CN106750854A - A kind of anti-aging plastics and preparation method thereof - Google Patents
A kind of anti-aging plastics and preparation method thereof Download PDFInfo
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
- C08L23/0846—Copolymers of ethene with unsaturated hydrocarbons containing other atoms than carbon or hydrogen atoms
- C08L23/0853—Vinylacetate
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Abstract
The invention discloses a kind of anti-aging plastics and preparation method thereof, including following parts by weight raw material：20 25 parts of EVA resin, 5 10 parts of mountain skin soil, 0.1 1 parts of laccase, 10 15 parts of ABS resin, 5 10 parts of flint clay, 2 10 parts of poly- glutaric acid propylene glycol ester, 28 parts of grape pip, 0.5 2 parts of isopropyl myristate, 0.2 1 parts of isopropyl palmitate, 13 parts of ethoxylated dodecyl alcohol, 12 parts of soybean oil, 25 parts of glass dust, 24 parts of tripropylene glycol butyl ether, 0.5 2 parts of 4 chloroacetyl acetacetic ester.The anti-aging plastics have good heat-resisting and ageing resistace, greatly improve the mechanical performance of product, and the anti-aging plastics preparation method is simple, low production cost；The anti-aging plastics also have the advantages that intensity high, good toughness, heat resistance be good, wear-resisting, service life is high.
Description
Technical field
The present invention relates to a kind of plastics, specifically a kind of anti-aging plastics and preparation method thereof.
Background technology
As science and technology is continued to develop with economic, play more next in daily life by the daily living article of plastics-production
More important effect.Plastics are with monomer as raw material, by addition polymerization or the macromolecular compound of polycondensation polymerized
(macromolecules) plastics (plastics) or resin (resin), are commonly called as, can freely change composition and body styles,
It is made up of the additive such as synthetic resin and filler, plasticizer, stabilizer, lubricant, colorant.
Synthetic resin is the main composition of plastics, and its content in the plastic is general 40%~100%.Due to content
Greatly, and the property of resin usually determines the property of plastics, so people often regard resin as the synonym of plastics.For example
Corvic is lumped together with igelite, phenolic resin and phenoplasts.Resin and plastics are two in fact
Different concepts.Resin is a kind of unprocessed original polymer, and it is applied not only to manufacture plastics, but also is coating, gluing
Agent and the raw material of synthetic fibers.
And most of plastics, in addition to key component resin, in addition it is also necessary to add other materials.Existing plastics in order to
Increase stability, ageing resistace, corrosion resistance, anti-microbial property of plastics etc., generally require to add more in the plastic
Additive, the preparation technology that this also result in plastic material is cumbersome, and production cost is higher；And plastic material be still present it is anti-
The shortcoming that ageing properties are low, intensity is relatively low, have impact on the product quality of plastic material, and service life is not high.
The content of the invention
It is an object of the invention to provide a kind of anti-aging plastics and preparation method thereof, to solve to be carried in above-mentioned background technology
The problem for going out.
To achieve the above object, the present invention provides following technical scheme：
A kind of anti-aging plastics, including following parts by weight raw material：EVA resin 20-25 parts, 5-10 parts of mountain skin soil, laccase
0.1-1 parts, ABS resin 10-15 parts, flint clay 5-10 parts, 2-10 parts of poly- glutaric acid propylene glycol ester, grape pip 2-8 parts, nutmeg
Isopropyl propionate 0.5-2 parts, isopropyl palmitate 0.2-1 parts, ethoxylated dodecyl alcohol 1-3 parts, soybean oil 1-2 parts, glass dust
2-5 parts, 2-4 parts of tripropylene glycol butyl ether, 0.5-2 parts of 4- chloroacetyl acetacetic esters.
