CN106752463A - 玻璃节能自洁玻璃 - Google Patents

玻璃节能自洁玻璃 Download PDF

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CN106752463A
CN106752463A CN201611112765.XA CN201611112765A CN106752463A CN 106752463 A CN106752463 A CN 106752463A CN 201611112765 A CN201611112765 A CN 201611112765A CN 106752463 A CN106752463 A CN 106752463A
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parts
glass
clean
emulsion
energy
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黄通达
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Guangxi Jade And Glass Energy-Saving Technology Co Ltd
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Guangxi Jade And Glass Energy-Saving Technology Co Ltd
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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D129/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal, or ketal radical; Coating compositions based on hydrolysed polymers of esters of unsaturated alcohols with saturated carboxylic acids; Coating compositions based on derivatives of such polymers
    • C09D129/14—Homopolymers or copolymers of acetals or ketals obtained by polymerisation of unsaturated acetals or ketals or by after-treatment of polymers of unsaturated alcohols
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/004—Reflecting paints; Signal paints
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/61—Additives non-macromolecular inorganic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/63—Additives non-macromolecular organic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/65—Additives macromolecular
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/011—Nanostructured additives
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Paints Or Removers (AREA)
  • Surface Treatment Of Glass (AREA)

Abstract

本发明涉及有机硅自清洁涂料，尤其是玻璃节能自洁玻璃，由以下原料按照重量份数制得，聚乙烯醇缩丁醛树脂40～55份、二甲基硅油乳液10～20份、十二烷基苯黄酸钠乳液1～5份、多官能团聚氨酯8～16份、聚甲基丙烯酰亚胺5～10份、纳米二氧化钛1～5份、固化剂5～12份。本发明玻璃节能自洁玻璃，具有优良的耐高低温性，最高温度可到达350摄氏度，使用寿命长。

Description

玻璃节能自洁玻璃
技术领域
本发明涉及有机硅自清洁涂料，尤其是玻璃节能自洁玻璃。
背景技术
玻璃广泛用作建筑玻璃窗、玻璃门、玻璃幕墙、汽车玻璃窗等，玻璃的隔热对世界节能降耗具有重大贡献，而具有热反射及热吸收性能的玻璃表面涂层对玻璃节能具有重大作用，但目前的玻璃反射膜和吸收膜的制造需要特殊工艺设备，且许多是与玻璃的制造同步进行的，另外，在玻璃上贴上一层具有红外反射功能的薄膜或镀膜，不但成本高，而且效果有限。
发明内容
为解决上述问题，本发明提供玻璃节能自洁玻璃，具体的技术方案为：
玻璃节能自洁玻璃，由以下原料按照重量份数制得，
聚乙烯醇缩丁醛树脂40～55份、二甲基硅油乳液10～20份、十二烷基苯黄酸钠乳液1～5份、多官能团聚氨酯8～16份、聚甲基丙烯酰亚胺5～10份、纳米二氧化钛1～5份、固化剂5～12份。
上述技术方案优选的方案为：由以下原料按照重量份数制得，
聚乙烯醇缩丁醛树脂49份、二甲基硅油乳液15份、十二烷基苯黄酸钠乳液3份、多官能团聚氨酯11份、聚甲基丙烯酰亚胺8份、纳米二氧化钛3份、固化剂8份。
由于上述技术方案的运用，本发明与现有技术相比具有下列优点和效果：
本发明玻璃节能自洁玻璃，隔热效果显著，很大程度降低了空调制冷的电能消耗，节能达35％左右。在寒冷的冬天，还能反射波长较长的室内暖气热辐射，有效阻挡室内热能透过玻璃门窗传导外泄，减少室内能量的损耗，可广泛应用于各类建筑物的玻璃门、窗之上。
具体实施方式
下面结合实施例对本发明作进一步描述：
实施例1
玻璃节能自洁玻璃，由以下原料按照重量份数经反应后制得：
聚乙烯醇缩丁醛树脂40份、二甲基硅油乳液10份、十二烷基苯黄酸钠乳液1份、多官能团聚氨酯8份、聚甲基丙烯酰亚胺5份、纳米二氧化钛1份、固化剂5份。
实施例2
玻璃节能自洁玻璃，由以下原料按照重量份数经反应后制得：
聚乙烯醇缩丁醛树脂55份、二甲基硅油乳液20份、十二烷基苯黄酸钠乳液5份、多官能团聚氨酯16份、聚甲基丙烯酰亚胺10份、纳米二氧化钛5份、固化剂12份。
实施例3
玻璃节能自洁玻璃，由以下原料按照重量份数经反应后制得：
聚乙烯醇缩丁醛树脂49份、二甲基硅油乳液15份、十二烷基苯黄酸钠乳液3份、多官能团聚氨酯11份、聚甲基丙烯酰亚胺8份、纳米二氧化钛3份、固化剂8份。
以上各实施例的制备方法：
(1)将聚乙烯醇缩丁醛树脂、二甲基硅油乳液、十二烷基苯黄酸钠乳液加到搅拌釜中，搅拌10分钟；
(2)继续将多官能团聚氨酯、聚甲基丙烯酰亚胺、纳米二氧化钛加到搅拌釜中，搅拌15分钟；
(3)最后加入固化剂，搅拌10分钟，充分混合均匀。

Claims (3)

1.玻璃节能自洁玻璃，其特征在于：由以下原料按照重量份数制得，
聚乙烯醇缩丁醛树脂40～55份、二甲基硅油乳液10～20份、十二烷基苯黄酸钠乳液1～5份、多官能团聚氨酯8～16份、聚甲基丙烯酰亚胺5～10份、纳米二氧化钛1～5份、固化剂5～12份。
2.根据权利要求1所述的玻璃节能自洁玻璃，其特征在于：由以下原料按照重量份数制得，聚乙烯醇缩丁醛树脂49份、二甲基硅油乳液15份、十二烷基苯黄酸钠乳液3份、多官能团聚氨酯11份、聚甲基丙烯酰亚胺8份、纳米二氧化钛3份、固化剂8份。
3.根据权利要求1或2所述的玻璃节能自洁玻璃，其特征在于：制备方法包括以下步骤：
(1)将聚乙烯醇缩丁醛树脂、二甲基硅油乳液、十二烷基苯黄酸钠乳液加到搅拌釜中，搅拌10分钟；
(2)继续将多官能团聚氨酯、聚甲基丙烯酰亚胺、纳米二氧化钛加到搅拌釜中，搅拌15分钟；
(3)最后加入固化剂，搅拌10分钟，充分混合均匀。
CN201611112765.XA 2016-12-06 2016-12-06 玻璃节能自洁玻璃 Pending CN106752463A (zh)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20200139614A (ko) * 2019-06-04 2020-12-14 숭실대학교산학협력단 초발수 코팅용 조성물, 이를 통해 형성된 초발수 코팅층 및 이의 형성방법

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20200139614A (ko) * 2019-06-04 2020-12-14 숭실대학교산학협력단 초발수 코팅용 조성물, 이를 통해 형성된 초발수 코팅층 및 이의 형성방법
KR102329640B1 (ko) * 2019-06-04 2021-11-22 숭실대학교 산학협력단 초발수 코팅용 조성물, 이를 통해 형성된 초발수 코팅층 및 이의 형성방법

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