CN106756029A - The method that a kind of useless brick of converter reclaims gold and silver - Google Patents
The method that a kind of useless brick of converter reclaims gold and silver Download PDFInfo
- Publication number
- CN106756029A CN106756029A CN201611002568.2A CN201611002568A CN106756029A CN 106756029 A CN106756029 A CN 106756029A CN 201611002568 A CN201611002568 A CN 201611002568A CN 106756029 A CN106756029 A CN 106756029A
- Authority
- CN
- China
- Prior art keywords
- silver
- useless brick
- gold
- obtaining
- lead
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B7/00—Working up raw materials other than ores, e.g. scrap, to produce non-ferrous metals and compounds thereof; Methods of a general interest or applied to the winning of more than two metals
- C22B7/001—Dry processes
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B11/00—Obtaining noble metals
- C22B11/02—Obtaining noble metals by dry processes
- C22B11/021—Recovery of noble metals from waste materials
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B11/00—Obtaining noble metals
- C22B11/06—Chloridising
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B7/00—Working up raw materials other than ores, e.g. scrap, to produce non-ferrous metals and compounds thereof; Methods of a general interest or applied to the winning of more than two metals
- C22B7/006—Wet processes
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
- C25C5/00—Electrolytic production, recovery or refining of metal powders or porous metal masses
- C25C5/02—Electrolytic production, recovery or refining of metal powders or porous metal masses from solutions
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Metallurgy (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Manufacturing & Machinery (AREA)
- Mechanical Engineering (AREA)
- Geology (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Manufacture And Refinement Of Metals (AREA)
- Electrolytic Production Of Metals (AREA)
Abstract
The present invention is the method that a kind of useless brick of converter reclaims gold and silver, and its step is：The useless brick of converter is split out into descendant's work point and sorts out useless brick that part is flooded by molten bath；The useless brick for sorting out is by obtaining the useless brick powder below 200 mesh after broken-fine grinding-grinding；Useless brick powder below 200 mesh obtains the concentrate rich in gold and silver by flotation；Will be enriched in concentrate collocation lead anode slurry input precious metals containing lead stove melting output precious metals containing lead, shoddye and the flue dust of gold and silver；Precious metals containing lead input point silver stove blowing is obtained into electrum, lead skim, bismuth slag and flue dust；Electrum energization electrolysis in the aqueous solution of nitric acid and silver nitrate obtains silver powder, anode scrap and silver anode slime；Silver powder founding reclaims gold into silver ingot product, the method reduced with aqueous solution chlorination-sodium sulfite after silver anode slime nitric acid point silver；The gold for obtaining founding after nitric acid washout impurity into ingot product.The method low consumption, the efficient gold, silver reclaimed in the useless brick of converter, realize the synthetical recovery of resource, remarkable in economical benefits.This method from the useless brick of smelting furnace and converting furnace suitable for extracting the noble metals such as gold, silver precious metal smelting.
Description
Technical field
The present invention relates to the method that a kind of useless brick of converter reclaims gold and silver, belong to precious metal smelting Comprehensive Recovery Technology field.
Background technology
The method being electrolysed with pyrogenic process is reclaimed in the smelting process of noble metal in lead, the Copper making by-product earth of positive pole, for melting
New furnace lining is changed after must being removed after for a period of time with the converter lining of blowing, the furnace lining changed due to being immersed in for a long time
In high temperature precious metal melt, infiltration has the noble metals such as gold, silver in furnace lining, and reclaiming this part noble metal has preferably reality meaning
Justice, can create good economic benefit.
At present, the method that noble metal is reclaimed from the useless brick of converter has the de- lead-nitric acid point of gravity treatment-sulfuric acid de-magging-alkali cleaning
Silver-chloroazotic acid Method for extracting gold.The method acid consumption is big, and a large amount of smelting wastewaters of output, economic benefit is low.
The content of the invention
The purpose of the present invention is directed to the problem that above-mentioned prior art is present, and proposes that a kind of useless brick of converter reclaims the side of gold and silver
Method, the method can the noble metal, remarkable in economical benefits such as low consumption, the efficient gold and silver reclaimed in useless brick.
The purpose of the present invention is realized by the following means：
The method that a kind of useless brick of converter reclaims gold and silver, comprises the following steps：
（1）After converter lining is split out, manual sorting goes out to be flooded by molten bath the useless brick of part；
（2）By step（1）The useless brick crusher in crushing for obtaining, the useless brick ball mill fine grinding after crushing obtains useless brick powder, so
It is milled to below 200 mesh with grinder afterwards；
（3）By step（2）The method of the useless brick powder flotation below 200 mesh for obtaining selects the concentrate rich in gold and silver；
（4）By step（3）The concentrate and lead anode slurry for obtaining are by 1:After sodium carbonate, reduction coal, iron filings, stone flour being allocated into after 2 collocation
It is well mixed；
（5）By step（4）Material input precious metals containing lead stove melting after well mixed, output precious metals containing lead, shoddye and flue dust；
（6）By step（5）The precious metals containing lead input point silver stove blowing for obtaining, output electrum, lead skim, bismuth slag and flue dust.