As further scheme of the invention：Raw material including following parts by weight：22 parts of EVA resin, mountain skin soil 8 parts,
0.5 part of laccase, 12 parts of ABS resin, 7 parts of flint clay, 5 parts of poly- glutaric acid propylene glycol ester, 3 parts of grape pip, isopropyl myristate
0.8 part, 0.5 part of isopropyl palmitate, 1.5 parts of ethoxylated dodecyl alcohol, 2 parts of soybean oil, 3 parts of glass dust, tripropylene glycol fourth
3 parts of ether, 0.8 part of 4- chloroacetyl acetacetic esters.
A kind of preparation method of anti-aging plastics, concretely comprises the following steps：
（1）EVA resin, mountain skin soil, laccase, ABS resin, flint clay, poly- glutaric acid propylene glycol ester, Portugal are weighed according to parts by weight
Grape seed, isopropyl myristate, isopropyl palmitate, ethoxylated dodecyl alcohol, soybean oil, glass dust, tripropylene glycol butyl ether,
4- chloroacetyl acetacetic esters, it is standby；
（2）Grape pip is placed on after frying 1-2min in soybean oil and taken out, drained, 200-300 mesh is then crushed to using pulverizer；
（3）Flint clay, glass dust, mountain skin soil and laccase are put into ball mill, using wet ball grinding, Ball-milling Time 15-
30min；
（4）High-speed mixer is put into after EVA resin, ABS resin are mixed, is mixed at a temperature of 200-250 DEG C, incorporation time
15-20min；
（5）By step（3）Gains and step（4）Gains mix, and by high-speed mixer, are mixed at a temperature of 120-150 DEG C
Close, incorporation time 5-10min；
（6）To step（5）4- chloroacetyl acetacetic esters, ethoxylated dodecyl alcohol, poly- glutaric acid third are added in gains successively
Diol ester, isopropyl palmitate, isopropyl myristate, tripropylene glycol butyl ether；By high-speed mixer, in 50-75 DEG C of temperature
Lower mixing, and a kind of material is added every 2-3min, it is well mixed, get product.
As further scheme of the invention：The step（4）It is put into after EVA resin, ABS resin are mixed mixed at a high speed
Conjunction machine, mixes, incorporation time 18min at a temperature of 220 DEG C.
As further scheme of the invention：The step（5）By step（3）Gains and step（4）Gains are mixed
Close, by high-speed mixer, mix at a temperature of 135 DEG C, incorporation time 6min.
As further scheme of the invention：The step（6）To step（5）4- chloracetyls are added in gains successively
Ethyl acetate, ethoxylated dodecyl alcohol, poly- glutaric acid propylene glycol ester, isopropyl palmitate, isopropyl myristate, 3 the third two
Alcohol butyl ether；By high-speed mixer, mix at a temperature of 65 DEG C, and a kind of material is added every 2.5min, be well mixed, obtain final product
Finished product.
Compared with prior art, the beneficial effects of the invention are as follows：
The anti-aging plastics have good heat-resisting and ageing resistace, greatly improve the mechanical performance of product, and should
Anti-aging plastics preparation method is simple, low production cost；The anti-aging plastics also have that intensity is high, good toughness, heat resistance are good,
More wear-resisting, service life advantage high.
Specific embodiment
The technical scheme of this patent is described in more detail with reference to specific embodiment.
Embodiment 1
A kind of anti-aging plastics, including following parts by weight raw material：20 parts of EVA resin, 5 parts of mountain skin soil, 0.1 part of laccase, ABS
10 parts of resin, 5 parts of flint clay, 2 parts of poly- glutaric acid propylene glycol ester, 2 parts of grape pip, 0.5 part of isopropyl myristate, palmitic acid are different
0.2 part of propyl ester, 1 part of ethoxylated dodecyl alcohol, 1 part of soybean oil, 2 parts of glass dust, 2 parts of tripropylene glycol butyl ether, 4- chloracetyl second
0.5 part of acetoacetic ester.
