CN106753113A - A kind of ceramic tile adhesive - Google Patents

A kind of ceramic tile adhesive Download PDF

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Publication number
CN106753113A
CN106753113A CN201611074270.2A CN201611074270A CN106753113A CN 106753113 A CN106753113 A CN 106753113A CN 201611074270 A CN201611074270 A CN 201611074270A CN 106753113 A CN106753113 A CN 106753113A
Authority
CN
China
Prior art keywords
parts
ceramic tile
dibutyl phthalate
adhesive
tile adhesive
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
CN201611074270.2A
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Chinese (zh)
Inventor
杨梅
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Guangxi University
Original Assignee
Guangxi University
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Guangxi University filed Critical Guangxi University
Priority to CN201611074270.2A priority Critical patent/CN106753113A/en
Publication of CN106753113A publication Critical patent/CN106753113A/en
Withdrawn legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J163/00Adhesives based on epoxy resins; Adhesives based on derivatives of epoxy resins
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/02Non-macromolecular additives
    • C09J11/04Non-macromolecular additives inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/02Non-macromolecular additives
    • C09J11/06Non-macromolecular additives organic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/08Macromolecular additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/08Stabilised against heat, light or radiation or oxydation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Adhesives Or Adhesive Processes (AREA)

Abstract

The invention discloses a kind of ceramic tile adhesive, it is made up of the following raw material of mass parts:50~100 parts of basalt fibre, 40~60 parts of sand, 10~20 parts of organobentonite, 1~20 part of aluminosilicate fiber, 0.1~5 part of dibutyl phthalate, 0.1~1 part of polyvinyl alcohol, 1~10 part of bisphenol A epoxide resin, 1~4 part of carboxymethylcellulose calcium, 1~10 part of phenolic resin, 1~5 part of Nano Silver, 1~7 part of guanylurea phosphate;Described dibutyl phthalate is made up of one or more of vinylacetate, tertiary ethylene carbonate, ethene acid esters, acrylate.Tile adhesives of the invention have a premium properties such as water proofing property higher, caking property, durability, and adhesive slurries have wetability and the water-retaining property can be with ceramic tile close adhesion, and seamless, adhesion strength is high.

