CN106756028A - A kind of germanium tetrachloride production apparatus for recovering metal - Google Patents
A kind of germanium tetrachloride production apparatus for recovering metal Download PDFInfo
- Publication number
- CN106756028A CN106756028A CN201510832023.3A CN201510832023A CN106756028A CN 106756028 A CN106756028 A CN 106756028A CN 201510832023 A CN201510832023 A CN 201510832023A CN 106756028 A CN106756028 A CN 106756028A
- Authority
- CN
- China
- Prior art keywords
- adsorption column
- material transfer
- connecting tube
- transfer pipe
- condensation chamber
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B7/00—Working up raw materials other than ores, e.g. scrap, to produce non-ferrous metals and compounds thereof; Methods of a general interest or applied to the winning of more than two metals
- C22B7/001—Dry processes
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B41/00—Obtaining germanium
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Geology (AREA)
- Manufacture And Refinement Of Metals (AREA)
Abstract
The invention discloses a kind of germanium tetrachloride production apparatus for recovering metal, including reative cell, condensation chamber and recovery room, the reative cell top is provided with blast pipe, the reative cell bottom is provided with drain pipe, the blast pipe and the condensation chamber are connected, the drain pipe and the recovery room are connected, the condensation chamber and the recovery room are connected, the first adsorption column and the second adsorption column are provided with the recovery room, the first material transfer pipe is wound with first adsorption column, the second material transfer pipe is wound with second adsorption column, described first material transfer pipe one end is connected by the first connecting tube and the condensation chamber, the other end is connected by the second connecting tube and the condensation chamber, described second material transfer pipe one end is connected by the 3rd connecting tube and the drain pipe, the second material transfer pipe other end is connected by the 4th connecting tube and the drain pipe.The germanium tetrachloride production apparatus for recovering metal that the present invention is provided, simple to operate, organic efficiency is high.
Description
Technical field
The present invention relates to technical field of semiconductors, a kind of germanium tetrachloride production apparatus for recovering metal is particularly related to.
Background technology
Germanium is a kind of important rare metal, is the most important semi-conducting material in addition to silicon, and germanium system product is widely used in semi-conductor industry, space flight and aviation, and light moves the fields such as communication, chemical catalyst, solar cell.Germanium is scattered in a variety of mineral and rock, but its content is not enough to directly be extracted from mineral, therefore the production of germanium includes germanium concentrate preparation, the extraction of germanium, germanium purification three phases.The main pyrometallurgical smelting by germanium lignite in source of current germanium is extracted, or from the accessory substance in heavy metal smelting process.
High-purity germanium tetrachloride product is the production indispensable critical materials of grade Silica-Based Optical Fibers high, and its purposes is to improve the refractive index of optical fiber, reduces light loss, and then improve the transmission range of optical fiber.The important performance indexes of optical fiber are decide due to the metal and hydrogen containing foreign content of high-purity germanium tetrachloride and distribution, its quality directly affects the quality of optical fiber.Therefore, the content requirement to metal impurities in high-purity germanium tetrachloride (Fe, Co, Cr, Mn, Cu etc.) and hydrogen containing foreign (OH, CH, HCl) is extremely low.
The high-purity germanium tetrachloride rectification process being widely used at present, it is impossible to metal impurities (Fe, Co, Cr, Mn, Cu etc.) are removed well, therefore, it is necessary to it is further studied and improved.
The content of the invention
The invention aims to solve the problems, such as to be previously mentioned in above-mentioned background technology, there is provided a kind of simple to operate, organic efficiency germanium tetrachloride production apparatus for recovering metal high.
To achieve these goals, technical scheme is as follows：
A kind of germanium tetrachloride production apparatus for recovering metal, including reative cell, condensation chamber and recovery room, the reative cell top is provided with blast pipe, the reative cell bottom is provided with drain pipe, the blast pipe and the condensation chamber are connected, the drain pipe and the recovery room are connected, the condensation chamber and the recovery room are connected, the first adsorption column and the second adsorption column are provided with the recovery room, the first material transfer pipe is wound with first adsorption column, the second material transfer pipe is wound with second adsorption column, described first material transfer pipe one end is connected by the first connecting tube and the condensation chamber, the other end is connected by the second connecting tube and the condensation chamber, described second material transfer pipe one end is connected by the 3rd connecting tube and the drain pipe, the second material transfer pipe other end is connected by the 4th connecting tube and the drain pipe.
Preferably, it is provided with hydraulic pump in first connecting tube.
Preferably, the first material transfer pipe is spirally wrapped around around first adsorption column.
Preferably, the second material transfer pipe is spirally wrapped around around second adsorption column.
Preferably, it is provided with magnetic absorption liquid in first adsorption column and second adsorption column.