（7）By step（6）The electrum for obtaining energization electrolysis in the aqueous solution of nitric acid and silver nitrate obtains silver powder, residual
Pole and silver anode slime；
（8）By step（7）The silver powder founding for obtaining is into silver ingot product；
（9）By step（7）Silver separating residues are obtained after the silver anode slime nitric acid for obtaining point silver；
（10）By step（9）The silver separating residues for obtaining aqueous solution chlorination method parting, the method that parting solution is reduced with sodium sulfite
Reclaim gold；
（11）By step（10）The gold for obtaining founding after nitric acid washout impurity into ingot product.
The present invention will permeate noble metal useless brick sort out after carry out fine grinding, it is levigate after useless brick powder floated
Choosing, will put into stove melting after the concentrate obtained by flotation and lead anode slurry collocation, floating using the effectively trapping of the lead in lead anode slurry
Gold and silver in concentrate selection.The present invention does not increase smelting wastewater amount, and sour consumption is not increased, and method is simple and reliable, efficient to reclaim useless brick
In the noble metal, remarkable in economical benefits such as gold and silver.
Brief description of the drawings
Accompanying drawing 1 is process chart of the invention；
Specific embodiment
The present invention is described in further detail with reference to example, but the invention is not restricted to embodiment
Embodiment 1：
（1）By the 13g/t containing gold below 200 mesh, the 218g/t containing gold is obtained after the useless brick powder flotation of argentiferous 0.83%, argentiferous 9.84%
Concentrate.
（2）In step（1）Concentrate 500kg and the 10t 52g/t containing gold for obtaining, the lead anode slurry of argentiferous 7.84% are allocated into
It is well mixed after 400kg sodium carbonate, 200kg reduction coals, 150kg iron filings, 100kg stone flours.
（3）By step（2）Material input precious metals containing lead stove melting after well mixed, output 265g/t containing gold, argentiferous 27.26%
Precious metals containing lead and containing golden 3g/t, the shoddye of argentiferous 0.13%.
（4）By step（3）The precious metals containing lead input point silver stove blowing for obtaining, output is containing gold 0.085%, the gold and silver of argentiferous 97.83%
Alloy.
（5）By step（4）The electrum for obtaining energization electrolysis in the aqueous solution of nitric acid and silver nitrate obtains quality hundred
Fraction be 99.99% silver powder and containing gold 1.32%, the silver anode slime of argentiferous 65.34%.
（6）By step（5）Obtained after the silver anode slime nitric acid for obtaining point silver containing gold 42.58%, point silver of argentiferous 13.65%
Slag.
（7）By step（6）The silver separating residues for obtaining are in L/S=10:Silver separating residues amount is added in the aqueous hydrochloric acid solution of 1 3mol/L
40% sodium chlorate chlorination after filter, filtrate adjustment pH to 1 after with sodium sulfite reduce obtain bronze.
（8）By step（7）99.95% bronze is obtained after the bronze nitric acid washout impurity for obtaining, finally by founding Cheng Jin
Ingot product.
Claims (1)
1. the method that a kind of useless brick of converter reclaims gold and silver, it is characterised in that：Comprise the following steps：
（1）After converter lining is split out, manual sorting goes out to be flooded by molten bath the useless brick of part；
（2）By step（1）The useless brick crusher in crushing for obtaining, the useless brick ball mill fine grinding after crushing obtains useless brick powder, so
It is milled to below 200 mesh with grinder afterwards；
（3）By step（2）The method of the useless brick powder flotation below 200 mesh for obtaining selects the concentrate rich in gold and silver；
（4）By step（3）The concentrate and lead anode slurry for obtaining are by 1:After sodium carbonate, reduction coal, iron filings, stone flour being allocated into after 2 collocation
It is well mixed；
（5）By step（4）Material input precious metals containing lead stove melting after well mixed, output precious metals containing lead, shoddye and flue dust；
（6）By step（5）The precious metals containing lead input point silver stove blowing for obtaining, output electrum, lead skim, bismuth slag and flue dust；
（7）By step（6）The electrum for obtaining energization electrolysis in the aqueous solution of nitric acid and silver nitrate obtain silver powder, anode scrap and
Silver anode slime；
（8）By step（7）The silver powder founding for obtaining is into silver ingot product；
（9）By step（7）Silver separating residues are obtained after the silver anode slime nitric acid for obtaining point silver；
（10）By step（9）The silver separating residues for obtaining aqueous solution chlorination method parting, the method that parting solution is reduced with sodium sulfite
Reclaim gold；
（11）By step（10）The gold for obtaining founding after nitric acid washout impurity into ingot product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611002568.2A CN106756029A (en) | 2016-11-15 | 2016-11-15 | The method that a kind of useless brick of converter reclaims gold and silver |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611002568.2A CN106756029A (en) | 2016-11-15 | 2016-11-15 | The method that a kind of useless brick of converter reclaims gold and silver |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106756029A true CN106756029A (en) | 2017-05-31 |
