CN106751934A - A kind of large volume 3D printing modified paraffin material and preparation method thereof - Google Patents
A kind of large volume 3D printing modified paraffin material and preparation method thereof Download PDFInfo
- Publication number
- CN106751934A CN106751934A CN201611015039.6A CN201611015039A CN106751934A CN 106751934 A CN106751934 A CN 106751934A CN 201611015039 A CN201611015039 A CN 201611015039A CN 106751934 A CN106751934 A CN 106751934A
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- China
- Prior art keywords
- printing
- large volume
- paraffin
- modified paraffin
- printing modified
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Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L91/00—Compositions of oils, fats or waxes; Compositions of derivatives thereof
- C08L91/06—Waxes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B33—ADDITIVE MANUFACTURING TECHNOLOGY
- B33Y—ADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3-D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3-D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING
- B33Y70/00—Materials specially adapted for additive manufacturing
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/06—Polyethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/24—Crystallisation aids
Abstract
The present invention relates to a kind of large volume 3D printing modified paraffin material and preparation method thereof, the features such as with low-shrinkage, low melting point and high intensity, high rigidity.The printed material is made up of paraffin 40 80%, enhancing hardening agent 10 40%, crystallization nucleating agent 4 20%, thermal conductivity conditioning agent 4 15%, and melting range is 92 96 DEG C, it is adaptable to fused glass pellet technique.The printing modified paraffin material reusable edible, the die surface for printing is smooth, it is adaptable to the printing of building element large volume mould.
Description
Technical field
The present invention relates to a kind of paraffin print die material, with the spy such as low-shrinkage, low melting point and high intensity, high rigidity
Point, belongs to the Material Field of rapid shaping.
Background technology
3D printing is a kind of emerging rapid shaping technique, can pass through printing device by special printed material according to design
3D models successively print increase material to manufacture three-dimensional objects.GRC（Fibre reinforced concrete）Plate has that complex contour is changeable, makes
The characteristics of type is different, traditional GRC moulds are made using the splicing of the materials such as plank, gypsum, cement, silica gel, the numerous length of operation,
It is very high to mould labor claim, it is time-consuming to take a lot of work.The rise of 3D printing technique gives GRC Mold Makings another good selection,
Using 3D printing automation, efficiency high, material and the advantage such as artificial are saved, by the printing of inexpensive, reusable edible the step of material one
Mould into needed for GRC, and then GRC plates are made, can greatly save the material and energy waste, shortening system of Mold Making process
Make the duration, improve producing efficiency, and the automated production level of GRC industries is greatly improved.
Current commercialized 3D printing material is generally powder or thick liquid, from price costly（From several
Hundred arrive tens of thousands of first per kilograms）, and commonly using once just discarding, cause cost rising and environmental pollution etc. seriously to ask
Topic.Using mould needed for 3D principles printing building product, it is necessary to special research and development are suitable for inexpensive, the reusable edible of building trade
And the mold materials of 3D printing process requirements can be met.And olefin material can repeat tens times and recycle, in being GRC industries
The mold materials of preferable environment-friendly type.Common natural paraffin wax, synthesis paraffin hardness are low, and intensity is not high, fusing point is too low, simultaneously because
Paraffin heat conductivility is poor, and internal heat difficulty passes to out, is used directly as mold materials, it may appear that problems with, 1. solidifies
Speed is slow, influences 3D printing efficiency, and the block internal-external temperature difference for 2. printing is big, produces big thermal stress uneven, causes impression block
The easy cracking phenomenon of tool；3. paraffin molten point scope is too wide, and the temperature printed with fused deposition method is not easily controlled.China
A kind of eutectic 3D printing paraffin is disclosed in patent 201510096056.6, because melting range is larger, intensity is not high, be only applicable
In the use of small mould, it is impossible to suitable for large scale building element mould.
The content of the invention
It is an object of the present invention to be directed to above-mentioned weak point, develop a kind of 3D special in architectural decoration and beat
Seal wax mold materials.
Large volume 3D printing modified paraffin material of the invention, is formed by the configuration of following raw materials by weight：Paraffin
40-80%, enhancing hardening agent 10-40%, crystallization nucleating agent 4-20%, thermal conductivity conditioning agent 4-15%.
Described paraffin is using one or two the combination in natural paraffin wax, synthesis paraffin.
Described enhancing hardening agent is using one or more combination in polyethylene, polypropylene, polybutene.
