CN106752418A - PP silane coupling agents - Google Patents
PP silane coupling agents Download PDFInfo
- Publication number
- CN106752418A CN106752418A CN201611232189.2A CN201611232189A CN106752418A CN 106752418 A CN106752418 A CN 106752418A CN 201611232189 A CN201611232189 A CN 201611232189A CN 106752418 A CN106752418 A CN 106752418A
- Authority
- CN
- China
- Prior art keywords
- parts
- silane coupling
- coupling agents
- dimethylbenzene
- toluene
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D123/00—Coating compositions based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Coating compositions based on derivatives of such polymers
- C09D123/26—Coating compositions based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Coating compositions based on derivatives of such polymers modified by chemical after-treatment
- C09D123/28—Coating compositions based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Coating compositions based on derivatives of such polymers modified by chemical after-treatment by reaction with halogens or compounds containing halogen
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Abstract
The invention discloses a kind of PP silane coupling agents and its manufacture method.It is made up of toluene, dimethylbenzene, carbon tetrachloride, chlorinated polypropylene, haloflex, polyvinyl butyral resin, phenolic aldehyde, polyester, maleic anhydride, organic peroxide, antistatic additive.PP silane coupling agents of the invention are formed by plurality of raw materials rational proportion.PP silane coupling agents according to the reacted prepared different soft and hard section of the different number of raw material reach the adhesive strength requirement of different PP products.Silane coupling agent of the invention has that high intensity, purposes is wide, low-cost advantage.
Description
Technical field
The present invention relates to a kind of PP silane coupling agents, specifically related to one kind exempts from treatment PP sheet materials and plastic foil bonding.
Background technology
Current China PP films industry is required for corona or flame treatment in printing and bonding, and unstable properties can not be long
Put, for production brings very big inconvenience;PP sheet materials are unable to corona or flame treatment, can only frosted, using being above restricted;PP is sealed
Edge strip industry prevents PP edge bands from normally using because that can not form effectively bonding;The present invention can make PP sheet materials, film, edge band
Without corona, flame and frosted, as long as coat product of the present invention and can just print, be bonded, use intensity is reached.
The content of the invention
The present invention solves the technical problem of a kind of PP products silane coupling agent is provided, silane coupling agent of the invention has high-strength
Degree, purposes are wide, low-cost advantage.
Silane coupling agent of the invention, by toluene, dimethylbenzene, carbon tetrachloride, chlorinated polypropylene, haloflex, polyvinyl alcohol
Butyral, phenolic aldehyde, polyester, maleic anhydride, organic peroxide, antistatic additive composition:
Described toluene 10-30 parts;
Described dimethylbenzene 10-50 parts;
Described carbon tetrachloride 10-30 parts;
Described chlorinated polypropylene 30-60 parts;
Described haloflex 1-5 parts;
Described polyvinyl butyral resin 1-5 parts;
Described phenolic aldehyde 1-5 parts;
Described polyester 1-5 parts;
Described maleic anhydride 1-3 parts;
Described organic peroxide 1-5 parts;
Described antistatic additive 0.5-3 parts;
Described number is parts by weight.
Preferably one is:
13.2 parts of the toluene;
20 parts of the dimethylbenzene;
13.2 parts of the carbon tetrachloride;
40 parts of the chlorinated polypropylene;
2 parts of the haloflex;
3.2 parts of the polyvinyl butyral resin;
1.2 parts of the phenolic aldehyde;
2 parts of the polyester;
1.2 parts of the maleic anhydride;
3.2 parts of the organic peroxide;
0.8 part of the antistatic additive;
Described number is parts by weight.
Preferably two are:
13.2 parts of the toluene;
20 parts of the dimethylbenzene;
13.2 parts of the carbon tetrachloride;
40 parts of the chlorinated polypropylene;
3.6 parts of the haloflex;
4 parts of the polyvinyl butyral resin;
0 part of the phenolic aldehyde;
0.8 part of the polyester;
1.2 parts of the maleic anhydride;
3.2 parts of the organic peroxide;
0.8 part of the antistatic additive;
Described number is parts by weight.