Compared with prior art, the germanium tetrachloride production apparatus for recovering metal that the present invention is provided, simple to operate, organic efficiency is high.
Brief description of the drawings
Technical scheme in order to illustrate more clearly the embodiments of the present invention, the accompanying drawing to be used needed for being described to embodiment below is briefly described, apparently, drawings in the following description are only some embodiments of the present invention, for those of ordinary skill in the art, without having to pay creative labor, other accompanying drawings can also be obtained according to these accompanying drawings.
Fig. 1 is the structural representation in the present embodiment.
Specific embodiment
Below in conjunction with the accompanying drawing in the embodiment of the present invention, the technical scheme in the embodiment of the present invention is clearly and completely described, it is clear that described embodiment is only a part of embodiment of the invention, rather than whole embodiments.Based on the embodiment in the present invention, the every other embodiment that those of ordinary skill in the art are obtained under the premise of creative work is not made belongs to the scope of protection of the invention.
Specific embodiment：
A kind of germanium tetrachloride production apparatus for recovering metal with reference to shown in Fig. 1,Including reative cell 1,Condensation chamber 7 and recovery room 10,The top of reative cell 1 is provided with blast pipe 6,The bottom of reative cell 1 is provided with drain pipe 2,Blast pipe 6 and condensation chamber 7 are connected,Drain pipe 2 and recovery room 10 are connected,Condensation chamber 7 and recovery room 10 are connected,The first adsorption column 3 and the second adsorption column 4 are provided with recovery room 10,The first material transfer pipe 5 is wound with first adsorption column 3,The second material transfer pipe 11 is wound with second adsorption column 4,The one end of first material transfer pipe 5 is connected by the first connecting tube 8 and condensation chamber 7,The other end is connected by the second connecting tube 12 and condensation chamber 7,The one end of second material transfer pipe 11 is connected by the 3rd connecting tube 13 and drain pipe 2,The other end of second material transfer pipe 11 is connected by the 4th connecting tube 14 and drain pipe 2.
In the present embodiment, hydraulic pump 9 is provided with the first connecting tube 8.
In the present embodiment, the first material transfer pipe 5 is spirally wrapped around around the first adsorption column 3.
In the present embodiment, the second material transfer pipe 11 is spirally wrapped around around the second adsorption column 4.
In the present embodiment, magnetic absorption liquid is provided with the first adsorption column 3 and the second adsorption column 4.
In the present embodiment, reacted gas is discharged from blast pipe 6 in reative cell 1, enter the first connecting tube 8 and the second connecting tube 12 after being condensed into condensation chamber 7, it is adsorbed into the first adsorption column 3, the liquid of the discharge of drain pipe 2 enters the 3rd connecting tube 13 and the 4th connecting tube 14, is adsorbed into the second adsorption column 4, metal is reclaimed, being provided with first adsorption column 3 and the second adsorption column 4 can be high with the magnetic absorption liquid of adsorbing metal, advantages of good adsorption effect, organic efficiency.
Presently preferred embodiments of the present invention is the foregoing is only, is not intended to limit the invention, all any modification, equivalents made within the scope of the present invention etc. should be included within the scope of the present invention.
Claims (5)
1. a kind of germanium tetrachloride production apparatus for recovering metal, it is characterised in that：Including reative cell, condensation chamber and recovery room, the reative cell top is provided with blast pipe, the reative cell bottom is provided with drain pipe, the blast pipe and the condensation chamber are connected, the drain pipe and the recovery room are connected, the condensation chamber and the recovery room are connected, the first adsorption column and the second adsorption column are provided with the recovery room, the first material transfer pipe is wound with first adsorption column, the second material transfer pipe is wound with second adsorption column, described first material transfer pipe one end is connected by the first connecting tube and the condensation chamber, the other end is connected by the second connecting tube and the condensation chamber, described second material transfer pipe one end is connected by the 3rd connecting tube and the drain pipe, the second material transfer pipe other end is connected by the 4th connecting tube and the drain pipe.
2. germanium tetrachloride production apparatus for recovering metal according to claim 1, it is characterised in that：Hydraulic pump is provided with first connecting tube.
3. germanium tetrachloride production apparatus for recovering metal according to claim 1, it is characterised in that：The first material transfer pipe is spirally wrapped around around first adsorption column.
4. germanium tetrachloride production apparatus for recovering metal according to claim 1, it is characterised in that：The second material transfer pipe is spirally wrapped around around second adsorption column.
