CN106751405A - A kind of high-quality macromolecule sheet material with health-care efficacy - Google Patents
A kind of high-quality macromolecule sheet material with health-care efficacy Download PDFInfo
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- CN106751405A CN106751405A CN201611210276.8A CN201611210276A CN106751405A CN 106751405 A CN106751405 A CN 106751405A CN 201611210276 A CN201611210276 A CN 201611210276A CN 106751405 A CN106751405 A CN 106751405A
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- CN
- China
- Prior art keywords
- parts
- sheet material
- health
- whisker
- care efficacy
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Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L55/00—Compositions of homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C08L23/00 - C08L53/00
- C08L55/02—ABS [Acrylonitrile-Butadiene-Styrene] polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/002—Physical properties
- C08K2201/003—Additives being defined by their diameter
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/002—Physical properties
- C08K2201/004—Additives being defined by their length
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Abstract
The invention discloses a kind of high-quality macromolecule sheet material with health-care efficacy, belong to building material field, be specifically made up of following material：ABS resin, polyphenylene sulfide, Lauxite resin, C 5 petroleum resin, stone flour additive, whisker additive, plasticizer, stabilizer, curing agent, ultra-violet absorber.Final obtained macromolecule sheet material of the invention has good sound insulation, heat-resisting, waterproof, flame-retarding characteristic, and can for a long time discharge the negative oxygen ion beneficial to human body, there is good fungistatic effect to staphylococcus aureus etc., and overall mechanical properties are preferably, use value is higher.
Description
Technical field
The invention belongs to building material field, and in particular to a kind of high-quality macromolecule sheet material with health-care efficacy.
Background technology
Macromolecule sheet material is one kind easily regeneration based plate being mixed by compositions such as resin, filler, auxiliary agents, with timber
The scarcity of resource, the usage amount of polymer floor is continuously increased, and is constantly risen in present building material field proportion.In room
Interior decoration aspect, macromolecule sheet material can be used for the laying on floor, wall and mat formation, hence it is evident that different from traditional timber, building stones etc.
Texture, is that house ornamentation adds more wide in range arranging scheme.For fitment material for family, with the lifting of people's demand, for material
Overall characteristic requirement also more and more higher, to there is temperature tolerance, mechanical property existing macromolecule sheet material not good more, and majority does not have
Standby antibiotic health care and other effects.
The content of the invention
The present invention is intended to provide a kind of high-quality macromolecule sheet material with health-care efficacy.
The present invention is achieved through the following technical solutions：
A kind of high-quality macromolecule sheet material with health-care efficacy, is made up of the material of following weight portion：
140 ~ 150 parts of ABS resins, 27 ~ 31 parts of polyphenylene sulfides, 13 ~ 15 parts of Lauxite resins, 5 ~ 8 parts of C 5 petroleum resins, 19
~ 22 parts of stone flour additives, 5 ~ 8 parts of whisker additives, 2 ~ 3 parts of plasticizer, 2 ~ 4 parts of stabilizers, 4 ~ 6 parts of curing agent, 1 ~ 2 part it is ultraviolet
Light absorbers；The mixed fillers by following weight portion material composition：14 ~ 16 parts of cordierites, 7 ~ 9 parts of olivines, 3 ~ 5 parts of north
Lapidation, 2 ~ 4 part of six ring stone；The blending whisker by following weight portion material composition：20 ~ 24 parts of calcium sulfate crystal whiskers, 5 ~ 7 parts of nitrogen
Change boron whisker, 6 ~ 9 parts of crystal whisker of hexa potassium titanate.
Preferably, it is made up of the material of following weight portion：
145 parts of ABS resins, 28 parts of polyphenylene sulfides, 14 parts of Lauxite resins, 7 parts of C 5 petroleum resins, 20 parts of stone flour additions
Agent, 7 parts of whisker additives, 2.5 parts of plasticizer, 3 parts of stabilizers, 5 parts of curing agent, 1.5 parts of ultra-violet absorbers；The mixing is filled out
Expect by the material composition of following weight portion：15 parts of cordierites, 8 parts of olivines, 4 parts of hokutolites, 3 part of six ring stone；The mix-crystal
Must be by the material composition of following weight portion：23 parts of calcium sulfate crystal whiskers, 6 parts of boron nitride crystal whiskers, 8 parts of crystal whisker of hexa potassium titanate.
Further, the plasticizer is the one kind in dicyclohexyl phthalate, diethyl phthalate.
Further, the stabilizer is the one kind in metal soap stabilizer and rare-earth stabilizer.
Further, the curing agent is the one kind in vinyl triamine, triethylene tetramine, dipropylenetriamine.
Further, the ultra-violet absorber is the one kind in Ultraviolet Absorber UV-P, ultra-violet absorber UV-O.
