CN106752876A - A kind of patience waterborne UV coating high and its preparation method and application - Google Patents
A kind of patience waterborne UV coating high and its preparation method and application Download PDFInfo
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- CN106752876A CN106752876A CN201710024585.4A CN201710024585A CN106752876A CN 106752876 A CN106752876 A CN 106752876A CN 201710024585 A CN201710024585 A CN 201710024585A CN 106752876 A CN106752876 A CN 106752876A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
- C09D175/14—Polyurethanes having carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1606—Antifouling paints; Underwater paints characterised by the anti-fouling agent
- C09D5/1637—Macromolecular compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/20—Diluents or solvents
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The present invention relates to aqueous woodware paint technical field, and in particular to a kind of patience waterborne UV coating high and its preparation method and application, including following raw material is constituted in parts by weight：50 ~ 80 parts of hyperbranched aqueous polyurethane acrylic emulsion, 1 ~ 5 part of mixed solvent, 0.1~0.5 part of defoamer, 1~5 part of wetting dispersing agent, 0.1~1.0 part of thickener, 1 ~ 5 part of flatting silica, 1 ~ 5 part of polytetrafluoroethylene (PTFE) wax powder, 1 ~ 3 part of light trigger, 1 ~ 2 part of PH conditioning agents, 8 ~ 25 parts of water, 0.1 ~ 0.2 part of antimildew disinfectant；The mixed solvent is trihydroxylic alcohol or derivatives thereof.The present invention, with water as primary solvent, compensate for the deficiency in existing water paint technology with nano polypropylene yogurt liquid and polyaminoester emulsion as main film forming substance, significantly improve stain resistance, endurance, wearability, the ageing-resistant performance of aqueous UV Tu layer.
Description
Technical field
The present invention relates to aqueous woodware paint technical field, and in particular to a kind of patience waterborne UV coating high and preparation method thereof
And application.
Background technology
Ultraviolet light (UV) coating can be divided into aqueous UV curing coating, UV cured powder paints and solvent-borne type UV coating.Relatively
For traditional UV coating, waterborne UV coating can tend to zero VOC (VOC), nonflammable, environmental pollution it is small and
Safety；Curing rate is fast, has the advantages that energy saving, curing performance are good, be adapted to high-speed automated production.The coating material solidified masters of UV
To be made up of light trigger, oligomer, reactive diluent, UV curing reactions belong to energy initiated polymerization, in light trigger
In the presence of under conditions of, through several seconds cross-linkable solidifyings of radical reaction, solidification is not by oxygen inhibition in air for film forming matter.Conventional solvent
Type UV solidifications are mostly acrylic compounds function monomer using reactive diluent, and volume contraction is big after solidification, influence Tu layer attachment
Power, and reactive diluent has certain volatility, there is certain harm to human body.Aqueous UV curing coating is due to without dilute
Agent monomer is released, but with water as diluent, it is possible to resolve volatile components toxicity and excitant, are a developing direction of coating.
But compared with traditional UV is coating material solidified, aqueous UV curing coating synthetic emulsion in the country's is more with toluene di-isocyanate(TDI) as former at present
Expect to make, double bond content and relative molecular mass are too low, and mechanical property is poor.As market is to water paint combination property
It is required that improving constantly, the combination property such as its wearability, endurance, hardness needs further to improve, thus to waterborne UV coating
Can increase extremely urgent.
Polytetrafluoroethylmodified modified Tissuemat E is the compound micro mist waxes of hardness PE/PTFE high, and the addition of PTFE changes significantly
It has been apt to the slippery and resistance to marring of polyethylene wax powder, has produced extraordinary cooperative effect.Preferable grain shape and more concentrate
Particle size range, molecular weight is neat, and easily dispersion, wearability is good.
The content of the invention
It is an object of the invention to overcome the deficiencies in the prior art, there is provided a kind of patience waterborne UV coating high and its preparation side
Method and application, the patience waterborne UV coating high compensate for present on existing aqueous UV coatings mechanical property and chemical property not
Foot, with stain resistance, chemical-resistant, resistance to ag(e)ing and wearability, the characteristics of gloss is adjustable.