Described crystallization nucleating agent uses calcium stearate, Sodium stearate, one or more combination in zinc stearate.
Described thermal conductivity conditioning agent is using the one kind in graphite, metal dust；Described metal dust uses copper powder or aluminium
One or more combination in powder.
The invention also discloses the preparation method of described large volume 3D printing modified paraffin material, including：
（1）Paraffin, enhancing hardening agent, crystallization nucleating agent, thermal conductivity conditioning agent are weighed in proportion；
（2）Under 80-120 DEG C of heating condition, stirring mixing 1-500 minutes；
（3）By the broken material that can be directly obtained for 3D printing of mixed powder after cooling.
Described modified paraffin material, its melting range is 92-96 DEG C, it is adaptable to fused glass pellet technique, its shaping
After the direct processing of mould prepares building element, powder of the circulation as new die can be again crushed, recycling number of times is 15-35
It is secondary.
The beneficial effects of the present invention are：
1. the enhancing hardening agent such as polyethylene, polypropylene, polybutene is used, hardness, the intensity of olefin material is effectively increased, is conducive to
Realize building element large volume mould.
2. the heat conductivility of printed material is improved with graphite, metal dust additive, it is to avoid large volume thermal conductivity is uneven
The problems such as crack of die for causing.
3. crystallization nucleating agent calcium stearate, zinc stearate are used, odium stearate effectively improves the crystal property of olefin material,
Regulation and control paraffin prints fusing point in narrow range.
4. can directly coordinate special 3D printing equipment after production gained feed powder is broken carries out fusion sediment printing, and need not be outer
Plus other printing auxiliary agents.
5. olefin material reusable edible, the die surface for printing is smooth.
Specific embodiment
Below in conjunction with specific embodiment, the invention will be further described.
Embodiment 1
（1）Natural paraffin wax 40%, polyethylene 40%, calcium stearate 5%, zinc stearate 5%, graphite 10% are weighed in proportion；
（2）Under 80 DEG C of heating conditions, stirring mixing 500 minutes；
（3）By the broken mold materials that can be directly obtained for the printing of 3D printing equipment of mixed powder after cooling.
Embodiment 2
（1）Chlorinated paraffin 80%, polypropylene 10%, Sodium stearate 4%, copper powder 6% are weighed in proportion；
（2）Under 100 DEG C of heating conditions, stirring mixing 270 minutes；
（3）By the broken mold materials that can be directly obtained for the printing of 3D printing equipment of mixed powder after cooling.
Embodiment 3
（1）Tissuemat E 60%, polyethylene 15%, polybutene 15%, zinc stearate 6%, aluminium powder 4% are weighed in proportion；
（2）Under 120 DEG C of heating conditions, stirring mixing 1 minute；
（3）By the broken mold materials that can be directly obtained for the printing of 3D printing equipment of mixed powder after cooling.
Embodiment 4
（1）Natural paraffin wax 20%, synthesis paraffin 15%, polyethylene 10%, polypropylene 10%, polybutene 10%, calcium stearate 10%, hard ester
Sour sodium 5%, zinc stearate 5%, copper powder 7%, aluminium powder 8% are weighed in proportion；
（2）Under 110 DEG C of heating conditions, stirring mixing 60 minutes；
（3）By the broken mold materials that can be directly obtained for the printing of 3D printing equipment of mixed powder after cooling.
Claims (9)
1. a kind of large volume 3D printing modified paraffin material, it is characterised in that：Its composition and percentage by weight are as follows：Paraffin 40-
80%th, enhancing hardening agent 10-40%, crystallization nucleating agent 4-20%, thermal conductivity conditioning agent -15%.
2. large volume 3D printing modified paraffin material according to claim 1, it is characterised in that：Described paraffin uses day
One or two combination in right paraffin, synthesis paraffin.
3. large volume 3D printing modified paraffin material according to claim 1, it is characterised in that：Described enhancing hardening agent
Using one or more combination in polyethylene, polypropylene, polybutene.
4. large volume 3D printing modified paraffin material according to claim 1, it is characterised in that：Described crystallization nucleating agent
Using calcium stearate, Sodium stearate, one or more combination in zinc stearate.
5. large volume 3D printing modified paraffin material according to claim 1, it is characterised in that：Described thermal conductivity conditioning agent
Using the one kind in graphite, metal dust.