A kind of preparation method of anti-aging plastics, concretely comprises the following steps：
（1）EVA resin, mountain skin soil, laccase, ABS resin, flint clay, poly- glutaric acid propylene glycol ester, Portugal are weighed according to parts by weight
Grape seed, isopropyl myristate, isopropyl palmitate, ethoxylated dodecyl alcohol, soybean oil, glass dust, tripropylene glycol butyl ether,
4- chloroacetyl acetacetic esters, it is standby；
（2）Grape pip is placed on after frying 1min in soybean oil and taken out, drained, 200 mesh are then crushed to using pulverizer；
（3）Flint clay, glass dust, mountain skin soil and laccase are put into ball mill, using wet ball grinding, Ball-milling Time 15min；
（4）High-speed mixer is put into after EVA resin, ABS resin are mixed, is mixed at a temperature of 200 DEG C, incorporation time 15min；
（5）By step（3）Gains and step（4）Gains mix, and by high-speed mixer, mix at a temperature of 120 DEG C, mix
Conjunction time 5min；
（6）To step（5）4- chloroacetyl acetacetic esters, ethoxylated dodecyl alcohol, poly- glutaric acid third are added in gains successively
Diol ester, isopropyl palmitate, isopropyl myristate, tripropylene glycol butyl ether；By high-speed mixer, mixed at a temperature of 50 DEG C
Close, and a kind of material is added every 2min, be well mixed, get product.
Embodiment 2
A kind of anti-aging plastics, including following parts by weight raw material：25 parts of EVA resin, 10 parts of mountain skin soil, 1 part of laccase, ABS
15 parts of resin, 10 parts of flint clay, 10 parts of poly- glutaric acid propylene glycol ester, 8 parts of grape pip, 2 parts of isopropyl myristate, palmitic acid are different
1 part of propyl ester, 3 parts of ethoxylated dodecyl alcohol, 2 parts of soybean oil, 5 parts of glass dust, 4 parts of tripropylene glycol butyl ether, 4- chloroethene ethyl acetoacetic acids
2 parts of ethyl ester.
A kind of preparation method of anti-aging plastics, concretely comprises the following steps：
（1）EVA resin, mountain skin soil, laccase, ABS resin, flint clay, poly- glutaric acid propylene glycol ester, Portugal are weighed according to parts by weight
Grape seed, isopropyl myristate, isopropyl palmitate, ethoxylated dodecyl alcohol, soybean oil, glass dust, tripropylene glycol butyl ether,
4- chloroacetyl acetacetic esters, it is standby；
（2）Grape pip is placed on after frying 2min in soybean oil and taken out, drained, 300 mesh are then crushed to using pulverizer；
（3）Flint clay, glass dust, mountain skin soil and laccase are put into ball mill, using wet ball grinding, Ball-milling Time 30min；
（4）High-speed mixer is put into after EVA resin, ABS resin are mixed, is mixed at a temperature of 250 DEG C, incorporation time 20min；
（5）By step（3）Gains and step（4）Gains mix, and by high-speed mixer, mix at a temperature of 150 DEG C, mix
Conjunction time 10min；
（6）To step（5）4- chloroacetyl acetacetic esters, ethoxylated dodecyl alcohol, poly- glutaric acid third are added in gains successively
Diol ester, isopropyl palmitate, isopropyl myristate, tripropylene glycol butyl ether；By high-speed mixer, mixed at a temperature of 75 DEG C
Close, and a kind of material is added every 3min, be well mixed, get product.
Embodiment 3
A kind of anti-aging plastics, including following parts by weight raw material：22 parts of EVA resin, 8 parts of mountain skin soil, 0.5 part of laccase, ABS
12 parts of resin, 7 parts of flint clay, 5 parts of poly- glutaric acid propylene glycol ester, 3 parts of grape pip, 0.8 part of isopropyl myristate, palmitic acid are different
0.5 part of propyl ester, 1.5 parts of ethoxylated dodecyl alcohol, 2 parts of soybean oil, 3 parts of glass dust, 3 parts of tripropylene glycol butyl ether, 4- chloracetyls
0.8 part of ethyl acetate.