Description

A kind of ceramic tile adhesive
Technical field
The present invention relates to building adhesive technical field, and in particular to a kind of ceramic tile adhesive.
Background technology
Ceramic tile adhesive is a kind of polymer cement, sand, pulp material through factory's premixing.High intensity is formed after mixing with water Thin primer scab, slurry, be widely used in the purposes such as interior decoration.Current ceramic tile adhesive, manages according to " organic-inorganic " By the ceramic tile adhesive of, development there is the characteristic of cement to have organic gel caking ability part characteristic high again, cement and common can be made up The defect of polymer mortar, has the advantages that water proofing property, caking property and good endurance, overcome ordinary cement, waterproof mortar or The tapestry brick that common wall and floor tile adhesive agent is made to exist during adhesive material bond loosely, hollowing, ftracture, come off, seeping water, performance it is unstable The drawback such as fixed.When but ceramic tile adhesive contacts aquation with ceramic tile, it may appear that adhesive wetability it is not strong and do not cause adhesive with The contact surface of ceramic tile produces gap, so as to optimize the formula of ceramic tile adhesive, improves the wetability and water-retaining property of adhesive, makes porcelain Brick gelling agent can closely and tile bonding, so as to improve the adhesion strength of adhesive.
The content of the invention
It is an object of the present invention in view of the shortcomings of the prior art, there is provided a kind of ceramic tile adhesive.
To achieve the above object, the present invention takes following technical scheme:
A kind of ceramic tile adhesive is made up of the following raw material of mass parts:It is 50~100 parts of basalt fibre, 40~60 parts of sand, organic 10~20 parts of bentonite, 1~20 part of aluminosilicate fiber, 0.1~5 part of dibutyl phthalate, 0.1~1 part of polyvinyl alcohol, bisphenol-A epoxy tree 1~10 part of fat, 1~4 part of carboxymethylcellulose calcium, 1~10 part of phenolic resin, 1~5 part of Nano Silver, 1~7 part of guanylurea phosphate;Institute The dibutyl phthalate stated is made up of one or more of vinylacetate, tertiary ethylene carbonate, ethene acid esters, acrylate.
Wherein, described dibutyl phthalate is 1~3 by mass ratio:1~6:1~4:1 vinylacetate, tertiary ethylene carbonate, Ethene acid esters, acrylate composition.
Preferably, a kind of ceramic tile adhesive is made up of the following raw material of mass parts:100 parts of basalt fibre, 50 parts of sand, have 15 parts of machine bentonite, 5 parts of aluminosilicate fiber, 1 part of dibutyl phthalate, 1 part of polyvinyl alcohol, 8 parts of bisphenol A epoxide resin, carboxymethyl cellulose 3 parts of element, 5 parts of phenolic resin, 3 parts of Nano Silver, 6 parts of guanylurea phosphate.
In the present invention, basalt fibre, sand, organobentonite, aluminosilicate fiber be inorganic component, bisphenol A epoxide resin, Carboxymethylcellulose calcium, phenolic resin, guanylurea phosphate, dibutyl phthalate are organic component, wherein, phenolic resin and guanylurea phosphate pair Bisphenol A epoxide resin has modifying function, can strengthen the adhesion strength and toughness of double epoxy resin, high bond strength it is organic Component and inorganic component coordinate, overcome inorganic component, organic component one-component adhesive bonding is insecure, stability is not high Shortcoming, and carboxymethylcellulose calcium and vinylacetate, tertiary ethylene carbonate, ethene acid esters, acrylate coordinate and improve gluing The stability of agent, wetability and adhesive slurries water-retaining property, improve the water proofing property after adhesive solidification is bonded, caking property and durable Property.
In the present invention, Nano Silver is antibiotic bacteriostat, prevent ceramic tile gap because making moist mouldy generation harmful bacteria.
Wherein, alumina silicate fibre has excellent insulating characteristicses, and acid and alkali resistance corrosivity is good, with excellent chemical stability, Improve the acidproof decay resistance and heat endurance of adhesive.
The beneficial effects of the invention are as follows:Tile adhesives of the invention have water proofing property, caking property and durability, adhesive Slurries have wetability and the water-retaining property can be with ceramic tile close adhesion, and seamless, adhesion strength is high.
Specific embodiment
With reference to specific embodiment, to further instruction of the present invention.
Embodiment 1
A kind of ceramic tile adhesive is made up of the following raw material of mass parts:100 parts of basalt fibre, 40 parts of sand, organic swelling 20 parts of soil, 1 part of aluminosilicate fiber, 5 parts of dibutyl phthalate, 0.1 part of polyvinyl alcohol, 10 parts of bisphenol A epoxide resin, carboxymethylcellulose calcium 1 Part, 10 parts of phenolic resin, 1 part of Nano Silver, 7 parts of guanylurea phosphate;Wherein, dibutyl phthalate is 3 by mass ratio:6:4:1 acetic acid second Alkene ester, tertiary ethylene carbonate, ethene acid esters, acrylate composition.
Embodiment 2
A kind of ceramic tile adhesive is made up of the following raw material of mass parts:100 parts of basalt fibre, 50 parts of sand, organic swelling Soil 15 parts, 5 parts of aluminosilicate fiber, 1 part of dibutyl phthalate, 1 part of polyvinyl alcohol, 8 parts of bisphenol A epoxide resin, 3 parts of carboxymethylcellulose calcium, 5 parts of phenolic resin, 3 parts of Nano Silver, 6 parts of guanylurea phosphate, wherein dibutyl phthalate are 1 by mass ratio:1:1:1 vinylacetate, Tertiary ethylene carbonate, ethene acid esters, acrylate composition.
Embodiment 3
A kind of ceramic tile adhesive is made up of the following raw material of mass parts:50 parts of basalt fibre, 60 parts of sand, organobentonite 10 parts, 20 parts of aluminosilicate fiber, 0.1 part of dibutyl phthalate, 1 part of polyvinyl alcohol, 1 part of bisphenol A epoxide resin, 4 parts of carboxymethylcellulose calcium, 1 part of phenolic resin, 5 parts of Nano Silver, 1 part of guanylurea phosphate;Wherein, dibutyl phthalate is 2 by mass ratio:5:3:1 vinylacetate, Tertiary ethylene carbonate, ethene acid esters, acrylate composition.
Embodiment 4
A kind of ceramic tile adhesive is made up of the following raw material of mass parts:80 parts of basalt fibre, 55 parts of sand, organobentonite 18 parts, 10 parts of aluminosilicate fiber, 3 parts of dibutyl phthalate, 0.8 part of polyvinyl alcohol, 9 parts of bisphenol A epoxide resin, 2 parts of carboxymethylcellulose calcium, 4 parts of phenolic resin, 4 parts of Nano Silver, 5 parts of guanylurea phosphate;Wherein, dibutyl phthalate is 1 by mass ratio:4:2:1 vinylacetate, Tertiary ethylene carbonate, ethene acid esters, acrylate composition.
Above content is confined to these explanations it cannot be assumed that the present invention is embodied, for the technical field of the invention Those of ordinary skill for, under the premise of present inventive concept is not departed from, some simple deduction or replace can also be made, all should When being considered as belonging to the scope of patent protection that claims by being submitted to of the present invention determine.

