CN106758515B - A kind of spray painted paper color fixing agent and preparation method thereof - Google Patents
A kind of spray painted paper color fixing agent and preparation method thereof Download PDFInfo
- Publication number
- CN106758515B CN106758515B CN201611136843.XA CN201611136843A CN106758515B CN 106758515 B CN106758515 B CN 106758515B CN 201611136843 A CN201611136843 A CN 201611136843A CN 106758515 B CN106758515 B CN 106758515B
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- parts
- fixing agent
- color fixing
- propylene glycol
- monomethyl ether
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Classifications
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- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
- D21H21/16—Sizing or water-repelling agents
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/10—Coatings without pigments
- D21H19/14—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/10—Coatings without pigments
- D21H19/14—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12
- D21H19/20—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12 comprising macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses a kind of spray painted paper color fixing agent and preparation method thereof, which is made of the raw material below according to parts by weight: 14-22 parts of polyvinyl alcohol, 5-13 parts of oxalic acid, 3-7 parts of n-butanol, 10-20 parts of propylene glycol monomethyl ether, 21-29 parts of styrene-acrylic emulsion.By styrene-acrylic emulsion and polyvinyl alcohol heating stirring, n-butanol is then added dropwise, cool down stir process；Oxalic acid solution heating stirring is added；Then the processing of propylene glycol monomethyl ether solution heating stirring is added dropwise, is down to room temperature up to color fixing agent.The present invention is applied for spray painted paper, improves the cationic degree of styrene-acrylic emulsion color fixing agent, can be significantly improved printing spray painted paper property, be improved print quality, especially greatly improve into the water-resistance of paper.The present invention greatly improves into paper and meets color density value after water, and raw material is simple, materials are extensive, is free of formaldehyde, and environmentally protective, pollution-free, colour fixation is good, and production technology is easy, and production cost is low, and performance is stablized, and is suitable for industrialized production, has a vast market foreground.
Description
Technical field
The present invention relates to color fixing agent technical field, specifically a kind of spray painted paper color fixing agent and preparation method thereof.
Background technique
Color fixing agent is the auxiliary agent of common fixation colorant in color spray paper and coating, and general character is cation and high molecular weight.Ion
Intensity is high, and strong in dichroic dye molecule active force, can capture and fix electronegative colorant rapidly, play the role of fixation.It is high
Molecular weight cationic polymer, such as polyethyleneimine, polyvinylamine, polydimethyl diallyl ammonium chloride and polystyrene methyl
The polyamines strong cation polymer such as trimethylamine chloride, is used equally for fixation, but these common color fixing agent often water-resistance
It is bad.Cationic styrene-acrylic emulsion is the copolymer of styrene and acrylate and cationic monomer, and when polymerization adds function monomer
Play the role of cross-linked disperse, be common water repellent surface sizing agent, filming function is strong, and enhancing waterproof action is prominent, different monomers
And proportion, synthetic method influence lotion final performance.Cationic styrene-acrylic emulsion molecule has cation group, provides and dyestuff
In conjunction with structure, the hydrophilic-structure of function monomer and emulsifier, can and dye molecule form hydrogen bond, from structure with fixation
Property.But the cationic degree of styrene-acrylic emulsion is not high, and main structure is hydrophobic, and the water-resistance of color fixing agent is poor.
Summary of the invention
The purpose of the present invention is to provide a kind of spray painted paper color fixing agent and preparation method thereof, to solve in above-mentioned background technique
The problem of proposition.
To achieve the above object, the invention provides the following technical scheme:
A kind of spray painted paper color fixing agent, is made of the raw material below according to parts by weight: 14-22 parts of polyvinyl alcohol, oxalic acid 5-13
Part, 3-7 parts of n-butanol, 10-20 parts of propylene glycol monomethyl ether, 21-29 parts of styrene-acrylic emulsion.
As a further solution of the present invention: the spray painted paper color fixing agent is made of the raw material below according to parts by weight: poly-
16-20 parts of vinyl alcohol, 7-11 parts of oxalic acid, 4-6 parts of n-butanol, 12-18 parts of propylene glycol monomethyl ether, 23-27 parts of styrene-acrylic emulsion.
As a further solution of the present invention: the spray painted paper color fixing agent is made of the raw material below according to parts by weight: poly-
18 parts of vinyl alcohol, 9 parts of oxalic acid, 5 parts of n-butanol, 15 parts of propylene glycol monomethyl ether, 25 parts of styrene-acrylic emulsion.