Further, the preparation method of the stone flour additive is that cordierite, olivine, hokutolite and six ring stones are common
Mixing, then the particle size for being ground into the grade particles such as four different grades of particles, respectively a, b, c, d, wherein a
It it is 70 ~ 100 μm, the particle size of the grade particles such as b is 1 ~ 20 μm, the particle size of the grade particles such as c is 400 ~ 700nm, d grades
The particle size of grain is 20 ~ 100nm, and the percentage of gross weight shared by grade particles such as tetra- kinds of a, b, c, d is respectively：10~15%、35~
40%th, 35 ~ 40%, 10 ~ 15%, finally again by the grade particles such as tetra- kinds of a, b, c, d be sufficiently mixed it is uniform after.
Further, the length of calcium sulfate crystal whiskers is 150 ~ 180 μm, the length of the boron nitride crystal whisker in the blending whisker
It is 80 ~ 110 μm to spend, and the length of the crystal whisker of hexa potassium titanate is 10 ~ 40 μm.
A kind of preparation method of the high-quality macromolecule sheet material with health-care efficacy, specifically by ABS resin, polyphenylene sulfide
It is ether, Lauxite resin, C 5 petroleum resin, stone flour additive, whisker additive, plasticizer, stabilizer, curing agent, ultraviolet
Light absorbers by corresponding weight portion weigh mixing after, then carry out mediate modeling white silk form.
The present invention has the advantages that：
The reasonably combined several resinous principles of the present invention as matrix, with the performance such as good waterproof, mould proof, heatproof, addition
Stone flour additive there is good heat resistance, the overall flame-retarding characteristic of resin can be lifted, while having certain antibacterial again
Health-care efficacy, after carrying out crushing and classification treatment to it, can be effectively improved asking for conventional additive influence resin matrix mechanical property
Topic, it is ensured that the quality of filling, the blending whisker of addition is made up of calcium sulfate crystal whiskers, boron nitride crystal whisker and crystal whisker of hexa potassium titanate,
Its cross-linking effect that can effectively lift each position between resin matrix, crackle bridging that enhancing whisker is played between resin matrix, partially
Turn effect and extract effect, further improve overall mechanical property.Final obtained macromolecule sheet material of the invention has good
Good sound insulation, heat-resisting, waterproof, flame-retarding characteristic, and the negative oxygen ion beneficial to human body can be for a long time discharged, to Staphylococcus aureus
Bacterium etc. has good fungistatic effect, and overall mechanical properties are preferably, and use value is higher.
Specific embodiment
Embodiment 1
A kind of high-quality macromolecule sheet material with health-care efficacy, is made up of the material of following weight portion：
140 parts of ABS resins, 27 parts of polyphenylene sulfides, 13 parts of Lauxite resins, 5 parts of C 5 petroleum resins, 19 parts of stone flour additions
Agent, 5 parts of whisker additives, 2 parts of plasticizer, 2 parts of stabilizers, 4 parts of curing agent, 1 part of ultra-violet absorber；The mixed fillers by
The material composition of following weight portion：14 parts of cordierites, 7 parts of olivines, 3 parts of hokutolites, 2 part of six ring stone；The blending whisker by
The material composition of following weight portion：20 parts of calcium sulfate crystal whiskers, 5 parts of boron nitride crystal whiskers, 6 parts of crystal whisker of hexa potassium titanate.
Further, the plasticizer is dicyclohexyl phthalate.
Further, the stabilizer is metal soap stabilizer.
Further, the curing agent is vinyl triamine.
Further, the ultra-violet absorber is Ultraviolet Absorber UV-P.
Further, the preparation method of the stone flour additive is that cordierite, olivine, hokutolite and six ring stones are common
Mixing, then the particle size for being ground into the grade particles such as four different grades of particles, respectively a, b, c, d, wherein a
It it is 70 ~ 100 μm, the particle size of the grade particles such as b is 1 ~ 20 μm, the particle size of the grade particles such as c is 400 ~ 700nm, d grades
The particle size of grain is 20 ~ 100nm, and the percentage of gross weight shared by grade particles such as tetra- kinds of a, b, c, d is respectively：10%、40%、
40%th, 10%, finally again by the grade particles such as tetra- kinds of a, b, c, d be sufficiently mixed it is uniform after.
Further, the length of calcium sulfate crystal whiskers is 150 ~ 180 μm, the length of the boron nitride crystal whisker in the blending whisker
It is 80 ~ 110 μm to spend, and the length of the crystal whisker of hexa potassium titanate is 10 ~ 40 μm.
A kind of preparation method of the high-quality macromolecule sheet material with health-care efficacy, specifically by ABS resin, polyphenylene sulfide
It is ether, Lauxite resin, C 5 petroleum resin, stone flour additive, whisker additive, plasticizer, stabilizer, curing agent, ultraviolet
Light absorbers by corresponding weight portion weigh mixing after, then carry out mediate modeling white silk form.