The purpose of the present invention is achieved through the following technical solutions：
A kind of patience waterborne UV coating high, including following raw material is constituted in parts by weight：
50~80 parts of hyperbranched aqueous polyurethane acrylic emulsion, 1~5 part of mixed solvent, 0.1~0.5 part of defoamer, profit
1~5 part of hygroscopic water powder, 0.1~1.0 part of thickener, 1~5 part of flatting silica, 1~5 part of polytetrafluoroethylene (PTFE) wax powder, light trigger 1~
3 parts, 1~2 part of PH conditioning agents, 8~25 parts of water, 0.1~0.2 part of antimildew disinfectant；
The mixed solvent is trihydroxylic alcohol or derivatives thereof.
Further, the solid content of the hyperbranched aqueous polyurethane acrylic emulsion be 43~47%, pH value be 6.5~
7。
Further, the mixed solvent be propylene glycol monomethyl ether, propandiol butyl ether, butyl, butyl glycol ether,
At least one in dipropylene, isopropanol.
Further, the wetting dispersing agent be the anionic wetting dispersing agent without solvent and NONYL PHENOL ETHOXYLATED,
At least one in nonionic wetting dispersing agent, polyfunctional group type wetting dispersing agent.
Further, the defoamer is organosiloxane class defoamer, polyethers defoamer, polyether-modified silicon class froth breaking
At least one in agent.
Further, the thickener is in acrylic thickener, polyurethanes thickener, cellulose ethers thickener
At least one.
Further, the flatting silica includes amorphous silica and delustring wax；The polytetrafluoroethylene (PTFE) wax powder be through
By polytetrafluoroethylmodified modified Tissuemat E or polytetrafluoroethylene (PTFE) and the mixture of Tissuemat E.
Further, the light trigger is crack type photoinitiator, carries in Hydrogen initiator, ionic initiator extremely
Few one kind.
The preparation method of above-mentioned patience waterborne UV coating high, comprises the following steps：
S1. in watersoluble polyurethane acrylic acid emulsion, mixed solvent being mixed into addition reactor with defoamer, 1200~
Oil-free contracting is dispersed under the rotating speed of 1500rpm；
S2. wetting dispersing agent, flatting silica, polytetrafluoroethylene (PTFE) are sequentially added into reactor, in the rotating speed of 1200~1500rpm
Under be dispersed to fineness≤25 μm；
S3. in thickener, light trigger, pH adjusting agent, antimildew disinfectant and water being sequentially added into stirred tank, 500~
Disperse 15~20min under the rotating speed of 800rpm, patience waterborne UV coating high is obtained.
The application of above-mentioned patience waterborne UV coating high, patience waterborne UV coating high is diluted adjust with 0.05~0.1 times of water
Section is coated on the old Tu layer base material through grinding process to working viscosity, and coating weight control is in 110~130g/m2, in normal temperature stream
Flat 2~3min makes surfacing, and 15~20min is then toasted under the conditions of 50 DEG C, bakes to paint film surface drying, then can be through amount
300mj/m2UV machines solidification.
The beneficial effects of the invention are as follows：
1st, using hyperbranched aqueous polyurethane acrylic emulsion (UV-WPUA), the emulsion has UV curing technologies, aqueous concurrently
PUA and the advantage of hyperbranched resin three, its dispersion have solid content higher, relatively low viscosity and good mobility and steady
Qualitative, its film forming matter has excellent film forming, adhesive force, moderate soft durometer and good water resistance, solvent resistance and heat
Stability；
2nd, patience waterborne UV coating high of the invention and composite membrane-forming auxiliary agent are arranged in pairs or groups, can be obviously improved coating film forming and
Stability at later stage；
3rd, the present invention is by being suitably introduced into polytetrafluoroethylmodified modified Tissuemat E, enhances paint film scratch resistance, ageing-resistant, anti-
Dirty and wearability, also suitably improves the hardness of paint film；
4th, product of the present invention directly add water it is usable, without use time limitation；
5th, aqueous UV lacquer paintings paint of the invention is aqueous, environmental protective product, it is adaptable to bamboo and wood device, plastics, field of leather.
Specific embodiment
Technical scheme is described in further detail with reference to specific embodiment, but protection scope of the present invention is not
It is confined to as described below.