A kind of preparation method of spray painted paper color fixing agent, comprises the steps of:
1) oxalic acid and deionized water are hybridly prepared into the oxalic acid solution that mass concentration is 27%；By propylene glycol monomethyl ether with go
Ionized water is hybridly prepared into the propylene glycol monomethyl ether solution that mass concentration is 35%；
2) by styrene-acrylic emulsion and polyvinyl alcohol, 76 DEG C are warming up to, and stir process 25min at such a temperature, then
N-butanol is added dropwise while stirring, is added dropwise in the time of 18min, 63 DEG C are down to after dripping and at such a temperature at stirring
Manage 68min；Then oxalic acid solution is added, in 93 DEG C of at a temperature of stir process 45min；Then it is added dropwise in the time of 13min
Propylene glycol monomethyl ether solution is down to room temperature in 122 DEG C of at a temperature of stir process 38-40min after dripping up to color fixing agent.
Compared with prior art, the beneficial effects of the present invention are:
The present invention is applied for spray painted paper, can be significantly improved printing spray painted paper property, be improved print quality, especially substantially
Improve into the water-resistance of paper.The present invention further improves the cationic degree of styrene-acrylic emulsion color fixing agent, increases cation group, increases
Add reactive group in combination, solves the problems, such as that color fixing agent hydrophobicity is poor.It is close that the present invention greatly improves into color after paper meets water
Angle value, raw material is simple, materials are extensive, is free of formaldehyde, and environmentally protective, pollution-free, colour fixation is good, and production technology is easy, production
At low cost, performance is stablized, and is suitable for industrialized production, has a vast market foreground.
Specific embodiment
Below in conjunction with the embodiment of the present invention, technical scheme in the embodiment of the invention is clearly and completely described,
Obviously, described embodiments are only a part of the embodiments of the present invention, instead of all the embodiments.Based in the present invention
Embodiment, every other embodiment obtained by those of ordinary skill in the art without making creative efforts, all
Belong to the scope of protection of the invention.
Embodiment 1
In the embodiment of the present invention, a kind of spray painted paper color fixing agent is made of: polyvinyl alcohol 14 raw material below according to parts by weight
Part, 5 parts of oxalic acid, 3 parts of n-butanol, 10 parts of propylene glycol monomethyl ether, 21 parts of styrene-acrylic emulsion.
Oxalic acid and deionized water are hybridly prepared into the oxalic acid solution that mass concentration is 27%；By propylene glycol monomethyl ether and go from
Sub- water is hybridly prepared into the propylene glycol monomethyl ether solution that mass concentration is 35%.By styrene-acrylic emulsion and polyvinyl alcohol, it is warming up to
76 DEG C, and stir process 25min at such a temperature, n-butanol is then added dropwise while stirring, is dripped in the time of 18min
Finish, 63 DEG C and at such a temperature stir process 68min are down to after dripping；Then oxalic acid solution is added, 93 DEG C at a temperature of
Stir process 45min；Then in the time of 13min be added dropwise propylene glycol monomethyl ether solution, after dripping 122 DEG C at a temperature of stir
Processing 38min is mixed, is down to room temperature up to color fixing agent.
Embodiment 2
In the embodiment of the present invention, a kind of spray painted paper color fixing agent is made of: polyvinyl alcohol 22 raw material below according to parts by weight
Part, 13 parts of oxalic acid, 7 parts of n-butanol, 20 parts of propylene glycol monomethyl ether, 29 parts of styrene-acrylic emulsion.
Oxalic acid and deionized water are hybridly prepared into the oxalic acid solution that mass concentration is 27%；By propylene glycol monomethyl ether and go from
Sub- water is hybridly prepared into the propylene glycol monomethyl ether solution that mass concentration is 35%.By styrene-acrylic emulsion and polyvinyl alcohol, it is warming up to
76 DEG C, and stir process 25min at such a temperature, n-butanol is then added dropwise while stirring, is dripped in the time of 18min
Finish, 63 DEG C and at such a temperature stir process 68min are down to after dripping；Then oxalic acid solution is added, 93 DEG C at a temperature of
Stir process 45min；Then in the time of 13min be added dropwise propylene glycol monomethyl ether solution, after dripping 122 DEG C at a temperature of stir
Processing 40min is mixed, is down to room temperature up to color fixing agent.
Embodiment 3
In the embodiment of the present invention, a kind of spray painted paper color fixing agent is made of: polyvinyl alcohol 16 raw material below according to parts by weight
Part, 7 parts of oxalic acid, 4 parts of n-butanol, 12 parts of propylene glycol monomethyl ether, 23 parts of styrene-acrylic emulsion.
