CN106747635A - 一种健康日用陶瓷的制备方法 - Google Patents

一种健康日用陶瓷的制备方法 Download PDF

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CN106747635A
CN106747635A CN201611131627.6A CN201611131627A CN106747635A CN 106747635 A CN106747635 A CN 106747635A CN 201611131627 A CN201611131627 A CN 201611131627A CN 106747635 A CN106747635 A CN 106747635A
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曾海洲
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Dehua Fujian Xiangyu Art Ceramics Co Ltd
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Abstract

本发明公开了一种健康日用陶瓷的制备方法，选用粉煤灰、麦饭石、岩浆岩、巫山黄土、石英、锂瓷石等富含常量元素的再生废物或者高温下形成自然结晶体的天然矿产资源，然后加入多种对人体健康有益的微量元素，精制成无机粉体材料，然后经过高速制浆机中加水捏合，并加入表面活性剂和甘油进行改性，然后经过梯度温控烧制，获得可有效净化和吸咐液体、固体、气体中释放的有害物质的健康日用陶瓷，陶瓷内呈多孔型蜂窝状组织，比表面积较大，具有较高的吸附活性，颗粒的粒径范围为80nm～150nm，并且珠壁具有多孔结构，孔隙率高达60%‑80%，有很强的吸附性，可实现温室气体零排放。

Description

一种健康日用陶瓷的制备方法
技术领域
本发明涉及陶瓷的生产方法，具体为一种健康日用陶瓷的制备方法。
背景技术
陶瓷的发明是中国人对人类的重大贡献。陶瓷自发明以来一直受到了广大群众的重视和喜爱，是人类生活中重要的组成部分。日用瓷器长期以来为广大人民群众所喜爱和使用，因为它有以下优点 ：第一，易于洗涤和保持洁净。日用瓷釉面光亮，细腻，使用沾污后容易冲刷。第二，热稳定性较好，传热慢。第三，化学性质稳定，经久耐用。这一点比金属制品如铜器、铁器、铝器等要优越，日用瓷具有一定的耐酸、碱、盐及大气中碳酸气侵蚀的能力，不易与这些物质发生化学反应，不生锈老化。
随着经济的发展，日常生活中人们接触到越来越多的有毒有害物质，但市面上的日用陶瓷够的功能较为单一，不能够有效净化和吸咐体、固体、气体中释放的有害物质。
发明内容
本发明要解决的技术问题是克服现有的日用陶瓷够的功能较为单一，不能够有效净化和吸咐体、固体、气体中释放的有害物质的缺陷，提供一种健康日用陶瓷的制备方法。
为了解决上述技术问题，本发明提供了如下的技术方案：
一种健康日用陶瓷的制备方法,包括以下步骤：
1）、原料制备：将以质量份数计的粉煤灰10～25份、麦饭石8～40份、岩浆岩20～30份、巫山黄土10～18份、石英6～12份、锂瓷石8～16份和微量元素0.5～2份精制成无机粉体材料，在高速制浆机中加水捏合，获得质量浓度为30%～40%的浆体半成品；
2）、加入3～5%质量分数的表面改性剂和6～8%质量分数的的甘油,搅拌3～5小时；
3)压力成坯 ；
4)美坯；
5)在1080℃～1205℃,烧制40～85min。
进一步的，所述步骤1）中的原料包括以下质量份数的各组分：粉煤灰18份、麦饭石30份、岩浆岩25份、巫山黄土14份、石英9份、锂瓷石12份和微量元素1份。
进一步的，所述步骤1）中高速制浆机的叶轮转速1500～1800转/分，捏合0.8～2小时。
进一步的，所述的表面活性剂一端具有异氰酸酯官能团，另一端具有乙烯不饱和键。
进一步的，步骤5）中先1155℃烧制20min，然后1102℃烧制10～15min，最后1080℃5～50min。
进一步的，所述的微量元素由包括以下组份：铁、钴、锰、铬、硒、镍、钼、钒、锡。
进一步的，所述的微量元素还包括钾、钠、钙、锌、钙、镁、磷、硒、铜、碘和氟。
进一步的，所述的步骤1）中无机粉体材料的粒径80nm～150nm。
本发明选用粉煤灰、麦饭石、岩浆岩、巫山黄土、石英、锂瓷石等富含SIO2、AL2O3、TiO2、FeO、Fe2O3、CaO、P2O3、MnO、K2O、Na2O等常量元素的再生废物或者高温下形成自然结晶体的天然矿产资源，然后加入铁、钴、锰、铬、硒、镍、钼、钒、锡和钾、钠、钙、锌、钙、镁、磷、硒、铜、碘和氟等多种对人体健康有益的微量元素，精制成无机粉体材料，然后经过高速制浆机中加水捏合，并加入表面活性剂和甘油进行改性，然后经过梯度温控烧制，获得可有效净化和吸咐液体、固体、气体中释放的有害物质的健康日用陶瓷，陶瓷内呈多孔型蜂窝状组织，比表面积较大，具有较高的吸附活性，颗粒的粒径范围为80nm～150nm，并且珠壁具有多孔结构，孔隙率高达60%-80%，有很强的吸附性，可实现温室气体零排放。
具体实施方式
以下对本发明的优选实施例进行说明，应当理解，此处所描述的优选实施例仅用于说明和解释本发明，并不用于限定本发明。
实施例1
一种健康日用陶瓷的制备方法,包括以下步骤：
1）、原料制备：将以质量份数计的粉煤灰10份、麦饭石～40份、岩浆岩20份、巫山黄土10份、石英6份、锂瓷石8份和微量元素0.5份精制成粒径为80nm的无机粉体材料，然后在高速制浆机中加水捏合，获得质量浓度为40%的浆体半成品；
高速制浆机的叶轮转速1500转/分，捏合2小时；
2）、加入5%质量分数的表面改性剂和8%质量分数的的甘油,搅拌5小时；所述的表面活性剂一端具有异氰酸酯官能团，另一端具有乙烯不饱和键；
3)压力成坯 ；
4)美坯；
5)在1205℃,烧制40min。
实施例2
一种健康日用陶瓷的制备方法,包括以下步骤：
1）、原料制备：将以质量份数计的粉煤灰25份、麦饭石40份、岩浆岩30份、巫山黄土18份、石英12份、锂瓷石16份和微量元素2份精制成无机粉体材料，在高速制浆机中加水捏合，获得质量浓度为30%的浆体半成品；
无机粉体材料的粒径150nm，微量元素由包括以下组份：铁、钴、锰、铬、硒、镍、钼、钒、锡；高速制浆机的叶轮转速1800转/分，捏合0.8小时；
2）、加入3%质量分数的表面改性剂和6%质量分数的的甘油,搅拌3小时；所述的表面活性剂一端具有异氰酸酯官能团，另一端具有乙烯不饱和键；
3)压力成坯 ；
4)美坯；
5)先1155℃烧制20min，然后1102℃烧制15min，最后1080℃ 50min。
实施例3
一种健康日用陶瓷的制备方法,包括以下步骤：
1）、原料制备：将以质量份数计的粉煤灰18份、麦饭石30份、岩浆岩25份、巫山黄土14份、石英9份、锂瓷石12份和微量元素1份精制成无机粉体材料，在高速制浆机中加水捏合，获得质量浓度为35%的浆体半成品；
无机粉体材料的粒径120nm，微量元素为铁、钴、锰、铬、硒、镍、钼、钒、锡、钾、钠、钙、锌、钙、镁、磷、硒、铜、碘和氟；高速制浆机的叶轮转速1650转/分，捏合1.2小时；
2）、加入4%质量分数的表面改性剂和7%质量分数的的甘油,搅拌4小时；所述的表面活性剂一端具有异氰酸酯官能团，另一端具有乙烯不饱和键。
3)压力成坯 ；
4)美坯；
5)先1155℃烧制20min，然后1102℃烧制12min，最后1080℃ 30min。
最后应说明的是：以上所述仅为本发明的优选实施例而已，并不用于限制本发明，尽管参照前述实施例对本发明进行了详细的说明，对于本领域的技术人员来说，其依然可以对前述各实施例所记载的技术方案进行修改，或者对其中部分技术特征进行等同替换。凡在本发明的精神和原则之内，所作的任何修改、等同替换、改进等，均应包含在本发明的保护范围之内。