6. large volume 3D printing modified paraffin material according to claim 5, it is characterised in that：Described metal dust is adopted
With one or more combination in copper powder or aluminium powder.
7. a kind of preparation method of the large volume 3D printing modified paraffin material described in any one of claim 1-6, its feature exists
In：Including：
（1）Paraffin, enhancing hardening agent, crystallization nucleating agent, thermal conductivity conditioning agent are weighed in proportion；
（2）Under 80-120 DEG C of heating condition, stirring mixing 1-500 minutes；
（3）By the broken material that can be directly obtained for 3D printing of mixed powder after cooling.
8. the preparation method of large volume 3D printing modified paraffin material according to claim 7, it is characterised in that：It is obtained and beats
The melting range for printing material is 92-96 DEG C.
9. the large volume 3D printing modified paraffin material described in any one of claim 1-6 in fused glass pellet technique should
With.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611015039.6A CN106751934A (en) | 2016-11-18 | 2016-11-18 | A kind of large volume 3D printing modified paraffin material and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611015039.6A CN106751934A (en) | 2016-11-18 | 2016-11-18 | A kind of large volume 3D printing modified paraffin material and preparation method thereof |
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| Publication Number | Publication Date |
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| CN106751934A true CN106751934A (en) | 2017-05-31 |
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ID=58969563
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201611015039.6A Pending CN106751934A (en) | 2016-11-18 | 2016-11-18 | A kind of large volume 3D printing modified paraffin material and preparation method thereof |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108102392A (en) * | 2017-12-19 | 2018-06-01 | 吴丹 | It is a kind of for 3D printing wax wire of lost foam casting and preparation method thereof |
| CN108676370A (en) * | 2018-05-08 | 2018-10-19 | 东莞恒天新材料有限公司 | The non-photocuring modelling wax of 3D printing based on graphene and its synthetic method |
| CN108714679A (en) * | 2018-06-06 | 2018-10-30 | 共享智能铸造产业创新中心有限公司 | A kind of 3 D-printing dusty material and its configuration method |
| CN109504105A (en) * | 2018-11-30 | 2019-03-22 | 广州市德馨蜡制品有限公司 | Based on MJP technology bullion 3D printing wax material and preparation method thereof |
| CN110297070A (en) * | 2019-06-27 | 2019-10-01 | 中国矿业大学 | A kind of three-dimensional solid-liquid coupling analog simulation system and method excavated for coal seam |
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| CN105504836A (en) * | 2015-12-31 | 2016-04-20 | 佛山市晗宇科技有限公司 | Low-needle-penetration paraffin supporting material used for 3D printing and preparation method thereof |
| CN105802257A (en) * | 2016-04-26 | 2016-07-27 | 付远 | 3D-printed molding resin for investment casting |
| CN106118082A (en) * | 2016-06-22 | 2016-11-16 | 佛山市晗宇科技有限公司 | A kind of high tenacity 3D prints wax moulding material and preparation method thereof |
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2016
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN105504836A (en) * | 2015-12-31 | 2016-04-20 | 佛山市晗宇科技有限公司 | Low-needle-penetration paraffin supporting material used for 3D printing and preparation method thereof |
| CN105802257A (en) * | 2016-04-26 | 2016-07-27 | 付远 | 3D-printed molding resin for investment casting |
| CN106118082A (en) * | 2016-06-22 | 2016-11-16 | 佛山市晗宇科技有限公司 | A kind of high tenacity 3D prints wax moulding material and preparation method thereof |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108102392A (en) * | 2017-12-19 | 2018-06-01 | 吴丹 | It is a kind of for 3D printing wax wire of lost foam casting and preparation method thereof |
| CN108676370A (en) * | 2018-05-08 | 2018-10-19 | 东莞恒天新材料有限公司 | The non-photocuring modelling wax of 3D printing based on graphene and its synthetic method |
| CN108714679A (en) * | 2018-06-06 | 2018-10-30 | 共享智能铸造产业创新中心有限公司 | A kind of 3 D-printing dusty material and its configuration method |
| CN109504105A (en) * | 2018-11-30 | 2019-03-22 | 广州市德馨蜡制品有限公司 | Based on MJP technology bullion 3D printing wax material and preparation method thereof |
| CN110297070A (en) * | 2019-06-27 | 2019-10-01 | 中国矿业大学 | A kind of three-dimensional solid-liquid coupling analog simulation system and method excavated for coal seam |
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