CN106752882A - A kind of metal anticorrosive paint for automobile parts and preparation method thereof - Google Patents

A kind of metal anticorrosive paint for automobile parts and preparation method thereof Download PDF

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Publication number
CN106752882A
CN106752882A CN201611073451.3A CN201611073451A CN106752882A CN 106752882 A CN106752882 A CN 106752882A CN 201611073451 A CN201611073451 A CN 201611073451A CN 106752882 A CN106752882 A CN 106752882A
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CN
China
Prior art keywords
parts
anticorrosive paint
preparation
metal anticorrosive
automobile parts
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
CN201611073451.3A
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Chinese (zh)
Inventor
张小莉
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
CHONGQING QINGYI MOULD MANUFACTURING Co Ltd
Original Assignee
CHONGQING QINGYI MOULD MANUFACTURING Co Ltd
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Publication date
Application filed by CHONGQING QINGYI MOULD MANUFACTURING Co Ltd filed Critical CHONGQING QINGYI MOULD MANUFACTURING Co Ltd
Priority to CN201611073451.3A priority Critical patent/CN106752882A/en
Publication of CN106752882A publication Critical patent/CN106752882A/en
Withdrawn legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D177/00Coating compositions based on polyamides obtained by reactions forming a carboxylic amide link in the main chain; Coating compositions based on derivatives of such polymers
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08Anti-corrosive paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/18Fireproof paints including high temperature resistant paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/63Additives non-macromolecular organic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/65Additives macromolecular
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/08Stabilised against heat, light or radiation or oxydation

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention discloses a kind of metal anticorrosive paint for automobile parts and preparation method thereof, its be mainly by constitutive material polyamide, barium sulfate, nano-calcium carbonate, tetramethylsilane, stalk ashes, butyl acetate, propane diols, dibutyl tin laurate, chlorinated paraffin and chlorinated alkenes by certain part by weight mix, dispersion after obtain finished product.The present invention prepare metal anticorrosive paint for automobile parts paint film adhesion is good, fast drying, heat-resist, it is environment friendly and pollution-free, and preparation method of the present invention is simple, low cost, is adapted to mass produce.

