump 10 is mixed up, makes the constant speed of its holding toward note in main channel inlet opening 1 Enter fluid to be measured, while mixing up No. 2 programs of micro-injection pump 11, it is kept a constant speed to focus channel feed liquor Inject pure fluid in hole 2, pure fluid can enable the particle in fluid to be measured in hybrid channel 7 as focusing on fluid effect Close to wall motion.No. 1 micro-injection pump 10 and No. 2 speed of micro-injection pump 11 will control proper, it is necessary to reach two mesh 's:As shown in Figures 3 and 4, particle will be moved in hybrid channel close to wall first, secondly particle energy when separation bend is entered Suitable speed is kept, makes different types of metallic particles produce displacement to differ larger movement locus.The control of flow velocity can root Shown according to the analog result of ansys simulation softwards, first determine a general value, adjust micro manually further according to this end value The speed setting of syringe pump, e.g., in the dynamic viscosity of copper aluminium hybrid particles is for the lubricant oil solution of 0.03979kg/m.s, in advance If speed when 0.3-1m/s, can realize preferably separating.
When metallic particles enters the curved passage of hybrid channel 7, due to the centrifugation suffered by dissimilar metals particle Power is differentiated, so can produce different movement locus after curved passage is entered, eventually flows to different split tunnels. Final different particle can be converged in different sorting holes, and the metal in sorting hole can be examined by LIBS detecting systems 12 Survey, confirm metal ingredient, check whether different metallic particles are stayed in the middle of different split tunnels, it is ensured that separation it is accurate Property.
Based on putting forward in microflow control technique, centrifugation principle, used technology and principle compares the present invention Simply, and the detection means equipment it is fairly simple, be easy to carry, and detection low cost, it is adaptable to on-line checking, is different Metallic particles is distinguished and provides a kind of new detection method.
Finally it should be noted that:Various embodiments above is merely illustrative of the technical solution of the present invention, rather than its limitations;To the greatest extent Pipe has been described in detail with reference to foregoing embodiments to the present invention, it will be understood by those within the art that:Its according to The technical scheme described in foregoing embodiments can so be modified, or which part or all technical characteristic are entered Row equivalent;And these modifications or replacement, the essence of appropriate technical solution is departed from various embodiments of the present invention technology The scope of scheme.

Claims (6)

1. the device that particle is separate in a kind of lubricating oil based on microflow control technique, it is characterised in that including:
Micro-fluidic chip, the micro-fluidic chip includes substrate (14) and the micro-fluidic chip master being arranged on the substrate (14) Body (13);The micro-fluidic chip body (13) is provided with a main channel (5) for fluid to be detected flowing, one and institute State the focus channel (6) for the flowing of focused particle fluid that main channel (5) is connected, one with the main channel (5) and institute The hybrid channel (7) for mixing fluid to be measured and focused particle fluid that focus channel (6) tail end is connected is stated, and is set In a plurality of split tunnel of the hybrid channel (7) tail end;
Micro-injection pump, has two, and one is connected with the main channel inlet opening (1) of the main channel (5), for default speed Degree to be measured fluid of the injection with metallic particles;Another is connected with the focus channel inlet opening (2) of the focus channel (6), The pure fluid without particle is injected to pre-set velocity;
LIBS detecting systems (12), the tail end with each bar split tunnel is connected, and is used to determine the metal types of each split tunnel Judge whether to reach separating effect.
2. the device that particle is separate in the lubricating oil based on microflow control technique according to claim 1, it is characterised in that institute Main channel (5) is stated including being arranged at the main channel inlet opening (1) that sample is thrown for lubricating oil sample of the main channel (5) end, The main channel (5) is rectangular passage for longitudinal section.
3. the device that particle is separate in the lubricating oil based on microflow control technique according to claim 1, it is characterised in that institute Focus channel (6) is stated including being arranged at the focus channel inlet opening for injecting pure fluid of the focus channel (6) end (2), the focus channel (6) for longitudinal section be rectangular passage, the focus channel (6) and the main channel (5) into 30 ° -90 ° of angle, the width of flow path of the aggregation passage (6) is wider than the width of flow path of the main channel (5).
4. the device that particle is separate in the lubricating oil based on microflow control technique according to claim 1, it is characterised in that institute State the head end and tail end of hybrid channel (7) respectively with the main channel (5), the focus channel (6) and the split tunnel phase Even, the hybrid channel (7) is the curved passage with gentle transition.
5. the device that particle is separate in the lubricating oil based on microflow control technique according to claim 1, it is characterised in that institute Stating split tunnel includes being arranged at the sorting hole for collecting the metallic particles after separating of the split tunnel tail end, described point N bars are provided with from passage, every split tunnel corresponds to a kind of metallic particles, and the split tunnel is rectangular logical for longitudinal section Road.
6. in a kind of lubricating oil based on microflow control technique as described in claim 1-5 any one particle sorting apparatus point From method, it is characterised in that comprise the following steps,
S1, two injecting programs of micro-injection pump of debugging, make its holding enter to the main channel respectively with constant speed Injection fluid to be measured and pure fluid in fluid apertures (1) and the focus channel inlet opening (2);
S2, the injection with fluid to be measured and pure fluid, fluid to be measured is by the main channel (5) and pure fluid by described poly- Burnt passage (6) mixing in the hybrid channel (7), pure fluid enables the particle in fluid to be measured close to the hybrid channel (7) wall motion;
S3, by coutroi velocity, when metallic particles enters the curved passage of the hybrid channel (7), different type metal Grain is subject to centrifugal forces to produce different motion track, eventually flow to different split tunnels, converge in sorting hole, lead to Cross LIBS systems to be detected, confirm metal ingredient, check whether different metallic particles are stayed in the middle of different split tunnels, Ensure separate accuracy.
CN201710028821.XA 2017-01-16 2017-01-16 The device and method that particle is separate in a kind of lubricating oil based on microflow control technique Pending CN106769361A (en)

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