5. germanium tetrachloride production apparatus for recovering metal according to claim 1, it is characterised in that：Magnetic absorption liquid is provided with first adsorption column and second adsorption column.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510832023.3A CN106756028A (en) | 2015-11-25 | 2015-11-25 | A kind of germanium tetrachloride production apparatus for recovering metal |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510832023.3A CN106756028A (en) | 2015-11-25 | 2015-11-25 | A kind of germanium tetrachloride production apparatus for recovering metal |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106756028A true CN106756028A (en) | 2017-05-31 |
Family
ID=58964864
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510832023.3A Pending CN106756028A (en) | 2015-11-25 | 2015-11-25 | A kind of germanium tetrachloride production apparatus for recovering metal |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106756028A (en) |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH10206019A (en) * | 1997-01-27 | 1998-08-07 | Eiko Seiki:Kk | Fractionation/melting furnace for metal waste material |
| JPH11293352A (en) * | 1998-02-12 | 1999-10-26 | Nkk Corp | Recovery of metal by reducing-separation of metal source containing plural kinds of metal oxides, and apparatus therefor |
| CN202744613U (en) * | 2012-09-24 | 2013-02-20 | 云南东昌金属加工有限公司 | Chloridizing distillation device for extracting germanium from germanium concentrate |
| CN104862500A (en) * | 2015-06-03 | 2015-08-26 | 云南天浩稀贵金属股份有限公司 | Metal germanium recovery device and metal germanium recovery method |
-
2015
- 2015-11-25 CN CN201510832023.3A patent/CN106756028A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH10206019A (en) * | 1997-01-27 | 1998-08-07 | Eiko Seiki:Kk | Fractionation/melting furnace for metal waste material |
| JPH11293352A (en) * | 1998-02-12 | 1999-10-26 | Nkk Corp | Recovery of metal by reducing-separation of metal source containing plural kinds of metal oxides, and apparatus therefor |
| CN202744613U (en) * | 2012-09-24 | 2013-02-20 | 云南东昌金属加工有限公司 | Chloridizing distillation device for extracting germanium from germanium concentrate |
| CN104862500A (en) * | 2015-06-03 | 2015-08-26 | 云南天浩稀贵金属股份有限公司 | Metal germanium recovery device and metal germanium recovery method |
Non-Patent Citations (2)
| Title |
|---|
| 李昭: ""锗氯化蒸馏设备的改进与应用"", 《南方金属》 * |
| 雷霆 等编著: "《锗冶金》", 31 March 2011 * |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101444681B (en) | Method for recovering tail gas from trichlorosilane production and special equipment thereof | |
| CN103833551A (en) | Separation equipment and separation method of methyl methacrylate (MMA) | |
| CN102601138A (en) | Novel process for producing micron-grade stainless steel fibers | |
| CN102328951A (en) | Method and device for removing hydrogen-containing impurities from germanium tetrachloride | |
| CN105347348A (en) | Water removal method for silicon tetrafluoride | |
| CN202880923U (en) | Titanium tetrachloride wet-process dust collecting and leaching device | |
| CN106756028A (en) | A kind of germanium tetrachloride production apparatus for recovering metal | |
| CN104140085B (en) | The apparatus and method of water and carbon dioxide in a kind of deep removal nitrous oxide | |
| CN106621757B (en) | Chlorosilane analysis waste gas recovery treatment device and treatment method | |
| CN103977666B (en) | The device of comprehensive utilization MOCVD device tail gas | |
| CN103626129B (en) | With industrial liquid chlorine for the method for electronic grade high-purity chlorine prepared by raw material | |
| CN100393615C (en) | Phosphorus and flourine absorbing and separating method in preparing kiln process phosphoric acid | |
| CN203954987U (en) | The device of comprehensive utilization MOCVD equipment tail gas | |
| CN205346848U (en) | Industrial grade boron trifluoride's purification device | |
| CN105174233A (en) | Ultra-clean high-purity sulfuric acid production method | |
| CN202953823U (en) | Electronic grade sulfur hexafluoride purification device | |
| CN104923026A (en) | Polysilicon tail gas recovering method and device thereof | |
| CN102642812A (en) | System for recovering hydrogen chloride from reductive tail gas | |
| CN201762264U (en) | Medium-pressure acetylene gas drying purification device | |
| CN101634514A (en) | Method for preparing pure krypton and pure xenon by full distillation | |
| CN204022481U (en) | A kind of silicon tetrachloride purification system | |
| CN102641646A (en) | Method for recovering hydrogen chloride from reduction tail gas | |
| CN105776161A (en) | Recovery method of cooling helium introduced into optical fiber cooling pipe in optical fiber production process | |
| CN202358933U (en) | Apparatus for removing hydrogen-containing impurities contained in germanium tetrachloride | |
| CN202625835U (en) | System for recovering hydrogen chloride from reduction exhaust gas |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20170531 |