CN106747231A - A kind of magnesium oxysulfide concrete concrete material and preparation method thereof - Google Patents
A kind of magnesium oxysulfide concrete concrete material and preparation method thereof Download PDFInfo
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- CN106747231A CN106747231A CN201510859737.3A CN201510859737A CN106747231A CN 106747231 A CN106747231 A CN 106747231A CN 201510859737 A CN201510859737 A CN 201510859737A CN 106747231 A CN106747231 A CN 106747231A
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- magnesium oxysulfide
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Abstract
The invention discloses a kind of magnesium oxysulfide concrete concrete material, it includes following components by weight：90~110 parts of light burnt powder；100~300 parts of sand；100~500 parts of rubble；1~3 part of additive；Baume degrees is 25~30 100~200 parts of Adlerika；Wherein, the additive is the mixing material of phosphate and flyash, and phosphate is 1 with the weight ratio of flyash：2.5~3.5.The preparation method of magnesium oxysulfide concrete concrete material as described above includes step：S101, by the light burnt powder, sand, rubble and additive according to the components by weight percent stir mix；S102, by magnesium sulfate solid dissolving in water, formed Adlerika；S103, Adlerika is added in the mixing material that step S101 is obtained, be uniformly mixed, obtain magnesium oxysulfide concrete concrete material.
Description
Technical field
The invention belongs to building material technical field, more particularly to a kind of magnesium oxysulfide concrete concrete material and its
Preparation method.
Background technology
Magnesium cement is a kind of special kinds cement, because it was sent out in 1867 by Frenchman's Sorel (Sorel)
Bright, so also known as magnesia oxychloride cement.Meanwhile, it with magnesia as main component, people traditionally also known as
It is magnesia cement.In many enterprises, people according to it with two kinds of magnesium compounds of magnesia and magnesium chloride be main
The characteristics of raw material, double magnesium cement are simply referred to as again.Magnesium cement be with the light burnt powder obtained by calcined magnesite stone or
Ashes (main component is MgO) obtained by low temperature calcination dolomite is cementing agent, with magnesium chloride hexahydrate
(MgCl2·6H2) etc. O water-soluble magnesium salt is blender, adds water, the light-burning magnesium powder and six water for being formed
Magnesium chloride as primary raw material, therefore, then generally, magnesium cement refers to just magnesia oxychloride cement.
The hardenite main component that magnesium cement is formed is 5Mg (OH)2·MgCl2·8H2O and
3Mg(OH)2·MgCl2·8H2Magnesia-magnesium chloride that O crystalline phases are constituted-water ternary compound crystalline phase double salt,
In addition, some Mg (OH)2Gel.Magnesium cement can be hardened quickly at normal temperatures and pressures, shape
Into the fragility artificial stone very higher than larger and hardness.Using its this hardening gelling, can be processed into
Various construction materials and ornament materials, have broad application prospects.At present, architectural engineering it
In the magnesium cement generally used all mainly with magnesia and magnesium chloride as main material is prepared from, but
It is that this cement can corrode metal in the halogen that gets damp, surface is easily caused for secondary decoration and is come off,
And this cement water resistance is very poor, and the life-span is shorter.Therefore to magnesia and magnesium chloride as main material system
Standby magnesia oxychloride cement is improved, to adapt to requirement of the modern construction engineering for magnesium cement.
The content of the invention
In order to solve the problems, such as prior art, the invention provides a kind of magnesium oxysulfide concrete concrete material
And preparation method thereof, the concrete material has good corrosion resistance and water-resistance.
For achieving the above object, present invention employs following technical scheme：
A kind of magnesium oxysulfide concrete concrete material, it includes following components by weight：Light burnt powder 90~110
Part；100~300 parts of sand；100~500 parts of rubble；1~3 part of additive；Baume degrees is 25~30 sulphur
100~200 parts of sour magnesium solution；Wherein, the additive is the mixing material of phosphate and flyash, phosphoric acid
Salt is 1 with the weight ratio of flyash：2.5~3.5.
Preferably, the number of the Adlerika is 140~180 parts.
Preferably, the number of the additive is 2 parts.
Preferably, the number of the rubble is 300~400 parts.
Preferably, the particle diameter of the rubble is 1~3cm.
Preferably, in the additive, phosphate is 1 with the weight ratio of flyash：3.
Preferably, the phosphate be ammonium dihydrogen phosphate, calcium dihydrogen phosphate and sodium dihydrogen phosphate in one kind or
It is two or more.
The preparation method of magnesium oxysulfide concrete concrete material as described above includes step：S101, will be described light
Burn powder, sand, rubble and additive and stirred according to the components by weight percent and mix；S102, by magnesium sulfate solid
It is dissolved in the water, forms Adlerika；S103, Adlerika is added to step S101 obtains it is mixed
In condensation material, it is uniformly mixed, obtains magnesium oxysulfide concrete concrete material.
Further, the method also includes the step of preparing the additive：First by the phosphate and powder
Coal ash mixes, and adds water to remix to form slurry；Then will be milled after the slurry drying, obtain described outer
Plus agent.