Embodiment
A kind of patience waterborne UV coating high, including following raw material is constituted in parts by weight：
50~80 parts of hyperbranched aqueous polyurethane acrylic emulsion, 1~5 part of mixed solvent, 0.1~0.5 part of defoamer, profit
1~5 part of hygroscopic water powder, 0.1~1.0 part of thickener, 1~5 part of flatting silica, 1~5 part of polytetrafluoroethylene (PTFE) wax powder, light trigger 1~
3 parts, 1~2 part of PH conditioning agents, 8~25 parts of water, 0.1~0.2 part of antimildew disinfectant；The mixed solvent be trihydroxylic alcohol or its spread out
It is biological.
Preferably, it is made up of in parts by weight following raw material：
70 parts of hyperbranched aqueous polyurethane acrylic emulsion, 2 parts of mixed solvent, 0.5 part of defoamer, 3 parts of wetting dispersing agent,
1 part of thickener, 5 parts of flatting silica, 2 parts of polytetrafluoroethylene (PTFE) wax powder, 2 parts of light trigger, 2 parts of PH conditioning agents, 8.3 parts of water is mould proof to kill
0.2 part of microbial inoculum；
The solid content of the hyperbranched aqueous polyurethane acrylic emulsion is 43~47%, and pH value is 6.5~7, the emulsion
Have the advantage of UV curing technologies, waterborne PUA and hyperbranched resin three concurrently, its dispersion has solid content higher, relatively low viscous
Degree and good mobility and stability.Its film forming matter has excellent film forming, adhesive force, moderate soft durometer and good
Water resistance, solvent resistance and heat endurance；
The mixed solvent is propylene glycol monomethyl ether, propandiol butyl ether, butyl, butyl glycol ether, DPG
At least one in butyl ether, isopropanol；As preferred mixed solvent be by mass ratio be 3:2 dipropylene, isopropanol
Middle composition；
The wetting dispersing agent is the anionic wetting dispersing agent without solvent and NONYL PHENOL ETHOXYLATED, nonionic profit
The TEGO Dispers 740W of at least one in hygroscopic water powder, polyfunctional group type wetting dispersing agent, preferably TEGO companies of Germany
(nonionic derivative of fatty acid), TEGO Dispers 755W (anionic polyacrylic acid sodium salt) or TEGO Dispers
760W (surfactant of polyfunctional group type and the aqueous solution containing pigment affinity groups)；
The defoamer be organosiloxane class defoamer, polyethers defoamer, polyether-modified silicon class defoamer in extremely
Few one kind, preferably BYK companies of Germany BYK024 (brokenly bubble polysiloxane solution belongs to organosiloxane class), EVONIK companies
TEGO foamex 810 (polysiloxane-polyether copolymer belongs to polyether-modified silicon class).
The thickener is at least in acrylic thickener, polyurethanes thickener, cellulose ethers thickener
Kind, the preferably Thixol 53L (acrylic acid copolymer soln) of France COATEX, Coapur830w (non-ion aqueous poly- ammonia
Ester), RM-8W thickeners or ROHM AND HAAS TT-935 thickeners；
The flatting silica includes amorphous silica and delustring wax；The polytetrafluoroethylene (PTFE) wax powder is via polytetrafluoroethyl-ne
The mixture of the modified Tissuemat E of alkene or polytetrafluoroethylene (PTFE) and Tissuemat E, preferably Clariant wax powder 9610F or day poem
0612；
The antimildew disinfectant is CMI (aqueous chlormethylisothiazo,ine ketone), MI (aqueous first without N-/O- formals
Base OIT), at least one in bronocot, (its is main for the preferably Parmetol A 28 of Shu Mei companies of Germany
Composition is CMI/MI and bronocot mixture) or Parmetol K20 (its main component is CMI/MI mixtures), also
There are the LXE bactericide and Britain's Shu Er MV bactericide of ROHM AND HAAS；
The pH adjusting agent is ammoniacal liquor, triethylamine or hydramine, the preferably small hydramine of smell, and the AMP-95 of such as Tao Shi (divides
Minor structure is 2-amino-2-methyl-1-propanol)；Adjustment pH value purpose is to ensure the stability during storage, general control
System is between pH7-9.