Embodiment 2
A kind of high-quality macromolecule sheet material with health-care efficacy, is made up of the material of following weight portion：
145 parts of ABS resins, 28 parts of polyphenylene sulfides, 14 parts of Lauxite resins, 7 parts of C 5 petroleum resins, 20 parts of stone flour additions
Agent, 7 parts of whisker additives, 2.5 parts of plasticizer, 3 parts of stabilizers, 5 parts of curing agent, 1.5 parts of ultra-violet absorbers；The mixing is filled out
Expect by the material composition of following weight portion：15 parts of cordierites, 8 parts of olivines, 4 parts of hokutolites, 3 part of six ring stone；The mix-crystal
Must be by the material composition of following weight portion：23 parts of calcium sulfate crystal whiskers, 6 parts of boron nitride crystal whiskers, 8 parts of crystal whisker of hexa potassium titanate.
Embodiment 3
A kind of high-quality macromolecule sheet material with health-care efficacy, is made up of the material of following weight portion：
150 parts of ABS resins, 31 parts of polyphenylene sulfides, 15 parts of Lauxite resins, 8 parts of C 5 petroleum resins, 22 parts of stone flour additions
Agent, 8 parts of whisker additives, 3 parts of plasticizer, 4 parts of stabilizers, 6 parts of curing agent, 2 parts of ultra-violet absorbers；The mixed fillers by
The material composition of following weight portion：16 parts of cordierites, 9 parts of olivines, 5 parts of hokutolites, 4 part of six ring stone；The blending whisker by
The material composition of following weight portion：24 parts of calcium sulfate crystal whiskers, 7 parts of boron nitride crystal whiskers, 9 parts of crystal whisker of hexa potassium titanate.
Comparative example 1
This comparative example 1 does special length grading treatment operation compared with Example 1, not to whisker additive, i.e., directly
With etc. the commercial sulfuric acid calcium pyroborate of mass parts, boron nitride crystal whisker, crystal whisker of hexa potassium titanate carry out mixing replacement, method step in addition
Rapid all same.
Comparative example 2
This comparative example 2 compared with Example 2, is not carried out at special particle crushing and classification to the composition in stone flour additive
Reason operation, i.e., directly with etc. the conventional commercial cordierite of mass parts, olivine, hokutolite, six ring stones substituted, in addition
Method and step all same.
Control group
Existing commercially available ABS resin based high molecular sheet material.
In order to contrast effect of the present invention, the macromolecule sheet material that above-mentioned six kinds of modes correspondence is made is processed into specification identical
Sample, and performance test is carried out to sample, specific correction data is as shown in table 1 below：
Table 1
| Tensile strength（MPa） | Impact strength（KJ/m2） | Dimension card（℃） | Bacteriostasis rate（%） | |
| Embodiment 1 | 51 | 45.4 | 123 | 95.2 |
| Embodiment 2 | 53 | 46.5 | 125 | 96.3 |
| Embodiment 3 | 52 | 46.1 | 124 | 95.8 |
| Comparative example 1 | 45 | 36.6 | 120 | 92.3 |
| Comparative example 2 | 48 | 40.8 | 118 | 91.2 |
| Control group | 41 | 33.4 | 116 | 70.3 |
Note：Tensile strength described in upper table 1 is tested with reference to GB/T 1040-1992；Described impact strength reference
ISO179-1 is tested；Described dimension card index is using the vicat softening temperature mark of Deutsche industry norm (DIN) DIN 53460
Standard is measured, specially measure certain pressure head under some force vertically be pierced into sample 1mm depth when temperature
Degree, according to test philosophy, vicat temperature is higher, then the heat resistance of material is better, conversely, then heat resistance is poorer；Described is antibacterial
Rate is to measure the bacteriostasis rate to staphylococcus aureus.
By can be seen that the obtained macromolecule sheet material overall characteristic of the present invention in upper table 1 preferably, and measure sheet material anion
Burst size is up to 3000/cm3More than, use value is higher.
Claims (9)
1. a kind of high-quality macromolecule sheet material with health-care efficacy, it is characterised in that be made up of the material of following weight portion：
140 ~ 150 parts of ABS resins, 27 ~ 31 parts of polyphenylene sulfides, 13 ~ 15 parts of Lauxite resins, 5 ~ 8 parts of C 5 petroleum resins, 19
~ 22 parts of stone flour additives, 5 ~ 8 parts of whisker additives, 2 ~ 3 parts of plasticizer, 2 ~ 4 parts of stabilizers, 4 ~ 6 parts of curing agent, 1 ~ 2 part it is ultraviolet
Light absorbers；The mixed fillers by following weight portion material composition：14 ~ 16 parts of cordierites, 7 ~ 9 parts of olivines, 3 ~ 5 parts of north
Lapidation, 2 ~ 4 part of six ring stone；The blending whisker by following weight portion material composition：20 ~ 24 parts of calcium sulfate crystal whiskers, 5 ~ 7 parts of nitrogen
Change boron whisker, 6 ~ 9 parts of crystal whisker of hexa potassium titanate.
