CN106751666A - A kind of arrangements for automotive doors interior trim plastic plate and preparation method thereof - Google Patents
A kind of arrangements for automotive doors interior trim plastic plate and preparation method thereof Download PDFInfo
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- CN106751666A CN106751666A CN201611165489.3A CN201611165489A CN106751666A CN 106751666 A CN106751666 A CN 106751666A CN 201611165489 A CN201611165489 A CN 201611165489A CN 106751666 A CN106751666 A CN 106751666A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L69/00—Compositions of polycarbonates; Compositions of derivatives of polycarbonates
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Vehicle Interior And Exterior Ornaments, Soundproofing, And Insulation (AREA)
Abstract
The present invention discloses a kind of arrangements for automotive doors interior trim plastic plate,The material matched by following parts by weight is made,Including 28 30 parts of aromatic copolycarbonate,16 20 parts of heliotropin,24 parts of sodium carbonate,11 15 parts of stannous chloride,12 14 parts of ferric trichloride,16 20 parts of MAO,22 24 parts of boric acid alkylolamides,35 40 parts of butylated hydroxy anisole,7 11 parts of zinc stearate,16 28 parts of peroxidized t-butyl perbenzoate,9 11 parts of diamond dust,8 12 parts of bis cyclopentadienyl zirconium dichloride,5 10 parts of polyvinylpyrrolidone,16 20 parts of calcium stearate,Penta 69 parts of tetrol,13 14 parts of ethoxyquinoline,20 25 parts of polyacrylonitrile-based carbon fibre,38 parts of BP,10 13 parts of 11 13 parts of polyvinyl formal and diisononyl phthalate,The arrangements for automotive doors interior trim plastic plate structure intensity is high,With antiageing effect,Anti-wear performance is good.
Description
Technical field
The present invention relates to a kind of arrangements for automotive doors interior trim plastic plate and preparation method thereof.
Background technology
Car door is the passage that the vehicle that comes in and goes out is provided for driver and passenger, and completely cuts off interference outside car, is subtracted to a certain extent
Light side impact, protects occupant.Also the moulding with car door attractive in appearance of automobile is relevant.The quality of car door, is mainly reflected in, car door
Crashworthiness, the sealing property of car door, the folding convenience of car door also has other indexs using function etc. certainly.Crashworthiness
Can be particularly important, because when vehicle occurs side impact, buffer distance is very short, it is easy to just hurt occupant.In good car door extremely
I haven't seen you for ages two collision prevention girders, and the deal of collision prevention girders is heavier, that is to say, that good car door is laid particular stress on really.But can not
Say that car door is more heavy better.Present new automobile, if it be can guarantee that in security performance etc., designer can be by every means
Mitigate weight (such as with new material) of the vehicle including car door to reduce power consumption.Press car door quantity different, can be car point
It is two, three, four, five cars etc..Car for public affair purposes is mostly four, and the car for domestic use is existing
Four also have three and five (back door is raising type), and the sport car of Sport Utility is mostly then two.Along open type car door：Even if
Can still borrow the pressure of air-flow to shut in running car, relatively safety, and be easy to driver to be observed backward in reversing, therefore quilt
It is widely used.Inverse open type car door：If be not closed completely in running car may be washed open by windstream, thus it is used less,
Typically just in order to improve HOP ON-CHOP OFF and just use in the case of being suitable to welcome's ceremony needs.Car door presses its production technology
Can be divided into following several:Monoblock type car door：Inner and outer plates are formed by bound edge after monoblock steel plate punched, and the first mould of the mode of production is thrown
Enter cost larger, but can accordingly reduce related cubing fixture, stock utilization is relatively low.Split type car door：By door frame assembly and
Car door inner and outer plates assembly welding is formed, and doorframe assembly can be produced using rolling mode, and cost is relatively low, and productivity ratio is higher, overall phase
Answer die cost relatively low, but later stage cubing fixture is relatively costly, and reliability of technology is poor.Monoblock type car door and split type car door
It is not very big to be differed in terms of holistic cost, mainly determines related structure type according to related modeling requirement.Due to mesh
The requirement of preceding vehicle configuration is higher, and production efficiency requirement is higher, car door overall structure tend to it is split type.
Existing arrangements for automotive doors inside uses plastic plate as decoration, but existing material structural strength is not high, does not have
There is antiageing effect, anti-wear performance is bad.