Claims (3)

1. a kind of ceramic tile adhesive, it is characterised in that it is made up of the following raw material of mass parts:50~100 parts of basalt fibre, 40~60 parts of sand, 10~20 parts of organobentonite, 1~20 part of aluminosilicate fiber, 0.1~5 part of dibutyl phthalate, polyvinyl alcohol 0.1~1 Part, 1~10 part of bisphenol A epoxide resin, 1~4 part of carboxymethylcellulose calcium, 1~10 part of phenolic resin, 1~5 part of Nano Silver, phosphoric acid 1~7 part of dicyandiamidines;Described dibutyl phthalate by vinylacetate, tertiary ethylene carbonate, ethene acid esters, one kind of acrylate or Several compositions.
2. a kind of ceramic tile adhesive according to claim 1, it is characterised in that described dibutyl phthalate by mass ratio be 1~ 3:1~6:1~4:1 vinylacetate, tertiary ethylene carbonate, ethene acid esters, acrylate composition.
3. a kind of ceramic tile adhesive according to claim 1, it is characterised in that it is made up of the following raw material of mass parts: It is 100 parts of basalt fibre, 50 parts of sand, 15 parts of organobentonite, 5 parts of aluminosilicate fiber, 1 part of dibutyl phthalate, 1 part of polyvinyl alcohol, double 8 parts of phenol A epoxy resin, 3 parts of carboxymethylcellulose calcium, 5 parts of phenolic resin, 3 parts of Nano Silver, 6 parts of guanylurea phosphate.
CN201611074270.2A 2016-11-29 2016-11-29 A kind of ceramic tile adhesive Withdrawn CN106753113A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201611074270.2A CN106753113A (en) 2016-11-29 2016-11-29 A kind of ceramic tile adhesive

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201611074270.2A CN106753113A (en) 2016-11-29 2016-11-29 A kind of ceramic tile adhesive

Publications (1)

Publication Number Publication Date
CN106753113A true CN106753113A (en) 2017-05-31

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CN201611074270.2A Withdrawn CN106753113A (en) 2016-11-29 2016-11-29 A kind of ceramic tile adhesive

Country Status (1)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107963870A (en) * 2017-12-13 2018-04-27 颍上永红建材有限公司 A kind of environment-friendly type glue for tile
CN112592665A (en) * 2020-12-31 2021-04-02 常德环创力达环保科技有限公司 Interior and exterior wall putty interface adhesive and preparation method thereof

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101875830A (en) * 2009-11-23 2010-11-03 黑龙江省科学院石油化学研究院 Phenolic resin/phosphate hybrid adhesive and preparation method thereof
CN104356986A (en) * 2014-10-24 2015-02-18 青岛克立克信息技术有限公司 Waterproof anticorrosive ceramic adhesive
CN104629653A (en) * 2013-11-09 2015-05-20 青岛诚运建筑工程有限公司 Strongly-adhesive environment-friendly building glue
CN104710148A (en) * 2013-12-13 2015-06-17 胡建辉 Ceramic tile adhesive
CN105400466A (en) * 2015-12-01 2016-03-16 烟台柳鑫新材料科技有限公司 Adhesive for cover plate and preparation method
CN105524576A (en) * 2016-01-21 2016-04-27 广西大学 Mildewproof and waterproof tile joint filling agent

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101875830A (en) * 2009-11-23 2010-11-03 黑龙江省科学院石油化学研究院 Phenolic resin/phosphate hybrid adhesive and preparation method thereof
CN104629653A (en) * 2013-11-09 2015-05-20 青岛诚运建筑工程有限公司 Strongly-adhesive environment-friendly building glue
CN104710148A (en) * 2013-12-13 2015-06-17 胡建辉 Ceramic tile adhesive
CN104356986A (en) * 2014-10-24 2015-02-18 青岛克立克信息技术有限公司 Waterproof anticorrosive ceramic adhesive
CN105400466A (en) * 2015-12-01 2016-03-16 烟台柳鑫新材料科技有限公司 Adhesive for cover plate and preparation method
CN105524576A (en) * 2016-01-21 2016-04-27 广西大学 Mildewproof and waterproof tile joint filling agent

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107963870A (en) * 2017-12-13 2018-04-27 颍上永红建材有限公司 A kind of environment-friendly type glue for tile
CN112592665A (en) * 2020-12-31 2021-04-02 常德环创力达环保科技有限公司 Interior and exterior wall putty interface adhesive and preparation method thereof

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Application publication date: 20170531

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