CN106752435A - One kind is for electric armour clamp corrosion-resistant composite organic modifying cinepazid water paint and preparation method thereof - Google Patents
One kind is for electric armour clamp corrosion-resistant composite organic modifying cinepazid water paint and preparation method thereof Download PDFInfo
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- CN106752435A CN106752435A CN201710018688.XA CN201710018688A CN106752435A CN 106752435 A CN106752435 A CN 106752435A CN 201710018688 A CN201710018688 A CN 201710018688A CN 106752435 A CN106752435 A CN 106752435A
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- China
- Prior art keywords
- preparation
- armour clamp
- electric armour
- resistant composite
- water paint
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D125/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Coating compositions based on derivatives of such polymers
- C09D125/02—Homopolymers or copolymers of hydrocarbons
- C09D125/04—Homopolymers or copolymers of styrene
- C09D125/08—Copolymers of styrene
- C09D125/14—Copolymers of styrene with unsaturated esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
- C08K3/346—Clay
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K9/00—Use of pretreated ingredients
- C08K9/04—Ingredients treated with organic substances
- C08K9/06—Ingredients treated with organic substances with silicon-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K9/00—Use of pretreated ingredients
- C08K9/10—Encapsulated ingredients
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
- C09D7/62—Additives non-macromolecular inorganic modified by treatment with other compounds
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Inorganic Chemistry (AREA)
- Dispersion Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
It is used for electric armour clamp corrosion-resistant composite organic modifying cinepazid water paint the invention discloses one kind, the coating is made up of the raw material of following weight portion：POSS monomers, imidazole type ion liquid, cellulose acetate, organic clay, solid content are 30 50% silicone modified styrene-acrylate emulsion 30 50, Lauryl Alcohol ester 12, defoamer 0.1 0.2, lauryl sodium sulfate 0.1 0.2, water 10 15, ethanol.
Description
Technical field
It is compounded with for electric armour clamp corrosion-resistant the present invention relates to electric armour clamp corrosion resistant coating technical field, more particularly to one kind
Machine Si modification styrene-acrylic water-borne coatings and preparation method thereof.
Background technology
Gold utensil is that the metal that fixed and supporting function is played in power transmission line connects the general designation of annex, is in because it
Natural exposing state, in use corrosion condition happen occasionally, especially corrosion feelings in some more rugged environment
Condition is particularly acute, and directly affects the safety of power network, therefore, it is most important using effective anti-corrosion protection measure.It is applied at present
The anti-corrosion of electric armour clamp is dip galvanized anti-corrosion using more method, but this method production process is seriously polluted, and
The coating for obtaining is partially thin, and thicknesses of layers is uneven, and protection effect is not enough in an outdoor environment, and plating property is poor again.
The protective coating that organic siliconresin is formed has excellent heat resistance, UV resistant, water-fast, weatherable
Can, it is particularly suitable for outdoor environment and uses, while there is excellent electrical property and recoatability, if be applied to electric armour clamp preventing
To be had broad application prospects in shield.But single organic siliconresin not only production cost is higher, and solidification temperature is high, solid
The change time is long, and film adhesion is also poor, using being restricted, often it is used with other resin compoundeds in actual applications.
《A kind of preparation of transparent epoxy modified organic silicone resin and performance》Epoxy modified silicone resin prepared by one text is that one kind will
The excellent product that both advantages are effectively combined, also achieves normal temperature cure, using epoxy modified silicone resin as filmogen,
Arrange in pairs or groups other auxiliary agents, the coating with excellent antiseptic effect can be obtained, but organic solvent is needed to use in process for preparation, it is right
Environment has larger harm.
The content of the invention
The object of the invention is exactly to make up the defect of prior art, there is provided one kind is compounded with for electric armour clamp corrosion-resistant
Machine Si modification styrene-acrylic water-borne coatings and preparation method thereof.
The present invention is achieved by the following technical solutions：
One kind is used for electric armour clamp corrosion-resistant composite organic modifying cinepazid water paint, and the coating is by following weight portion
Raw material is made：POSS monomers 2-3, imidazole type ion liquid 5-10, cellulose acetate 1-2, organic clay 1-2, solid content are 30-
50% silicone modified styrene-acrylate emulsion 30-50, Lauryl Alcohol ester 1-2, defoamer 0.1-0.2, lauryl sodium sulfate 0.1-
0.2nd, water 10-15, ethanol 12-15.