The content of the invention
In view of this, it is high it is an object of the present invention to provide a kind of structural strength, with antiageing effect, the good vapour of anti-wear performance
Car vehicle door interior trim plastic plate.
In order to solve the above-mentioned technical problem, the technical scheme is that：
A kind of arrangements for automotive doors interior trim plastic plate, the material matched by following parts by weight is made, including aromatic polycarbonate
Ester 28-30 parts, heliotropin 16-20 parts, sodium carbonate 2-4 parts, stannous chloride 11-15 parts, ferric trichloride 12-14 parts, aluminium methyl
16-20 parts of oxygen alkane, 22-24 parts of boric acid alkylolamides, butylated hydroxy anisole 35-40 parts, zinc stearate 7-11 parts, peroxidating
T-butyl perbenzoate 16-28 parts, diamond dust 9-11 parts, bis cyclopentadienyl zirconium dichloride 8-12 parts, polyvinylpyrrolidone 5-10 parts, stearic acid
Calcium 16-20 parts, penta tetrol 6-9 parts, ethoxyquinoline 13-14 parts, polyacrylonitrile-based carbon fibre 20-25 parts, BP 3-8
Part, polyvinyl formal 11-13 parts and diisononyl phthalate 10-13 parts.
Preferably, be made up of the material that following parts by weight are matched, including 28 parts of aromatic copolycarbonate, heliotropin
16 parts, 2 parts of sodium carbonate, 11 parts of stannous chloride, 12 parts of ferric trichloride, 16 parts of MAO, 22 parts of boric acid alkylolamides, fourth
35 parts of base BHA, 7 parts of zinc stearate, 16 parts of peroxidized t-butyl perbenzoate, 9 parts of diamond dust, 8 parts of bis cyclopentadienyl zirconium dichloride,
5 parts of polyvinylpyrrolidone, 16 parts of calcium stearate, 6 parts of penta tetrol, 13 parts of ethoxyquinoline, 20 parts of polyacrylonitrile-based carbon fibre,
10 parts of 3 parts of BP, 11 parts of polyvinyl formal and diisononyl phthalate.
Preferably, be made up of the material that following parts by weight are matched, including 29 parts of aromatic copolycarbonate, heliotropin
18 parts, 3 parts of sodium carbonate, 13 parts of stannous chloride, 13 parts of ferric trichloride, 18 parts of MAO, 23 parts of boric acid alkylolamides, fourth
37.5 parts of base BHA, 9 parts of zinc stearate, 22 parts of peroxidized t-butyl perbenzoate, 10.5 parts of diamond dust, bis cyclopentadienyl zirconium dichloride
10 parts, 7.5 parts of polyvinylpyrrolidone, 18 parts of calcium stearate, 7.5 parts of penta tetrol, 13.5 parts of ethoxyquinoline, polyacrylonitrile-radical
11.5 parts of 22.5 parts of carbon fiber, 5.5 parts of BP, 12 parts of polyvinyl formal and diisononyl phthalate.
Preferably, be made up of the material that following parts by weight are matched, including 30 parts of aromatic copolycarbonate, heliotropin
20 parts, 4 parts of sodium carbonate, 15 parts of stannous chloride, 14 parts of ferric trichloride, 20 parts of MAO, 24 parts of boric acid alkylolamides, fourth
40 parts of base BHA, 11 parts of zinc stearate, 28 parts of peroxidized t-butyl perbenzoate, 11 parts of diamond dust, bis cyclopentadienyl zirconium dichloride 12
Part, 10 parts of polyvinylpyrrolidone, 20 parts of calcium stearate, 9 parts of penta tetrol, 14 parts of ethoxyquinoline, polyacrylonitrile-based carbon fibre
13 parts of 25 parts, 8 parts of BP, 13 parts of polyvinyl formal and diisononyl phthalate.
