CN106009439A - High-wear-resistance teflon engineering plastic - Google Patents

High-wear-resistance teflon engineering plastic Download PDF

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Publication number
CN106009439A
CN106009439A CN201610606013.2A CN201610606013A CN106009439A CN 106009439 A CN106009439 A CN 106009439A CN 201610606013 A CN201610606013 A CN 201610606013A CN 106009439 A CN106009439 A CN 106009439A
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Prior art keywords
parts
teflon
engineering plastics
graphite
ethylene
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Pending
Application number
CN201610606013.2A
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Chinese (zh)
Inventor
陆华平
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Suzhou New District Teflon Plastic Products Factory
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Suzhou New District Teflon Plastic Products Factory
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Priority to CN201610606013.2A priority Critical patent/CN106009439A/en
Publication of CN106009439A publication Critical patent/CN106009439A/en
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L27/00Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
    • C08L27/02Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L27/12Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
    • C08L27/18Homopolymers or copolymers or tetrafluoroethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04Homopolymers or copolymers of ethene
    • C08L23/08Copolymers of ethene
    • C08L23/0846Copolymers of ethene with unsaturated hydrocarbons containing other atoms than carbon or hydrogen atoms
    • C08L23/0853Vinylacetate
    • C08L23/0861Saponified vinylacetate
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L83/00Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
    • C08L83/04Polysiloxanes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/014Additives containing two or more different additives of the same subgroup in C08K
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2207/00Properties characterising the ingredient of the composition
    • C08L2207/06Properties of polyethylene
    • C08L2207/066LDPE (radical process)

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Processes Of Treating Macromolecular Substances (AREA)

Abstract

The invention discloses a high-wear-resistance teflon engineering plastic. The high-wear-resistance teflon engineering plastic comprises the following components in parts by weight: 2-5 parts of thermoplastic resin master batch, 3-6 parts of nano titanium dioxide, 1-4 parts of superpressure polyethylene, 2-5 parts of polyvinylidene fluoride, 0.3-0.9 part of polytetrafluoroethylene, 5-10 parts of teflon, 6-7 parts of dibutyl phthalate, 1-5 parts of hexyl diisocyanate, 6-10 parts of ethylene-vinyl alcohol copolymer, 2-5 parts of dibasic lead phosphite, 1-4 parts of graphite, 1-4 parts of carbon black and 5-10 parts of silicon rubber. The high-wear-resistance teflon engineering plastic has the advantages of low density, high impact strength, good quality and long service life, is convenient for processing, has favorable functions, and has an important position in the market.