Magnesium oxysulfide concrete concrete material provided in an embodiment of the present invention and preparation method thereof, magnesium oxysulfide concrete is mixed
Solidifying soil material mainly includes light burnt powder and Adlerika, is MgOMgSO4H2O ternary gelling system groups
Into magnesian, and wherein add specific additive, have compared to magnesia oxychloride cement better
Corrosion resistance and water-resistance, the concrete material hardening after intensity it is high, it is easy to use.
Brief description of the drawings
Fig. 1 is the process chart of the preparation method of the magnesium oxysulfide concrete concrete material of the embodiment of the present invention.
Specific embodiment
To make the object, technical solutions and advantages of the present invention clearer, below in conjunction with the accompanying drawings to of the invention
Specific embodiment is described in detail.The example of these preferred embodiments is illustrated in the accompanying drawings.
What the embodiments of the present invention for describing shown in accompanying drawing and with reference to the accompanying drawings were merely exemplary, and the present invention
It is not limited to these implementation methods.
The embodiment of the present invention provide firstly a kind of magnesium oxysulfide concrete concrete material, and it is included by weight
Following components：90~110 parts of light burnt powder；100~300 parts of sand；100~500 parts of rubble；Additive 1~3
Part；Baume degrees is 25~30 100~200 parts of Adlerika；Wherein, the additive be phosphate with
The mixing material of flyash, phosphate is 1 with the weight ratio of flyash：2.5~3.5.Wherein, the phosphate
Can select as one or more in ammonium dihydrogen phosphate, calcium dihydrogen phosphate and sodium dihydrogen phosphate.
Further, the embodiment of the present invention additionally provides the system of magnesium oxysulfide concrete concrete material as described above
Preparation Method.Specifically, refering to Fig. 1, the method comprising the steps of：S101, by the light burnt powder, sand, broken
Stone and additive are stirred according to the components by weight percent and mixed.S102, by magnesium sulfate solid dissolving in water, shape
Into Adlerika.S103, Adlerika is added in the mixing material that step S101 is obtained, stirred
It is well mixed, obtain magnesium oxysulfide concrete concrete material.
Wherein, the additive is prepared according to following technique：The phosphate and flyash are mixed first
Close, add water to remix to form slurry；Then will be milled after the slurry drying, obtain the additive.
Embodiment 1
It is additional using light burnt powder 100kg, sand 150kg, rubble 200kg (particle diameter is between 1~3cm)
(ammonium dihydrogen phosphate is 1 according to weight ratio with flyash to agent 1.5kg：2.5 ratio mixing), after being well mixed,
The Baume degrees for adding 140kg is 25 Adlerika, is well mixed again, obtains magnesium oxysulfide concrete coagulation
Soil material.
By magnesium oxysulfide concrete concrete material injection experimentses mould obtained above, the demoulding after 24h, maintenance 28
After it, test obtains its more than compression strength 42MPa.
Embodiment 2
It is additional using light burnt powder 100kg, sand 100kg, rubble 500kg (particle diameter is between 1~3cm)
(calcium dihydrogen phosphate is 1 according to weight ratio with flyash to agent 3kg：3.5 ratio mixing), after being well mixed,
The Baume degrees for adding 200kg is 28 Adlerika, is well mixed again, obtains magnesium oxysulfide concrete coagulation
Soil material.
By magnesium oxysulfide concrete concrete material injection experimentses mould obtained above, the demoulding after 24h, maintenance 28
After it, test obtains its more than compression strength 35MPa.
Embodiment 3
Using light burnt powder 90kg, sand 250kg, rubble 300kg (particle diameter is between 1~3cm), additive
(sodium dihydrogen phosphate is 1 according to weight ratio with flyash to 2kg：3 ratio mixing), after being well mixed, add
The Baume degrees of 180kg is 30 Adlerika, is well mixed again, obtains magnesium oxysulfide concrete concrete material
Material.
By magnesium oxysulfide concrete concrete material injection experimentses mould obtained above, the demoulding after 24h, maintenance 28
After it, test obtains its more than compression strength 40MPa.
Embodiment 4
It is additional using light burnt powder 110kg, sand 300kg, rubble 100kg (particle diameter is between 1~3cm)
(ammonium dihydrogen phosphate, calcium dihydrogen phosphate and flyash are 1 according to weight ratio to agent 1kg：1：6 ratio mixing),
After well mixed, the Baume degrees for adding 100kg is 28 Adlerika, is well mixed again, obtains sulphur
Oxygen magnesium cement concrete material.
By magnesium oxysulfide concrete concrete material injection experimentses mould obtained above, the demoulding after 24h, maintenance 28
After it, test obtains its more than compression strength 45MPa.
In sum, magnesium oxysulfide concrete concrete material provided in an embodiment of the present invention and preparation method thereof, sulphur
Oxygen magnesium cement concrete material mainly includes light burnt powder and Adlerika, is MgOMgSO4H2O ternarys
The magnesian of gelling system composition, and specific additive is wherein added, have compared to magnesia oxychloride cement
There is better corrosion resistance and water-resistance, intensity is high after concrete material hardening, easy to use.
