CN106751181A - A kind of smooth PVC foam frid in surface - Google Patents
A kind of smooth PVC foam frid in surface Download PDFInfo
- Publication number
- CN106751181A CN106751181A CN201611132632.9A CN201611132632A CN106751181A CN 106751181 A CN106751181 A CN 106751181A CN 201611132632 A CN201611132632 A CN 201611132632A CN 106751181 A CN106751181 A CN 106751181A
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- pvc foam
- acid
- smooth pvc
- sulphur
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08L27/06—Homopolymers or copolymers of vinyl chloride
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/14—Applications used for foams
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
Abstract
The invention discloses a kind of smooth PVC foam frid in surface, its raw material includes by weight：65 85 parts of polyvinyl chloride resin, 37 parts of polystyrene, 4 10 parts of methyl silicone rubber, 10 16 parts of phenolic resin, 0.6 1.2 parts of sulphur, 1.5 3.5 parts of zinc oxide, 0.4 1 parts of vulcanization accelerator NS, 48 parts of foaming agent, 20 30 parts of Graphene, 48 parts of anthracite, 8 16 parts of Attagel, 4 10 parts of barium titanate, 8 16 parts of apatite, 1.5 2.5 parts of epoxy aliphatic acid methyl ester, 1.5 2.5 parts of terephthalic acid (TPA) dibutyl ester, 12 parts of pine tar, double 12 parts of the dodecane esters of thio-2 acid, 48 parts of dimethyl silicone polymer, 26 parts of age resistor.The smooth PVC foam frid in surface proposed by the present invention, surface smoothness is high, and hardness is high.
Description
Technical field
The present invention relates to PVC technical fields, more particularly to a kind of smooth PVC foam frid in surface.
Background technology
The smooth PVC foam frid in surface is a kind of novel plastic material of external 20 century 70 exploitation, because its is only
Special production Technology, makes it have excellent performance, is widely used in building, car and boat, furniture, decorations, advertisement
Make, put on display the industries such as label, appearance of the city environmental protection, tourism, the smooth PVC foam frid in surface for using at present has surface smoothness
Difference, hardness are low, it would be highly desirable to solve.
The content of the invention
Based on the technical problem that background technology is present, the present invention proposes a kind of smooth PVC foam frid in surface, surface light
Cleanliness is high, and hardness is high.
A kind of smooth PVC foam frid in surface proposed by the present invention, its raw material includes by weight：Polyvinyl chloride resin 65-85
Part, polystyrene 3-7 parts, methyl silicone rubber 4-10 parts, phenolic resin 10-16 parts, sulphur 0.6-1.2 parts, zinc oxide 1.5-3.5
Part, vulcanization accelerator NS 0.4-1 parts, foaming agent 4-8 parts, Graphene 20-30 parts, anthracite 4-8 parts, Attagel 8-16 parts, titanium
Sour barium 4-10 parts, apatite 8-16 parts, epoxy aliphatic acid methyl ester 1.5-2.5 parts, 1.5-2.5 parts of terephthalic acid (TPA) dibutyl ester, pine
Tar 1-2 parts, double 1-2 parts, dimethyl silicone polymer 4-8 parts, age resistor 2-6 parts of the dodecane esters of thio-2 acid.
Preferably, polyvinyl chloride resin, polystyrene, methyl silicone rubber, the weight ratio of phenolic resin are 70-80：4-6：6-8：
12-14。
Preferably, sulphur, zinc oxide, the weight ratio of vulcanization accelerator NS are 0.8-1：2-3：0.6-0.8.
Preferably, Graphene, anthracite, Attagel, barium titanate, the weight ratio of apatite are 22-28：5-7：10-14：6-
8：10-14.
Preferably, double dodecane esters of epoxy aliphatic acid methyl ester, terephthalic acid (TPA) dibutyl ester, pine tar, thio-2 acid, poly-
The weight ratio of dimethyl siloxane is 1.8-2.2：1.7-2.3：1.2-1.8：1.4-1.8：5-7.