Description

A kind of high abrasion Teflon engineering plastics
Technical field
The present invention relates to a kind of Teflon functional plastics, particularly relate to high abrasion Teflon engineering plastics.
Background technology
Along with progress and the development of the productivity of society, functional plastics of the prior art the most gradually cannot meet the social need day by day increased, it is therefore desirable to researches and develops a kind of functional good plastics and meets use demand instantly.
Summary of the invention
Technical problem is how of present invention mainly solves provides that a kind of density is little, impact strength is big, easy to process, quality good, service life is long, is a kind of functional good functional plastics, occupies the plastic formula of important position in the market.
nullFor solving above-mentioned technical problem,The technical scheme that the present invention uses is: provide a kind of high abrasion Teflon engineering plastics,Including: thermoplastic resin masterbatch、Nano titanium oxide、Super high pressure polyethylene、Polyvinylidene fluoride、Politef、Teflon、Dibutyl phthalate、Hexamethylene diisocyanate、Ethylene-vinyl alcohol copolymer、Dibasic lead phosphite、Graphite、White carbon black and silicone rubber,Described high abrasion Teflon engineering plastics calculate according to mass percent,Including following weight portion: thermoplastic resin masterbatch 2-5 part、Nano titanium oxide 3-6 part、Super high pressure polyethylene 1-4 part、Polyvinylidene fluoride 2-5 part、Politef 0.3-0.9 part、Teflon 5-10 part、Dibutyl phthalate 6-7 part、Hexamethylene diisocyanate 1-5 part、Ethylene-vinyl alcohol copolymer 6-10 part、Dibasic lead phosphite 2-5 part、Graphite 1-4 part、White carbon black 1-4 part and silicone rubber 5-10 part.
In a preferred embodiment, described high abrasion Teflon engineering plastics calculate according to mass percent, including following weight portion: thermoplastic resin masterbatch 3 parts, nano titanium oxide 4 parts, super high pressure polyethylene 2 parts, polyvinylidene fluoride 3 parts, politef 0.5 part, Teflon 7 parts, dibutyl phthalate 6 parts, hexamethylene diisocyanate 3 parts, ethylene-vinyl alcohol copolymer 7 parts, dibasic lead phosphite 4 parts, 2 parts of graphite, white carbon black 2 parts and 7 parts of silicone rubber.
In a preferred embodiment, described high abrasion Teflon engineering plastics calculate according to mass percent, including following weight portion: thermoplastic resin masterbatch 4 parts, nano titanium oxide 5 parts, super high pressure polyethylene 3 parts, polyvinylidene fluoride 4 parts, politef 0.8 part, Teflon 8 parts, dibutyl phthalate 6.5 parts, hexamethylene diisocyanate 4 parts, ethylene-vinyl alcohol copolymer 8 parts, dibasic lead phosphite 4 parts, 3 parts of graphite, white carbon black 3 parts and 8 parts of silicone rubber.
The invention has the beneficial effects as follows: density is little, impact strength is big, easy to process, quality good, service life is long, be a kind of functional good functional plastics, occupy important position in the market.
Detailed description of the invention
Technical scheme in the embodiment of the present invention will be clearly and completely described below, it is clear that described embodiment is only a part of embodiment of the present invention rather than whole embodiments.Based on the embodiment in the present invention, all other embodiments that those of ordinary skill in the art are obtained under not making creative work premise, broadly fall into the scope of protection of the invention.
nullA kind of high abrasion Teflon engineering plastics are provided in one particular embodiment of the present invention,Described high abrasion Teflon engineering plastics include: thermoplastic resin masterbatch、Nano titanium oxide、Super high pressure polyethylene、Polyvinylidene fluoride、Politef、Teflon、Dibutyl phthalate、Hexamethylene diisocyanate、Ethylene-vinyl alcohol copolymer、Dibasic lead phosphite、Graphite、White carbon black and silicone rubber,Described high abrasion Teflon engineering plastics calculate according to mass percent,Including following weight portion: thermoplastic resin masterbatch 2-5 part、Nano titanium oxide 3-6 part、Super high pressure polyethylene 1-4 part、Polyvinylidene fluoride 2-5 part、Politef 0.3-0.9 part、Teflon 5-10 part、Dibutyl phthalate 6-7 part、Hexamethylene diisocyanate 1-5 part、Ethylene-vinyl alcohol copolymer 6-10 part、Dibasic lead phosphite 2-5 part、Graphite 1-4 part、White carbon black 1-4 part and silicone rubber 5-10 part.
Embodiment 1: described high abrasion Teflon engineering plastics calculate according to mass percent, including following weight portion: thermoplastic resin masterbatch 3 parts, nano titanium oxide 4 parts, super high pressure polyethylene 2 parts, polyvinylidene fluoride 3 parts, politef 0.5 part, Teflon 7 parts, dibutyl phthalate 6 parts, hexamethylene diisocyanate 3 parts, ethylene-vinyl alcohol copolymer 7 parts, dibasic lead phosphite 4 parts, 2 parts of graphite, white carbon black 2 parts and 7 parts of silicone rubber.
Embodiment 2: described high abrasion Teflon engineering plastics calculate according to mass percent, including following weight portion: thermoplastic resin masterbatch 4 parts, nano titanium oxide 5 parts, super high pressure polyethylene 3 parts, polyvinylidene fluoride 4 parts, politef 0.8 part, Teflon 8 parts, dibutyl phthalate 6.5 parts, hexamethylene diisocyanate 4 parts, ethylene-vinyl alcohol copolymer 8 parts, dibasic lead phosphite 4 parts, 3 parts of graphite, white carbon black 3 parts and 8 parts of silicone rubber.
Therefore, the invention have the advantages that density is little, impact strength is big, easy to process, quality good, service life is long, be a kind of functional good functional plastics, occupy important position in the market.
The foregoing is only embodiments of the invention; not thereby the scope of the claims of the present invention is limited; every equivalent structure utilizing description of the invention content to be made or equivalence flow process conversion; or directly or indirectly it is used in other relevant technical field, the most in like manner it is included in the scope of patent protection of the present invention.