Description

A kind of metal anticorrosive paint for automobile parts and preparation method thereof
Technical field
It is by the polyamide resin of macromolecule the present invention relates to a kind of metal anticorrosive paint for automobile parts and preparation method thereof Fat, butyl acetate composition, it is adaptable to coastal area air industrial antisepsis.
Background technology
Used industry anti-corrosion paint in recent years protect metal with epoxy zinc-rich paint be most.Due to the density of metal zinc Than larger, in order to not make zinc powder settling or slow down the sinking speed of zinc powder, it is necessary to add a certain amount of sagging inhibitor in paint;It is anti-settling The viscosity of the addition paint of agent is consequently increased, and the resin of small-molecular-weight will be as much as possible selected when polyamide is selected (E44);In order to be able to meet brushability during construction, be to adding substantial amounts of solvent in paint, solvent serious harm workman during construction Healthy, paint solvent in the drying process polluted in evaporateing into air environment, solvent make improve construction cost;Small molecule The fragility of paint film is big after amount resin solidification, and the big paint film in temperature change of metal heat-expansion shrinkage system is easily cracked or comes off.
Magnalium kirsite density is small, theoretical generation electricity (being 3.6 times of zinc), magnalium kirsite adding in corrosion resistant coating greatly Dosage is only 50% or so of zinc powder to be obtained with optimal coating performance, and coating resistance is up to more than 500K Ω .cm2, electricity Electrode potential can long-time stable in -0.85v (SCE) below, it is 1 year that one coat effectively protects the life-span.
The content of the invention
In order to alleviate shortcomings and deficiencies of the prior art, present invention aim at a kind of auto parts and components anti-corrosion of metal of offer Paint and preparation method thereof.
The present invention is adopted the following technical scheme that to achieve these goals:
Metal anticorrosive paint for automobile parts, it is characterised in that the weight portion of its constitutive material is:Polyamide 29-42 Part, barium sulfate 1-4 parts, nano-calcium carbonate 1-4 parts, tetramethylsilane 2-6 parts, 2-6 parts of stalk ashes, butyl acetate 7-15 parts, Propane diols 10-16 parts, dibutyl tin laurate 1-5 parts, chlorinated paraffin 2-6 parts and chlorinated alkenes 4-12 parts.
The preparation method of described metal anticorrosive paint for automobile parts, it is characterised in that comprise the following steps:
1) by the weight portion of constitutive material by polyamide, barium sulfate, nano-calcium carbonate, tetramethylsilane and propane diols Mixing and stirring, disperses at a high speed and is ground to below 35um fineness;
2) stalk ashes, butyl acetate, dibutyl tin laurate, chlorination are added by weight in above-mentioned reaction system Paraffin and chlorinated alkenes, disperse at a high speed 4-12 minutes under 650-800 revs/min of rotating speed, obtain finished product.
Beneficial effects of the present invention:
The present invention prepare metal anticorrosive paint for automobile parts paint film adhesion is good, fast drying, heat-resist, environmental protection is without dirt Dye, and preparation method of the present invention is simple, low cost, is adapted to large-scale production.
Specific embodiment
Embodiment 1
Metal anticorrosive paint for automobile parts, the weight portion of its constitutive material is:30 parts of polyamide, 1 part of barium sulfate, receive 1 part of calcium carbonate of rice, 2 parts of tetramethylsilane, 2 parts of stalk ashes, 8 parts of butyl acetate, 10 parts of propane diols, dibutyl tin laurate 5 parts of 1 part, 2 parts of chlorinated paraffin and chlorinated alkenes.
The preparation method of metal anticorrosive paint for automobile parts, comprises the following steps:
1) by the weight portion of constitutive material by polyamide, barium sulfate, nano-calcium carbonate, tetramethylsilane and propane diols Mixing and stirring, disperses at a high speed and is ground to below 35um fineness;
2) stalk ashes, butyl acetate, dibutyl tin laurate, chlorination are added by weight in above-mentioned reaction system Paraffin and chlorinated alkenes, disperse at a high speed 4-12 minutes under 650-800 revs/min of rotating speed, obtain finished product.
Embodiment 2
Metal anticorrosive paint for automobile parts, the weight portion of its constitutive material is:35 parts of polyamide, 2 parts of barium sulfate, receive 2 parts of calcium carbonate of rice, 3 parts of tetramethylsilane, 4 parts of stalk ashes, 10 parts of butyl acetate, 12 parts of propane diols, di lauric dibutyl 8 parts of 2 parts of tin, 3 parts of chlorinated paraffin and chlorinated alkenes.
The preparation method of metal anticorrosive paint for automobile parts, comprises the following steps:
1) by the weight portion of constitutive material by polyamide, barium sulfate, nano-calcium carbonate, tetramethylsilane and propane diols Mixing and stirring, disperses at a high speed and is ground to below 35um fineness;
2) stalk ashes, butyl acetate, dibutyl tin laurate, chlorination are added by weight in above-mentioned reaction system Paraffin and chlorinated alkenes, disperse at a high speed 4-12 minutes under 650-800 revs/min of rotating speed, obtain finished product.
Embodiment 3
Metal anticorrosive paint for automobile parts, the weight portion of its constitutive material is:40 parts of polyamide, 3 parts of barium sulfate, receive 3 parts of calcium carbonate of rice, 5 parts of tetramethylsilane, 5 parts of stalk ashes, 15 parts of butyl acetate, 15 parts of propane diols, di lauric dibutyl 10 parts of 3 parts of tin, 5 parts of chlorinated paraffin and chlorinated alkenes.
The preparation method of metal anticorrosive paint for automobile parts, comprises the following steps:
1) by the weight portion of constitutive material by polyamide, barium sulfate, nano-calcium carbonate, tetramethylsilane and propane diols Mixing and stirring, disperses at a high speed and is ground to below 35um fineness;
2) stalk ashes, butyl acetate, dibutyl tin laurate, chlorination are added by weight in above-mentioned reaction system Paraffin and chlorinated alkenes, disperse at a high speed 4-12 minutes under 650-800 revs/min of rotating speed, obtain finished product.
Embodiment 4
Technology for detection is carried out using the metal anti-corrosion paint of embodiment 1, it is as a result as follows:
1st, adhesive force/level≤1 grade;2nd, pliability/level:2 grades;3rd, heat resistance:200 DEG C stand intact;4th, alkali resistance:20% NaOH stands intact for 30 days;5th, 15% sulfuric acid of acid resistance stands intact for 40 days;6th, heat-resisting salt 5% sodium chloride 7 days is complete It is good lossless.
Finally illustrate, the above embodiments are merely illustrative of the technical solutions of the present invention and it is unrestricted, this area is common Other modifications or equivalent that technical staff is made to technical scheme, without departing from technical solution of the present invention Spirit and scope, all should cover in the middle of scope of the presently claimed invention.

Claims (2)

1. a kind of metal anticorrosive paint for automobile parts, it is characterised in that the weight portion of its constitutive material is:Polyamide 29-42 Part, barium sulfate 1-4 parts, nano-calcium carbonate 1-4 parts, tetramethylsilane 2-6 parts, 2-6 parts of stalk ashes, butyl acetate 7-15 parts, Propane diols 10-16 parts, dibutyl tin laurate 1-5 parts, chlorinated paraffin 2-6 parts and chlorinated alkenes 4-12 parts.
2. a kind of preparation method of metal anticorrosive paint for automobile parts as claimed in claim 1, it is characterised in that including following Step:
1) by the weight portion of constitutive material by polyamide, barium sulfate, nano-calcium carbonate, tetramethylsilane and mixed with propylene glycol Stir, disperse at a high speed and be ground to below 35um fineness;
2) stalk ashes, butyl acetate, dibutyl tin laurate, chlorinated paraffin are added by weight in above-mentioned reaction system And chlorinated alkenes, disperse at a high speed under 650-800 revs/min of rotating speed 4-12 minutes, obtain finished product.
CN201611073451.3A 2016-11-29 2016-11-29 A kind of metal anticorrosive paint for automobile parts and preparation method thereof Withdrawn CN106752882A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201611073451.3A CN106752882A (en) 2016-11-29 2016-11-29 A kind of metal anticorrosive paint for automobile parts and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201611073451.3A CN106752882A (en) 2016-11-29 2016-11-29 A kind of metal anticorrosive paint for automobile parts and preparation method thereof

Publications (1)

Publication Number Publication Date
CN106752882A true CN106752882A (en) 2017-05-31

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Family Applications (1)

Application Number Title Priority Date Filing Date
CN201611073451.3A Withdrawn CN106752882A (en) 2016-11-29 2016-11-29 A kind of metal anticorrosive paint for automobile parts and preparation method thereof

Country Status (1)

Country Link
CN (1) CN106752882A (en)

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Application publication date: 20170531

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