Preferably, its raw material includes by weight：Polyvinyl chloride resin 70-80 parts, polystyrene 4-6 parts, methyl silicone rubber 6-8
Part, phenolic resin 12-14 parts, sulphur 0.8-1 parts, zinc oxide 2-3 parts, vulcanization accelerator NS 0.6-0.8 parts, foaming agent 5-7
Part, Graphene 22-28 parts, anthracite 5-7 parts, Attagel 10-14 parts, barium titanate 6-8 parts, apatite 10-14 parts, epoxidised fatty
Sour methyl esters 1.8-2.2 parts, 1.7-2.3 parts of terephthalic acid (TPA) dibutyl ester, pine tar 1.2-1.8 parts, the double dodecanes of thio-2 acid
Ester 1.4-1.8 parts, dimethyl silicone polymer 5-7 parts, age resistor 3-5 parts.
The present invention is obtained using conventional fabrication process.
The present invention is cooperateed with as base material using polyvinyl chloride resin, methyl silicone rubber, phenolic resin, polystyrene, with sulphur, sulphur
Change accelerator NS, zinc oxide mating reaction, not only extreme hardness after solidification, and also heat endurance is fabulous；And Graphene, phosphorus are grey
Stone, anthracite, barium titanate, Attagel mating reaction, not only mutual good dispersion, and major ingredient synergy, by after solidification,
Surface is smooth, and without salient point groove etc., and dimethyl silicone polymer is burnt with epoxy aliphatic acid methyl ester, terephthalic acid (TPA) dibutyl ester, pine
The double dodecane esters effects of oil, thio-2 acid, on the premise of component Interaction Force is strengthened, hardening and high lubricating effect,
Make of the invention wear-resisting further enhanced with surface flatness.
Specific embodiment
Below, technical scheme is described in detail by specific embodiment.
Embodiment 1
A kind of smooth PVC foam frid in surface proposed by the present invention, its raw material includes by weight：65 parts of polyvinyl chloride resin, gathers
7 parts of styrene, 4 parts of methyl silicone rubber, 16 parts of phenolic resin, 0.6 part of sulphur, 3.5 parts of zinc oxide, vulcanization accelerator NS 0.4
Part, 8 parts of foaming agent, 20 parts of Graphene, 8 parts of anthracite, 8 parts of Attagel, 10 parts of barium titanate, 8 parts of apatite, epoxyfatty acid first
2.5 parts of ester, 1.5 parts of terephthalic acid (TPA) dibutyl ester, 2 parts of pine tar, double 1 part of the dodecane esters of thio-2 acid, polydimethylsiloxanes
8 parts of alkane, 2 parts of age resistor.
Embodiment 2
A kind of smooth PVC foam frid in surface proposed by the present invention, its raw material includes by weight：85 parts of polyvinyl chloride resin, gathers
3 parts of styrene, 10 parts of methyl silicone rubber, 10 parts of phenolic resin, 1.2 parts of sulphur, 1.5 parts of zinc oxide, 1 part of vulcanization accelerator NS,
4 parts of foaming agent, 30 parts of Graphene, 4 parts of anthracite, 16 parts of Attagel, 4 parts of barium titanate, 16 parts of apatite, epoxy aliphatic acid methyl ester
1.5 parts, 2.5 parts of terephthalic acid (TPA) dibutyl ester, 1 part of pine tar, double 2 parts of the dodecane esters of thio-2 acid, dimethyl silicone polymer 4
Part, 6 parts of age resistor.
Embodiment 3
A kind of smooth PVC foam frid in surface proposed by the present invention, its raw material includes by weight：70 parts of polyvinyl chloride resin, gathers
6 parts of styrene, 6 parts of methyl silicone rubber, 14 parts of phenolic resin, 0.8 part of sulphur, 3 parts of zinc oxide, 0.6 part of vulcanization accelerator NS,
7 parts of foaming agent, 22 parts of Graphene, 7 parts of anthracite, 10 parts of Attagel, 8 parts of barium titanate, 10 parts of apatite, epoxy aliphatic acid methyl ester
2.2 parts, 1.7 parts of terephthalic acid (TPA) dibutyl ester, 1.8 parts of pine tar, double 1.4 parts of the dodecane esters of thio-2 acid, poly dimethyl silicon
7 parts of oxygen alkane, 3 parts of age resistor.