Oxalic acid and deionized water are hybridly prepared into the oxalic acid solution that mass concentration is 27%；By propylene glycol monomethyl ether and go from
Sub- water is hybridly prepared into the propylene glycol monomethyl ether solution that mass concentration is 35%.By styrene-acrylic emulsion and polyvinyl alcohol, it is warming up to
76 DEG C, and stir process 25min at such a temperature, n-butanol is then added dropwise while stirring, is dripped in the time of 18min
Finish, 63 DEG C and at such a temperature stir process 68min are down to after dripping；Then oxalic acid solution is added, 93 DEG C at a temperature of
Stir process 45min；Then in the time of 13min be added dropwise propylene glycol monomethyl ether solution, after dripping 122 DEG C at a temperature of stir
Processing 39min is mixed, is down to room temperature up to color fixing agent.
Embodiment 4
In the embodiment of the present invention, a kind of spray painted paper color fixing agent is made of: polyvinyl alcohol 20 raw material below according to parts by weight
Part, 11 parts of oxalic acid, 6 parts of n-butanol, 18 parts of propylene glycol monomethyl ether, 27 parts of styrene-acrylic emulsion.
Oxalic acid and deionized water are hybridly prepared into the oxalic acid solution that mass concentration is 27%；By propylene glycol monomethyl ether and go from
Sub- water is hybridly prepared into the propylene glycol monomethyl ether solution that mass concentration is 35%.By styrene-acrylic emulsion and polyvinyl alcohol, it is warming up to
76 DEG C, and stir process 25min at such a temperature, n-butanol is then added dropwise while stirring, is dripped in the time of 18min
Finish, 63 DEG C and at such a temperature stir process 68min are down to after dripping；Then oxalic acid solution is added, 93 DEG C at a temperature of
Stir process 45min；Then in the time of 13min be added dropwise propylene glycol monomethyl ether solution, after dripping 122 DEG C at a temperature of stir
Processing 39min is mixed, is down to room temperature up to color fixing agent.
Embodiment 5
In the embodiment of the present invention, a kind of spray painted paper color fixing agent is made of: polyvinyl alcohol 18 raw material below according to parts by weight
Part, 9 parts of oxalic acid, 5 parts of n-butanol, 15 parts of propylene glycol monomethyl ether, 25 parts of styrene-acrylic emulsion.
Oxalic acid and deionized water are hybridly prepared into the oxalic acid solution that mass concentration is 27%；By propylene glycol monomethyl ether and go from
Sub- water is hybridly prepared into the propylene glycol monomethyl ether solution that mass concentration is 35%.By styrene-acrylic emulsion and polyvinyl alcohol, it is warming up to
76 DEG C, and stir process 25min at such a temperature, n-butanol is then added dropwise while stirring, is dripped in the time of 18min
Finish, 63 DEG C and at such a temperature stir process 68min are down to after dripping；Then oxalic acid solution is added, 93 DEG C at a temperature of
Stir process 45min；Then in the time of 13min be added dropwise propylene glycol monomethyl ether solution, after dripping 122 DEG C at a temperature of stir
Processing 39min is mixed, is down to room temperature up to color fixing agent.
Comparative example 1
It is other consistent with embodiment 5 in addition to no propylene glycol monomethyl ether.
Comparative example 2
It is other consistent with embodiment 5 in addition to no n-butanol.
Comparative example 3
It is other consistent with embodiment 5 in addition to no propylene glycol monomethyl ether, n-butanol.
Color fixing agent obtained by above-described embodiment 1-5 and comparative example 1-3 is applied over color spray spray painted paper respectively, printing color is close
Degree is measured using X-Rite color densitometer, measures four color densities after washing by water 1 minute to color lump, and four color density high explanation is anti-after bath
Aqueous good, four color densities are C (indigo plant), M (red), Y (Huang), K (ink).It measures color density value and is shown in Table 1.
Table 1
As can be seen from Table 1, after lacking propylene glycol monomethyl ether or n-butanol, after color lump bath 1min, the color of four colors is close
Angle value has very big decline, and it is poor to illustrate to lack color fixing agent water-resistance obtained when propylene glycol monomethyl ether or n-butanol；In comparison,
The color fixing agent of embodiment 1-5 preparation, after color lump bath 1min, color density value detected is high, illustrates that water repelling property obtains
Very big improvement.
It is obvious to a person skilled in the art that invention is not limited to the details of the above exemplary embodiments, Er Qie
In the case where without departing substantially from spirit or essential attributes of the invention, the present invention can be realized in other specific forms.Therefore, no matter
From the point of view of which point, the present embodiments are to be considered as illustrative and not restrictive, and the scope of the present invention is by appended power
Benefit requires rather than above description limits, it is intended that all by what is fallen within the meaning and scope of the equivalent elements of the claims
Variation is included within the present invention.