Claims (8)

1.一种健康日用陶瓷的制备方法,其特征在于，包括以下步骤：
1）、原料制备：将以质量份数计的粉煤灰10～25份、麦饭石8～40份、岩浆岩20～30份、巫山黄土10～18份、石英6～12份、锂瓷石8～16份和微量元素0.5～2份精制成无机粉体材料，在高速制浆机中加水捏合，获得质量浓度为30%～40%的浆体半成品；
2）、加入3～5%质量分数的表面改性剂和6～8%质量分数的的甘油,搅拌3～5小时；
3)压力成坯 ；
4)美坯；
5)在1080℃～1205℃,烧制40～85min。
2.如权利要求1所述的健康日用陶瓷的制备方法,其特征在于，所述步骤1）中的原料包括以下质量份数的各组分：粉煤灰18份、麦饭石30份、岩浆岩25份、巫山黄土14份、石英9份、锂瓷石12份和微量元素1份。
3.如权利要求1所述的健康日用陶瓷的制备方法,其特征在于，所述步骤1）中高速制浆机的叶轮转速1500～1800转/分，捏合0.8～2小时。
4.如权利要求1所述的健康日用陶瓷的制备方法,其特征在于，所述的表面活性剂一端具有异氰酸酯官能团，另一端具有乙烯不饱和键。
5.如权利要求1所述的健康日用陶瓷的制备方法,其特征在于，所述步骤5）中先1155℃烧制20min，然后1102℃烧制10～15min，最后1080℃ 5～50min。
6.如权利要求1所述的健康日用陶瓷的制备方法,其特征在于，所述的微量元素由包括以下组份：铁、钴、锰、铬、硒、镍、钼、钒、锡。
7.如权利要求6所述的健康日用陶瓷的制备方法,其特征在于，所述的微量元素还包括钾、钠、钙、锌、钙、镁、磷、硒、铜、碘和氟。
8.如权利要求1所述的健康日用陶瓷的制备方法,其特征在于，所述的步骤1）中无机粉体材料的粒径80nm～150nm。
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CN108546103A (zh) * 2018-07-09 2018-09-18 福建泉州顺盛达集团有限公司 一种低温强化瓷的制备方法
CN109133861A (zh) * 2018-11-14 2019-01-04 齐齐哈尔市碾子山区民乐麦饭石工艺品厂 一种麦饭石陶器的制作方法

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CN108546103A (zh) * 2018-07-09 2018-09-18 福建泉州顺盛达集团有限公司 一种低温强化瓷的制备方法
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CN109133861B (zh) * 2018-11-14 2021-08-03 齐齐哈尔市碾子山区民乐麦饭石工艺品厂 一种麦饭石陶器的制作方法

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