Family
ID=58968579
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201611002568.2A Pending CN106756029A (en) | 2016-11-15 | 2016-11-15 | The method that a kind of useless brick of converter reclaims gold and silver |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106756029A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107299229A (en) * | 2017-06-06 | 2017-10-27 | 郴州市金贵银业股份有限公司 | The method for reclaiming high silver-colored cigarette ash and the various slag charges rich in silver in silver-colored smelting process |
| CN110551904A (en) * | 2019-10-18 | 2019-12-10 | 广西森合高新科技股份有限公司 | Non-cyanogen gold leaching and gold extraction method for high-sulfur-arsenic-carbon refractory gold concentrate |
| CN110699712A (en) * | 2019-10-18 | 2020-01-17 | 浙江宏达新材料发展有限公司 | Silver electrolysis process and apparatus |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101255500A (en) * | 2008-04-02 | 2008-09-03 | 河南豫光金铅股份有限公司 | Smelting method for separating value metals from anode mud by firing process and device thereof |
| CN102061395A (en) * | 2010-12-10 | 2011-05-18 | 四会市鸿明贵金属有限公司 | Smelting and separating method of noble lead |
| CN105268541A (en) * | 2015-11-23 | 2016-01-27 | 郴州市金贵银业股份有限公司 | Method for recycling metals from furnace lining waste bricks |
-
2016
- 2016-11-15 CN CN201611002568.2A patent/CN106756029A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101255500A (en) * | 2008-04-02 | 2008-09-03 | 河南豫光金铅股份有限公司 | Smelting method for separating value metals from anode mud by firing process and device thereof |
| CN102061395A (en) * | 2010-12-10 | 2011-05-18 | 四会市鸿明贵金属有限公司 | Smelting and separating method of noble lead |
| CN105268541A (en) * | 2015-11-23 | 2016-01-27 | 郴州市金贵银业股份有限公司 | Method for recycling metals from furnace lining waste bricks |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107299229A (en) * | 2017-06-06 | 2017-10-27 | 郴州市金贵银业股份有限公司 | The method for reclaiming high silver-colored cigarette ash and the various slag charges rich in silver in silver-colored smelting process |
| CN110551904A (en) * | 2019-10-18 | 2019-12-10 | 广西森合高新科技股份有限公司 | Non-cyanogen gold leaching and gold extraction method for high-sulfur-arsenic-carbon refractory gold concentrate |
| CN110699712A (en) * | 2019-10-18 | 2020-01-17 | 浙江宏达新材料发展有限公司 | Silver electrolysis process and apparatus |
| CN110699712B (en) * | 2019-10-18 | 2021-03-16 | 浙江宏达新材料发展有限公司 | Silver electrolysis process |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104263965B (en) | The method that gold and lead are reclaimed in difficult-treating gold mine collocation lead containing sludge raw material oxygen enriched molten bath melting | |
| CN108325738A (en) | The step recovery method of metallic aluminium in a kind of aluminium ash | |
| CN106756029A (en) | The method that a kind of useless brick of converter reclaims gold and silver | |
| CN104017991A (en) | Process for efficiently and selectively separating copper in lead copper matte | |
| CN105349791A (en) | Method for selectively extracting copper from iron-copper-matte materials | |
| CN111085336A (en) | Method for recovering iron raw material from rotary kiln slag and harmlessly converting tail slag | |
| CN111363912B (en) | Method for treating rare earth tailings | |
| CN110965079B (en) | Method for efficiently and comprehensively recycling iron-rich metallurgical tailings | |
| CN111872402A (en) | Method for producing wet-grinding iron powder and reduced iron powder by using iron-containing smelting slag | |
| CN102925705A (en) | Method for recovering valuable metals from furnace blocks of silver-refining furnaces | |
| CN106222421A (en) | Gold mud treatment method | |
| CN103205567A (en) | Method for enriching gold and platinum group metal in process of melting copper-nickel sulfide ore | |
| CN107460336A (en) | A kind of processing method of golden cyanide residue | |
| CN106119559A (en) | Comprehensive utilization method of iron slag containing noble metal | |
| CN104046787B (en) | A kind of cyanidation tailings method of comprehensive utilization | |
| CN104762490A (en) | Gold concentrate slagging smelting gold extraction method | |
| CN104004917A (en) | Method for recovering terne metal from scrap copper anode mud | |
| CN104152711A (en) | Method and device for performing all-mud cyaniding recycling on gold ores | |
| CN105268541A (en) | Method for recycling metals from furnace lining waste bricks | |
| CN112718230B (en) | Copper oxide ore recovery method | |
| CN112813278A (en) | Recovery processing method of copper dross | |
| JP2022114298A (en) | Method for recovering silver | |
| CN112593026A (en) | Method for aggregating and separating high-melting-point phase in high-temperature melt | |
| CN106544525A (en) | A kind of ore-dressing technique for smelting useless stove brick synthetical recovery noble metal | |
| CN110777394A (en) | Method for electrolyzing and recovering lead from lead-containing slag by using chlorination diaphragm |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20170531 |
|
| RJ01 | Rejection of invention patent application after publication |