Described imidazole type ion liquid be 1- ethyl-3-methylimidazoles acetate, 1- butyl -3- methylimidazole villaumites,
One kind in 1- butyl -3- methylimidazole hexafluorophosphates.
A kind of described preparation method for electric armour clamp corrosion-resistant composite organic modifying cinepazid water paint is：
(1) cellulose acetate first is subsequently added by imidazole type ion liquid input reaction vessel, system is heated to 60-
80 DEG C, stirring is completely dissolved that to be configured to mixed solution standby to it；
(2) ethanol, organic clay, POSS monomers are taken, mixed grinding mixing 1-2h in gained slurry input reactor, is opened
Agitating device is opened, solution prepared by step (1) is added dropwise, continue to stir mixing 2-3h, subsequent system suction filtration, gained after completion of dropping
Product vacuum disperses standby after drying；
(3) agitating device in water input retort, will be opened, rotating speed is that 300-500 turns/min, sequentially adds step (2)
The material of preparation, lauryl sodium sulfate, silicone modified styrene-acrylate emulsion is added after stirring mixing 30-50min, continues to stir mixed
1-2h is closed, other leftover materials are eventually adding, through viscosity regulation, packaging after stirring 40-50min, obtained final product.
Electric armour clamp anti-corrosion coating prepared by the present invention is kept away using waterborne organic silicon modifying cinepazid emulsion as filmogen
The use of organic solvent is exempted from, the protection film layer of high adhesion force and enhanced water resistance can have been formed on metalwork surface, while adding
Organic clay, the POSS monomer hydridization fillers of Surface coating nanometer CAM, this filler have excellent modified increasing
Potent fruit, further improves the corrosion-resistant and plasticity of coating, improve conventional inorganic fillers and resin emulsion poor compatibility,
The defect such as price is high, is finally obtained smooth, fine and close, tough, durable water-repellent preservation coating, and protection well is played to gold utensil
Effect.
Specific embodiment
One kind is used for electric armour clamp corrosion-resistant composite organic modifying cinepazid water paint, and the coating is by following weight portion
Raw material is made：POSS monomers 2,1- ethyl-3-methylimidazoles acetate 5, cellulose acetate 1, organic clay 1, solid content are
30% silicone modified styrene-acrylate emulsion 30, Lauryl Alcohol ester 1, defoamer 0.1, lauryl sodium sulfate 0.1, water 10, ethanol
12。
The preparation method of the coating is：
(1) cellulose acetate first is subsequently added by imidazole type ion liquid input reaction vessel, system is heated to 60
DEG C, stirring is completely dissolved that to be configured to mixed solution standby to it；
(2) ethanol, organic clay, POSS monomers are taken, mixed grinding mixing 1h in gained slurry input reactor, is opened
Agitating device, is added dropwise solution prepared by step (1), continues to stir mixing 2h, subsequent system suction filtration, products therefrom after completion of dropping
Disperse after vacuum drying standby；
(3) by water input retort, agitating device is opened, rotating speed is 300 turns/min, sequentially adds step (2) preparation
Material, lauryl sodium sulfate, add silicone modified styrene-acrylate emulsion after stirring mixing 30min, continue to stir mixing 1h, most
After add other leftover materials, through viscosity regulation, packaging after stirring 40min, obtain final product.
The coating of preparation carries out performance test according to relevant criterion, and test result is as follows：
| Project | Index |
| Paint film appearance | It is smooth |
| Viscosity/s | 52 |
| Surface drying | 1.8h |
| Do solid work | 24h |
| Adhesive force | 1 grade |
| Impact strength | 50kg.cm |
| Resistance to salt water (3%NaCl) | 168h is unchanged |
| Corrosion potential | -0.92V |
Claims (3)
1. it is a kind of to be used for electric armour clamp corrosion-resistant composite organic modifying cinepazid water paint, it is characterised in that the coating by with
The raw material of lower weight portion is made：POSS monomers 2-3, imidazole type ion liquid 5-10, cellulose acetate 1-2, organic clay 1-2,
Solid content is silicone modified styrene-acrylate emulsion 30-50, Lauryl Alcohol ester 1-2, defoamer 0.1-0.2, the dodecyl of 30-50%
Sodium sulphate 0.1-0.2, water 10-15, ethanol 12-15.