The preparation method of above-mentioned aqueous basecoat agent, is carried out as steps described below:
Successively by toluene, dimethylbenzene, carbon tetrachloride, chlorinated polypropylene, haloflex, polyvinyl butyral resin, phenolic aldehyde, poly-
Ester, maleic anhydride, organic peroxide, antistatic additive are poured into reactor, are stirred 240 minutes under 40 ° of constant temperature, form uniform
Solution.
The beneficial effects of the invention are as follows:Aqueous basecoat agent of the invention is formed by plurality of raw materials rational proportion, according to raw material
The PP silane coupling agents of the reacted prepared different soft and hard section of different numbers reach the adhesive strength requirement of different PP products.
Described above is only the general introduction of technical solution of the present invention, in order to better understand technological means of the invention,
And can be practiced according to the content of specification, described in detail as after with presently preferred embodiments of the present invention below.
Embodiment 1:PP silane coupling agents of the invention, by toluene, dimethylbenzene, carbon tetrachloride, chlorinated polypropylene, chlorinated polyethylene
Alkene, polyvinyl butyral resin, phenolic aldehyde, polyester, maleic anhydride, organic peroxide, antistatic additive composition;
13.2 parts of the toluene;
20 parts of the dimethylbenzene;
13.2 parts of the carbon tetrachloride;
40 parts of the chlorinated polypropylene;
2 parts of the haloflex;
3.2 parts of the polyvinyl butyral resin;
1.2 parts of the phenolic aldehyde;
2 parts of the polyester;
1.2 parts of the maleic anhydride;
3.2 parts of the organic peroxide;
0.8 part of the antistatic additive;
Described number is parts by weight.
Embodiment 2:PP silane coupling agents of the invention, by toluene, dimethylbenzene, carbon tetrachloride, chlorinated polypropylene, chlorinated polyethylene
Alkene, polyvinyl butyral resin, phenolic aldehyde, polyester, maleic anhydride, organic peroxide, antistatic additive composition;
13.2 parts of the toluene;
20 parts of the dimethylbenzene;
13.2 parts of the carbon tetrachloride;
40 parts of the chlorinated polypropylene;
3.6 parts of the haloflex;
4 parts of the polyvinyl butyral resin;
0 part of the phenolic aldehyde;
0.8 part of the polyester;
1.2 parts of the maleic anhydride;
3.2 parts of the organic peroxide;
0.8 part of the antistatic additive;
Described number is parts by weight.
The preparation method of the PP silane coupling agents of embodiment 1 and embodiment 2, is carried out as steps described below:
Successively by toluene, dimethylbenzene, carbon tetrachloride, chlorinated polypropylene, haloflex, polyvinyl butyral resin, phenolic aldehyde, poly-
Ester, maleic anhydride, organic peroxide, antistatic additive are poured into reactor, are stirred 240 minutes under 40 ° of constant temperature, form uniform
Solution.
Embodiments of the invention are the foregoing is only, the scope of the claims of the invention is not thereby limited, it is every to utilize this hair
Equivalent structure or equivalent flow conversion that bright description is made, or directly or indirectly it is used in other related technology necks
Domain, is included within the scope of the present invention.
Claims (4)
1. a kind of PP silane coupling agents, it is characterised in that:PP silane coupling agents of the invention, are gathered by toluene, dimethylbenzene, carbon tetrachloride, chlorination
Propylene, haloflex, polyvinyl butyral resin, phenolic aldehyde, polyester, maleic anhydride, organic peroxide, antistatic additive composition;
Described toluene 10-30 parts;Described dimethylbenzene 10-50 parts;Described carbon tetrachloride 10-30 parts;Described chlorinated polypropylene 30-60 parts;
Described haloflex 1-5 parts;Described polyvinyl butyral resin 1-5 parts;Described phenolic aldehyde 1-5 parts;Described polyester 1-5 parts;It is described
Maleic anhydride 1-3 parts;Described organic peroxide 1-5 parts;Described antistatic additive 0.5-3 parts;Described number is parts by weight.