According to formula take hyperbranched aqueous polyurethane acrylic emulsion add stirred tank in, 1200~1500r/min turn
The homogeneous mixture of mixed solvent and defoamer is added under the conditions of speed, thickener is added, it is accurate to weigh, disperse 15min, detection
After oil-free contracting PH conditioning agents, wetting dispersing agent, flatting silica, polytetrafluoroethylmodified modified poly- second are sequentially added in 800~1000r/min
Alkene wax powder, regulation rotating speed to 1200~1500r/min dispersion 20min, scraper plate to fineness≤25um, rear rotational speed regulation to 500~
800r/min sequentially adds light trigger, antimildew disinfectant, water stirring 15min, and it is to complete above-mentioned to form uniform coating system
The preparation process of aqueous UV clear finish.
Above-mentioned aqueous UV varnish when in use, adds the water of host 10% to adjust to working viscosity, is applied to old Tu layer
On base material, coating weight is 120g/m2, then 2~3min of levelling at normal temperatures, then is positioned over 50 DEG C of air dry oven 20min, most
It is set to solidify to form transparent paint film by the UV curing that amount can be 300mj/m2.Physical test is carried out to lacquer painting, is tested
Result such as table 1.
The physical test table of the lacquer painting of table 1
| Test event | Test result | Testing standard |
| Hardness | 1H | GB 6379-2006 |
| Impact resistance | 2 grades | GB/T 4893.9-2013 |
| Adhesive force | 0 grade | GB/T 4893.4-2013 |
| Gloss | 30±2 | GB/T 4893.6-2013 |
| Abrasion performance | 300 2 grades of ＞ | GB/T 4893.8-2013 |
Anti-pollution test, test result such as table 2 are carried out to lacquer painting.
The anti-pollution test table of the lacquer painting of table 2
The patience waterborne UV coating high that the present invention is provided does patience contrast test with the market competitive product, and test result is such as
Table 3.
The patience contrast test table of the patience waterborne UV coating high of table 3 and competitive product
Wherein competitive product 1 is aqueous double-component varnish, and the aqueous UV clear finish of competitive product 2, competitive product 3 is aqueous list
Component varnish.
The patience waterborne UV coating high that the present invention is provided adhesive force test, test result such as table 4 in different old substrates.
The patience waterborne UV coating high of table 4 adhesive force test table in different old substrates
The patience waterborne UV coating high that the present invention is provided easily produces stronger adhesion on different old figure layer base materials,
Excellent mechanical-physical and preferably anti-dirty property, while especially being protruded in chemicals-resistant agent ageing-resistant performance.
The above is only the preferred embodiment of the present invention, it should be understood that the present invention is not limited to described herein
Form, is not to be taken as the exclusion to other embodiment, and can be used for various other combinations, modification and environment, and can be at this
In the text contemplated scope, it is modified by the technology or knowledge of above-mentioned teaching or association area.And those skilled in the art are entered
Capable change and change does not depart from the spirit and scope of the present invention, then all should be in the protection domain of appended claims of the present invention
It is interior.
Claims (10)
1. a kind of patience waterborne UV coating high, it is characterised in that constituted in parts by weight including following raw material：
50 ~ 80 parts of hyperbranched aqueous polyurethane acrylic emulsion, 1 ~ 5 part of mixed solvent, 0.1~0.5 part of defoamer, wetting and dispersing
1~5 part of agent, 0.1~1.0 part of thickener, 1 ~ 5 part of flatting silica, 1 ~ 5 part of polytetrafluoroethylene (PTFE) wax powder, 1 ~ 3 part of light trigger, PH is adjusted
1 ~ 2 part of agent of section, 8 ~ 25 parts of water, 0.1 ~ 0.2 part of antimildew disinfectant；
The mixed solvent is trihydroxylic alcohol or derivatives thereof.
2. a kind of patience waterborne UV coating high according to claim 1, it is characterised in that the hyperbranched aqueous polyurethane
The solid content of acrylic emulsion is 43 ~ 47%, and pH value is 6.5 ~ 7.