Claims (3)

  1. null1. high abrasion Teflon engineering plastics,It is characterized in that,Including: thermoplastic resin masterbatch、Nano titanium oxide、Super high pressure polyethylene、Polyvinylidene fluoride、Politef、Teflon、Dibutyl phthalate、Hexamethylene diisocyanate、Ethylene-vinyl alcohol copolymer、Dibasic lead phosphite、Graphite、White carbon black and silicone rubber,Described high abrasion Teflon engineering plastics calculate according to mass percent,Including following weight portion: thermoplastic resin masterbatch 2-5 part、Nano titanium oxide 3-6 part、Super high pressure polyethylene 1-4 part、Polyvinylidene fluoride 2-5 part、Politef 0.3-0.9 part、Teflon 5-10 part、Dibutyl phthalate 6-7 part、Hexamethylene diisocyanate 1-5 part、Ethylene-vinyl alcohol copolymer 6-10 part、Dibasic lead phosphite 2-5 part、Graphite 1-4 part、White carbon black 1-4 part and silicone rubber 5-10 part.
  2. High abrasion Teflon engineering plastics the most according to claim 1, it is characterized in that, described high abrasion Teflon engineering plastics calculate according to mass percent, including following weight portion: thermoplastic resin masterbatch 3 parts, nano titanium oxide 4 parts, super high pressure polyethylene 2 parts, polyvinylidene fluoride 3 parts, politef 0.5 part, Teflon 7 parts, dibutyl phthalate 6 parts, hexamethylene diisocyanate 3 parts, ethylene-vinyl alcohol copolymer 7 parts, dibasic lead phosphite 4 parts, 2 parts of graphite, white carbon black 2 parts and 7 parts of silicone rubber.
  3. High abrasion Teflon engineering plastics the most according to claim 1, it is characterized in that, described high abrasion Teflon engineering plastics calculate according to mass percent, including following weight portion: thermoplastic resin masterbatch 4 parts, nano titanium oxide 5 parts, super high pressure polyethylene 3 parts, polyvinylidene fluoride 4 parts, politef 0.8 part, Teflon 8 parts, dibutyl phthalate 6.5 parts, hexamethylene diisocyanate 4 parts, ethylene-vinyl alcohol copolymer 8 parts, dibasic lead phosphite 4 parts, 3 parts of graphite, white carbon black 3 parts and 8 parts of silicone rubber.
CN201610606013.2A 2016-07-29 2016-07-29 High-wear-resistance teflon engineering plastic Pending CN106009439A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106957502A (en) * 2017-05-31 2017-07-18 苏州新区特氟龙塑料制品厂 A kind of heat-resistant deformable plastic
CN112029282A (en) * 2020-09-11 2020-12-04 合肥普和普耐磨材料技术有限公司 Formula and preparation method of high-wear-resistance engineering plastic

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104774365A (en) * 2015-04-17 2015-07-15 柳州蔚园塑料彩印包装有限责任公司 Wear-resisting engineering plastic
CN105367960A (en) * 2015-11-30 2016-03-02 无锡大塘复合材料有限公司 Heat-conductive hard Teflon plastic
CN105623046A (en) * 2016-02-22 2016-06-01 太仓市晨洲塑业有限公司 Antibacterial engineering plastic

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104774365A (en) * 2015-04-17 2015-07-15 柳州蔚园塑料彩印包装有限责任公司 Wear-resisting engineering plastic
CN105367960A (en) * 2015-11-30 2016-03-02 无锡大塘复合材料有限公司 Heat-conductive hard Teflon plastic
CN105623046A (en) * 2016-02-22 2016-06-01 太仓市晨洲塑业有限公司 Antibacterial engineering plastic

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106957502A (en) * 2017-05-31 2017-07-18 苏州新区特氟龙塑料制品厂 A kind of heat-resistant deformable plastic
CN112029282A (en) * 2020-09-11 2020-12-04 合肥普和普耐磨材料技术有限公司 Formula and preparation method of high-wear-resistance engineering plastic

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Application publication date: 20161012