A kind of preparation method of anti-aging plastics, concretely comprises the following steps：
（1）EVA resin, mountain skin soil, laccase, ABS resin, flint clay, poly- glutaric acid propylene glycol ester, Portugal are weighed according to parts by weight
Grape seed, isopropyl myristate, isopropyl palmitate, ethoxylated dodecyl alcohol, soybean oil, glass dust, tripropylene glycol butyl ether,
4- chloroacetyl acetacetic esters, it is standby；
（2）Grape pip is placed on after frying 1.5min in soybean oil and taken out, drained, 220 mesh are then crushed to using pulverizer；
（3）Flint clay, glass dust, mountain skin soil and laccase are put into ball mill, using wet ball grinding, Ball-milling Time 16min；
（4）High-speed mixer is put into after EVA resin, ABS resin are mixed, is mixed at a temperature of 220 DEG C, incorporation time 18min；
（5）By step（3）Gains and step（4）Gains mix, and by high-speed mixer, mix at a temperature of 135 DEG C, mix
Conjunction time 6min；
（6）To step（5）4- chloroacetyl acetacetic esters, ethoxylated dodecyl alcohol, poly- glutaric acid third are added in gains successively
Diol ester, isopropyl palmitate, isopropyl myristate, tripropylene glycol butyl ether；By high-speed mixer, mixed at a temperature of 65 DEG C
Close, and a kind of material is added every 2.5min, be well mixed, get product.
Comparative example 1
A kind of anti-aging plastics, including following parts by weight raw material：22 parts of EVA resin, 8 parts of mountain skin soil, 0.5 part of laccase, ABS
12 parts of resin, 7 parts of flint clay, 5 parts of poly- glutaric acid propylene glycol ester, 3 parts of grape pip, 0.8 part of isopropyl myristate, palmitic acid are different
0.5 part of propyl ester, 1.5 parts of ethoxylated dodecyl alcohol, 2 parts of soybean oil, 3 parts of glass dust, 3 parts of tripropylene glycol butyl ether.
A kind of preparation method of anti-aging plastics, concretely comprises the following steps：
（1）EVA resin, mountain skin soil, laccase, ABS resin, flint clay, poly- glutaric acid propylene glycol ester, Portugal are weighed according to parts by weight
Grape seed, isopropyl myristate, isopropyl palmitate, ethoxylated dodecyl alcohol, soybean oil, glass dust, tripropylene glycol butyl ether,
It is standby；
（2）Grape pip is placed on after frying 1.5min in soybean oil and taken out, drained, 220 mesh are then crushed to using pulverizer；
（3）Flint clay, glass dust, mountain skin soil and laccase are put into ball mill, using wet ball grinding, Ball-milling Time 16min；
（4）High-speed mixer is put into after EVA resin, ABS resin are mixed, is mixed at a temperature of 220 DEG C, incorporation time 18min；
（5）By step（3）Gains and step（4）Gains mix, and by high-speed mixer, mix at a temperature of 135 DEG C, mix
Conjunction time 6min；
（6）To step（5）Ethoxylated dodecyl alcohol, poly- glutaric acid propylene glycol ester, palmitic acid isopropyl are added in gains successively
Ester, isopropyl myristate, tripropylene glycol butyl ether；By high-speed mixer, mix at a temperature of 65 DEG C, and add every 2.5min
Plus a kind of material, it is well mixed, get product.
Comparative example 2
A kind of anti-aging plastics, including following parts by weight raw material：22 parts of EVA resin, 8 parts of mountain skin soil, 0.5 part of laccase, ABS
12 parts of resin, 7 parts of flint clay, 3 parts of grape pip, 0.8 part of isopropyl myristate, 0.5 part of isopropyl palmitate, laruyl alcohol polyoxy
1.5 parts of vinethene, 2 parts of soybean oil, 3 parts of glass dust, 3 parts of tripropylene glycol butyl ether, 0.8 part of 4- chloroacetyl acetacetic esters.