2. PP silane coupling agents according to claim 1, it is characterised in that:13.2 parts of the toluene;20 parts of the dimethylbenzene;Institute
State 13.2 parts of carbon tetrachloride;40 parts of the chlorinated polypropylene;2 parts of the haloflex;The polyvinyl butyral resin 3.2
Part;1.2 parts of the phenolic aldehyde;2 parts of the polyester;1.2 parts of the maleic anhydride;3.2 parts of the organic peroxide;It is described anti-quiet
0.8 part of electric agent;Described number is parts by weight.
3. PP silane coupling agents according to claim 1, it is characterised in that:13.2 parts of the toluene;20 parts of the dimethylbenzene;Institute
State 13.2 parts of carbon tetrachloride;40 parts of the chlorinated polypropylene;3.6 parts of the haloflex;The polyvinyl butyral resin 4
Part;0 part of the phenolic aldehyde;0.8 part of the polyester;1.2 parts of the maleic anhydride;3.2 parts of the organic peroxide;It is described anti-quiet
0.8 part of electric agent;Described number is parts by weight.
4. PP silane coupling agents preparation method according to any one of claim 1 to 3, it is characterised in that enter as steps described below
OK:Successively by toluene, dimethylbenzene, carbon tetrachloride, chlorinated polypropylene, haloflex, polyvinyl butyral resin, phenolic aldehyde, polyester,
Maleic anhydride, organic peroxide, antistatic additive are poured into reactor, are stirred 240 minutes under 40 ° of constant temperature, form uniform molten
Liquid.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201611232189.2A CN106752418A (en) | 2016-12-28 | 2016-12-28 | PP silane coupling agents |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201611232189.2A CN106752418A (en) | 2016-12-28 | 2016-12-28 | PP silane coupling agents |
Publications (1)
Publication Number | Publication Date |
---|---|
CN106752418A true CN106752418A (en) | 2017-05-31 |
Family
ID=58921442
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201611232189.2A Pending CN106752418A (en) | 2016-12-28 | 2016-12-28 | PP silane coupling agents |
Country Status (1)
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CN (1) | CN106752418A (en) |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6410636B2 (en) * | 2000-04-25 | 2002-06-25 | 3M Innovative Properties Company | Water dispersed primers |
CN102873953A (en) * | 2012-09-13 | 2013-01-16 | 北京康得新复合材料股份有限公司 | Pre-coating film without primer coating, two-way stretch polypropylene film thereof and preparation method of polypropylene film |
CN102994015A (en) * | 2011-09-09 | 2013-03-27 | 中国科学院化学研究所 | Primer used for waterless offset printing plate-making, and preparation method and application thereof |
CN103319959A (en) * | 2013-06-09 | 2013-09-25 | 广州市承信公路工程检验有限公司 | Bridge cable polyethylene protective primer and preparation method thereof |
CN105585989A (en) * | 2015-12-16 | 2016-05-18 | 浙江凌志精细化工有限公司 | Accelerant composition applied to bonding of addition type silicone rubber and PP |
-
2016
- 2016-12-28 CN CN201611232189.2A patent/CN106752418A/en active Pending
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6410636B2 (en) * | 2000-04-25 | 2002-06-25 | 3M Innovative Properties Company | Water dispersed primers |
CN102994015A (en) * | 2011-09-09 | 2013-03-27 | 中国科学院化学研究所 | Primer used for waterless offset printing plate-making, and preparation method and application thereof |
CN102873953A (en) * | 2012-09-13 | 2013-01-16 | 北京康得新复合材料股份有限公司 | Pre-coating film without primer coating, two-way stretch polypropylene film thereof and preparation method of polypropylene film |
CN103319959A (en) * | 2013-06-09 | 2013-09-25 | 广州市承信公路工程检验有限公司 | Bridge cable polyethylene protective primer and preparation method thereof |
CN105585989A (en) * | 2015-12-16 | 2016-05-18 | 浙江凌志精细化工有限公司 | Accelerant composition applied to bonding of addition type silicone rubber and PP |
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PB01 | Publication | ||
PB01 | Publication | ||
SE01 | Entry into force of request for substantive examination | ||
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RJ01 | Rejection of invention patent application after publication | ||
RJ01 | Rejection of invention patent application after publication |
Application publication date: 20170531 |