2. a kind of high-quality macromolecule sheet material with health-care efficacy according to claim 1, it is characterised in that by as follows
The material of weight portion is made：
145 parts of ABS resins, 28 parts of polyphenylene sulfides, 14 parts of Lauxite resins, 7 parts of C 5 petroleum resins, 20 parts of stone flour additions
Agent, 7 parts of whisker additives, 2.5 parts of plasticizer, 3 parts of stabilizers, 5 parts of curing agent, 1.5 parts of ultra-violet absorbers；The mixing is filled out
Expect by the material composition of following weight portion：15 parts of cordierites, 8 parts of olivines, 4 parts of hokutolites, 3 part of six ring stone；The mix-crystal
Must be by the material composition of following weight portion：23 parts of calcium sulfate crystal whiskers, 6 parts of boron nitride crystal whiskers, 8 parts of crystal whisker of hexa potassium titanate.
3. a kind of high-quality macromolecule sheet material with health-care efficacy according to claim 1 and 2, it is characterised in that institute
It is the one kind in dicyclohexyl phthalate, diethyl phthalate to state plasticizer.
4. a kind of high-quality macromolecule sheet material with health-care efficacy according to claim 1 and 2, it is characterised in that institute
It is the one kind in metal soap stabilizer and rare-earth stabilizer to state stabilizer.
5. a kind of high-quality macromolecule sheet material with health-care efficacy according to claim 1 and 2, it is characterised in that institute
It is the one kind in vinyl triamine, triethylene tetramine, dipropylenetriamine to state curing agent.
6. a kind of high-quality macromolecule sheet material with health-care efficacy according to claim 1 and 2, it is characterised in that institute
It is the one kind in Ultraviolet Absorber UV-P, ultra-violet absorber UV-O to state ultra-violet absorber.
7. a kind of high-quality macromolecule sheet material with health-care efficacy according to claim 1 and 2, it is characterised in that institute
The preparation method for stating stone flour additive is to mix cordierite, olivine, hokutolite and six ring stones jointly, then is ground
Into four different grades of particles, respectively a, b, c, d, the particle size of the grade particles such as wherein a is 70 ~ 100 μm, b grades
The particle size of grain is 1 ~ 20 μm, and the particle size of the grade particles such as c is 400 ~ 700nm, the particle size of the grade particles such as d for 20 ~
100nm, and the percentage of gross weight shared by grade particles such as tetra- kinds of a, b, c, d is respectively：10~15%、35~40%、35~40%、10~
15%, finally again by the grade particles such as tetra- kinds of a, b, c, d be sufficiently mixed it is uniform after.
8. a kind of high-quality macromolecule sheet material with health-care efficacy according to claim 1 and 2, it is characterised in that institute
It is 150 ~ 180 μm to state the length of calcium sulfate crystal whiskers in blending whisker, and the length of the boron nitride crystal whisker is 80 ~ 110 μm, described six
The length of potassium titanate crystal whisker is 10 ~ 40 μm.
9. a kind of preparation method of the high-quality macromolecule sheet material with health-care efficacy as claimed in claim 1 or 2, its feature
It is, specifically by ABS resin, polyphenylene sulfide, Lauxite resin, C 5 petroleum resin, stone flour additive, whisker addition
Agent, plasticizer, stabilizer, curing agent, ultra-violet absorber by corresponding weight portion weigh mixing after, then carry out mediate modeling practice and
Into.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611210276.8A CN106751405A (en) | 2016-12-24 | 2016-12-24 | A kind of high-quality macromolecule sheet material with health-care efficacy |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611210276.8A CN106751405A (en) | 2016-12-24 | 2016-12-24 | A kind of high-quality macromolecule sheet material with health-care efficacy |
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| CN106751405A true CN106751405A (en) | 2017-05-31 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201611210276.8A Pending CN106751405A (en) | 2016-12-24 | 2016-12-24 | A kind of high-quality macromolecule sheet material with health-care efficacy |
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Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102304268A (en) * | 2011-04-27 | 2012-01-04 | 刘立文 | Modified acrylonitrile-butadiene-styrene copolymer and preparation process thereof |
-
2016
- 2016-12-24 CN CN201611210276.8A patent/CN106751405A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102304268A (en) * | 2011-04-27 | 2012-01-04 | 刘立文 | Modified acrylonitrile-butadiene-styrene copolymer and preparation process thereof |
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Application publication date: 20170531 |