A kind of preparation method of anti-aging plastics, concretely comprises the following steps：
（1）EVA resin, mountain skin soil, laccase, ABS resin, flint clay, grape pip, myristic acid isopropyl are weighed according to parts by weight
Ester, isopropyl palmitate, ethoxylated dodecyl alcohol, soybean oil, glass dust, tripropylene glycol butyl ether, 4- chloroacetyl acetacetic esters,
It is standby；
（2）Grape pip is placed on after frying 1.5min in soybean oil and taken out, drained, 220 mesh are then crushed to using pulverizer；
（3）Flint clay, glass dust, mountain skin soil and laccase are put into ball mill, using wet ball grinding, Ball-milling Time 16min；
（4）High-speed mixer is put into after EVA resin, ABS resin are mixed, is mixed at a temperature of 220 DEG C, incorporation time 18min；
（5）By step（3）Gains and step（4）Gains mix, and by high-speed mixer, mix at a temperature of 135 DEG C, mix
Conjunction time 6min；
（6）To step（5）4- chloroacetyl acetacetic esters, ethoxylated dodecyl alcohol, palmitic acid isopropyl are added in gains successively
Ester, isopropyl myristate, tripropylene glycol butyl ether；By high-speed mixer, mix at a temperature of 65 DEG C, and add every 2.5min
Plus a kind of material, it is well mixed, get product.
4- chloroacetyl acetacetic esters are not added with comparative example 1, poly- glutaric acid propylene glycol ester is not added with comparative example 2.
Performance test is carried out to above example 1-3 and comparative example 1-2, performance test knot is carried out before artificial accelerated aging
Fruit such as table 1：
The performance test results before the embodiment 1-3 of table 1 and comparative example 1-2 artificial accelerated agings
The performance test results such as table 2 is carried out after artificial accelerated aging：
The performance test results after the embodiment 1-3 of table 2 and comparative example 1-2 artificial accelerated agings
Be can be seen that after artificial accelerated aging by table 1-2, the properties in embodiment 1-3 and comparative example 1-2 have
It is certain to decline, but the hydraulic performance decline in embodiment 1-3 is not obvious, and comparative example 1 is more obvious with the hydraulic performance decline of comparative example 2.
Therefore, 4- chloroacetyl acetacetic esters and poly- glutaric acid propylene glycol ester are with the addition of in embodiment 1-3, plastic material can be effectively improved
Ageing resistace, and the intensity of the plastics is high, and good toughness, heat resistance is good, and anti-wear performance is good.
The anti-aging plastics have good heat-resisting and ageing resistace, greatly improve the mechanical performance of product, and
And the anti-aging plastics preparation method is simple, low production cost；The anti-aging plastics also have intensity high, good toughness, heat resistance
Can good, more wear-resisting, service life advantage high.
The better embodiment to this patent is explained in detail above, but this patent is not limited to above-mentioned embodiment party
Formula, in the ken that one skilled in the relevant art possesses, can also be on the premise of this patent objective not be departed from
Make a variety of changes.
Claims (6)
1. a kind of anti-aging plastics, it is characterised in that the raw material including following parts by weight：EVA resin 20-25 parts, mountain skin soil
5-10 parts, laccase 0.1-1 parts, ABS resin 10-15 parts, flint clay 5-10 parts, 2-10 parts of poly- glutaric acid propylene glycol ester, grape pip
2-8 parts, isopropyl myristate 0.5-2 parts, isopropyl palmitate 0.2-1 parts, ethoxylated dodecyl alcohol 1-3 parts, soybean oil
1-2 parts, glass dust 2-5 parts, 2-4 parts of tripropylene glycol butyl ether, 0.5-2 parts of 4- chloroacetyl acetacetic esters.
2. anti-aging plastics material according to claim 1, it is characterised in that the raw material including following parts by weight：EVA
22 parts of resin, 8 parts of mountain skin soil, 0.5 part of laccase, 12 parts of ABS resin, 7 parts of flint clay, 5 parts of poly- glutaric acid propylene glycol ester, grape pip
3 parts, 0.8 part of isopropyl myristate, 0.5 part of isopropyl palmitate, 1.5 parts of ethoxylated dodecyl alcohol, 2 parts of soybean oil, glass
3 parts of glass powder, 3 parts of tripropylene glycol butyl ether, 0.8 part of 4- chloroacetyl acetacetic esters.