By experimental verification, the concrete material can add in concrete on a large scale to the corrosivity very little of reinforcing bar
Enter reinforcing bar, be made armored concrete.
The above is only the specific embodiment of the application, it is noted that common for the art
For technical staff, on the premise of the application principle is not departed from, some improvements and modifications can also be made,
These improvements and modifications also should be regarded as the protection domain of the application.
Claims (9)
1. a kind of magnesium oxysulfide concrete concrete material, it is characterised in that including following components by weight：
90~110 parts of light burnt powder；
100~300 parts of sand；
100~500 parts of rubble；
1~3 part of additive；
Baume degrees is 25~30 100~200 parts of Adlerika；
Wherein, the additive is the weight of the mixing material of phosphate and flyash, phosphate and flyash
Than being 1：2.5~3.5.
2. magnesium oxysulfide concrete concrete material according to claim 1, it is characterised in that the sulfuric acid
The number of magnesium solution is 140~180 parts.
3. magnesium oxysulfide concrete concrete material according to claim 1, it is characterised in that described additional
The number of agent is 2 parts.
4. magnesium oxysulfide concrete concrete material according to claim 1, it is characterised in that the rubble
Number be 300~400 parts.
5. magnesium oxysulfide concrete concrete material according to claim 1, it is characterised in that the rubble
Particle diameter be 1~3cm.
6. magnesium oxysulfide concrete concrete material according to claim 1, it is characterised in that described additional
In agent, phosphate is 1 with the weight ratio of flyash：3.
7. according to any described magnesium oxysulfide concrete concrete materials of claim 1-6, it is characterised in that institute
Phosphate is stated for one or more in ammonium dihydrogen phosphate, calcium dihydrogen phosphate and sodium dihydrogen phosphate.
8. the preparation method of a kind of magnesium oxysulfide concrete concrete material as described in claim 1-7 is any, its
It is characterised by, the method comprising the steps of：
S101, by the light burnt powder, sand, rubble and additive according to the components by weight percent stir mix；
S102, by magnesium sulfate solid dissolving in water, formed Adlerika；
S103, Adlerika is added in the mixing material that step S101 is obtained, is uniformly mixed,
Obtain magnesium oxysulfide concrete concrete material.
9. the preparation method of magnesium oxysulfide concrete concrete material according to claim 8, it is characterised in that
The method also includes the step of preparing the additive：The phosphate is mixed with flyash first, is added
Water remixes to form slurry；Then will be milled after the slurry drying, obtain the additive.
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113772978A (en) * | 2021-10-20 | 2021-12-10 | 辽宁科技大学 | Method for preparing composite magnesium oxysulfate cement capable of being constructed in winter by using desulfurization solution |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN87103530A (en) * | 1987-05-12 | 1987-11-25 | 中国科学院青海盐湖研究所 | Anticorrosive magnesia cement |
| KR101014868B1 (en) * | 2009-11-26 | 2011-02-15 | 전남대학교산학협력단 | Alkali-activated binder including magnesium with no cement, mortar, concrete, and concrete products using the same |
| CN102060490A (en) * | 2010-11-22 | 2011-05-18 | 中国科学院青海盐湖研究所 | Unburned and non-autoclaved caustic calcined dolomite brick and building block |
| CN102924038A (en) * | 2012-12-04 | 2013-02-13 | 中国科学院青海盐湖研究所 | Modified magnesium oxy-sulfur cement |
| CN104529377A (en) * | 2014-12-03 | 2015-04-22 | 中国科学院青海盐湖研究所 | Water-resistant magnesium oxychloride cement, preparation method and application thereof |
-
2015
- 2015-11-30 CN CN201510859737.3A patent/CN106747231A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN87103530A (en) * | 1987-05-12 | 1987-11-25 | 中国科学院青海盐湖研究所 | Anticorrosive magnesia cement |
| KR101014868B1 (en) * | 2009-11-26 | 2011-02-15 | 전남대학교산학협력단 | Alkali-activated binder including magnesium with no cement, mortar, concrete, and concrete products using the same |
| CN102060490A (en) * | 2010-11-22 | 2011-05-18 | 中国科学院青海盐湖研究所 | Unburned and non-autoclaved caustic calcined dolomite brick and building block |
| CN102924038A (en) * | 2012-12-04 | 2013-02-13 | 中国科学院青海盐湖研究所 | Modified magnesium oxy-sulfur cement |
| CN104529377A (en) * | 2014-12-03 | 2015-04-22 | 中国科学院青海盐湖研究所 | Water-resistant magnesium oxychloride cement, preparation method and application thereof |
Non-Patent Citations (1)
| Title |
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| 陈雅福: "《建筑材料》", 28 February 1998, 华南理工大学出版社 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113772978A (en) * | 2021-10-20 | 2021-12-10 | 辽宁科技大学 | Method for preparing composite magnesium oxysulfate cement capable of being constructed in winter by using desulfurization solution |
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Application publication date: 20170531 |