The invention solves the problems that another technical problem be that a kind of preparation method of arrangements for automotive doors interior trim plastic plate is provided, including
Following steps：
1) by aromatic copolycarbonate 28-30 parts, heliotropin 16-20 parts, sodium carbonate 2-4 parts, stannous chloride 11-15
Part, ferric trichloride 12-14 parts, MAO 16-20 parts, 22-24 parts of boric acid alkylolamides, butylated hydroxy anisole 35-
5-10 is soaked in 40 parts, zinc stearate 7-11 parts, the peroxidized t-butyl perbenzoate 16-28 parts hydrochloric acid solutions for putting into 1-2%
Minute, it is standby；
2) by step 1) to put into the temperature adjustment of middle reactor after gained raw material filtering be 135-140 DEG C, mixing speed
It is 1700-1900r/min, the reaction time is 25-30 minutes, standby；
3) by diamond dust 9-11 parts, bis cyclopentadienyl zirconium dichloride 8-12 parts, polyvinylpyrrolidone 5-10 parts, calcium stearate 16-20
Part, penta tetrol 6-9 parts, ethoxyquinoline 13-14 parts, polyacrylonitrile-based carbon fibre 20-25 parts, BP 3-8 parts, poly- second
In 11-13 parts of enol formal and diisononyl phthalate 10-13 parts of banbury, regulation heating-up temperature is 180-185 DEG C,
Heating 2-5 minutes, it is standby；
4) by step 2) gained raw material put into step 3) banbury in mix, lifting heating-up temperature to 220 DEG C, reaction
It is 1-2 minutes, standby；
5) by step 4) during gained raw material puts into injection machine, heating is in molten condition, then raw material is molded into mould,
Shaping.
The technology of the present invention effect major embodiment is in the following areas：The aromatic copolycarbonate of addition, boric acid alkylolamides,
Butylated hydroxy anisole and zinc stearate cause that material structural strength is high, 7.5 parts of penta tetrol, ethoxyquinoline, poly- third of addition
Alkene itrile group carbon fiber, BP, polyvinyl formal have an antiageing effect, the diamond dust of addition, bis cyclopentadienyl zirconium dichloride,
Polyvinylpyrrolidone causes that material wear-resistant performance is good；The preparation method of use causes material good forming effect, structural stability
It is high.
Specific embodiment
Embodiment 1
A kind of arrangements for automotive doors interior trim plastic plate, the material matched by following parts by weight is made, including aromatic polycarbonate
28 parts of ester, 16 parts of heliotropin, 2 parts of sodium carbonate, 11 parts of stannous chloride, 12 parts of ferric trichloride, 16 parts of MAO, boric acid alkane
22 parts of base alkylolamides, 35 parts of butylated hydroxy anisole, 7 parts of zinc stearate, 16 parts of peroxidized t-butyl perbenzoate, 9 parts of diamond dust,
8 parts of bis cyclopentadienyl zirconium dichloride, 5 parts of polyvinylpyrrolidone, 16 parts of calcium stearate, 6 parts of penta tetrol, 13 parts of ethoxyquinoline, polypropylene
10 parts of 20 parts of itrile group carbon fiber, 3 parts of BP, 11 parts of polyvinyl formal and diisononyl phthalate.
A kind of preparation method of arrangements for automotive doors interior trim plastic plate, comprises the following steps：
1) by 28 parts of aromatic copolycarbonate, 16 parts of heliotropin, 2 parts of sodium carbonate, 11 parts of stannous chloride, ferric trichloride 12
Part, 16 parts of MAO, 22 parts of boric acid alkylolamides, 35 parts of butylated hydroxy anisole, 7 parts of zinc stearate, benzoyl peroxide
16 parts of t-butyl formate soaks 5-10 minutes in putting into the hydrochloric acid solution of 1-2%, standby；
2) by step 1) to put into the temperature adjustment of middle reactor after gained raw material filtering be 135-140 DEG C, mixing speed
It is 1700-1900r/min, the reaction time is 25-30 minutes, standby；
3) by 9 parts of diamond dust, 8 parts of bis cyclopentadienyl zirconium dichloride, 5 parts of polyvinylpyrrolidone, 16 parts of calcium stearate, 6 parts of penta tetrol,
13 parts of ethoxyquinoline, 20 parts of polyacrylonitrile-based carbon fibre, 3 parts of BP, 11 parts of polyvinyl formal and adjacent benzene two
In 10 parts of banburies of formic acid dinonyl, regulation heating-up temperature is 180-185 DEG C, is heated 2-5 minutes, standby；
4) by step 2) gained raw material put into step 3) banbury in mix, lifting heating-up temperature to 220 DEG C, reaction
It is 1-2 minutes, standby；
5) by step 4) during gained raw material puts into injection machine, heating is in molten condition, then raw material is molded into mould,
Shaping.