3. a kind of preparation method of anti-aging plastics material as described in claim 1-2 is any, it is characterised in that specific steps
For：
（1）EVA resin, mountain skin soil, laccase, ABS resin, flint clay, poly- glutaric acid propylene glycol ester, Portugal are weighed according to parts by weight
Grape seed, isopropyl myristate, isopropyl palmitate, ethoxylated dodecyl alcohol, soybean oil, glass dust, tripropylene glycol butyl ether,
4- chloroacetyl acetacetic esters, it is standby；
（2）Grape pip is placed on after frying 1-2min in soybean oil and taken out, drained, 200-300 mesh is then crushed to using pulverizer；
（3）Flint clay, glass dust, mountain skin soil and laccase are put into ball mill, using wet ball grinding, Ball-milling Time 15-
30min；
（4）High-speed mixer is put into after EVA resin, ABS resin are mixed, is mixed at a temperature of 200-250 DEG C, incorporation time
15-20min；
（5）By step（3）Gains and step（4）Gains mix, and by high-speed mixer, are mixed at a temperature of 120-150 DEG C
Close, incorporation time 5-10min；
（6）To step（5）4- chloroacetyl acetacetic esters, ethoxylated dodecyl alcohol, poly- glutaric acid third are added in gains successively
Diol ester, isopropyl palmitate, isopropyl myristate, tripropylene glycol butyl ether；By high-speed mixer, in 50-75 DEG C of temperature
Lower mixing, and a kind of material is added every 2-3min, it is well mixed, get product.
4. the preparation method of anti-aging plastics material according to claim 3, it is characterised in that the step（4）By EVA
High-speed mixer is put into after resin, ABS resin mixing, is mixed at a temperature of 220 DEG C, incorporation time 18min.
5. the preparation method of anti-aging plastics material according to claim 3, it is characterised in that the step（5）Will step
Suddenly（3）Gains and step（4）Gains mix, and by high-speed mixer, mix at a temperature of 135 DEG C, incorporation time 6min.
6. the preparation method of anti-aging plastics material according to claim 3, it is characterised in that the step（6）Xiang Bu
Suddenly（5）4- chloroacetyl acetacetic esters, ethoxylated dodecyl alcohol, poly- glutaric acid propylene glycol ester, palm are added in gains successively
Isopropyl propionate, isopropyl myristate, tripropylene glycol butyl ether；By high-speed mixer, mix at a temperature of 65 DEG C, and every
2.5min adds a kind of material, is well mixed, and gets product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611078003.2A CN106750854A (en) | 2016-11-30 | 2016-11-30 | A kind of anti-aging plastics and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611078003.2A CN106750854A (en) | 2016-11-30 | 2016-11-30 | A kind of anti-aging plastics and preparation method thereof |
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| Publication Number | Publication Date |
|---|---|
| CN106750854A true CN106750854A (en) | 2017-05-31 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201611078003.2A Pending CN106750854A (en) | 2016-11-30 | 2016-11-30 | A kind of anti-aging plastics and preparation method thereof |
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Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102153806A (en) * | 2011-04-20 | 2011-08-17 | 江苏爱特恩高分子材料有限公司 | Plastic filling master batch and preparation method thereof |
| CN103351519A (en) * | 2013-06-19 | 2013-10-16 | 安徽天星光纤通信设备有限公司 | Low-smoke, halogen-free and flame-retardant cable material and preparation method thereof |
-
2016
- 2016-11-30 CN CN201611078003.2A patent/CN106750854A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102153806A (en) * | 2011-04-20 | 2011-08-17 | 江苏爱特恩高分子材料有限公司 | Plastic filling master batch and preparation method thereof |
| CN103351519A (en) * | 2013-06-19 | 2013-10-16 | 安徽天星光纤通信设备有限公司 | Low-smoke, halogen-free and flame-retardant cable material and preparation method thereof |
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