3. a kind of patience waterborne UV coating high according to claim 1, it is characterised in that the mixed solvent is propane diols
At least one in methyl ether, propandiol butyl ether, butyl, butyl glycol ether, dipropylene, isopropanol.
4. a kind of patience waterborne UV coating high according to claim 1, it is characterised in that the wetting dispersing agent be without
The anionic wetting dispersing agent of solvent and NONYL PHENOL ETHOXYLATED, nonionic wetting dispersing agent, polyfunctional group type wetting and dispersing
At least one in agent.
5. a kind of patience waterborne UV coating high according to claim 1, it is characterised in that the defoamer is organic silica
At least one in alkanes defoamer, polyethers defoamer, polyether-modified silicon class defoamer.
6. a kind of patience waterborne UV coating high according to claim 1, it is characterised in that the thickener is acrylic compounds
At least one in thickener, polyurethanes thickener, cellulose ethers thickener.
7. a kind of patience waterborne UV coating high according to claim 1, it is characterised in that the flatting silica includes unformed
Silica and delustring wax；The polytetrafluoroethylene (PTFE) wax powder is via polytetrafluoroethylmodified modified Tissuemat E or polytetrafluoroethyl-ne
The mixture of alkene and Tissuemat E.
8. a kind of patience waterborne UV coating high according to claim 1, it is characterised in that the light trigger is cracking type
Light trigger, at least one carried in Hydrogen initiator, ionic initiator.
9. a kind of preparation method of patience waterborne UV coating high as described in claim 1 ~ 8, it is characterised in that including following step
Suddenly：
S1. by watersoluble polyurethane acrylic acid emulsion, mixed solvent mix with defoamer addition reactor in, in 1200 ~ 1500rpm
Rotating speed under be dispersed to oil-free contracting；
S2. wetting dispersing agent, flatting silica, polytetrafluoroethylene (PTFE) are sequentially added into reactor, is divided under the rotating speed of 1200 ~ 1500rpm
It is dissipated to fineness≤25 μm；
S3. in thickener, light trigger, pH adjusting agent, antimildew disinfectant and water being sequentially added into stirred tank, in 500 ~ 800rpm
Rotating speed under disperse 15 ~ 20min, be obtained patience waterborne UV coating high.
10. a kind of application of patience waterborne UV coating high as described in claim 1 ~ 8, it is characterised in that with 0.05 ~ 0.1 times
Patience waterborne UV coating high is diluted to working viscosity by water, is coated on the old Tu layer base material through grinding process, coating weight
Control is in 110 ~ 130g/m2, make surfacing in 2 ~ 3min of normal temperature levelling, 15 ~ 20min is then toasted under the conditions of 50 DEG C, bake
Can be then 300mj/m through amount to paint film surface drying2UV machines solidification.
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Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107384069A (en) * | 2017-06-30 | 2017-11-24 | 天长市巨龙车船涂料有限公司 | A kind of waterborne UV coating |
| CN107793917A (en) * | 2017-10-27 | 2018-03-13 | 北京展辰新材料有限公司 | A kind of water-based UV varnish of Diamond Search and preparation method and application |
| CN107903800A (en) * | 2017-10-31 | 2018-04-13 | 北京展辰新材料有限公司 | A kind of water-based UV varnish of large arch dam and preparation method and application |
| CN109486388A (en) * | 2018-09-30 | 2019-03-19 | 佛山阳光逸采涂料科技有限公司 | UV LED UV-curable waterborne timber coatings for furniture and preparation method thereof |
| CN109486394A (en) * | 2018-11-15 | 2019-03-19 | 上海展辰涂料有限公司 | A kind of aqueous UV floor paint of high abrasion and preparation method thereof |
| CN110157322A (en) * | 2019-04-25 | 2019-08-23 | 苏州市超邦涂料有限公司 | High durable UV water paint and preparation method thereof |
| CN110698971A (en) * | 2019-09-12 | 2020-01-17 | 湖南松井新材料股份有限公司 | Water-based UV (ultraviolet) dirt-resistant self-cleaning coating and preparation method and application thereof |
| CN114958180A (en) * | 2022-06-30 | 2022-08-30 | 湖南松井新材料股份有限公司 | Water-based paint for covering epoxy glass fiber screen prints and preparation method and application thereof |
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