Embodiment 2
A kind of arrangements for automotive doors interior trim plastic plate, the material matched by following parts by weight is made, including aromatic polycarbonate
29 parts of ester, 18 parts of heliotropin, 3 parts of sodium carbonate, 13 parts of stannous chloride, 13 parts of ferric trichloride, 18 parts of MAO, boric acid alkane
23 parts of base alkylolamides, 37.5 parts of butylated hydroxy anisole, 9 parts of zinc stearate, 22 parts of peroxidized t-butyl perbenzoate, diamond dust
10.5 parts, 10 parts of bis cyclopentadienyl zirconium dichloride, 7.5 parts of polyvinylpyrrolidone, 18 parts of calcium stearate, 7.5 parts of penta tetrol, ethoxyquinoline
13.5 parts, 22.5 parts of polyacrylonitrile-based carbon fibre, 5.5 parts of BP, 12 parts of polyvinyl formal and phthalic acid
11.5 parts of dinonyl.
A kind of preparation method of arrangements for automotive doors interior trim plastic plate, comprises the following steps：
1) by 29 parts of aromatic copolycarbonate, 18 parts of heliotropin, 3 parts of sodium carbonate, 13 parts of stannous chloride, ferric trichloride 13
Part, 18 parts of MAO, 23 parts of boric acid alkylolamides, 37.5 parts of butylated hydroxy anisole, 9 parts of zinc stearate, peroxidating
22 parts of t-butyl perbenzoate soaks 5-10 minutes in putting into the hydrochloric acid solution of 1-2%, standby；
2) by step 1) to put into the temperature adjustment of middle reactor after gained raw material filtering be 135-140 DEG C, mixing speed
It is 1700-1900r/min, the reaction time is 25-30 minutes, standby；
3) by 10.5 parts of diamond dust, 10 parts of bis cyclopentadienyl zirconium dichloride, 7.5 parts of polyvinylpyrrolidone, 18 parts of calcium stearate, penta 4
7.5 parts of alcohol, 13.5 parts of ethoxyquinoline, 22.5 parts of polyacrylonitrile-based carbon fibre, 5.5 parts of BP, polyvinyl alcohol contracting first
In 12 parts of aldehyde and 11.5 parts of banburies of diisononyl phthalate, regulation heating-up temperature is 180-185 DEG C, is heated 2-5 minutes,
It is standby；
4) by step 2) gained raw material put into step 3) banbury in mix, lifting heating-up temperature to 220 DEG C, reaction
It is 1-2 minutes, standby；
5) by step 4) during gained raw material puts into injection machine, heating is in molten condition, then raw material is molded into mould,
Shaping.
Embodiment 3
A kind of arrangements for automotive doors interior trim plastic plate, the material matched by following parts by weight is made, including aromatic polycarbonate
30 parts of ester, 20 parts of heliotropin, 4 parts of sodium carbonate, 15 parts of stannous chloride, 14 parts of ferric trichloride, 20 parts of MAO, boric acid alkane
24 parts of base alkylolamides, 40 parts of butylated hydroxy anisole, 11 parts of zinc stearate, 28 parts of peroxidized t-butyl perbenzoate, diamond dust 11
It is part, 12 parts of bis cyclopentadienyl zirconium dichloride, 10 parts of polyvinylpyrrolidone, 20 parts of calcium stearate, 9 parts of penta tetrol, 14 parts of ethoxyquinoline, poly-
13 parts of 25 parts of acrylonitrile base carbon fiber, 8 parts of BP, 13 parts of polyvinyl formal and diisononyl phthalate.
A kind of preparation method of arrangements for automotive doors interior trim plastic plate, comprises the following steps：
1) by 30 parts of aromatic copolycarbonate, 20 parts of heliotropin, 4 parts of sodium carbonate, 15 parts of stannous chloride, ferric trichloride 14
Part, 20 parts of MAO, 24 parts of boric acid alkylolamides, 40 parts of butylated hydroxy anisole, 11 parts of zinc stearate, benzoyl peroxide
28 parts of t-butyl formate soaks 5-10 minutes in putting into the hydrochloric acid solution of 1-2%, standby；
2) by step 1) to put into the temperature adjustment of middle reactor after gained raw material filtering be 135-140 DEG C, mixing speed
It is 1700-1900r/min, the reaction time is 25-30 minutes, standby；
3) by 11 parts of diamond dust, 12 parts of bis cyclopentadienyl zirconium dichloride, 10 parts of polyvinylpyrrolidone, 20 parts of calcium stearate, penta tetrol 9
Part, 14 parts of ethoxyquinoline, 25 parts of polyacrylonitrile-based carbon fibre, 8 parts of BP, 13 parts of polyvinyl formal and adjacent benzene
In 13 parts of banburies of dioctyl phthalate dinonyl, regulation heating-up temperature is 180-185 DEG C, is heated 2-5 minutes, standby；
4) by step 2) gained raw material put into step 3) banbury in mix, lifting heating-up temperature to 220 DEG C, reaction
It is 1-2 minutes, standby；
5) by step 4) during gained raw material puts into injection machine, heating is in molten condition, then raw material is molded into mould,
Shaping.