Embodiment 4
A kind of smooth PVC foam frid in surface proposed by the present invention, its raw material includes by weight：80 parts of polyvinyl chloride resin, gathers
4 parts of styrene, 8 parts of methyl silicone rubber, 12 parts of phenolic resin, 1 part of sulphur, 2 parts of zinc oxide, 0.8 part of vulcanization accelerator NS, hair
5 parts of infusion, 28 parts of Graphene, 5 parts of anthracite, 14 parts of Attagel, 6 parts of barium titanate, 14 parts of apatite, epoxy aliphatic acid methyl ester
1.8 parts, 2.3 parts of terephthalic acid (TPA) dibutyl ester, 1.2 parts of pine tar, double 1.8 parts of the dodecane esters of thio-2 acid, poly dimethyl silicon
5 parts of oxygen alkane, 5 parts of age resistor.
Embodiment 5
A kind of smooth PVC foam frid in surface proposed by the present invention, its raw material includes by weight：75 parts of polyvinyl chloride resin, gathers
5 parts of styrene, 7 parts of methyl silicone rubber, 13 parts of phenolic resin, 0.9 part of sulphur, 2.5 parts of zinc oxide, vulcanization accelerator NS 0.7
Part, 6 parts of foaming agent, 25 parts of Graphene, 6 parts of anthracite, 12 parts of Attagel, 7 parts of barium titanate, 12 parts of apatite, epoxyfatty acid
2 parts of methyl esters, 2 parts of terephthalic acid (TPA) dibutyl ester, 1.5 parts of pine tar, double 1.6 parts of the dodecane esters of thio-2 acid, poly dimethyl silicon
6 parts of oxygen alkane, 4 parts of age resistor.
The above, the only present invention preferably specific embodiment, but protection scope of the present invention is not limited thereto,
Any one skilled in the art the invention discloses technical scope in, technology according to the present invention scheme and its
Inventive concept is subject to equivalent or change, should all be included within the scope of the present invention.
Claims (6)
1. the smooth PVC foam frid in a kind of surface, it is characterised in that its raw material includes by weight：Polyvinyl chloride resin 65-85 parts, gather
Styrene 3-7 parts, methyl silicone rubber 4-10 parts, phenolic resin 10-16 parts, sulphur 0.6-1.2 parts, zinc oxide 1.5-3.5 parts, sulphur
Change 0.4-1 parts of accelerator NS, foaming agent 4-8 parts, Graphene 20-30 parts, anthracite 4-8 parts, Attagel 8-16 parts, barium titanate
4-10 parts, apatite 8-16 parts, epoxy aliphatic acid methyl ester 1.5-2.5 parts, 1.5-2.5 parts of terephthalic acid (TPA) dibutyl ester, pine tar
1-2 parts, double 1-2 parts, dimethyl silicone polymer 4-8 parts, age resistor 2-6 parts of the dodecane esters of thio-2 acid.
2. the smooth PVC foam frid in surface according to claim 1, it is characterised in that polyvinyl chloride resin, polystyrene, methyl silicon
Rubber, the weight ratio of phenolic resin are 70-80：4-6：6-8：12-14.
3. the smooth PVC foam frid in surface according to claim 1, it is characterised in that sulphur, zinc oxide, vulcanization accelerator
The weight ratio of NS is 0.8-1：2-3：0.6-0.8.
4. the smooth PVC foam frid in surface according to claim 1, it is characterised in that Graphene, anthracite, Attagel, titanium
Sour barium, the weight ratio of apatite are 22-28：5-7：10-14：6-8：10-14.