2. as claimed in claim 1 a kind of for electric armour clamp corrosion-resistant composite organic modifying cinepazid water paint, it is special
Levy and be, described imidazole type ion liquid is 1- ethyl-3-methylimidazoles acetate, 1- butyl -3- methylimidazole villaumites, 1-
One kind in butyl -3- methylimidazole hexafluorophosphates.
3. a kind of preparation for electric armour clamp corrosion-resistant composite organic modifying cinepazid water paint as claimed in claim 1
Method, it is characterised in that described preparation method is：
（1）First by imidazole type ion liquid input reaction vessel, cellulose acetate is subsequently added, system is heated to 60-80 DEG C,
Stirring is completely dissolved that to be configured to mixed solution standby to it；
（2）Ethanol, organic clay, POSS monomers are taken, mixed grinding mixing 1-2h, gained slurry is put into reactor, and unlatching is stirred
Device is mixed, step is added dropwise（1）The solution of preparation, continues to stir mixing 2-3h, subsequent system suction filtration, products therefrom after completion of dropping
Disperse after vacuum drying standby；
（3）In water input retort, agitating device will be opened, rotating speed is that 300-500 turns/min, sequentially adds step（2）Prepare
Material, lauryl sodium sulfate, add silicone modified styrene-acrylate emulsion after stirring mixing 30-50min, continue to stir mixing 1-
2h, is eventually adding other leftover materials, through viscosity regulation, packaging after stirring 40-50min, obtains final product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710018688.XA CN106752435A (en) | 2017-01-10 | 2017-01-10 | One kind is for electric armour clamp corrosion-resistant composite organic modifying cinepazid water paint and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710018688.XA CN106752435A (en) | 2017-01-10 | 2017-01-10 | One kind is for electric armour clamp corrosion-resistant composite organic modifying cinepazid water paint and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106752435A true CN106752435A (en) | 2017-05-31 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710018688.XA Pending CN106752435A (en) | 2017-01-10 | 2017-01-10 | One kind is for electric armour clamp corrosion-resistant composite organic modifying cinepazid water paint and preparation method thereof |
Country Status (1)
| Country | Link |
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| CN (1) | CN106752435A (en) |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102443330A (en) * | 2011-10-17 | 2012-05-09 | 重庆文理学院 | Coating material and its preparation method |
| CN105295578A (en) * | 2015-11-30 | 2016-02-03 | 桂林市和鑫防水装饰材料有限公司 | Silicone-modified styrene-acrylic emulsion coating and preparation method thereof |
| CN105368174A (en) * | 2015-11-23 | 2016-03-02 | 苏州盖德精细材料有限公司 | Single liquid type metal antirust paint and preparation method thereof |
-
2017
- 2017-01-10 CN CN201710018688.XA patent/CN106752435A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102443330A (en) * | 2011-10-17 | 2012-05-09 | 重庆文理学院 | Coating material and its preparation method |
| CN105368174A (en) * | 2015-11-23 | 2016-03-02 | 苏州盖德精细材料有限公司 | Single liquid type metal antirust paint and preparation method thereof |
| CN105295578A (en) * | 2015-11-30 | 2016-02-03 | 桂林市和鑫防水装饰材料有限公司 | Silicone-modified styrene-acrylic emulsion coating and preparation method thereof |
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| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| CB03 | Change of inventor or designer information | ||
| CB03 | Change of inventor or designer information |
Inventor after: Yang Zhiwu Inventor after: Cui Shuqing Inventor after: Zhao Shiwu Inventor after: Fu Xiang Inventor after: Zhang Yongchun Inventor after: Li Lei Inventor before: Cui Shuqing Inventor before: Zhao Jie Inventor before: Zhao Shiwu Inventor before: Fu Xiang Inventor before: Zhang Yongchun Inventor before: Li Lei |
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| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20170531 |