Experimental example
Experimental subjects：Choose general-utility car vehicle door interior trim plastic plate, cars vehicle door interior trim plastic plate with it is of the invention
Arrangements for automotive doors interior trim plastic plate is contrasted.
Requirement of experiment：Above-mentioned general-utility car vehicle door interior trim plastic plate, cars vehicle door interior trim plastic plate and the present invention
Arrangements for automotive doors interior trim plastic plate weight it is consistent.
Experimental technique：Anti-wear performance is detected using ASTM D3884 abrasion test methods；The anti-aging time is by old
Change chamber to be detected, and adjust test temperature temperature for 120 DEG C, relative humidity is 85%, and air pressure is 106kPa, ozone
Concentration is 45%, and ultraviolet illumination intensity is 25uw/cm2, obtains the aging time；Compression strength passes through GB/T 529-1999
Standard is tested using intensity test machine；
Concrete outcome is as shown in the table：
With reference to upper table, the data of different arrangements for automotive doors interior trim plastic plates gained under identical experimental technique are contrasted, this
More preferably, more preferably, structural strength is higher for antiageing effect for the wearability of the arrangements for automotive doors interior trim plastic plate of invention.
The technology of the present invention effect major embodiment is in the following areas：The aromatic copolycarbonate of addition, boric acid alkylolamides,
Butylated hydroxy anisole and zinc stearate cause that material structural strength is high, 7.5 parts of penta tetrol, ethoxyquinoline, poly- third of addition
Alkene itrile group carbon fiber, BP, polyvinyl formal have an antiageing effect, the diamond dust of addition, bis cyclopentadienyl zirconium dichloride,
Polyvinylpyrrolidone causes that material wear-resistant performance is good；The preparation method of use causes material good forming effect, structural stability
It is high.
Certainly, it is more than representative instance of the invention, in addition, the present invention can also have other various specific implementations
The technical scheme that mode, all use equivalents or equivalent transformation are formed, all falls within the scope of protection of present invention.
Claims (5)
1. a kind of arrangements for automotive doors interior trim plastic plate, it is characterised in that：The material matched by following parts by weight is made, including fragrance
28-30 parts of adoption carbonic ester, heliotropin 16-20 parts, sodium carbonate 2-4 parts, stannous chloride 11-15 parts, ferric trichloride 12-14
Part, MAO 16-20 parts, 22-24 parts of boric acid alkylolamides, butylated hydroxy anisole 35-40 parts, zinc stearate 7-11
Part, peroxidized t-butyl perbenzoate 16-28 parts, diamond dust 9-11 parts, bis cyclopentadienyl zirconium dichloride 8-12 parts, polyvinylpyrrolidone 5-10
Part, calcium stearate 16-20 parts, penta tetrol 6-9 parts, ethoxyquinoline 13-14 parts, polyacrylonitrile-based carbon fibre 20-25 parts, oxidation
Benzoyl 3-8 parts, polyvinyl formal 11-13 parts and diisononyl phthalate 10-13 parts.
2. a kind of arrangements for automotive doors interior trim plastic plate as claimed in claim 1, it is characterised in that：Matched by following parts by weight
Material is made, including 28 parts of aromatic copolycarbonate, 16 parts of heliotropin, 2 parts of sodium carbonate, 11 parts of stannous chloride, ferric trichloride
12 parts, 16 parts of MAO, 22 parts of boric acid alkylolamides, 35 parts of butylated hydroxy anisole, 7 parts of zinc stearate, peroxidating
16 parts of t-butyl perbenzoate, 9 parts of diamond dust, 8 parts of bis cyclopentadienyl zirconium dichloride, 5 parts of polyvinylpyrrolidone, 16 parts of calcium stearate, penta 4
6 parts of alcohol, 13 parts of ethoxyquinoline, 20 parts of polyacrylonitrile-based carbon fibre, 3 parts of BP, 11 parts of polyvinyl formal and
10 parts of diisononyl phthalate.