5. the smooth PVC foam frid in surface according to claim 1, it is characterised in that epoxy aliphatic acid methyl ester, terephthaldehyde
The double dodecane esters of sour dibutyl ester, pine tar, thio-2 acid, the weight ratio of dimethyl silicone polymer are 1.8-2.2：1.7-2.3：
1.2-1.8：1.4-1.8：5-7.
6. the smooth PVC foam frid in surface according to claim 1, it is characterised in that its raw material includes by weight：PVC
Resin 70-80 parts, polystyrene 4-6 parts, methyl silicone rubber 6-8 parts, phenolic resin 12-14 parts, sulphur 0.8-1 parts, zinc oxide
2-3 parts, vulcanization accelerator NS 0.6-0.8 parts, foaming agent 5-7 parts, Graphene 22-28 parts, anthracite 5-7 parts, Attagel 10-
14 parts, barium titanate 6-8 parts, apatite 10-14 parts, epoxy aliphatic acid methyl ester 1.8-2.2 parts, terephthalic acid (TPA) dibutyl ester 1.7-
2.3 parts, pine tar 1.2-1.8 parts, thio-2 acid double 1.4-1.8 parts of dodecane esters, prevent old by dimethyl silicone polymer 5-7 parts
Agent 3-5 parts.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611132632.9A CN106751181A (en) | 2016-12-09 | 2016-12-09 | A kind of smooth PVC foam frid in surface |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611132632.9A CN106751181A (en) | 2016-12-09 | 2016-12-09 | A kind of smooth PVC foam frid in surface |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106751181A true CN106751181A (en) | 2017-05-31 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201611132632.9A Withdrawn CN106751181A (en) | 2016-12-09 | 2016-12-09 | A kind of smooth PVC foam frid in surface |
Country Status (1)
| Country | Link |
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| CN (1) | CN106751181A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109228523A (en) * | 2018-08-31 | 2019-01-18 | 徐州冠新塑编有限公司 | Transparent packing bag and preparation method thereof with high planarization |
| CN111171479A (en) * | 2020-03-25 | 2020-05-19 | 湖南翰坤实业有限公司 | Modified PVC composite building enclosure material |
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|---|---|---|---|---|
| CN85106222A (en) * | 1985-08-17 | 1987-02-18 | 成都科技大学 | High hard and the soft PVC product of filling |
| CN102363663A (en) * | 2011-09-29 | 2012-02-29 | 芜湖海杉型材有限公司 | Multi-component plastic section bar and its preparation method |
| CN104479245A (en) * | 2014-11-28 | 2015-04-01 | 安徽雄峰实业有限公司 | Formula and preparation method of environment-friendly sectional materials |
| CN105038026A (en) * | 2015-07-31 | 2015-11-11 | 联塑市政管道（河北）有限公司 | Flame-retardant smoke-suppressing PVC wire way and preparation method thereof |
-
2016
- 2016-12-09 CN CN201611132632.9A patent/CN106751181A/en not_active Withdrawn
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN85106222A (en) * | 1985-08-17 | 1987-02-18 | 成都科技大学 | High hard and the soft PVC product of filling |
| CN102363663A (en) * | 2011-09-29 | 2012-02-29 | 芜湖海杉型材有限公司 | Multi-component plastic section bar and its preparation method |
| CN104479245A (en) * | 2014-11-28 | 2015-04-01 | 安徽雄峰实业有限公司 | Formula and preparation method of environment-friendly sectional materials |
| CN105038026A (en) * | 2015-07-31 | 2015-11-11 | 联塑市政管道（河北）有限公司 | Flame-retardant smoke-suppressing PVC wire way and preparation method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 曲通馨: "《绝热材料与绝热工程实用手册》", 31 August 1998, 中国建材工业出版社 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109228523A (en) * | 2018-08-31 | 2019-01-18 | 徐州冠新塑编有限公司 | Transparent packing bag and preparation method thereof with high planarization |
| CN111171479A (en) * | 2020-03-25 | 2020-05-19 | 湖南翰坤实业有限公司 | Modified PVC composite building enclosure material |
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Application publication date: 20170531 |
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