In addition, it should be understood that although this specification is described in terms of embodiments, but not each embodiment is only wrapped
Containing an independent technical solution, this description of the specification is merely for the sake of clarity, and those skilled in the art should
It considers the specification as a whole, the technical solutions in the various embodiments may also be suitably combined, forms those skilled in the art
The other embodiments being understood that.
Claims (3)
1. a kind of spray painted paper color fixing agent, which is characterized in that the primary raw material according to parts by weight includes: 14-22 parts of polyvinyl alcohol, grass
5-13 parts sour, 3-7 parts of n-butanol, 10-20 parts of propylene glycol monomethyl ether, 21-29 parts of styrene-acrylic emulsion；
This kind of color fixing agent the preparation method comprises the following steps:
1) oxalic acid and deionized water are hybridly prepared into the oxalic acid solution that mass concentration is 27%；By propylene glycol monomethyl ether and deionization
Water is hybridly prepared into the propylene glycol monomethyl ether solution that mass concentration is 35%；
2) by styrene-acrylic emulsion and polyvinyl alcohol, 76 DEG C are warming up to, and stir process 25min at such a temperature, then side is stirred
It mixes side and n-butanol is added dropwise, be added dropwise in the time of 18min, 63 DEG C and at such a temperature stir process are down to after dripping
68min；Then oxalic acid solution is added, in 93 DEG C of at a temperature of stir process 45min；Then third is added dropwise in the time of 13min
Glycol methyl ether solution is down to room temperature in 122 DEG C of at a temperature of stir process 38-40min after dripping up to color fixing agent.
2. spray painted paper color fixing agent according to claim 1, which is characterized in that the primary raw material according to parts by weight includes: poly-
16-20 parts of vinyl alcohol, 7-11 parts of oxalic acid, 4-6 parts of n-butanol, 12-18 parts of propylene glycol monomethyl ether, 23-27 parts of styrene-acrylic emulsion.
3. spray painted paper color fixing agent according to claim 1, which is characterized in that the primary raw material according to parts by weight includes: poly-
18 parts of vinyl alcohol, 9 parts of oxalic acid, 5 parts of n-butanol, 15 parts of propylene glycol monomethyl ether, 25 parts of styrene-acrylic emulsion.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611136843.XA CN106758515B (en) | 2016-12-12 | 2016-12-12 | A kind of spray painted paper color fixing agent and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201611136843.XA CN106758515B (en) | 2016-12-12 | 2016-12-12 | A kind of spray painted paper color fixing agent and preparation method thereof |
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| Publication Number | Publication Date |
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| CN106758515A CN106758515A (en) | 2017-05-31 |
| CN106758515B true CN106758515B (en) | 2019-07-16 |
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102120791A (en) * | 2010-11-19 | 2011-07-13 | 苏州博纳化学科技有限公司 | Preparation method of dispersant |
| CN103074805A (en) * | 2012-12-24 | 2013-05-01 | 广东轻工职业技术学院 | Surface-sizing fixing agent for color ink-jet paper and preparation method and application thereof |
| CN103437224A (en) * | 2013-08-30 | 2013-12-11 | 徐文 | Novel color fixative for textiles |
| CN103643567A (en) * | 2013-12-06 | 2014-03-19 | 成路凯尔服装（苏州）有限公司 | Synthesis method of multifunctional silk fabric fixing agent |
-
2016
- 2016-12-12 CN CN201611136843.XA patent/CN106758515B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102120791A (en) * | 2010-11-19 | 2011-07-13 | 苏州博纳化学科技有限公司 | Preparation method of dispersant |
| CN103074805A (en) * | 2012-12-24 | 2013-05-01 | 广东轻工职业技术学院 | Surface-sizing fixing agent for color ink-jet paper and preparation method and application thereof |
| CN103437224A (en) * | 2013-08-30 | 2013-12-11 | 徐文 | Novel color fixative for textiles |
| CN103643567A (en) * | 2013-12-06 | 2014-03-19 | 成路凯尔服装（苏州）有限公司 | Synthesis method of multifunctional silk fabric fixing agent |
Non-Patent Citations (1)
| Title |
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| 苯丙乳液在彩喷纸表面施胶中的应用;颜进华等;《中华纸业》;20130223;第34卷(第4期);10-13 |
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Effective date of registration: 20190618 Address after: 276000 meters northeast of Miaoling Village, Machanghu Town, Lanshan District, Linyi City, Shandong Province Applicant after: Linyi Meihua Decorative Paper Co., Ltd. Address before: 450000 D502, 1 tower, 96 Ruida Road, Zhengzhou high tech Industrial Development Zone, Henan. Applicant before: Zhengzhou Information Technology Co., Ltd. |
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