3. a kind of arrangements for automotive doors interior trim plastic plate as claimed in claim 1, it is characterised in that：Matched by following parts by weight
Material is made, including 29 parts of aromatic copolycarbonate, 18 parts of heliotropin, 3 parts of sodium carbonate, 13 parts of stannous chloride, ferric trichloride
13 parts, 18 parts of MAO, 23 parts of boric acid alkylolamides, 37.5 parts of butylated hydroxy anisole, 9 parts of zinc stearate, peroxide
Change 22 parts of t-butyl perbenzoate, 10.5 parts of diamond dust, 10 parts of bis cyclopentadienyl zirconium dichloride, 7.5 parts of polyvinylpyrrolidone, calcium stearate 18
Part, 7.5 parts of penta tetrol, 13.5 parts of ethoxyquinoline, 22.5 parts of polyacrylonitrile-based carbon fibre, 5.5 parts of BP, polyethylene
11.5 parts of 12 parts of alcohol formal and diisononyl phthalate.
4. a kind of arrangements for automotive doors interior trim plastic plate as claimed in claim 1, it is characterised in that：Matched by following parts by weight
Material is made, including 30 parts of aromatic copolycarbonate, 20 parts of heliotropin, 4 parts of sodium carbonate, 15 parts of stannous chloride, ferric trichloride
14 parts, 20 parts of MAO, 24 parts of boric acid alkylolamides, 40 parts of butylated hydroxy anisole, 11 parts of zinc stearate, peroxidating
28 parts of t-butyl perbenzoate, 11 parts of diamond dust, 12 parts of bis cyclopentadienyl zirconium dichloride, 10 parts of polyvinylpyrrolidone, 20 parts of calcium stearate, penta
9 parts of tetrol, 14 parts of ethoxyquinoline, 25 parts of polyacrylonitrile-based carbon fibre, 8 parts of BP, 13 parts of polyvinyl formal
With 13 parts of diisononyl phthalate.
5. a kind of preparation method of arrangements for automotive doors interior trim plastic plate, it is characterised in that：Comprise the following steps：
1) by aromatic copolycarbonate 28-30 parts, heliotropin 16-20 parts, sodium carbonate 2-4 parts, stannous chloride 11-15 parts, three
Iron chloride 12-14 parts, MAO 16-20 parts, 22-24 parts of boric acid alkylolamides, butylated hydroxy anisole 35-40 parts,
Soaked 5-10 minutes in zinc stearate 7-11 parts, the peroxidized t-butyl perbenzoate 16-28 parts hydrochloric acid solution for putting into 1-2%,
It is standby；
2) by step 1) to put into the temperature adjustment of middle reactor after gained raw material filtering be 135-140 DEG C, mixing speed is
1700-1900r/min, the reaction time is 25-30 minutes, standby；
3) by diamond dust 9-11 parts, bis cyclopentadienyl zirconium dichloride 8-12 parts, polyvinylpyrrolidone 5-10 parts, calcium stearate 16-20 parts, penta
Tetrol 6-9 parts, ethoxyquinoline 13-14 parts, polyacrylonitrile-based carbon fibre 20-25 parts, BP 3-8 parts, polyvinyl alcohol
In formal 11-13 parts and diisononyl phthalate 10-13 part banbury, regulation heating-up temperature is 180-185 DEG C, is heated
It is 2-5 minutes, standby；
4) by step 2) gained raw material put into step 3) banbury in mix, lifting heating-up temperature to 220 DEG C, react 1-2
Minute, it is standby；
5) by step 4) during gained raw material puts into injection machine, heating is in molten condition, then raw material is molded into mould, is molded
.
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107474509A (en) * | 2017-08-18 | 2017-12-15 | 苏州格瑞格登新材料科技有限公司 | A kind of environmental-protection flame-retardant polycarbafil material and preparation method thereof |
| CN107573604A (en) * | 2017-08-30 | 2018-01-12 | 芜湖天鸿汽车零部件有限公司 | A kind of air conditioning for automobiles air port grid material and preparation method thereof |
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| CN107573604A (en) * | 2017-08-30 | 2018-01-12 | 芜湖天鸿汽车零部件有限公司 | A kind of air conditioning for automobiles air port grid material and preparation method thereof |
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